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Chlorine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 151 to 200

Chlorine anion + 1,1,1',1'-Tetrafluorodimethyl ether = (Chlorine anion bullet 1,1,1',1'-Tetrafluorodimethyl ether)

By formula: Cl- + C2H2F4O = (Cl- bullet C2H2F4O)

Quantity Value Units Method Reference Comment
Deltar118.0 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar78.7 ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Deltar71.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Pentafluorodimethyl ether = (Chlorine anion bullet Pentafluorodimethyl ether)

By formula: Cl- + C2HF5O = (Cl- bullet C2HF5O)

Quantity Value Units Method Reference Comment
Deltar73.2 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar47.3 ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Deltar50.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Silicon tetrachloride = (Chlorine anion bullet Silicon tetrachloride)

By formula: Cl- + Cl4Si = (Cl- bullet Cl4Si)

Quantity Value Units Method Reference Comment
Deltar105. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B
Deltar101. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar73.6 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B

(Chlorine anion bullet 7Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 8Hydrogen cyanide)

By formula: (Cl- bullet 7CHN) + CHN = (Cl- bullet 8CHN)

Quantity Value Units Method Reference Comment
Deltar34. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.1 ± 9.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet Acetone) + Acetone = (Chlorine anion bullet 2Acetone)

By formula: (Cl- bullet C3H6O) + C3H6O = (Cl- bullet 2C3H6O)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 4.2kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar23. ± 9.2kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; B

(Chlorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 3Carbon disulfide)

By formula: (Cl- bullet 2CS2) + CS2 = (Cl- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar30.1 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar3. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet 21-Propanol) + 1-Propanol = (Chlorine anion bullet 31-Propanol)

By formula: (Cl- bullet 2C3H8O) + C3H8O = (Cl- bullet 3C3H8O)

Quantity Value Units Method Reference Comment
Deltar59.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar20. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 3Ethanol) + Ethanol = (Chlorine anion bullet 4Ethanol)

By formula: (Cl- bullet 3C2H6O) + C2H6O = (Cl- bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar50.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar13. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 3Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 4Isopropyl Alcohol)

By formula: (Cl- bullet 3C3H8O) + C3H8O = (Cl- bullet 4C3H8O)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 31-Propanol) + 1-Propanol = (Chlorine anion bullet 41-Propanol)

By formula: (Cl- bullet 3C3H8O) + C3H8O = (Cl- bullet 4C3H8O)

Quantity Value Units Method Reference Comment
Deltar55.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar134.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar15. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 32-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 42-Propanol, 2-methyl-)

By formula: (Cl- bullet 3C4H10O) + C4H10O = (Cl- bullet 4C4H10O)

Quantity Value Units Method Reference Comment
Deltar53.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 4Ethanol) + Ethanol = (Chlorine anion bullet 5Ethanol)

By formula: (Cl- bullet 4C2H6O) + C2H6O = (Cl- bullet 5C2H6O)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar128.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 4Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 5Isopropyl Alcohol)

By formula: (Cl- bullet 4C3H8O) + C3H8O = (Cl- bullet 5C3H8O)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar128.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar10. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 41-Propanol) + 1-Propanol = (Chlorine anion bullet 51-Propanol)

By formula: (Cl- bullet 4C3H8O) + C3H8O = (Cl- bullet 5C3H8O)

Quantity Value Units Method Reference Comment
Deltar52.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar138.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar11. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 42-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion bullet 52-Propanol, 2-methyl-)

By formula: (Cl- bullet 4C4H10O) + C4H10O = (Cl- bullet 5C4H10O)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar135.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 5Ethanol) + Ethanol = (Chlorine anion bullet 6Ethanol)

By formula: (Cl- bullet 5C2H6O) + C2H6O = (Cl- bullet 6C2H6O)

Quantity Value Units Method Reference Comment
Deltar46.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 5Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 6Isopropyl Alcohol)

By formula: (Cl- bullet 5C3H8O) + C3H8O = (Cl- bullet 6C3H8O)

Quantity Value Units Method Reference Comment
Deltar47.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 51-Propanol) + 1-Propanol = (Chlorine anion bullet 61-Propanol)

By formula: (Cl- bullet 5C3H8O) + C3H8O = (Cl- bullet 6C3H8O)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion bullet 7Isopropyl Alcohol)

By formula: (Cl- bullet 6C3H8O) + C3H8O = (Cl- bullet 7C3H8O)

Quantity Value Units Method Reference Comment
Deltar46.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 61-Propanol) + 1-Propanol = (Chlorine anion bullet 71-Propanol)

By formula: (Cl- bullet 6C3H8O) + C3H8O = (Cl- bullet 7C3H8O)

Quantity Value Units Method Reference Comment
Deltar46.0 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar126.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 10Methyl Alcohol)

By formula: (Cl- bullet 9CH4O) + CH4O = (Cl- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar31. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.1J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 2Carbon disulfide)

By formula: (Cl- bullet CS2) + CS2 = (Cl- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar32.2 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar66.1J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar13. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 6Methyl Alcohol)

