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Chlorine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 251 to 300

Chlorine anion + Toluene = (Chlorine anion bullet Toluene)

By formula: Cl- + C7H8 = (Cl- bullet C7H8)

Quantity Value Units Method Reference Comment
Deltar16.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
17.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, fluoro- = (Chlorine anion bullet Benzene, fluoro-)

By formula: Cl- + C6H5F = (Cl- bullet C6H5F)

Quantity Value Units Method Reference Comment
Deltar24.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Triphenylmethane = (Chlorine anion bullet Triphenylmethane)

By formula: Cl- + C19H16 = (Cl- bullet C19H16)

Quantity Value Units Method Reference Comment
Deltar17.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
17.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, iodo- = (Chlorine anion bullet Benzene, iodo-)

By formula: Cl- + C6H5I = (Cl- bullet C6H5I)

Quantity Value Units Method Reference Comment
Deltar30.1kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

(Chlorine anion bullet Benzene, hexafluoro-) + Benzene, hexafluoro- = (Chlorine anion bullet 2Benzene, hexafluoro-)

By formula: (Cl- bullet C6F6) + C6F6 = (Cl- bullet 2C6F6)

Quantity Value Units Method Reference Comment
Deltar57.7kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Mizuse, et al., 1987gas phase; M

Chlorine anion + sulphur trioxide = (Chlorine anion bullet sulphur trioxide)

By formula: Cl- + O3S = (Cl- bullet O3S)

Quantity Value Units Method Reference Comment
Deltar225. ± 13.kJ/molCIDTHao, Gilbert, et al., 2006gas phase; 0K threshold 53.0 kcal/mol. scaled to 298K with B3LYP data.; B

Chlorine anion + Benzene, (1-methylethyl)- = (Chlorine anion bullet Benzene, (1-methylethyl)-)

By formula: Cl- + C9H12 = (Cl- bullet C9H12)

Quantity Value Units Method Reference Comment
Deltar23.0kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
21.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Acetophenone = (Chlorine anion bullet Acetophenone)

By formula: Cl- + C8H8O = (Cl- bullet C8H8O)

Quantity Value Units Method Reference Comment
Deltar39.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, 1-methyl-4-nitro- = (Chlorine anion bullet Benzene, 1-methyl-4-nitro-)

By formula: Cl- + C7H7NO2 = (Cl- bullet C7H7NO2)

Quantity Value Units Method Reference Comment
Deltar31.4kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
31.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

(Chlorine anion bullet 2Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 3Dimethyl Sulfoxide)

By formula: (Cl- bullet 2C2H6OS) + C2H6OS = (Cl- bullet 3C2H6OS)

Quantity Value Units Method Reference Comment
Deltar62.3kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet 3Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 4Dimethyl Sulfoxide)

By formula: (Cl- bullet 3C2H6OS) + C2H6OS = (Cl- bullet 4C2H6OS)

Quantity Value Units Method Reference Comment
Deltar61.1kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar156.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet 4Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 5Dimethyl Sulfoxide)

By formula: (Cl- bullet 4C2H6OS) + C2H6OS = (Cl- bullet 5C2H6OS)

Quantity Value Units Method Reference Comment
Deltar57.7kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar168.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion bullet Pyridine) + Pyridine = (Chlorine anion bullet 2Pyridine)

By formula: (Cl- bullet C5H5N) + C5H5N = (Cl- bullet 2C5H5N)

Quantity Value Units Method Reference Comment
Deltar49.0kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M

(Chlorine anion bullet Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion bullet 2Dimethyl Sulfoxide)

By formula: (Cl- bullet C2H6OS) + C2H6OS = (Cl- bullet 2C2H6OS)

Quantity Value Units Method Reference Comment
Deltar66.9kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

Chlorine anion + Nitrous oxide = (Chlorine anion bullet Nitrous oxide)

By formula: Cl- + N2O = (Cl- bullet N2O)

Quantity Value Units Method Reference Comment
Deltar24. ± 1.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar80.3J/mol*KPHPMSHiraoka, Aruga, et al., 1993gas phase; M

Chlorine anion + Methane = CH4Cl-

By formula: Cl- + CH4 = CH4Cl-

Quantity Value Units Method Reference Comment
Deltar15.9kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar-9.04kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

