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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSCP-Sil PONA GBBP-1DB-5HP-5MS
Column length (m) 30.100.50.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.140.60.60.60.
Tend (C) 250.230.220.240.280.
Heat rate (K/min) 2.5.2.3.3.
Initial hold (min) 8.10.   
Final hold (min) 30.25.20.  
I 1240.1229.1213.1246.1243.
ReferenceBenkaci-Ali, Baaliouamer, et al., 2007Cunicao, Lopes, et al., 2007Duquesnoy, Castola, et al., 2007Flamini, Cioni, et al., 2007Kundakovic, Fokialakis, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-1HP-101Equity-5HP-5MSBP-1
Column length (m) 60.25.60.30.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.20.250.250.25
Phase thickness (μm) 0.250.21.0.250.25
Tstart (C) 60.70.40.60.60.
Tend (C) 230.200.260.280.220.
Heat rate (K/min) 2.3.5.3.2.
Initial hold (min)  2.1.  
Final hold (min) 30.15.15. 20.
I 1215.1207.1282.1244.1213.
ReferenceMuselli, Rossi, et al., 2007Politeo, Jukic, et al., 2007Rocha, Coelho, et al., 2007Vagionas, Ngassapa, et al., 2007Bousmaha, Boti, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSDB-5DB-5BP-1
Column length (m) 30.30.30.50.50.
Carrier gas  HeN2N2He
Substrate      
Column diameter (mm) 0.250.250.250.20.22
Phase thickness (μm) 1.0.250.250.320.25
Tstart (C) 50.60.60.60.60.
Tend (C) 290.280.240.220.220.
Heat rate (K/min) 10.3.3.5.2.
Initial hold (min) 1. 3.3. 
Final hold (min) 10. 3.5.20.
I 1281.1192.1243.1242.1221.
ReferenceBylaite and Meyer, 2006Chorianopoulos N., Evergets E., et al., 2006Dob, Dahmane, et al., 2006Esmaeili, Nematollahi, et al., 2006Gonny, Cavaleiro, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1DB-1HP-5HP-5SPB-1
Column length (m) 30.30.25.25.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.250.250.2
Tstart (C) 60.60.60.60.70.
Tend (C) 240.240.240.240.220.
Heat rate (K/min) 4.4.4.4.3.
Initial hold (min)      
Final hold (min)     15.
I 1255.1199.1242.1193.1211.
ReferenceRezazadeh, Hamedani, et al., 2006Rezazadeh, Hamedani, et al., 2006Rezazadeh, Hamedani, et al., 2006Rezazadeh, Hamedani, et al., 2006Salgueiro L.R., Pinto E., et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5MSDB-5CP Sil 5 CBSE-54
Column length (m) 30.30.30.25.50.
Carrier gas HeH2HeH2H2
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.250.25 0.27
Tstart (C) 60.50.40.80.50.
Tend (C) 280.285.230.270.300.
Heat rate (K/min) 4.4.36.10.5.
Initial hold (min) 5. 1.  
Final hold (min)      
I 1242.1237.1244.1214.1262.
ReferenceSaroglou, Dorizas, et al., 2006Vujisic L., Vuckovic I., et al., 2006Zeller and Rychlik, 2006Ziegenbein, Hanssen, et al., 2006Brantner, Pfeifhofer, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5RTX-1DB-1MDN-5HP-5
Column length (m) 30.60.30.30.30.
Carrier gas N2 N2HeHe
Substrate      
Column diameter (mm) 0.250.220.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.50.50.60.
Tend (C) 220.220.260.250.260.
Heat rate (K/min) 5.2.2.3.3.
Initial hold (min) 10. 3.  
Final hold (min)  20.5.  
I 1243.1218.1210.1240.1245.
ReferenceCioni, Flamini, et al., 2005Cozzani, Muselli, et al., 2005Dob T., Berramdane T., et al., 2005Dugo, Mondello, et al., 2005Javidnia, Miri, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5MSSE-54HP-5MS
Column length (m) 30.30.30.25.60.
Carrier gas HeHeHeH2He
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 50.50.60.50.60.
Tend (C) 250.250.250.250.200.
Heat rate (K/min) 4.4.4.4.2.
Initial hold (min) 5.5.2.  
