Chlorine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Chlorine anion + Water = (Chlorine anion • Water)

By formula: Cl- + H2O = (Cl- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr60. ± 20.kJ/molAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Δr81. ± 10.J/mol*KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr40. ± 20.kJ/molAVGN/AAverage of 9 values; Individual data points

Chlorine anion + Methyl Alcohol = (Chlorine anion • Methyl Alcohol)

By formula: Cl- + CH4O = (Cl- • CH4O)

Quantity Value Units Method Reference Comment
Δr69. ± 10.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr101.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr92.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr95.8J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr61.9J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr42. ± 3.kJ/molAVGN/AAverage of 10 values; Individual data points

Chlorine anion + Hydrogen chloride = (Chlorine anion • Hydrogen chloride)

By formula: Cl- + HCl = (Cl- • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr124. ± 4.2kJ/molN/AMetz, Kitsopoulos, et al., 1988gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Δr99.6 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Δr96.7 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr99.16 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Δr85.4kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl-)SO2; M
Δr98.3J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Δr98.3J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr95.4J/mol*KN/AUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M
Quantity Value Units Method Reference Comment
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1987gas phase; K = 0.60 for HCl..Cl- + DCL <=> DCl..Cl- + HCl, anchored to Larson and McMahon, 1984, 32; B
Δr72. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B
Δr66.9 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr69.9 ± 1.3kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B
Δr56.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M

Chlorine anion + Sulfur dioxide = (Chlorine anion • Sulfur dioxide)

By formula: Cl- + O2S = (Cl- • O2S)

Quantity Value Units Method Reference Comment
Δr92.9 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Δr87.4 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr92.9 ± 9.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..Cl- in Keesee, Lee, et al., 1980; B,M
Δr91.21 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Δr87.4kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Δr101.J/mol*KN/ABohringer, Fahey, et al., 1984gas phase; switching reaction(Cl-)H2O), Entropy change calculated or estimated; Keesee and Castleman, 1980; M
Δr87.0J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr97.1J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr65.7 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B
Δr61.5 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr62.8 ± 6.7kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..Cl- in Keesee, Lee, et al., 1980; B,M
Δr61.9 ± 1.3kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B
Δr61.5kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
59.4296.FAFehsenfeld and Ferguson, 1974gas phase; switching reaction(Cl-)H2O; M

Chlorine anion + Benzene = (Chlorine anion • Benzene)

By formula: Cl- + C6H6 = (Cl- • C6H6)

Quantity Value Units Method Reference Comment
Δr25.1 ± 1.9kJ/molN/ATschurl, Ueberfluss, et al., 2007gas phase; B
Δr39. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr41.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr36.kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr43.5kJ/molPHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr71.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr71.5J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr92.J/mol*KN/ASunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr17. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr16. ± 6.7kJ/molIMREChowdhury and Kebarle, 1986gas phase; B
Δr20. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr15.9kJ/molIMREFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
16.300.PHPMSChowdhury and Kebarle, 1986gas phase; M
16.300.PHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

(Chlorine anion • 2Water) + Water = (Chlorine anion • 3Water)

By formula: (Cl- • 2H2O) + H2O = (Cl- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr93.7J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr97.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr21. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Chlorine anion + Acetonitrile = (Chlorine anion • Acetonitrile)

By formula: Cl- + C2H3N = (Cl- • C2H3N)

Quantity Value Units Method Reference Comment
Δr61. ± 10.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr65.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr65.7J/mol*KPHPMSYamabe, Furumiya, et al., 1986gas phase; M
Δr59.8J/mol*KPHPMSSieck, 1985gas phase; M
Δr59.8J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Δr89.5J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr42.68 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr38. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr37. ± 11.kJ/molTDAsYamabe, Furumiya, et al., 1986gas phase; B
Δr42.26 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Δr38. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion • Water) + Water = (Chlorine anion • 2Water)

By formula: (Cl- • H2O) + H2O = (Cl- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr53. ± 5.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr85.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr87.0J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr27.2kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr27. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr27.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr28.kJ/molFAFehsenfeld and Ferguson, 1974gas phase; M

