Methyl tetradecanoate
- Formula: C15H30O2
- Molecular weight: 242.3975
- IUPAC Standard InChI: InChI=1S/C15H30O2/c1-3-4-5-6-7-8-9-10-11-12-13-14-15(16)17-2/h3-14H2,1-2H3
- IUPAC Standard InChIKey: ZAZKJZBWRNNLDS-UHFFFAOYSA-N
- CAS Registry Number: 124-10-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tetradecanoic acid, methyl ester; Myristic acid, methyl ester; Metholeneat 2495; Methyl myristate; Methyl n-tetradecanoate; Uniphat A50; Emery 2214; Acide myristique methyl ester; Methyl myristylate
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Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | RTx-1 | HP-5 MS | DB-5 MS | HP-5 MS | HP-5MS |
| Column length (m) | 60. | 30. | 30. | 30. | 30. |
| Carrier gas | Helium | Helium | Helium | Helium | He |
| Substrate | |||||
| Column diameter (mm) | 0.22 | 0.25 | 0.25 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 70. | 60. | 35. | 60. |
| Tend (C) | 230. | 290. | 240. | 195. | 250. |
| Heat rate (K/min) | 2. | 5. | 3. | 2. | 2. |
| Initial hold (min) | 5. | 8. | |||
| Final hold (min) | 35. | 10. | 30. | 15. | |
| I | 1708. | 1727. | 1724. | 1725. | 1723. |
| Reference | Dib, Bendahou, et al., 2010 | Radulovic, Blagojevic, et al., 2010 | Silva, Pott, et al., 2010 | Kim and Chung, 2009 | Ferhat, Tigrine-Kordjani, et al., 2007 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-1 | Elite-5MS | BPX-5 | DB-5 | HP-5 |
| Column length (m) | 30. | 30. | 25. | 30. | 60. |
| Carrier gas | He | He | He | He | |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.32 | 0.22 | 0.25 | 0.32 |
| Phase thickness (μm) | 0.15 | 0.5 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 40. | 50. | 40. | 30. |
| Tend (C) | 220. | 280. | 300. | 280. | 260. |
| Heat rate (K/min) | 3. | 4. | 5. | 8. | 2. |
| Initial hold (min) | 5. | 5. | 2. | ||
| Final hold (min) | 10. | 28. | |||
| I | 1738. | 1723. | 1726. | 1723. | 1727.4 |
| Reference | Ouattara, Koudou, et al., 2007 | Tava, Pecetti, et al., 2007 | Dickschat, Bode, et al., 2005 | Jelén, Krawczyk, et al., 2005 | Leffingwell and Alford, 2005 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | SPB-5 | DB-5 | HP-5MS | HP-5 | DB-5 |
| Column length (m) | 30. | 25. | 30. | 30. | 30. |
| Carrier gas | He | He | He | Helium | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.32 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 60. | 60. | 60. | 40. | 60. |
| Tend (C) | 250. | 200. | 285. | 250. | 240. |
| Heat rate (K/min) | 4. | 2. | 4.3 | 5. | 3. |
| Initial hold (min) | 2. | 2. | |||
| Final hold (min) | 20. | 80. | 5. | ||
| I | 1725. | 1723. | 1727. | 1706. | 1722. |
| Reference | Pino, Marbot, et al., 2005 | Rout, Misra, et al., 2005 | Tesevic, Nikicevic, et al., 2005 | N/A | Tellez, Khan, et al., 2004 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | DB-1 | DB-5 | DB-5 | Optima-1 | DB-5 |
| Column length (m) | 30. | 30. | 30. | 25. | 30. |
| Carrier gas | Helium | He | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.32 | 0.25 | 0.25 | 0.20 | 0.25 |
| Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
| Tstart (C) | 160. | 40. | 60. | 50. | 60. |
| Tend (C) | 252. | 290. | 240. | 250. | 270. |
| Heat rate (K/min) | 10. | 4. | 3. | 3. | 3. |
| Initial hold (min) | 3. | ||||
| Final hold (min) | |||||
| I | 1710. | 1724. | 1725. | 1709. | 1729. |
| Reference | Krop, 2003 | da Camara, Shepherd, et al., 2002 | Tellez, Khan, et al., 2002 | Brun, Bessière, et al., 2001 | Palmeira, Conserva, et al., 2001 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
|---|---|---|---|---|---|
| Active phase | OV-101 | DB-5 | Ultra-1 | DB-1 | DB-1 |
| Column length (m) | 50. | 30. | 25. | 60. | 60. |
| Carrier gas | Nitrogen | N2 | He | He | He |
| Substrate | |||||
| Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 | 0.25 |
| Phase thickness (μm) | 0.215 | 0.25 | 0.25 | 0.25 | |
| Tstart (C) | 40. | 50. | 80. | 50. | 50. |
| Tend (C) | 200. | 300. | 260. | 240. | 240. |