Final hold (min) 15.15.20. 10.
I 1244.1243.1242.1194.1243.
ReferenceMahattanatawee, Goodner, et al., 2005Mahattanatawee, Goodner, et al., 2005Pino, Mesa, et al., 2005Simionatto, Porto, et al., 2005Smadja, Rondeau, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Mega 5MSSE-54SPB-1SPB-1HP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 40.60.70.70.60.
Tend (C) 240.260.220.220.280.
Heat rate (K/min) 3.2.3.3.3.
Initial hold (min) 2.5.   
Final hold (min)   15.15. 
I 1229.1239.1212.1211.1241.
ReferenceVerzera, Trozzi, et al., 2005Alma, Nitz, et al., 2004Antunes, Sevinate-Pinto, et al., 2004Cavaleiro, Salgueiro, et al., 2004Chorianopoulos, Kalpoutzakis, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5RSL-200HP-5HP-5
Column length (m) 30.30.30.25.30.
Carrier gas HeHeH2He 
Substrate      
Column diameter (mm) 0.250.250.320.20.25
Phase thickness (μm) 0.25 0.250.331.
Tstart (C) 60.60.40.60.-30.
Tend (C) 280.260.280.240.250.
Heat rate (K/min) 3.3.6.3.10.
Initial hold (min)   5. 1.
Final hold (min)   5.7. 
I 1192.1243.1258.1241.1246.
ReferenceChorianopoulos, Kalpoutzakis, et al., 2004Javidnia, Miri, et al., 2004Ngassoum, Ousmaila, et al., 2004Sartoratto, Machado, et al., 2004Siegmund, Derler, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5Optima 5DB-5RTX-1SPB-1
Column length (m) 50.25.30.60.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.250.250.220.25
Phase thickness (μm) 0.20.250.250.250.25
Tstart (C) 35.60.60.60.35.
Tend (C) 250.280.240.230.225.
Heat rate (K/min) 3.3.3.2.4.
Initial hold (min) 15.   5.
Final hold (min) 40.20. 45.20.
I 1245.1236.1245.1217.1218.
ReferenceStashenko, Jaramillo, et al., 2004Vérité, Nacer, et al., 2004Bader, Flamini, et al., 2003Cavalli, Tomi, et al., 2003Chisholm, Jell, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5HP-5MSCP Sil 5 CBDB-1
Column length (m) 30.30.30.60.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.40.
Tend (C) 240.240.280.280.325.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min)    10. 
Final hold (min)    60. 
I 1244.1244.1243.1211.1205.7
ReferenceFlamini, Luigi Cioni, et al., 2003Macchioni, Cioni, et al., 2003Mimica-Dukic, Kujundzic, et al., 2003Pino, Almora, et al., 2003Sun and Stremple, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5Mega 5MSHP-5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.40.60.50.
Tend (C) 280.280.240.275.280.
Heat rate (K/min) 3.3.3.4.3.
Initial hold (min)   2. 5.
Final hold (min)      
I 1242.1253.1229.1244.1242.
ReferenceTsiri, Kretsi, et al., 2003Tsiri, Kretsi, et al., 2003Verzera, Trozzi, et al., 2003Afsharypuor and Suleimany, 2002Economakis, Skaltsa, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5HP-1CP Sil 5 CBCP Sil 5 CB
Column length (m) 30.30.24.25.30.
Carrier gas  HeHeN2H2
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.250.170.250.25
Tstart (C) 50.60.60.60.60.
Tend (C) 280.260.250.280.280.
Heat rate (K/min) 3.4.4.4.2.
Initial hold (min) 5. 2.6.10.
Final hold (min)   20. 40.
I 1193.1242.1211.1207.1207.
ReferenceEconomakis, Skaltsa, et al., 2002Javidnia, Miri, et al., 2002Nath, Sarma, et al., 2002Pino, Marbot, et al., 2002Pino, Marbot, et al., 2002, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-5RTX-5HP-5HP-5HP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 45.45.60.60.60.
Tend (C) 250.250.280.380.280.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min) 6.6.5. 5.
Final hold (min)      
I 1242.1254.1240.1241.1242.