Chlorine anion + 2-Propanol, 2-methyl- = (Chlorine anion • 2-Propanol, 2-methyl-)

By formula: Cl- + C4H10O = (Cl- • C4H10O)

Quantity Value Units Method Reference Comment
Δr77. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr115.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr100.J/mol*KPHPMSSieck, 1985gas phase; M
Δr97.9J/mol*KN/ALarson and McMahon, 1984gas phase; Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr110.J/mol*KPHPMSKebarle, 1977gas phase; M
Δr43.1J/mol*KN/AYamdagni and Kebarle, 1971gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr48.45kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr51.5 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr48.53kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr46.4 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr46.4 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Chlorine anion + Benzonitrile, 4-hydroxy- = (Chlorine anion • Benzonitrile, 4-hydroxy-)

By formula: Cl- + C7H5NO = (Cl- • C7H5NO)

Quantity Value Units Method Reference Comment
Δr147. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M,M
Δr148.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr120.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr110.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr114. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
103.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
110.300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
108.300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Acetone = (Chlorine anion • Acetone)

By formula: Cl- + C3H6O = (Cl- • C3H6O)

Quantity Value Units Method Reference Comment
Δr56. ± 6.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSSieck, 1985gas phase; M
Δr82.0J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr71.5J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr82.4J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr33.8 ± 0.84kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr30.5kJ/molTDAsHiraoka, Morise, et al., 1986gas phase; B
Δr36.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr34. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr33. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + Trichloromethane = (Chlorine anion • Trichloromethane)

By formula: Cl- + CHCl3 = (Cl- • CHCl3)

Quantity Value Units Method Reference Comment
Δr63.6 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Δr81.6 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr75.73kJ/molMoblGiles and Grimsrud, 1993gas phase; B
Δr75.7 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr79.9 ± 2.9kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KN/ALarson and McMahon, 1984, 2gas phase; From thermochemical cycle(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Δr103.J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Δr61.9J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr47. ± 5.kJ/molAVGN/AAverage of 6 values; Individual data points

Chlorine anion + Phenol = (Chlorine anion • Phenol)

By formula: Cl- + C6H6O = (Cl- • C6H6O)

Quantity Value Units Method Reference Comment
Δr109. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Δr109. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Δr115.kJ/molPHPMSKebarle, 1977gas phase; M
Δr111.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr81.2 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr100.J/mol*KPHPMSKebarle, 1977gas phase; M
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr64.9J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3 ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Δr77.4 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Δr61.9 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
66.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Chlorine anion + Benzene, chloro- = (Chlorine anion • Benzene, chloro-)

By formula: Cl- + C6H5Cl = (Cl- • C6H5Cl)

Quantity Value Units Method Reference Comment
Δr50.21 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Δr56.9 ± 4.2kJ/molIMRELarson and McMahon, 1984gas phase; B,B,M
Δr52.7kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr69.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr93.7J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr29.7 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Δr29. ± 4.2kJ/molIMRELarson and McMahon, 1984gas phase; B,B,M
Δr27.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
27.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

(Chlorine anion • 3Water) + Water = (Chlorine anion • 4Water)

By formula: (Cl- • 3H2O) + H2O = (Cl- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr40.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr44. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr45.6 ± 2.9kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Δr46.4 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr104.J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr108.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr16. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr14.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr14.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr17. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Chlorine anion + Chloromethane = (Chlorine anion • Chloromethane)

By formula: Cl- + CH3Cl = (Cl- • CH3Cl)

Quantity Value Units Method Reference Comment
Δr43.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr49.0 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr51.0 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr36.0 ± 0.84kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Δr63.6 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B
Quantity Value Units Method Reference Comment
Δr85.8J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr64.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr24.3 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr20.3kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr26. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr17.2 ± 2.1kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B
Δr45.2 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Chlorine anion + Formic acid = (Chlorine anion • Formic acid)

By formula: Cl- + CH2O2 = (Cl- • CH2O2)

