Chlorine anion


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar153.36J/mol*KReviewChase, 1998Data last reviewed in June, 1982

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Chlorine anion + Water = (Chlorine anion • Water)

By formula: Cl- + H2O = (Cl- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr60. ± 20.kJ/molAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Δr81. ± 10.J/mol*KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr40. ± 20.kJ/molAVGN/AAverage of 9 values; Individual data points

Chlorine anion + Methyl Alcohol = (Chlorine anion • Methyl Alcohol)

By formula: Cl- + CH4O = (Cl- • CH4O)

Quantity Value Units Method Reference Comment
Δr69. ± 10.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr101.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr92.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr95.8J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr61.9J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr42. ± 3.kJ/molAVGN/AAverage of 10 values; Individual data points

Chlorine anion + Hydrogen chloride = (Chlorine anion • Hydrogen chloride)

By formula: Cl- + HCl = (Cl- • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr124. ± 4.2kJ/molN/AMetz, Kitsopoulos, et al., 1988gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Δr99.6 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Δr96.7 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr99.16 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Δr85.4kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl-)SO2; M
Δr98.3J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Δr98.3J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr95.4J/mol*KN/AUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M
Quantity Value Units Method Reference Comment
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1987gas phase; K = 0.60 for HCl..Cl- + DCL <=> DCl..Cl- + HCl, anchored to Larson and McMahon, 1984, 32; B
Δr72. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B
Δr66.9 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr69.9 ± 1.3kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B
Δr56.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980; M

Chlorine anion + Sulfur dioxide = (Chlorine anion • Sulfur dioxide)

By formula: Cl- + O2S = (Cl- • O2S)

Quantity Value Units Method Reference Comment
Δr92.9 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B,M
Δr87.4 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr92.9 ± 9.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..Cl- in Keesee, Lee, et al., 1980; B,M
Δr91.21 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Δr87.4kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M
Δr101.J/mol*KN/ABohringer, Fahey, et al., 1984gas phase; switching reaction(Cl-)H2O), Entropy change calculated or estimated; Keesee and Castleman, 1980; M
Δr87.0J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr97.1J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr65.7 ± 8.4kJ/molTDAsCaldwell and Kebarle, 1985gas phase; B
Δr61.5 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr62.8 ± 6.7kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..Cl- in Keesee, Lee, et al., 1980; B,M
Δr61.9 ± 1.3kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B
Δr61.5kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
59.4296.FAFehsenfeld and Ferguson, 1974gas phase; switching reaction(Cl-)H2O; M

Chlorine anion + Benzene = (Chlorine anion • Benzene)

By formula: Cl- + C6H6 = (Cl- • C6H6)

Quantity Value Units Method Reference Comment
Δr25.1 ± 1.9kJ/molN/ATschurl, Ueberfluss, et al., 2007gas phase; B
Δr39. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr41.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr36.kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr43.5kJ/molPHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr71.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr71.5J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr92.J/mol*KN/ASunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr17. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr16. ± 6.7kJ/molIMREChowdhury and Kebarle, 1986gas phase; B
Δr20. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr15.9kJ/molIMREFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
16.300.PHPMSChowdhury and Kebarle, 1986gas phase; M
16.300.PHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

(Chlorine anion • 2Water) + Water = (Chlorine anion • 3Water)

By formula: (Cl- • 2H2O) + H2O = (Cl- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr93.7J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr97.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr21. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Chlorine anion + Acetonitrile = (Chlorine anion • Acetonitrile)

By formula: Cl- + C2H3N = (Cl- • C2H3N)

Quantity Value Units Method Reference Comment
Δr61. ± 10.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr65.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr65.7J/mol*KPHPMSYamabe, Furumiya, et al., 1986gas phase; M
Δr59.8J/mol*KPHPMSSieck, 1985gas phase; M
Δr59.8J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Δr89.5J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr42.68 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr38. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr37. ± 11.kJ/molTDAsYamabe, Furumiya, et al., 1986gas phase; B
Δr42.26 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Δr38. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion • Water) + Water = (Chlorine anion • 2Water)