Chlorine anion + Cl3Er = Cl10Er3-

By formula: Cl- + Cl3Er = Cl10Er3-

Quantity Value Units Method Reference Comment
Deltar330. ± 59.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion = C6H14Cl-

By formula: Cl- = C6H14Cl-

Quantity Value Units Method Reference Comment
Deltar42.59kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.4kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C7H16Cl-

By formula: Cl- = C7H16Cl-

Quantity Value Units Method Reference Comment
Deltar44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar15.1kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C7H14Cl-

By formula: Cl- = C7H14Cl-

Quantity Value Units Method Reference Comment
Deltar44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar14.8kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C8H18Cl-

By formula: Cl- = C8H18Cl-

Quantity Value Units Method Reference Comment
Deltar49.12kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar18.7kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C8H16Cl-

By formula: Cl- = C8H16Cl-

Quantity Value Units Method Reference Comment
Deltar44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C5H12Cl-

By formula: Cl- = C5H12Cl-

Quantity Value Units Method Reference Comment
Deltar37.5kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.9kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C5H10Cl-

By formula: Cl- = C5H10Cl-

Quantity Value Units Method Reference Comment
Deltar35.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.9kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C6H12Cl-

By formula: Cl- = C6H12Cl-

Quantity Value Units Method Reference Comment
Deltar40.0kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Deltar12.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion + Chlorine = (Chlorine anion bullet Chlorine)

By formula: Cl- + Cl2 = (Cl- bullet Cl2)

Quantity Value Units Method Reference Comment
Deltar71.1kJ/molSAMSRobbiani and Franklin, 1979gas phase; based on Cl- + SO2Cl2 <--> Cl3- + SO2; National Bureau of Standards, 1968; M

(Chlorine anion bullet Cl3La) + Cl3La = (Chlorine anion bullet 2Cl3La)

By formula: (Cl- bullet Cl3La) + Cl3La = (Cl- bullet 2Cl3La)

Quantity Value Units Method Reference Comment
Deltar136. ± 15.kJ/molMSButman, Kudin, et al., 1987gas phase; Knudsen cell; M

(Chlorine anion bullet 11Acetonitrile) + Acetonitrile = (Chlorine anion bullet 12Acetonitrile)

By formula: (Cl- bullet 11C2H3N) + C2H3N = (Cl- bullet 12C2H3N)

Quantity Value Units Method Reference Comment
Deltar-2. ± 7.1kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 13Acetonitrile) + Acetonitrile = (Chlorine anion bullet 14Acetonitrile)

By formula: (Cl- bullet 13C2H3N) + C2H3N = (Cl- bullet 14C2H3N)

Quantity Value Units Method Reference Comment
Deltar-2. ± 7.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 10Acetonitrile) + Acetonitrile = (Chlorine anion bullet 11Acetonitrile)

By formula: (Cl- bullet 10C2H3N) + C2H3N = (Cl- bullet 11C2H3N)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 6.7kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 12Acetonitrile) + Acetonitrile = (Chlorine anion bullet 13Acetonitrile)

By formula: (Cl- bullet 12C2H3N) + C2H3N = (Cl- bullet 13C2H3N)

Quantity Value Units Method Reference Comment
Deltar4. ± 7.5kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion bullet 9Acetonitrile) + Acetonitrile = (Chlorine anion bullet 10Acetonitrile)

By formula: (Cl- bullet 9C2H3N) + C2H3N = (Cl- bullet 10C2H3N)

Quantity Value Units Method Reference Comment
Deltar8.8 ± 6.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

Chlorine anion + F6S- = (Chlorine anion bullet F6S-)

By formula: Cl- + F6S- = (Cl- bullet F6S-)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
7.5300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

(Chlorine anion bullet 8Acetonitrile) + Acetonitrile = (Chlorine anion bullet 9Acetonitrile)

By formula: (Cl- bullet 8C2H3N) + C2H3N = (Cl- bullet 9C2H3N)

Quantity Value Units Method Reference Comment
Deltar18. ± 5.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

Chlorine anion + 1,1,3,3-tetrafluoroacetone = (Chlorine anion bullet 1,1,3,3-tetrafluoroacetone)

By formula: Cl- + C3H2F4O = (Cl- bullet C3H2F4O)

Quantity Value Units Method Reference Comment
Deltar75.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Sulfur hexafluoride = (Chlorine anion bullet Sulfur hexafluoride)