Quantity Value Units Method Reference Comment
Δr115. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Δr116. ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; B
Δr107. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr156. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B,M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr101.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr166.J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr84.1 ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Δr77.0 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr106. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B

Chlorine anion + Phenol, 4-chloro- = (Chlorine anion • Phenol, 4-chloro-)

By formula: Cl- + C6H5ClO = (Cl- • C6H5ClO)

Quantity Value Units Method Reference Comment
Δr124. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr126.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr110.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr92.5 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
81.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
87.9300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Phenol, 4-fluoro- = (Chlorine anion • Phenol, 4-fluoro-)

By formula: Cl- + C6H5FO = (Cl- • C6H5FO)

Quantity Value Units Method Reference Comment
Δr117. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr120.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr106.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr86.2 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
75.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
80.8300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Ethanol = (Chlorine anion • Ethanol)

By formula: Cl- + C2H6O = (Cl- • C2H6O)

Quantity Value Units Method Reference Comment
Δr74.9 ± 1.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr73.6 ± 2.1kJ/molTDAsHiraoka, 1987gas phase; B,B,M
Δr72.4 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr99.2J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr96.7J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr44.56kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr43.9 ± 8.4kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr43.9 ± 8.4kJ/molTDAsHiraoka, 1987gas phase; B
Δr43.5 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8295.ICRRiveros, 1974gas phase; switching reaction(Cl-)CH3OH; Riveros, Breda, et al., 1973; M

(Chlorine anion • Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 2Methyl Alcohol)

By formula: (Cl- • CH4O) + CH4O = (Cl- • 2CH4O)

Quantity Value Units Method Reference Comment
Δr59.0 ± 1.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr57.32 ± 0.84kJ/molTDAsEvans and Keesee, 1991gas phase; B,M
Δr59.0 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr54.4 ± 2.9kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr92.0J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr81.2J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr30.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr29.7kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr30.1 ± 1.7kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 2Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 3Methyl Alcohol)

By formula: (Cl- • 2CH4O) + CH4O = (Cl- • 3CH4O)

Quantity Value Units Method Reference Comment
Δr48.12 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr45.2 ± 1.3kJ/molTDAsEvans and Keesee, 1991gas phase; B,M
Δr49.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr51.5 ± 2.5kJ/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr95.0J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr98.7J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr21.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr16.7kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr21. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr21.8 ± 1.3kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

Chlorine anion + Benzene, nitro- = (Chlorine anion • Benzene, nitro-)

By formula: Cl- + C6H5NO2 = (Cl- • C6H5NO2)

Quantity Value Units Method Reference Comment
Δr68.2 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Δr69.0kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr81.2J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr43.9 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B
Δr29.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
43.9300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
32.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Borane, triethyl- = (Chlorine anion • Borane, triethyl-)

By formula: Cl- + C6H15B = (Cl- • C6H15B)

Quantity Value Units Method Reference Comment
Δr99.6 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr99.6kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Δr92.0J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr72.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr72.0kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Hydrogen cation = Hydrogen chloride

By formula: Cl- + H+ = HCl

Quantity Value Units Method Reference Comment
Δr1394.9kJ/molN/AMartin and Hepburn, 1998gas phase; Given: ΔHacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol; B
Δr1396. ± 8.8kJ/molG+TSFujio, McIver, et al., 1981gas phase; value altered from reference due to change in acidity scale; B
Δr1377.0kJ/molN/ACheck, Faust, et al., 2001gas phase; FeCC-(q); ; ΔS(EA)=5.0; B
Quantity Value Units Method Reference Comment
Δr1372.8 ± 0.42kJ/molH-TSMartin and Hepburn, 1998gas phase; Given: ΔHacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol; B
Δr1374. ± 8.4kJ/molIMREFujio, McIver, et al., 1981gas phase; value altered from reference due to change in acidity scale; B
Δr1354.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeCC-(q); ; ΔS(EA)=5.0; B

Chlorine anion + Acetic acid = (Chlorine anion • Acetic acid)

By formula: Cl- + C2H4O2 = (Cl- • C2H4O2)