By formula: (Cl- • H2O) + H2O = (Cl- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr53. ± 5.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr85.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr87.0J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr27.2kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr27. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr27.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr28.kJ/molFAFehsenfeld and Ferguson, 1974gas phase; M

Chlorine anion + 2-Propanol, 2-methyl- = (Chlorine anion • 2-Propanol, 2-methyl-)

By formula: Cl- + C4H10O = (Cl- • C4H10O)

Quantity Value Units Method Reference Comment
Δr77. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr115.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr100.J/mol*KPHPMSSieck, 1985gas phase; M
Δr97.9J/mol*KN/ALarson and McMahon, 1984gas phase; Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr110.J/mol*KPHPMSKebarle, 1977gas phase; M
Δr43.1J/mol*KN/AYamdagni and Kebarle, 1971gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr48.45kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr51.5 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr48.53kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr46.4 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr46.4 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Chlorine anion + Benzonitrile, 4-hydroxy- = (Chlorine anion • Benzonitrile, 4-hydroxy-)

By formula: Cl- + C7H5NO = (Cl- • C7H5NO)

Quantity Value Units Method Reference Comment
Δr147. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M,M
Δr148.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr120.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr110.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr114. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
103.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
110.300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
108.300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Acetone = (Chlorine anion • Acetone)

By formula: Cl- + C3H6O = (Cl- • C3H6O)

Quantity Value Units Method Reference Comment
Δr56. ± 6.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSSieck, 1985gas phase; M
Δr82.0J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr71.5J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr82.4J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr33.8 ± 0.84kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr30.5kJ/molTDAsHiraoka, Morise, et al., 1986gas phase; B
Δr36.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr34. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr33. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + Trichloromethane = (Chlorine anion • Trichloromethane)

By formula: Cl- + CHCl3 = (Cl- • CHCl3)

Quantity Value Units Method Reference Comment
Δr63.6 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Δr81.6 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr75.73kJ/molMoblGiles and Grimsrud, 1993gas phase; B
Δr75.7 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr79.9 ± 2.9kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KN/ALarson and McMahon, 1984, 2gas phase; From thermochemical cycle(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Δr103.J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Δr61.9J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr47. ± 5.kJ/molAVGN/AAverage of 6 values; Individual data points

Chlorine anion + Phenol = (Chlorine anion • Phenol)

By formula: Cl- + C6H6O = (Cl- • C6H6O)

Quantity Value Units Method Reference Comment
Δr109. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Δr109. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Δr115.kJ/molPHPMSKebarle, 1977gas phase; M
Δr111.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr81.2 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr100.J/mol*KPHPMSKebarle, 1977gas phase; M
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr64.9J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3 ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Δr77.4 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Δr61.9 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
66.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Chlorine anion + Benzene, chloro- = (Chlorine anion • Benzene, chloro-)

By formula: Cl- + C6H5Cl = (Cl- • C6H5Cl)

Quantity Value Units Method Reference Comment
Δr50.21 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Δr56.9 ± 4.2kJ/molIMRELarson and McMahon, 1984gas phase; B,B,M
Δr52.7kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr69.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr93.7J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr29.7 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Δr29. ± 4.2kJ/molIMRELarson and McMahon, 1984gas phase; B,B,M
Δr27.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
27.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

(Chlorine anion • 3Water) + Water = (Chlorine anion • 4Water)

By formula: (Cl- • 3H2O) + H2O = (Cl- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr40.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr44. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr45.6 ± 2.9kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Δr46.4 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr104.J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr108.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr16. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr14.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr14.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr17. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Chlorine anion + Chloromethane = (Chlorine anion • Chloromethane)

By formula: Cl- + CH3Cl = (Cl- • CH3Cl)

