Boranamine


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
11.0 ± 0.1EIKwon and McGee, 1970RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
B+19.2 ± 0.05?EIRothgery, McGee, et al., 1975LLK
HB+18.0 ± 0.1NH3EIRothgery, McGee, et al., 1975LLK
H2B+17.2 ± 0.2NH2EIRothgery, McGee, et al., 1975LLK

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 NH stretch 3451 gas IR Gerry, Lewis-Bevan, et al., 1985
1 NH stretch 3437 Ar IR Carpenter and Ault, 1991
1 NH stretch 3439 N2 IR Carpenter and Ault, 1991
2 BH stretch 2495 gas IR Gerry, Lewis-Bevan, et al., 1985
2 BH stretch 2499 Ar IR Carpenter and Ault, 1991
2 BH stretch 2506 N2 IR Carpenter and Ault, 1991
3 NH2 scissors 1625 gas IR Gerry, Lewis-Bevan, et al., 1985
3 NH2 scissors 1620 Ar IR Carpenter and Ault, 1991
3 NH2 scissors 1617 N2 IR Carpenter and Ault, 1991
4 BN stretch 1337.47 gas IR Gerry, Lewis-Bevan, et al., 1985
4 BN stretch 1334 Ar IR Carpenter and Ault, 1991
4 BN stretch 1346 N2 IR Carpenter and Ault, 1991
5 BH2 scissors 1225 gas IR Gerry, Lewis-Bevan, et al., 1985
a2 6 Torsion 820 T gas IR Anderson, Gerry, et al.
b1 7 NH2 wag 1005 gas IR Gerry, Lewis-Bevan, et al., 1985
7 NH2 wag 1002 Ar IR Carpenter and Ault, 1991
7 NH2 wag 1001 N2 IR Carpenter and Ault, 1991
8 BH2 wag 612 s gas IR Anderson, Gerry, et al.
8 BH2 wag 608 s Ar IR Carpenter and Ault, 1991
8 BH2 wag 647 s N2 IR Carpenter and Ault, 1991
b2 9 NH stretch 3534 gas IR Gerry, Lewis-Bevan, et al., 1985
9 NH stretch 3519 Ar IR Carpenter and Ault, 1991
9 NH stretch 3523 N2 IR Carpenter and Ault, 1991
10 BH stretch 2564 gas IR Gerry, Lewis-Bevan, et al., 1985
10 BH stretch 2568 Ar IR Carpenter and Ault, 1991
10 BH stretch 2568 N2 IR Carpenter and Ault, 1991
11 NH2 rock 1131 gas IR Gerry, Lewis-Bevan, et al., 1985
11 NH2 rock 1120 Ar IR Carpenter and Ault, 1991
11 NH2 rock 1122 N2 IR Carpenter and Ault, 1991
12 BH2 rock 742 w gas IR Anderson, Gerry, et al.

Additional references: Jacox, 1994, page 309; Sugie, Takeo, et al., 1979; Vormann, Dreizler, et al., 1991

Notes

wWeak
sStrong
TTentative assignment or approximate value

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kwon and McGee, 1970
Kwon, C.T.; McGee, H.A., Jr., Cryochemical preparation of monomeric aminoborane, Inorg. Chem., 1970, 9, 2458. [all data]

Rothgery, McGee, et al., 1975
Rothgery, E.F.; McGee, H.A., Jr.; Pusatcioglu, S., Aminodifluoroborane, Inorg. Chem., 1975, 14, 2236. [all data]

Gerry, Lewis-Bevan, et al., 1985
Gerry, M.C.L.; Lewis-Bevan, W.; Merer, A.J.; Westwood, N.P.C., The infrared spectrum of gaseous aminoborane, H2N«58875»BH2: Location of the fundamentals and rotational structure in the 401 band (BN stretching vibration at 1337 cm-1), J. Mol. Spectrosc., 1985, 110, 1, 153, https://doi.org/10.1016/0022-2852(85)90219-X . [all data]

Carpenter and Ault, 1991
Carpenter, J.D.; Ault, B.S., Infrared matrix isolation characterization of aminoborane and related compounds, J. Phys. Chem., 1991, 95, 9, 3502, https://doi.org/10.1021/j100162a013 . [all data]

Anderson, Gerry, et al.
Anderson, W.D.; Gerry, M.C.L.; Lewis-Bevan, W.; Merer, A.J.; Steunenberg, D.M., 41st Symposium on Molecular Spectroscopy, Columbus, Ohio, June 1986.. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Sugie, Takeo, et al., 1979
Sugie, M.; Takeo, H.; Matsumura, C., Microwave spectrum of aminoborane, BH2NH2, Chem. Phys. Lett., 1979, 64, 3, 573, https://doi.org/10.1016/0009-2614(79)80247-X . [all data]

Vormann, Dreizler, et al., 1991
Vormann, K.; Dreizler, H.; Doose, J.; Guarnieri, A., Z. Naturforsch., 1991, 46a, 770. [all data]


Notes

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