Quantity Value Units Method Reference Comment
Δr102.1 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Δr90.4 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Δr100. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr100.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr80.8J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr77.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr66.1 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B
Δr69.9 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Chlorine anion + Ammonia = (Chlorine anion • Ammonia)

By formula: Cl- + H3N = (Cl- • H3N)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr<30.5 ± 1.7kJ/molN/ATschurl and Boesl, 2008gas phase; B
Δr34.3 ± 0.42kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B,M
Δr37. ± 5.0kJ/molN/AMarkovich, Chesnovsky, et al., 1993gas phase; B
Δr44. ± 17.kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr64.4J/mol*KHPMSEvans, Keesee, et al., 1987gas phase; M
Δr83.3J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)CH3F, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr15.1 ± 0.84kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B
Δr19. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Chlorine anion + p-Cresol = (Chlorine anion • p-Cresol)

By formula: Cl- + C7H8O = (Cl- • C7H8O)

Quantity Value Units Method Reference Comment
Δr107. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr108.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr112.J/mol*KPHPMSCummings, French, et al., 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
64.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
69.5300.PHPMSCummings, French, et al., 1977gas phase; M

Chlorine anion + Isopropyl Alcohol = (Chlorine anion • Isopropyl Alcohol)

By formula: Cl- + C3H8O = (Cl- • C3H8O)

Quantity Value Units Method Reference Comment
Δr81.17 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr76.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr97.1J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr47.36kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr45.61kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

(Chlorine anion • 6Water) + Water = (Chlorine anion • 7Water)

By formula: (Cl- • 6H2O) + H2O = (Cl- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B
Δr28.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr34.kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AHiraoka, Mizuse, et al., 1988, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr8.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + Methylene chloride = (Chlorine anion • Methylene chloride)

By formula: Cl- + CH2Cl2 = (Cl- • CH2Cl2)

Quantity Value Units Method Reference Comment
Δr66.1 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr61.9 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr64.9 ± 1.3kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.5J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M
Δr92.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr38. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr37.0kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr37.2 ± 2.5kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B

Chlorine anion + Phosphorus trifluoride = (Chlorine anion • Phosphorus trifluoride)

By formula: Cl- + F3P = (Cl- • F3P)

Quantity Value Units Method Reference Comment
Δr64.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr64.9kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr38. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr38.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + 1-Propanol = (Chlorine anion • 1-Propanol)

By formula: Cl- + C3H8O = (Cl- • C3H8O)

Quantity Value Units Method Reference Comment
Δr85.4 ± 2.1kJ/molTDAsHiraoka, 1987gas phase; B,B,M
Δr74.1 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr121.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr97.1J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr48.95kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr49.0 ± 8.4kJ/molTDAsHiraoka, 1987gas phase; B
Δr45.2 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Chlorine anion + Hydrogen cyanide = (Chlorine anion • Hydrogen cyanide)

By formula: Cl- + CHN = (Cl- • CHN)

Quantity Value Units Method Reference Comment
Δr91.2 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,B,M
Δr87.9 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr79.1J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr99.2J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr67.8 ± 6.7kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B
Δr67.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Δr58.2 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Chlorine anion + Carbon dioxide = (Chlorine anion • Carbon dioxide)

By formula: Cl- + CO2 = (Cl- • CO2)

Quantity Value Units Method Reference Comment
Δr28.5 ± 2.1kJ/molPDisArnold, Bradforth, et al., 1995gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Δr31.8kJ/molTDEqHiraoka, Shoda, et al., 1986gas phase; B,M
Δr33.5 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Δr82.0J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr8.79kJ/molTDEqHiraoka, Shoda, et al., 1986gas phase; B
Δr8.79 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Chlorine anion • 3Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 4Methyl Alcohol)

By formula: (Cl- • 3CH4O) + CH4O = (Cl- • 4CH4O)

Quantity Value Units Method Reference Comment
Δr43.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr43.93kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr46.9 ± 2.5kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr110.J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr15. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr15.5kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr13.8 ± 0.84kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 4Water) + Water = (Chlorine anion • 5Water)