Quantity Value Units Method Reference Comment
Δr43.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr49.0 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr51.0 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr36.0 ± 0.84kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Δr63.6 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B
Quantity Value Units Method Reference Comment
Δr85.8J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr64.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr24.3 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr20.3kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr26. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr17.2 ± 2.1kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B
Δr45.2 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Chlorine anion + Formic acid = (Chlorine anion • Formic acid)

By formula: Cl- + CH2O2 = (Cl- • CH2O2)

Quantity Value Units Method Reference Comment
Δr115. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Δr116. ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; B
Δr107. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr156. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B,M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr101.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr166.J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr84.1 ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Δr77.0 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr106. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B

Chlorine anion + Phenol, 4-chloro- = (Chlorine anion • Phenol, 4-chloro-)

By formula: Cl- + C6H5ClO = (Cl- • C6H5ClO)

Quantity Value Units Method Reference Comment
Δr124. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr126.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr110.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr92.5 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
81.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
87.9300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Phenol, 4-fluoro- = (Chlorine anion • Phenol, 4-fluoro-)

By formula: Cl- + C6H5FO = (Cl- • C6H5FO)

Quantity Value Units Method Reference Comment
Δr117. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr120.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr106.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr86.2 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
75.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
80.8300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Ethanol = (Chlorine anion • Ethanol)

By formula: Cl- + C2H6O = (Cl- • C2H6O)

Quantity Value Units Method Reference Comment
Δr74.9 ± 1.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr73.6 ± 2.1kJ/molTDAsHiraoka, 1987gas phase; B,B,M
Δr72.4 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr99.2J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr96.7J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr44.56kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr43.9 ± 8.4kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr43.9 ± 8.4kJ/molTDAsHiraoka, 1987gas phase; B
Δr43.5 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8295.ICRRiveros, 1974gas phase; switching reaction(Cl-)CH3OH; Riveros, Breda, et al., 1973; M

(Chlorine anion • Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 2Methyl Alcohol)

By formula: (Cl- • CH4O) + CH4O = (Cl- • 2CH4O)

Quantity Value Units Method Reference Comment
Δr59.0 ± 1.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr57.32 ± 0.84kJ/molTDAsEvans and Keesee, 1991gas phase; B,M
Δr59.0 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr54.4 ± 2.9kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr92.0J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr81.2J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr30.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr29.7kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr30.1 ± 1.7kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 2Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 3Methyl Alcohol)

By formula: (Cl- • 2CH4O) + CH4O = (Cl- • 3CH4O)

Quantity Value Units Method Reference Comment
Δr48.12 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr45.2 ± 1.3kJ/molTDAsEvans and Keesee, 1991gas phase; B,M
Δr49.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr51.5 ± 2.5kJ/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr95.0J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr98.7J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr21.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr16.7kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr21. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr21.8 ± 1.3kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

Chlorine anion + Benzene, nitro- = (Chlorine anion • Benzene, nitro-)

By formula: Cl- + C6H5NO2 = (Cl- • C6H5NO2)

Quantity Value Units Method Reference Comment
Δr68.2 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Δr69.0kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr81.2J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr43.9 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B
Δr29.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
43.9300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
32.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Borane, triethyl- = (Chlorine anion • Borane, triethyl-)

By formula: Cl- + C6H15B = (Cl- • C6H15B)

Quantity Value Units Method Reference Comment
Δr99.6 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr99.6kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Δr92.0J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr72.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr72.0kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Hydrogen cation = Hydrogen chloride

By formula: Cl- + H+ = HCl

Quantity Value Units Method Reference Comment
Δr1394.9kJ/molN/AMartin and Hepburn, 1998gas phase; Given: ΔHacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol; B
Δr1396. ± 8.8kJ/molG+TSFujio, McIver, et al., 1981gas phase; value altered from reference due to change in acidity scale; B
Δr1377.0kJ/molN/ACheck, Faust, et al., 2001gas phase; FeCC-(q); ; ΔS(EA)=5.0; B
Quantity Value Units Method Reference Comment
Δr1372.8 ± 0.42kJ/molH-TSMartin and Hepburn, 1998gas phase; Given: ΔHacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol; B
Δr1374. ± 8.4kJ/molIMREFujio, McIver, et al., 1981gas phase; value altered from reference due to change in acidity scale; B
Δr1354.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeCC-(q); ; ΔS(EA)=5.0; B