By formula: Cl- + F6S = (Cl- bullet F6S)

Quantity Value Units Method Reference Comment
Deltar<7.53kJ/molIMRBChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzene, bromo- = (Chlorine anion bullet Benzene, bromo-)

By formula: Cl- + C6H5Br = (Cl- bullet C6H5Br)

Quantity Value Units Method Reference Comment
Deltar28.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B,M

Chlorine anion + 1,3-Pentadiene, (E)- = (Chlorine anion bullet 1,3-Pentadiene, (E)-)

By formula: Cl- + C5H8 = (Cl- bullet C5H8)

Quantity Value Units Method Reference Comment
Deltar15.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + CAS Reg. No. 10025-71-5 = Cl3Te-

By formula: Cl- + CAS Reg. No. 10025-71-5 = Cl3Te-

Quantity Value Units Method Reference Comment
Deltar170. ± 7.1kJ/molCIDTLobring, Hao, et al., 2003gas phase; B

Chlorine anion + Selenium dichloride = Cl3Se-

By formula: Cl- + Cl2Se = Cl3Se-

Quantity Value Units Method Reference Comment
Deltar133. ± 9.2kJ/molCIDTLobring, Hao, et al., 2003gas phase; B

Chlorine anion + CAS Reg. No. 193208-57-0 = Cl4FSn-

By formula: Cl- + CAS Reg. No. 193208-57-0 = Cl4FSn-

Quantity Value Units Method Reference Comment
Deltar251. ± 12.kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Methane, trifluoroiodo- = CClF3I-

By formula: Cl- + CF3I = CClF3I-

Quantity Value Units Method Reference Comment
Deltar98.74 ± 0.84kJ/molTDAsBogdanov and McMahon, 2006gas phase; B

Chlorine anion + Phosphorus oxychloride = Cl4OP-

By formula: Cl- + Cl3OP = Cl4OP-

Quantity Value Units Method Reference Comment
Deltar43.1 ± 5.0kJ/molCIDTCheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Germanium tetrachloride = Cl5Ge-

By formula: Cl- + Cl4Ge = Cl5Ge-

Quantity Value Units Method Reference Comment
Deltar141. ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Trichlorofluorosilane = Cl4FSi-

By formula: Cl- + Cl3FSi = Cl4FSi-

Quantity Value Units Method Reference Comment
Deltar115. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + CAS Reg. No. 24422-20-6 = Cl4FGe-

By formula: Cl- + CAS Reg. No. 24422-20-6 = Cl4FGe-

Quantity Value Units Method Reference Comment
Deltar167. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Thiophosphoryl chloride = Cl4PS-

By formula: Cl- + Cl3PS = Cl4PS-

Quantity Value Units Method Reference Comment
Deltar41.0 ± 4.0kJ/molCIDTCheck, Lobring, et al., 2003gas phase; B

Chlorine anion + 1,4-Pentadiene = (Chlorine anion bullet 1,4-Pentadiene)

By formula: Cl- + C5H8 = (Cl- bullet C5H8)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Stannane, chlorotrimethyl- = C3H9Cl2Sn-

By formula: Cl- + C3H9ClSn = C3H9Cl2Sn-

Quantity Value Units Method Reference Comment
Deltar131. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + CAS Reg. No. 152748-52-2 = Cl2FSi-

By formula: Cl- + CAS Reg. No. 152748-52-2 = Cl2FSi-

Quantity Value Units Method Reference Comment
Deltar205. ± 8.4kJ/molCIDTPoutsma, Schroeder, et al., 2004gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

French, Ikuta, et al., 1982
French, M.A.; Ikuta, S.; Kebarle, P., Hydrogen bonding of O-H and C-H hydrogen donors to Cl-. Results from mass spectrometric measurement of the ion-molecule equilibria RH + Cl- = RHCl-, Can. J. Chem., 1982, 60, 1907. [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., High Symmetric Structure of the Gas Phase Ion Cluster X-..C6F6 (X = Cl, Br, I), J. Phys. Chem., 1987, 91, 20, 5294, https://doi.org/10.1021/j100304a032 . [all data]

Hao, Gilbert, et al., 2006
Hao, C.; Gilbert, T.M.; Sunderlin, L.S., The Bond Dissociation Energies of SO3-X- (X = F, Cl, Br, and I), Can. J. Chem., 2006, 83, 11, 2013-2019, https://doi.org/10.1139/v05-216 . [all data]