By formula: (Cl- • 4H2O) + H2O = (Cl- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr40. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr28.0kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr40. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr13. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr12. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Chlorine anion + 2-Propanone, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion • 2-Propanone, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3F6O = (Cl- • C3F6O)

Quantity Value Units Method Reference Comment
Δr120. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr95.8 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr73.6 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr68.2kJ/molICRLarson and McMahon, 1984, 3gas phase; switching reaction(Cl-)(C2H5)3B; M

(Chlorine anion • 3Acetonitrile) + Acetonitrile = (Chlorine anion • 4Acetonitrile)

By formula: (Cl- • 3C2H3N) + C2H3N = (Cl- • 4C2H3N)

Quantity Value Units Method Reference Comment
Δr45.6 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Δr37.7 ± 3.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr25.9kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr111.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr45.2J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr12. ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr12.6kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Chlorine anion + 2-Propanone, 1,1,1,3,3-pentafluoro- = (Chlorine anion • 2-Propanone, 1,1,1,3,3-pentafluoro-)

By formula: Cl- + C3HF5O = (Cl- • C3HF5O)

Quantity Value Units Method Reference Comment
Δr109. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr97.9kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr72.0 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M,M

Chlorine anion + 2-Propanol, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion • 2-Propanol, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3H2F6O = (Cl- • C3H2F6O)

Quantity Value Units Method Reference Comment
Δr111.kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr79.5kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M

(Chlorine anion • 2Acetonitrile) + Acetonitrile = (Chlorine anion • 3Acetonitrile)

By formula: (Cl- • 2C2H3N) + C2H3N = (Cl- • 3C2H3N)

Quantity Value Units Method Reference Comment
Δr46.9 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Δr50.2 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr44.35kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr84.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr22. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr19.2kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Chlorine anion + Carbon disulfide = (Chlorine anion • Carbon disulfide)

By formula: Cl- + CS2 = (Cl- • CS2)

Quantity Value Units Method Reference Comment
Δr36.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Δr49.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr58.2J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Δr84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr19. ± 9.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Δr24. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

(Chlorine anion • Acetonitrile) + Acetonitrile = (Chlorine anion • 2Acetonitrile)

By formula: (Cl- • C2H3N) + C2H3N = (Cl- • 2C2H3N)

Quantity Value Units Method Reference Comment
Δr52.3 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Δr50.2 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr51.04kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr68.2J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr79.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr32. ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr27.6kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Chlorine anion + C4H4F6O = (Chlorine anion • C4H4F6O)

By formula: Cl- + C4H4F6O = (Cl- • C4H4F6O)

Quantity Value Units Method Reference Comment
Δr111.kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr79.5kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M

(Chlorine anion • 5Water) + Water = (Chlorine anion • 6Water)

By formula: (Cl- • 5H2O) + H2O = (Cl- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr35.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr37. ± 2.kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr10. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

Chlorine anion + Methane, bromo- = (Chlorine anion • Methane, bromo-)

By formula: Cl- + CH3Br = (Cl- • CH3Br)

Quantity Value Units Method Reference Comment
Δr52.3 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr45.6 ± 2.1kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Δr51. ± 13.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Δr53.6J/mol*KHPMSDougherty and Roberts, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr28.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr30. ± 5.0kJ/molTDAsDougherty and Roberts, 1974gas phase; B

(Chlorine anion • Hydrogen chloride) + Hydrogen chloride = (Chlorine anion • 2Hydrogen chloride)

By formula: (Cl- • HCl) + HCl = (Cl- • 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.60 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Δr58.6kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Δr102.J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr33.1 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B

Chlorine anion + Cl4Th = (Chlorine anion • Cl4Th)

By formula: Cl- + Cl4Th = (Cl- • Cl4Th)

Quantity Value Units Method Reference Comment
Δr101.kJ/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr73.6kJ/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M

Chlorine anion + C2H3ClO2 = (Chlorine anion • C2H3ClO2)

By formula: Cl- + C2H3ClO2 = (Cl- • C2H3ClO2)