Chlorine anion + Acetic acid = (Chlorine anion • Acetic acid)

By formula: Cl- + C2H4O2 = (Cl- • C2H4O2)

Quantity Value Units Method Reference Comment
Δr102.1 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Δr90.4 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Δr100. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr100.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr80.8J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr77.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr66.1 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B
Δr69.9 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Chlorine anion + Ammonia = (Chlorine anion • Ammonia)

By formula: Cl- + H3N = (Cl- • H3N)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr<30.5 ± 1.7kJ/molN/ATschurl and Boesl, 2008gas phase; B
Δr34.3 ± 0.42kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B,M
Δr37. ± 5.0kJ/molN/AMarkovich, Chesnovsky, et al., 1993gas phase; B
Δr44. ± 17.kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr64.4J/mol*KHPMSEvans, Keesee, et al., 1987gas phase; M
Δr83.3J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)CH3F, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr15.1 ± 0.84kJ/molTDAsEvans, Keesee, et al., 1987gas phase; B
Δr19. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Chlorine anion + p-Cresol = (Chlorine anion • p-Cresol)

By formula: Cl- + C7H8O = (Cl- • C7H8O)

Quantity Value Units Method Reference Comment
Δr107. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr108.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr112.J/mol*KPHPMSCummings, French, et al., 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
64.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
69.5300.PHPMSCummings, French, et al., 1977gas phase; M

Chlorine anion + Isopropyl Alcohol = (Chlorine anion • Isopropyl Alcohol)

By formula: Cl- + C3H8O = (Cl- • C3H8O)

Quantity Value Units Method Reference Comment
Δr81.17 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr76.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr97.1J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr47.36kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr45.61kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

(Chlorine anion • 6Water) + Water = (Chlorine anion • 7Water)

By formula: (Cl- • 6H2O) + H2O = (Cl- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B
Δr28.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr34.kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AHiraoka, Mizuse, et al., 1988, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr8.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + Methylene chloride = (Chlorine anion • Methylene chloride)

By formula: Cl- + CH2Cl2 = (Cl- • CH2Cl2)

Quantity Value Units Method Reference Comment
Δr66.1 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr61.9 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr64.9 ± 1.3kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.5J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M
Δr92.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr38. ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Δr37.0kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr37.2 ± 2.5kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B

Chlorine anion + Phosphorus trifluoride = (Chlorine anion • Phosphorus trifluoride)

By formula: Cl- + F3P = (Cl- • F3P)

Quantity Value Units Method Reference Comment
Δr64.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr64.9kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr38. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr38.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + 1-Propanol = (Chlorine anion • 1-Propanol)

By formula: Cl- + C3H8O = (Cl- • C3H8O)

Quantity Value Units Method Reference Comment
Δr85.4 ± 2.1kJ/molTDAsHiraoka, 1987gas phase; B,B,M
Δr74.1 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr121.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr97.1J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr48.95kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr49.0 ± 8.4kJ/molTDAsHiraoka, 1987gas phase; B
Δr45.2 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Chlorine anion + Hydrogen cyanide = (Chlorine anion • Hydrogen cyanide)

By formula: Cl- + CHN = (Cl- • CHN)

Quantity Value Units Method Reference Comment
Δr91.2 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,B,M
Δr87.9 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr79.1J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr99.2J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr67.8 ± 6.7kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B
Δr67.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Δr58.2 ± 8.4kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,M

Chlorine anion + Carbon dioxide = (Chlorine anion • Carbon dioxide)

By formula: Cl- + CO2 = (Cl- • CO2)