ReferenceShellie, Mondello, et al., 2002Shellie, Mondello, et al., 2002Aligiannis, Kalpoutzakis, et al., 2001Couladis, Tsortanidou, et al., 2001Giamakis, Kretsi, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-5HP-5DB-5CP Sil 5 CB
Column length (m) 60.50.50.30.50.
Carrier gas HeHeHeH2He
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.4
Tstart (C) 50.50.50.60.60.
Tend (C) 250.250.250.240.280.
Heat rate (K/min) 2.52.52.53.3.
Initial hold (min) 5.5.5. 10.
Final hold (min)     60.
I 1226.1242.1193.1242.1211.
ReferenceGuilliard, Delgado, et al., 2001Guilliard, Delgado, et al., 2001Guilliard, Delgado, et al., 2001Nogueira, Bittrich, et al., 2001Pino and Marbot, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSBPX-5BPX-5HP-5HP-5
Column length (m) 30.50.50.30.30.
Carrier gas HeH2H2HeHe
Substrate      
Column diameter (mm) 0.250.220.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.40.40.
Tend (C) 280.180.180.200.200.
Heat rate (K/min) 4.4.4.2.2.
Initial hold (min) 5.5.5.5.5.
Final hold (min)  5.5.20.20.
I 1241.1271.1222.1254.1195.
ReferenceSkaltsa, Mavrommati, et al., 2001Zabaras and Wyllie, 2001Zabaras and Wyllie, 2001Kim, Thuy, et al., 2000Kim, Thuy, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5DB-5Mega 5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.40.70.70.40.
Tend (C) 200.200.230.230.240.
Heat rate (K/min) 2.2.2.2.3.
Initial hold (min) 5.5.  2.
Final hold (min) 20.20.   
I 1251.1186.1234.1243.1229.
ReferenceKim, Thuy, et al., 2000Kim, Thuy, et al., 2000Song, Sawamura, et al., 2000Song, Sawamura, et al., 2000, 2Verzera, la Rosa, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Mega 5MSOV-101DB-1CP Sil 5 CBOV-1
Column length (m) 30.25.30.25.25.
Carrier gas HeN2 He 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.25 0.25 0.3
Tstart (C) 40.50.50.60.50.
Tend (C) 240.200.220.260.200.
Heat rate (K/min) 3.5.3.5.3.
Initial hold (min) 2. 3. 1.
Final hold (min)     20.
I 1229.1223.1211.1222.1204.
ReferenceVerzera, Trozzi, et al., 2000Menut, Bessiere, et al., 1999Muselli, Hoi, et al., 1999Weyerstahl, Marschall, et al., 1999Bicchi, Rubiolo, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1DB-5Methyl SiliconeOV-101OV-101
Column length (m) 50.30.25.15.50.
Carrier gas HeHeHe N2
Substrate      
Column diameter (mm) 0.220.260.20.320.25
Phase thickness (μm) 0.250.250.3  
Tstart (C) 60.50.40.35.80.
Tend (C) 230.225.200.250.200.
Heat rate (K/min) 2.2.2.6.2.
Initial hold (min)    3. 
Final hold (min) 35.20.   
I 1213.1239.1227.1220.1220.
ReferenceMariotti, Tomi, et al., 1997Sagrero-Nieves, Bartley, et al., 1997Píry, Príbela, et al., 1995Chisholm, Guiher, et al., 1994Yang, Sugisawa, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase OV-101HP-1OV-101
Column length (m) 50.50.50.
Carrier gas N2HeH2
Substrate    
Column diameter (mm) 0.250.320.32
Phase thickness (μm)  1.05 
Tstart (C) 80.40.50.
Tend (C) 200.230.200.
Heat rate (K/min) 2.2.2.
Initial hold (min)    
Final hold (min)  40. 
I 1224.1187.1213.
ReferenceYang, Sugisawa, et al., 1992Tang, Zhang, et al., 1990Pieribattesti, Smadja, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Benkaci-Ali, Baaliouamer, et al., 2007
Benkaci-Ali, F.; Baaliouamer, A.; Meklati, B.Y.; Chemat, F., Chemical composition of seed essential oils from Algerian Nigella sativa extracted by microwave and hydrodistillation, Flavour Fragr. J., 2007, 22, 2, 148-153, https://doi.org/10.1002/ffj.1773 . [all data]