Quantity Value Units Method Reference Comment
Δr59.0kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr33.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Evans and Keesee, 1991
Evans, D.H.; Keesee, R.G., Thermodynamics of Gas-Phase Mixed-Solvent Cluster Ions - Water and Methanol on K+ and Cl- and Comparison to Liquid Solutions, J. Phys. Chem., 1991, 95, 9, 3558, https://doi.org/10.1021/j100162a024 . [all data]

Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S., Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH, Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4 . [all data]

Sieck, 1985
Sieck, L.W., Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure., J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049 . [all data]

Larson and McMahon, 1984
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French, Ikuta, et al., 1982
French, M.A.; Ikuta, S.; Kebarle, P., Hydrogen bonding of O-H and C-H hydrogen donors to Cl-. Results from mass spectrometric measurement of the ion-molecule equilibria RH + Cl- = RHCl-, Can. J. Chem., 1982, 60, 1907. [all data]

Yamdagni, Payzant, et al., 1973
Yamdagni, R.; Payzant, J.D.; Kebarle, P., Solvation of Cl- and O2- with H2O, CH3OH, and CH3CN in the gas phase, Can. J. Chem., 1973, 51, 2507. [all data]

Metz, Kitsopoulos, et al., 1988
Metz, R.B.; Kitsopoulos, T.; Weaver, A.; Neumark, D.M., Study of the Transition State Region in the Cl+HCl Reaction by Photoelectron Spectroscopy of ClHCl-, J. Chem. Phys., 1988, 88, 2, 1463, https://doi.org/10.1063/1.454218 . [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Larson and McMahon, 1984, 2
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Larson, J.W.; McMahon, T.B., Isotope Effects in Proton Transfer Reactions. An Ion Cyclotron Resonance Determination of the Equilibrium Deuterium Isotope Effect in the Bichloride Ion, J. Phys. Chem., 1987, 91, 3, 554, https://doi.org/10.1021/j100287a013 . [all data]

Larson and McMahon, 1984, 3
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Bohringer, Fahey, et al., 1984
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Fehsenfeld and Ferguson, 1974
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Sunner, Nishizawa, et al., 1981
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Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Hiraoka, Mizuse, et al., 1988, 2
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

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Yamdagni, R.; Kebarle, P., Solvation of negative ions by protic and aprotic solvents. Gas phase solvation of halide ions by acetonitrile and water molecules, J. Am. Chem. Soc., 1972, 94, 2940. [all data]

Li, Ross, et al., 1996
Li, C.; Ross, P.; Szulejko, J.; McMahon, T.B., High-Pressure Mass Spectrometric Investigations of the Potential Energy Surfaces of Gas-Phase Sn2 Reactions., J. Am. Chem. Soc., 1996, 118, 39, 9360, https://doi.org/10.1021/ja960565o . [all data]

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Kebarle, 1977
Kebarle, P., Ion Thermochemistry and Solvation from Gas Phase Ion Equilibria, Ann. Rev. Phys. Chem., 1977, 28, 1, 445, https://doi.org/10.1146/annurev.pc.28.100177.002305 . [all data]

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Cummings, French, et al., 1977
Cummings, J.B.; French, M.A.; Kebarle, P., Effect of charge delocalization on hydrogen bonding to negative ions and solvation of negative ions. Substituted phenols and phenoxide ions, J. Am. Chem. Soc., 1977, 99, 6999. [all data]

Paul and Kebarle, 1990
Paul, G.J.C.; Kebarle, P., Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-), Can. J. Chem., 1990, 68, 11, 2070, https://doi.org/10.1139/v90-316 . [all data]

Hiraoka, Takimoto, et al., 1986
Hiraoka, K.; Takimoto, H.; Morise, K.; Shoda, T.; Nakamura, S., Ion-Molecule Reactions in Gaseous Acetone, Bull. Chem. Soc. Japan, 1986, 59, 7, 2247, https://doi.org/10.1246/bcsj.59.2247 . [all data]