Quantity Value Units Method Reference Comment
Δr28.5 ± 2.1kJ/molPDisArnold, Bradforth, et al., 1995gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Δr31.8kJ/molTDEqHiraoka, Shoda, et al., 1986gas phase; B,M
Δr33.5 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Δr82.0J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr8.79kJ/molTDEqHiraoka, Shoda, et al., 1986gas phase; B
Δr8.79 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Chlorine anion • 3Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 4Methyl Alcohol)

By formula: (Cl- • 3CH4O) + CH4O = (Cl- • 4CH4O)

Quantity Value Units Method Reference Comment
Δr43.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr43.93kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr46.9 ± 2.5kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr110.J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr15. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr15.5kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr13.8 ± 0.84kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 4Water) + Water = (Chlorine anion • 5Water)

By formula: (Cl- • 4H2O) + H2O = (Cl- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr40. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr28.0kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr40. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr13. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr12. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Chlorine anion + 2-Propanone, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion • 2-Propanone, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3F6O = (Cl- • C3F6O)

Quantity Value Units Method Reference Comment
Δr120. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr95.8 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr73.6 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr68.2kJ/molICRLarson and McMahon, 1984, 3gas phase; switching reaction(Cl-)(C2H5)3B; M

(Chlorine anion • 3Acetonitrile) + Acetonitrile = (Chlorine anion • 4Acetonitrile)

By formula: (Cl- • 3C2H3N) + C2H3N = (Cl- • 4C2H3N)

Quantity Value Units Method Reference Comment
Δr45.6 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Δr37.7 ± 3.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr25.9kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr111.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr45.2J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr12. ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr12.6kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Chlorine anion + 2-Propanone, 1,1,1,3,3-pentafluoro- = (Chlorine anion • 2-Propanone, 1,1,1,3,3-pentafluoro-)

By formula: Cl- + C3HF5O = (Cl- • C3HF5O)

Quantity Value Units Method Reference Comment
Δr109. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr97.9kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr72.0 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M,M

Chlorine anion + 2-Propanol, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion • 2-Propanol, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3H2F6O = (Cl- • C3H2F6O)

Quantity Value Units Method Reference Comment
Δr111.kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr79.5kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M

(Chlorine anion • 2Acetonitrile) + Acetonitrile = (Chlorine anion • 3Acetonitrile)

By formula: (Cl- • 2C2H3N) + C2H3N = (Cl- • 3C2H3N)

Quantity Value Units Method Reference Comment
Δr46.9 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Δr50.2 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr44.35kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr84.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr22. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr19.2kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Chlorine anion + Carbon disulfide = (Chlorine anion • Carbon disulfide)

By formula: Cl- + CS2 = (Cl- • CS2)

Quantity Value Units Method Reference Comment
Δr36.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Δr49.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr58.2J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Δr84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr19. ± 9.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Δr24. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

(Chlorine anion • Acetonitrile) + Acetonitrile = (Chlorine anion • 2Acetonitrile)

By formula: (Cl- • C2H3N) + C2H3N = (Cl- • 2C2H3N)

Quantity Value Units Method Reference Comment
Δr52.3 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Δr50.2 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr51.04kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr68.2J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr79.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr32. ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr27.6kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

Chlorine anion + C4H4F6O = (Chlorine anion • C4H4F6O)

By formula: Cl- + C4H4F6O = (Cl- • C4H4F6O)

Quantity Value Units Method Reference Comment
Δr111.kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M
Quantity Value Units Method Reference Comment
Δr79.5kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984; M

(Chlorine anion • 5Water) + Water = (Chlorine anion • 6Water)

By formula: (Cl- • 5H2O) + H2O = (Cl- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr35.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr37. ± 2.kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr10. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

Chlorine anion + Methane, bromo- = (Chlorine anion • Methane, bromo-)

By formula: Cl- + CH3Br = (Cl- • CH3Br)

Quantity Value Units Method Reference Comment
Δr52.3 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr45.6 ± 2.1kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Δr51. ± 13.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Δr53.6J/mol*KHPMSDougherty and Roberts, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr28.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr30. ± 5.0kJ/molTDAsDougherty and Roberts, 1974gas phase; B