By formula: (Cl- bullet 5CH4O) + CH4O = (Cl- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.9J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Ethanol) + Ethanol = (Chlorine anion bullet 7Ethanol)

By formula: (Cl- bullet 6C2H6O) + C2H6O = (Cl- bullet 7C2H6O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 7Methyl Alcohol)

By formula: (Cl- bullet 6CH4O) + CH4O = (Cl- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar33. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.1J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Ethanol) + Ethanol = (Chlorine anion bullet 8Ethanol)

By formula: (Cl- bullet 7C2H6O) + C2H6O = (Cl- bullet 8C2H6O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 8Methyl Alcohol)

By formula: (Cl- bullet 7CH4O) + CH4O = (Cl- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 9Methyl Alcohol)

By formula: (Cl- bullet 8CH4O) + CH4O = (Cl- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar86.2J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 1-Propanol) + 1-Propanol = (Chlorine anion bullet 21-Propanol)

By formula: (Cl- bullet C3H8O) + C3H8O = (Cl- bullet 2C3H8O)

Quantity Value Units Method Reference Comment
Deltar66.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 2Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 3Hydrogen cyanide)

By formula: (Cl- bullet 2CHN) + CHN = (Cl- bullet 3CHN)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.1kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 3Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 4Hydrogen cyanide)

By formula: (Cl- bullet 3CHN) + CHN = (Cl- bullet 4CHN)

Quantity Value Units Method Reference Comment
Deltar46.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.9J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar17.6kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 2Hydrogen cyanide)

By formula: (Cl- bullet CHN) + CHN = (Cl- bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar74.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar46.44kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 4Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 5Hydrogen cyanide)

By formula: (Cl- bullet 4CHN) + CHN = (Cl- bullet 5CHN)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar10.5kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 5Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 6Hydrogen cyanide)

By formula: (Cl- bullet 5CHN) + CHN = (Cl- bullet 6CHN)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.28kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion bullet 6Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion bullet 7Hydrogen cyanide)

By formula: (Cl- bullet 6CHN) + CHN = (Cl- bullet 7CHN)

Quantity Value Units Method Reference Comment
Deltar33. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.18kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

Chlorine anion + Benzene, 1-fluoro-3-nitro- = (Chlorine anion bullet Benzene, 1-fluoro-3-nitro-)

By formula: Cl- + C6H4FNO2 = (Cl- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar78.2 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar51.5 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + p-Benzoquinone, 2,3,5,6-tetrafluoro- = (Chlorine anion bullet p-Benzoquinone, 2,3,5,6-tetrafluoro-)

By formula: Cl- + C6F4O2 = (Cl- bullet C6F4O2)

Quantity Value Units Method Reference Comment
Deltar113. ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzonitrile, 4-nitro- = (Chlorine anion bullet Benzonitrile, 4-nitro-)

By formula: Cl- + C7H4N2O2 = (Cl- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar83.7 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar58.6 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion bullet Aluminum chloride fluoride)

By formula: Cl- + AlClF2 = (Cl- bullet AlClF2)

Quantity Value Units Method Reference Comment
Deltar311. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100K. See also AlCl2F..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Benzene, 1-nitro-3-(trifluoromethyl)- = (Chlorine anion bullet Benzene, 1-nitro-3-(trifluoromethyl)-)

By formula: Cl- + C7H4F3NO2 = (Cl- bullet C7H4F3NO2)

Quantity Value Units Method Reference Comment
Deltar81.6 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.0 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion bullet Aluminum chloride fluoride)

By formula: Cl- + AlCl2F = (Cl- bullet AlCl2F)

Quantity Value Units Method Reference Comment
Deltar315. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiemnts at 800-1100K. See also AlCl3..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Pyridine = (Chlorine anion bullet Pyridine)

By formula: Cl- + C5H5N = (Cl- bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar53.1 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar28. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

Chlorine anion + Aluminum fluoride = (Chlorine anion bullet Aluminum fluoride)

By formula: Cl- + AlF3 = (Cl- bullet AlF3)

Quantity Value Units Method Reference Comment
Deltar311. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiment at 800-1100 K. See also AlClF2..F-; value altered from reference due to conversion from electron convention to ion convention; B

(Chlorine anion bullet 4Nitrous oxide) + Nitrous oxide = (Chlorine anion bullet 5Nitrous oxide)

By formula: (Cl- bullet 4N2O) + N2O = (Cl- bullet 5N2O)

Quantity Value Units Method Reference Comment
Deltar20.kJ/molPHPMSHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AHiraoka, Aruga, et al., 1993gas phase; Entropy change calculated or estimated; M

Chlorine anion + Dimethyl Sulfoxide = (Chlorine anion bullet Dimethyl Sulfoxide)

By formula: Cl- + C2H6OS = (Cl- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar77.82kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar52.30kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

Chlorine anion + Deuterium oxide = (Chlorine anion bullet Deuterium oxide)

By formula: Cl- + D2O = (Cl- bullet D2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.50 ± 0.84kJ/molIMRELarson and McMahon, 1988gas phase; Anchored to Keesee and Castleman, 19802: HOH..Cl- + DOD <=> DOD..Cl- + HOH, Keq=0.77; B

(Chlorine anion bullet Water bullet Methyl Alcohol) + Water = (Chlorine anion bullet 2Water bullet Methyl Alcohol)

By formula: (Cl- bullet H2O bullet CH4O) + H2O = (Cl- bullet 2H2O bullet CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.5kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar64.9J/mol*KHPMSEvans and Keesee, 1991gas phase; M

Chlorine anion + AlCl3 = (Chlorine anion bullet AlCl3)

By formula: Cl- + AlCl3 = (Cl- bullet AlCl3)

Quantity Value Units Method Reference Comment
Deltar321. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

(Chlorine anion bullet Methyl Alcohol) + Water = (Chlorine anion bullet Water bullet Methyl Alcohol)

By formula: (Cl- bullet CH4O) + H2O = (Cl- bullet H2O bullet CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar45.6kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar70.7J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion bullet 2Methyl Alcohol) + Water = (Chlorine anion bullet Water bullet 2Methyl Alcohol)

By formula: (Cl- bullet 2CH4O) + H2O = (Cl- bullet H2O bullet 2CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar32.kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar46.J/mol*KHPMSEvans and Keesee, 1991gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bogdanov, Lee, et al., 2001
Bogdanov, B.; Lee, H.J.S.; McMahon, T.B., Influence of fluorine substitution on the structures and thermochemistry of chloride ion-ether complexes in the gas phase, Int. J. Mass Spectrom., 2001, 210, 387-402, https://doi.org/10.1016/S1387-3806(01)00404-3 . [all data]

Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ion cyclotron resonance halide-exchange equilibria, J. Phys. Chem., 1984, 88, 1083. [all data]

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]

Meot-ner, Cybulski, et al., 1988
Meot-ner, M.; Cybulski, S.M.; Scheiner, S.; Liebman, J.F., Is CN- Significantly Anisotropic? Comparison of CN- vs. Cl-: Clustering with HCN and Condensed Phase Thermochemistry, J. Phys. Chem., 1988, 92, 10, 2738, https://doi.org/10.1021/j100321a009 . [all data]

Hiraoka, Takimoto, et al., 1986
Hiraoka, K.; Takimoto, H.; Morise, K.; Shoda, T.; Nakamura, S., Ion-Molecule Reactions in Gaseous Acetone, Bull. Chem. Soc. Japan, 1986, 59, 7, 2247, https://doi.org/10.1246/bcsj.59.2247 . [all data]

Hiraoka, Fujimaki, et al., 1993
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Bond Strengths of the Gas-Phase Cluster Ions X-(CS2)n (X = F, Cl, Br and I), Chem. Phys. Lett., 1993, 208, 5-6, 491, https://doi.org/10.1016/0009-2614(93)87178-6 . [all data]

Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S., Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH, Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4 . [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Pervova, Korobov, et al., 1992
Pervova, Y.U.; Korobov, M.V.; Sidorov, L.N., Enthalpies of Bonds Rupture in AlClnF4-n(-) Anions, Russ. J. Phys. Chem., 1992, 66, 635. [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Determination of the Stabilities and Structures of X-(C6H6) Clusters (X = Cl, Br, and I), Chem. Phys. Lett., 1988, 147, 2-3, 174, https://doi.org/10.1016/0009-2614(88)85078-4 . [all data]

Hiraoka, Aruga, et al., 1993
Hiraoka, K.; Aruga, K.; Fujimaki, S.; Yamabe, S., Comparative Study of the Gas Phase Bond Strengths of CO2 and N2O with the Halide Ions, J. Am. Soc. Mass Spectrom., 1993, 4, 1, 58, https://doi.org/10.1016/1044-0305(93)85043-W . [all data]

Magnera, Caldwell, et al., 1984
Magnera, T.F.; Caldwell, G.; Sumner, J.; Ikuta, S.; Kebarle, P., Solvation of the halide anions in dimethyl sulfoxide. Factors involved in enhanced reactivity of negative ions in dipolar aprotic solvents, J. Am. Chem. Soc., 1984, 106, 6140. [all data]

Larson and McMahon, 1988
Larson, J.W.; McMahon, T.B., Equilibrium Isotope Effects on the Hydration of Gas Phase Ions. The Effect of H-Bond Formation on Deuterium Isotopic Fractionation Factors for H3O+,H5O2+,F(HOH)-, and Cl(HOH)-, J. Am. Chem. Soc., 1988, 110, 4, 1087, https://doi.org/10.1021/ja00212a015 . [all data]

Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr., Heats of formation of SO2Cl- and (SO2)2Cl-, J. Am. Chem. Soc., 1980, 102, 1446. [all data]

Evans and Keesee, 1991
Evans, D.H.; Keesee, R.G., Thermodynamics of Gas-Phase Mixed-Solvent Cluster Ions - Water and Methanol on K+ and Cl- and Comparison to Liquid Solutions, J. Phys. Chem., 1991, 95, 9, 3558, https://doi.org/10.1021/j100162a024 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References