| Heat rate (K/min) | 2. | 6. | 3. | 3. | 3. |
| Initial hold (min) | 10. | 4. | |||
| Final hold (min) | 20. | ||||
| I | 1707. | 1727. | 1707. | 1705. | 1708. |
| Reference | Tamura, Boonbumrung, et al., 2000 | Wang, Jin, et al., 1992 | Okumura, 1991 | Shiota, 1991 | Shiota, 1991 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
| Column type | Capillary | Capillary | Capillary |
|---|---|---|---|
| Active phase | OV-101 | OV-101 | OV-101 |
| Column length (m) | 50. | 50. | 30. |
| Carrier gas | Hydrogen | ||
| Substrate | |||
| Column diameter (mm) | 0.32 | 0.32 | 0.35 |
| Phase thickness (μm) | |||
| Tstart (C) | 40. | 50. | 60. |
| Tend (C) | 225. | 225. | 270. |
| Heat rate (K/min) | 4. | 4. | 4. |
| Initial hold (min) | 0.1 | 0.1 | 0.5 |
| Final hold (min) | 30. | 30. | |
| I | 1708. | 1707. | 1712. |
| Reference | Stern, Flath, et al., 1985 | Stern, Flath, et al., 1985 | Ehrhardt, Osterroht, et al., 1980 |
| Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dib, Bendahou, et al., 2010
Dib, M.A.; Bendahou, M.; Bendiabdellah, A.; Djabou, N.; Allali, H.; Tabti, B.; Paolini, J.; Costa, J.,
Partial chemical composition and antimicrobial activity of Daucus crinitus Desf. extracts,
Grasas y Aceites, 2010, 61, 3, 271-278, https://doi.org/10.3989/gya.122609
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Radulovic, Blagojevic, et al., 2010
Radulovic, N.; Blagojevic, P.; Palic, R.,
Comparative study of the leaf volatiles of Arctostaphylos uva-ursi (L.) Spreng. and Vaccinium vitis-idaea L. (Ericaceae),
Molecules, 2010, 15, 9, 6168-6185, https://doi.org/10.3390/molecules15096168
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Silva, Pott, et al., 2010
Silva, D.B.; Pott, A.; Oliveira, D.C.R.,
Analyses of the headspace volatile constituents of aerial parts (leaves and stems), flowers and fruits of Bidens gardneri Bak. and Bidens sulphurea (Cav.) Sch. Bip. using solid-phase microextraction,
J. Essen. Oil Res., 2010, 22, 6, 560-563, https://doi.org/10.1080/10412905.2010.9700400
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Kim and Chung, 2009
Kim, J.-S.; Chung, H.Y.,
GC-MS analysis of the volatile components in dried boxthorn (Lycium chimensis) Fruit,
J. Korean Soc. Appl. Biol. Chem., 2009, 52, 5, 516-524, https://doi.org/10.3839/jksabc.2009.088
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Ferhat, Tigrine-Kordjani, et al., 2007
Ferhat, M.A.; Tigrine-Kordjani, N.; Chemat, S.; Meklati, B.Y.; Chemat, F.,
Rapid Extraction of Volatile Compounds Using a New Simultaneous Microwave Distillation: Solvent Extraction Device,
Chromatographia, 2007, 65, 3-4, 217-222, https://doi.org/10.1365/s10337-006-0130-5
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Ouattara, Koudou, et al., 2007
Ouattara, L.; Koudou, J.; Obame, L.C.E.; Karou, D.S.; Traore, A.; Bessiere, J.M.,
Chemical composition and antibacterial activity of Cochlospermum planchoni Hook. f. ex Planch essential oil from Burkina Faso,
Pakistan J. Biol. Sci., 2007, 10, 22, 4177-4179, https://doi.org/10.3923/pjbs.2007.4177.4179
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Tava, Pecetti, et al., 2007
Tava, A.; Pecetti, L.; Ricci, M.; Pagnotta, M.A.; Russi, L.,
Volatile compounds from leaves and flowers of Bituminaria bituminosa (L.) Stirt. (Fabaceae) from Italy,
Flavour Fragr. J., 2007, 22, 5, 363-370, https://doi.org/10.1002/ffj.1806
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Dickschat, Bode, et al., 2005
Dickschat, J.S.; Bode, H.B.; Kroppenstedt, R.M.; Müller, R.; Schulz, S.,
Biosynthesis of iso-fatty acids in myxobacteria,
Org. Biomol. Chem., 2005, 3, 15, 2824-2831, https://doi.org/10.1039/b504889c
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Jelén, Krawczyk, et al., 2005
Jelén, H.H.; Krawczyk, J.; Larsen, T.O.; Jarosz, A.; Golebniak, B.,
Main compounds responsible for off-odour of strawberries infected by Phytophthora cactorum,
Lett. Appl. Microbiol., 2005, 40, 4, 255-259, https://doi.org/10.1111/j.1472-765X.2005.01668.x