(Chlorine anion • Hydrogen chloride) + Hydrogen chloride = (Chlorine anion • 2Hydrogen chloride)

By formula: (Cl- • HCl) + HCl = (Cl- • 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.60 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Δr58.6kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Δr102.J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr33.1 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B

Chlorine anion + Cl4Th = (Chlorine anion • Cl4Th)

By formula: Cl- + Cl4Th = (Cl- • Cl4Th)

Quantity Value Units Method Reference Comment
Δr101.kJ/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr73.6kJ/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M

Chlorine anion + C2H3ClO2 = (Chlorine anion • C2H3ClO2)

By formula: Cl- + C2H3ClO2 = (Cl- • C2H3ClO2)

Quantity Value Units Method Reference Comment
Δr59.0kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr33.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

Chlorine anion + Hydrogen cation = Hydrogen chloride

By formula: Cl- + H+ = HCl

Quantity Value Units Method Reference Comment
Δr1394.9kJ/molN/AMartin and Hepburn, 1998gas phase; Given: ΔHacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol
Δr1396. ± 8.8kJ/molG+TSFujio, McIver, et al., 1981gas phase; value altered from reference due to change in acidity scale
Δr1377.0kJ/molN/ACheck, Faust, et al., 2001gas phase; FeCC-(q); ; ΔS(EA)=5.0
Quantity Value Units Method Reference Comment
Δr1372.8 ± 0.42kJ/molH-TSMartin and Hepburn, 1998gas phase; Given: ΔHacid(0K)=116288.7±0.6 cm-1, or 332.486±0.002 kcal/mol
Δr1374. ± 8.4kJ/molIMREFujio, McIver, et al., 1981gas phase; value altered from reference due to change in acidity scale
Δr1354.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeCC-(q); ; ΔS(EA)=5.0

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

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Sieck, 1985
Sieck, L.W., Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure., J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049 . [all data]

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Metz, R.B.; Kitsopoulos, T.; Weaver, A.; Neumark, D.M., Study of the Transition State Region in the Cl+HCl Reaction by Photoelectron Spectroscopy of ClHCl-, J. Chem. Phys., 1988, 88, 2, 1463, https://doi.org/10.1063/1.454218 . [all data]

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Kebarle, P., Ion Thermochemistry and Solvation from Gas Phase Ion Equilibria, Ann. Rev. Phys. Chem., 1977, 28, 1, 445, https://doi.org/10.1146/annurev.pc.28.100177.002305 . [all data]

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Bogdanov, B.; Peschke, M.; Tonner, D.S.; Szulejko, J.E.; McMahon, T.B., Stepwise solvation of halides by alcohol molecules in the gas phase, Int. J. Mass Spectrom., 1999, 187, 707-725, https://doi.org/10.1016/S1387-3806(98)14180-5 . [all data]

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Paul, G.J.C.; Kebarle, P., Stabilities in the Gas Phase of the Hydrogen Bonded Complexes, YC6H4OH-X-, of Substituted Phenols, YC6H4OH, with the Halide Anions X-(Cl-, Br-), Can. J. Chem., 1990, 68, 11, 2070, https://doi.org/10.1139/v90-316 . [all data]

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Bofdanov, B.; McMahon, T.B., Structures, Thermochemistry, and Infrared Spectra of Chloride Ion-Fluorinated Acetone Complexes and Neutral Fluorinated Acetones in the Gas Phase: Experiment and Theory, Int. J. Mass Spectrom., 2002, 219, 3, 593-613, https://doi.org/10.1016/S1387-3806(02)00745-5 . [all data]

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Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

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Walker, B.W.; Sunderlin, L.S., The thermochemistry of formic acid halide anion clusters, Int. J. Mass Spectrom., 1999, 184, 2-3, 183-189, https://doi.org/10.1016/S1387-3806(99)00008-1 . [all data]

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Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References