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Duquesnoy, E.; Castola, V.; Casanova, J., Composition and chemical variability of the twig oil of Abies alba Miller from Corsica, Flavour Fragr. J., 2007, 22, 4, 293-299, https://doi.org/10.1002/ffj.1796 . [all data]

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Flamini, G.; Cioni, P.L.; Morelli, I.; Bader, A., Essential oils of the aerial parts of three Salvia species from Jordan: Salvia lanigera, S. spinosa and S. syriaca, Food Chem., 2007, 100, 2, 732-735, https://doi.org/10.1016/j.foodchem.2005.10.032 . [all data]

Kundakovic, Fokialakis, et al., 2007
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Muselli, Rossi, et al., 2007
Muselli, A.; Rossi, P.-G.; Desjobert, J.-M.; Bernardini, A.-F.; Berti, L.; Costa, J., Chemical composition and antibacterial activity of Otanthus maritimus (L.) Hoffmanns. Link essential oils from Corsica, Flavour Fragr. J., 2007, 22, 3, 217-223, https://doi.org/10.1002/ffj.1787 . [all data]

Politeo, Jukic, et al., 2007
Politeo, O.; Jukic, M.; Milos, M., Chemical composition and antioxidant capacity of free volatile aglycones from basil (Ocimum basilicum L.) compared with its essential oil, Food Chem., 2007, 101, 1, 379-385, https://doi.org/10.1016/j.foodchem.2006.01.045 . [all data]

Rocha, Coelho, et al., 2007
Rocha, S.M.; Coelho, E.; Zrostlikova, J.; Delgadillo, I.; Coimbra b, M.A., Comprehensive two-dimensional gas chromatography with time-of-flight mass spectrometry of monoterpenoids as a powerful tool for grape origin traceability, J. Chromatogr. A, 2007, 1161, 1-2, 292-299, https://doi.org/10.1016/j.chroma.2007.05.093 . [all data]

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Vagionas, K.; Ngassapa, O.; Runyoro, D.; Graikou, K.; Gortzi, O.; Chinou, I., Chemical analysis of edible aromatic plants growing in Tanzania, Food Chem., 2007, 105, 4, 1711-1717, https://doi.org/10.1016/j.foodchem.2007.05.029 . [all data]

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Bousmaha, L.; Boti, J.B.; Bekkara, F.A.; Castola, V.; Casanova, J., Infraspecific chemical variability of the essential oil of Lavandula dentata L. from Algeria, Flavour Fragr. J., 2006, 21, 2, 368-372, https://doi.org/10.1002/ffj.1659 . [all data]

Bylaite and Meyer, 2006
Bylaite, E.; Meyer, A.S., · Characterisation of volatile aroma compounds of orange juices by three dynamic and static headspace gas chromatography techniques, Eur. Food Res. Technol., 2006, 222, 1-2, 176-184, https://doi.org/10.1007/s00217-005-0141-8 . [all data]

Chorianopoulos N., Evergets E., et al., 2006
Chorianopoulos N.; Evergets E.; Mallouchos A.; Kalpoutzakis E.; Nychas G.J.; Haroutounian S.A., Characterization of the essential oil volatiles of Satureja thymbra and Satureja parnassica: Influence of harvesting time and antimicrobial activity, J. Agric. Food Chem., 2006, 54, 8, 3139-3145, https://doi.org/10.1021/jf053183n . [all data]

Dob, Dahmane, et al., 2006
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Esmaeili, Nematollahi, et al., 2006
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Gonny, Cavaleiro, et al., 2006
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Zeller and Rychlik, 2006
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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References