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Leffingwell and Alford, 2005
Leffingwell, J.C.; Alford, E.D.,
Volatile constituents of Perique tobacco,
Electron. J. Environ. Agric. Food Chem., 2005, 4, 2, 899-915. [all data]
Pino, Marbot, et al., 2005
Pino, J.A.; Marbot, R.; Rosado, A.; Vázquez, C.,
Volatile constituents of genipap (Genipa americana L.) fruit from Cuba,
Flavour Fragr. J., 2005, 20, 6, 583-586, https://doi.org/10.1002/ffj.1491
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Rout, Misra, et al., 2005
Rout, P.K.; Misra, R.; Sahoo, S.; Sree, A.; Rao, Y.R.,
Extraction of kewda (Pandanus fascicularis Lam.) flowers with hexane: composition of concrete, absolute and wax,
Flavour Fragr. J., 2005, 20, 4, 442-444, https://doi.org/10.1002/ffj.1466
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Tesevic, Nikicevic, et al., 2005
Tesevic, V.; Nikicevic, N.; Jovanovic, A.; Djokovic, D.; Vujisic, L.; Vuckovic, I.; Bonic, M.,
Volatile components from old plum brandies,
Food Technol. Biotechnol., 2005, 43, 4, 367-372. [all data]
Tellez, Khan, et al., 2004
Tellez, M.R.; Khan, I.A.; Schaneberg, B.T.; Crockett, S.L.; Rimando, A.M.; Kobaisy, M.,
Steam distillation-solid-phase microextraction for the detection of Ephedra sinica in herbal preparations,
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Krop, 2003
Krop, H.B.,
Thermodynamic approaches for the environmental chemistry of organic pollutants (Dissertation), 2003. [all data]
da Camara, Shepherd, et al., 2002
da Camara, C.A.G.; Shepherd, S.L.K.; Joaquim, D.R.G.,
Análise químnica da cultura de tecidos do híbrido Clusia paralicola X Clusia weddelliana,
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Tellez, Khan, et al., 2002
Tellez, M.R.; Khan, I.A.; Kobaisy, M.; Schrader, K.K.; Dayan, F.E.; Osbrink, W.,
Composition of the essential oil of Lepidium meyenii (Walp.),
Phytochemistry, 2002, 61, 2, 149-155, https://doi.org/10.1016/S0031-9422(02)00208-X
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Brun, Bessière, et al., 2001
Brun, G.; Bessière, J.-M.; Dijoux-Franca, M.-G.; David, B.; Mariotte, A.-M.,
Volatile components of Catharanthus roseus (L.) G. Don (Apocynaceae),
Flavour Fragr. J., 2001, 16, 2, 116-119, https://doi.org/10.1002/ffj.958
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Palmeira, Conserva, et al., 2001
Palmeira, S.F., Jr.; Conserva, L.M.; Andrade, E.H.A.; Guilhon, G.M.S.P.,
Analysis by GC-MS of the hexane extract of the aerial parts of Aristolochia acutifolia Duchtr.,
Flavour Fragr. J., 2001, 16, 2, 85-88, https://doi.org/10.1002/1099-1026(200103/04)16:2<85::AID-FFJ948>3.0.CO;2-2
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Tamura, Boonbumrung, et al., 2000
Tamura, H.; Boonbumrung, S.; Yoshizawa, T.; Varanyanond, W.,
Volatile components of the essential oil in the pulp of four yellow mangoes (Mangifera indica L.) in Thailand,
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Wang, Jin, et al., 1992
Wang, X.; Jin, Z.; Xu, X.,
Analysis of fatty acids in bacteria by using gas chromatographic retention indices,
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Okumura, 1991
Okumura, T.,
retention indices of environmental chemicals on methyl silicone capillary column,
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Shiota, 1991
Shiota, H.,
Volatile components of pawpaw fruit (Asimina triloba Dunal.),
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Stern, Flath, et al., 1985
Stern, D.J.; Flath, R.A.; Mon, T.R.; Teranishi, R.; Lundin, R.E.; Benson, M.E.,
Crude oleic acid volatiles,
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Ehrhardt, Osterroht, et al., 1980
Ehrhardt, M.; Osterroht, C.; Petrick, G.,
Fatty-acid methyl esters dissolved in seawater and associated with suspended particulate material,
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Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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