Bofdanov and McMahon, 2002
Bofdanov, B.; McMahon, T.B., Structures, Thermochemistry, and Infrared Spectra of Chloride Ion-Fluorinated Acetone Complexes and Neutral Fluorinated Acetones in the Gas Phase: Experiment and Theory, Int. J. Mass Spectrom., 2002, 219, 3, 593-613, https://doi.org/10.1016/S1387-3806(02)00745-5 . [all data]

Hiraoka, Morise, et al., 1986
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Hiraoka, Mizuno, et al., 2001
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Giles and Grimsrud, 1993
Giles, K.; Grimsrud, E.P., Measurements of Equilibria and Reactivity of Cluster Ions at Atmospheric Pressure - Reactions of Cl-(CHCl3)0-2 with CH3Br and CH3I, J. Phys. Chem., 1993, 97, 7, 1318, https://doi.org/10.1021/j100109a012 . [all data]

Dougherty, Dalton, et al., 1974
Dougherty, R.C.; Dalton, J.; Roberts, J.D., SN2 reactions in the gas phase: Structure of the transition state, Org. Mass Spectrom., 1974, 8, 77. [all data]

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J., Hydration of Negative Ions in the Gas Phase, J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145 . [all data]

Walker and Sunderlin, 1999
Walker, B.W.; Sunderlin, L.S., The thermochemistry of formic acid halide anion clusters, Int. J. Mass Spectrom., 1999, 184, 2-3, 183-189, https://doi.org/10.1016/S1387-3806(99)00008-1 . [all data]

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Hiraoka, K., Relation Between Gas Phase Stepwise and Bulk Solvation of Cl- with Water and Aliphatic Alcohols, Bull. Chem. Soc. Japan, 1987, 60, 7, 2555, https://doi.org/10.1246/bcsj.60.2555 . [all data]

Riveros, 1974
Riveros, J.M., Formation and Relative Stability of Negative Clustered Ions by Ion Cyclotron Resonance Spectroscopy, Adv. Mass Spectrom., 1974, 6, 277. [all data]

Riveros, Breda, et al., 1973
Riveros, J.M.; Breda, A.C.; Blair, L.K., Formation and relative stability of chloride ion clusters in the gas phase by ICR spectroscopy, J. Am. Chem. Soc., 1973, 95, 4066. [all data]

Martin and Hepburn, 1998
Martin, J.D.D.; Hepburn, J.W., Determination of bond dissociation energies by threshold ion-pair production spectroscopy: An improved D-0(HCl), J. Chem. Phys., 1998, 109, 19, 8139-8142, https://doi.org/10.1063/1.477476 . [all data]

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Fujio, M.; McIver, R.T., Jr.; Taft, R.W., Effects on the acidities of phenols from specific substituent-solvent interactions. Inherent substituent parameters from gas phase acidities, J. Am. Chem. Soc., 1981, 103, 4017. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

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Evans, D.H.; Keesee, R.G.; Castleman Jr., The Association of Ammonia with Halide Ions in the Gas Phase, J. Chem. Phys., 1987, 86, 5, 2927, https://doi.org/10.1063/1.452043 . [all data]

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Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 6. Interaction Energies of the Acetate Ion with Organic Molecules. Comparison of CH3COO- with Cl-, CN-, and SH-, J. Am. Chem. Soc., 1988, 110, 12, 3854, https://doi.org/10.1021/ja00220a022 . [all data]

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Arnold, D.W.; Bradforth, S.E.; Kim, E.H.; Neumark, D.M., Study of halogen carbon dioxide clusters and the fluoroformyloxyl radical by photodetachment of X(-)(CO2) (X=I,Cl,Br) and FCO2-, J. Chem. Phys., 1995, 102, 9, 3493, https://doi.org/10.1063/1.468575 . [all data]

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Markovich, Perera, et al., 1996
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Dougherty and Roberts, 1974
Dougherty, R.C.; Roberts, J.D., SN2 reactions in the gas phase. Nucleophilicity effects, Org. Mass Spectrom., 1974, 8, 81. [all data]

Keesee and Castleman, 1986
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Notes

Go To: Top, Reaction thermochemistry data, References