Water

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-241.826 ± 0.040kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Δfgas-241.83kJ/molReviewChase, 1998Data last reviewed in March, 1979
Quantity Value Units Method Reference Comment
gas,1 bar188.835 ± 0.010J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
gas,1 bar188.84J/mol*KReviewChase, 1998Data last reviewed in March, 1979

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 500. to 1700.1700. to 6000.
A 30.0920041.96426
B 6.8325148.622053
C 6.793435-1.499780
D -2.5344800.098119
E 0.082139-11.15764
F -250.8810-272.1797
G 223.3967219.7809
H -241.8264-241.8264
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in March, 1979 Data last reviewed in March, 1979

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-285.830 ± 0.040kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Δfliquid-285.83kJ/molReviewChase, 1998Data last reviewed in March, 1979
Quantity Value Units Method Reference Comment
liquid69.95 ± 0.03J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
liquid,1 bar69.95J/mol*KReviewChase, 1998Data last reviewed in March, 1979

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 500.
A -203.6060
B 1523.290
C -3196.413
D 2474.455
E 3.855326
F -256.5478
G -488.7163
H -285.8304
ReferenceChase, 1998
Comment Data last reviewed in March, 1979

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil373.17 ± 0.04KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Ptriple0.0061barN/ASato, Watanabe, et al., 1991Uncertainty assigned by TRC = 1.×10-7 bar; TRC
Quantity Value Units Method Reference Comment
Tc647. ± 2.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Pc220.64barN/ASato, Watanabe, et al., 1991Uncertainty assigned by TRC = 0.05 bar; TRC
Pc220.60barN/ABrunner, 1990Uncertainty assigned by TRC = 0.12 bar; TRC
Pc220.46barN/AMorita, Sato, et al., 1989Uncertainty assigned by TRC = 0.25 bar; based on analysis of their obs. PVT and vapor pressure data some other data from literature; TRC
Pc220.64barN/AAleksandrov, 1986Uncertainty assigned by TRC = 0.30 bar; TRC
Pc220.64barN/ASifner, 1985Uncertainty assigned by TRC = 0.0001 bar; TRC
Quantity Value Units Method Reference Comment
ρc17.9mol/lN/ASato, Watanabe, et al., 1991Uncertainty assigned by TRC = 0.2 mol/l; TRC
ρc17.91mol/lN/AMorita, Sato, et al., 1989Uncertainty assigned by TRC = 0.083 mol/l; based on analysis of obs. PVT and vapor pressure data; TRC
ρc17.9mol/lN/AAleksandrov, 1986Uncertainty assigned by TRC = 0.2 mol/l; TRC
ρc17.9mol/lN/ASifner, 1985Uncertainty assigned by TRC = 0.2 mol/l; TRC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
379. to 573.3.55959643.748-198.043Liu and Lindsay, 1970Coefficents calculated by NIST from author's data.
273. to 303.5.402211838.675-31.737Bridgeman and Aldrich, 1964Coefficents calculated by NIST from author's data.
304. to 333.5.203891733.926-39.485Bridgeman and Aldrich, 1964Coefficents calculated by NIST from author's data.
334. to 363.5.07681659.793-45.854Bridgeman and Aldrich, 1964Coefficents calculated by NIST from author's data.
344. to 373.5.083541663.125-45.622Bridgeman and Aldrich, 1964Coefficents calculated by NIST from author's data.
293. to 343.6.209632354.7317.559Gubkov, Fermor, et al., 1964Coefficents calculated by NIST from author's data.
255.9 to 373.4.65431435.264-64.848Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Chlorine anion + Water = (Chlorine anion • Water)

By formula: Cl- + H2O = (Cl- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr60. ± 20.kJ/molAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Δr81. ± 10.J/mol*KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr40. ± 20.kJ/molAVGN/AAverage of 9 values; Individual data points

(Hydronium cation • 2Water) + Water = (Hydronium cation • 3Water)

By formula: (H3O+ • 2H2O) + H2O = (H3O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr73. ± 4.kJ/molAVGN/AAverage of 9 out of 16 values; Individual data points
Quantity Value Units Method Reference Comment
Δr118. ± 8.J/mol*KAVGN/AAverage of 6 out of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Δr39.kJ/molFABierbaum, Golde, et al., 1976gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
38.300.HPMSArifov, Pozharov, et al., 1971gas phase; M
38.296.SAMSPuckett and Teague, 1971gas phase; M
35.300.PHPMSGood, Durden, et al., 1970gas phase; M
35.307.PHPMSGood, Durden, et al., 1970, 2gas phase; M

CH2OH+ + Water = (CH2OH+ • Water)

By formula: CH3O+ + H2O = (CH3O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr119.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; switching reaction(H3O+)H2O; Davidson, Sunner J., et al., 1979, