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Chlorine anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 301 to 314

Chlorine anion + C3H9ClGe = C3H9Cl2Ge-

By formula: Cl- + C3H9ClGe = C3H9Cl2Ge-

Quantity Value Units Method Reference Comment
Deltar92.9 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Tin(IV) chloride = Cl5Sn-

By formula: Cl- + Cl4Sn = Cl5Sn-

Quantity Value Units Method Reference Comment
Deltar235. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Thionyl chloride = Cl3OS-

By formula: Cl- + Cl2OS = Cl3OS-

Quantity Value Units Method Reference Comment
Deltar85.4 ± 7.5kJ/molCIDTBachrach, Hayes, et al., 2001gas phase

Chlorine anion + Silane, chlorotrimethyl- = C3H9Cl2Si-

By formula: Cl- + C3H9ClSi = C3H9Cl2Si-

Quantity Value Units Method Reference Comment
Deltar59.8 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase

Chlorine anion + Sulfur dichloride = Cl3S-

By formula: Cl- + Cl2S = Cl3S-

Quantity Value Units Method Reference Comment
Deltar84.9 ± 7.9kJ/molCIDTGailbreath, Pommerening, et al., 2000gas phase

Chlorine anion + Cl3Sb = Cl4Sb-

By formula: Cl- + Cl3Sb = Cl4Sb-

Quantity Value Units Method Reference Comment
Deltar160. ± 7.9kJ/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + Phosphorus trichloride = Cl4P-

By formula: Cl- + Cl3P = Cl4P-

Quantity Value Units Method Reference Comment
Deltar90.0 ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + Arsenic trichloride = AsCl4-

By formula: Cl- + AsCl3 = AsCl4-

Quantity Value Units Method Reference Comment
Deltar115. ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Deltar153. ± 15.kJ/molCIDTWalker, Check, et al., 2002gas phase

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Deltar84.1 ± 6.7kJ/molCIDTHammad and Wenthold, 2000gas phase

Chlorine anion = C4HClF9-

By formula: Cl- = C4HClF9-

Quantity Value Units Method Reference Comment
Deltar64.9 ± 1.3kJ/molIMREGuerrero, Herrero, et al., 2009gas phase

Chlorine anion + seleninyl dichloride = Cl3OSe-

By formula: Cl- + Cl2OSe = Cl3OSe-

Quantity Value Units Method Reference Comment
Deltar149.8kJ/molN/ALobring, Hao, et al., 2003gas phase

Chlorine anion + Phosphorus difluoride monochloride = Cl2F2P-

By formula: Cl- + ClF2P = Cl2F2P-

Quantity Value Units Method Reference Comment
Deltar98.99kJ/molN/ACheck, Lobring, et al., 2003gas phase

Chlorine anion = ClN2O-

By formula: Cl- = ClN2O-

Quantity Value Units Method Reference Comment
Deltar18.8 ± 0.42kJ/molN/ABoesl, Distelrath, et al., 2008gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]

Bachrach, Hayes, et al., 2001
Bachrach, S.M.; Hayes, J.M.; Check, C.E.; Sunderlin, L.S., Potential energy surface of SOCl3-, J. Phys. Chem. A, 2001, 105, 41, 9595-9597, https://doi.org/10.1021/jp012412f . [all data]

Gailbreath, Pommerening, et al., 2000
Gailbreath, B.D.; Pommerening, C.A.; Bachrach, S.M.; Sunderlin, L.S., Potential Energy Surface of SCl3-, J. Phys. Chem., 2000, 104, 13, 2958, https://doi.org/10.1021/jp993671w . [all data]

Walker, Check, et al., 2002
Walker, B.W.; Check, C.E.; Lobring, K.C.; Pommerening, C.A.; Sunderlin, L.S., The Thermochemistry of Group 15 Tetrachloride Anions, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 469, https://doi.org/10.1016/S1044-0305(02)00369-0 . [all data]

Hammad and Wenthold, 2000
Hammad, L.A.; Wenthold, P.G., Synthesis, characterization, and reactivity of the m-xylylene anion in the gas phase. The enthalpy of formation of m-xylylene, J. Am. Chem. Soc., 2000, 122, 45, 11203-11211, https://doi.org/10.1021/ja002138n . [all data]

Guerrero, Herrero, et al., 2009
Guerrero, A.; Herrero, R.; Davalos, J.Z.; Koppel, I.; Abboud, J.L.M.; Chana, A.; Koppel, I.A., Hydrogen-Bonding Interactions of (CF3)(3)CH and (CF3)(3)C- in the Gas Phase. An Experimental (FT-ICR) and Computational Study, J. Phys. Chem. A, 2009, 113, 23, 6422-6429, https://doi.org/10.1021/jp811057m . [all data]

Lobring, Hao, et al., 2003
Lobring, K.C.; Hao, C.T.; Forbes, J.K.; Ivanov, M.R.J.; Bachrach, S.M.; Sunderlin, L.S., Bond strengths in ChCl(3)(-) and ChOCl(3)(-) (Ch = S, Se, Te): Experiment and theory, J. Phys. Chem. A, 2003, 107, 50, 11153-11160, https://doi.org/10.1021/jp030388v . [all data]

Check, Lobring, et al., 2003
Check, C.E.; Lobring, K.C.; Keating, P.R.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of hypervalent phosphorus-halogen bonds, J. Phys. Chem. A, 2003, 107, 42, 8961-8967, https://doi.org/10.1021/jp030287x . [all data]

Boesl, Distelrath, et al., 2008
Boesl, U.; Distelrath, V.; Selzle, H., The weakly-bound complex Cl center dot N2O studied by high resolution photodetachment photoelectron spectroscopy, Phys. Chem. Chem. Phys., 2008, 10, 41, 6252-6257, https://doi.org/10.1039/b807992g . [all data]


Notes

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