Magnera, Caldwell, et al., 1984
Magnera, T.F.; Caldwell, G.; Sumner, J.; Ikuta, S.; Kebarle, P., Solvation of the halide anions in dimethyl sulfoxide. Factors involved in enhanced reactivity of negative ions in dipolar aprotic solvents, J. Am. Chem. Soc., 1984, 106, 6140. [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Determination of the Stabilities and Structures of X-(C6H6) Clusters (X = Cl, Br, and I), Chem. Phys. Lett., 1988, 147, 2-3, 174, https://doi.org/10.1016/0009-2614(88)85078-4 . [all data]

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S., Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes, J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n . [all data]

Pogrebnoi, Motalov, et al., 2002
Pogrebnoi, A.M.; Motalov, V.B.; Kuznetsov, A.Y.; Kudin, L.S.; Khasanshin, I.V., Molecular and ionic associates in the saturated vapor over erbium trichloride and the ErCl3-DyCl3 system, Russ. J. Inorg. Chem., 2002, 47, 96-100. [all data]

Ziegler, Gamble, et al., 2013
Ziegler, B.E.; Gamble, T.N.; Li, C.; McMahon, T.B., Weak Ion-Molecule Interactions in the Gas Phase: A High-Pressure Mass Spectrometry and Computational Study of Chloride-Alkane Interactions, J. Phys. Chem. A, 2013, 117, 28, 5785-5793, https://doi.org/10.1021/jp403422q . [all data]

Robbiani and Franklin, 1979
Robbiani, R.; Franklin, J.L., Negative ion-molecule reaction in sulfuryl halides, J. Am. Chem. Soc., 1979, 101, 3709. [all data]

National Bureau of Standards, 1968
National Bureau of Standards, US, Technical Note 270 - 3 in The NBS Tables of Chemical Thermodynamic Properties, 1968. [all data]

Butman, Kudin, et al., 1987
Butman, M.F.; Kudin, L.S.; Burdukovskaya, G.G.; Krasnov, K.S.; Bozhko, N.V., Mass Spectrometric Determination of the Enthalpy of Formation of the Gaseous Ions LaCl4- and La2Cl7-, Russ. J. Phys. Chem., 1987, 61, 1518. [all data]

Markovich, Perera, et al., 1996
Markovich, G.; Perera, L.; Berkowitz, M.L.; Cheshnovsky, O., The Solvation of Cl-, Br-, and I- in Acetonitrile Cluster: Photoelectron Spectroscopy and Molecular Dynamics Simulations., J. Chem. Phys., 1996, 105, 7, 2675, https://doi.org/10.1063/1.472131 . [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ion cyclotron resonance halide-exchange equilibria, J. Phys. Chem., 1984, 88, 1083. [all data]

Lobring, Hao, et al., 2003
Lobring, K.C.; Hao, C.T.; Forbes, J.K.; Ivanov, M.R.J.; Bachrach, S.M.; Sunderlin, L.S., Bond strengths in ChCl(3)(-) and ChOCl(3)(-) (Ch = S, Se, Te): Experiment and theory, J. Phys. Chem. A, 2003, 107, 50, 11153-11160, https://doi.org/10.1021/jp030388v . [all data]

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]

Bogdanov and McMahon, 2006
Bogdanov, B.; McMahon, T.B., Gas phase S(N)2 reactions of halide ions with trifluoromethyl halides: Front- and back-side attack vs. complex formation, J. Phys. Chem. A, 2006, 110, 4, 1350-1363, https://doi.org/10.1021/jp0541011 . [all data]

Check, Lobring, et al., 2003
Check, C.E.; Lobring, K.C.; Keating, P.R.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of hypervalent phosphorus-halogen bonds, J. Phys. Chem. A, 2003, 107, 42, 8961-8967, https://doi.org/10.1021/jp030287x . [all data]

Poutsma, Schroeder, et al., 2004
Poutsma, J.C.; Schroeder, O.E.; Squires, R.R., Experimental chloride ion affinities and theoretical predictions for the absolute heats of formation of SiCl2 and SiClF, Chem. Phys. Lett., 2004, 389, 4-6, 433-437, https://doi.org/10.1016/j.cplett.2004.03.137 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References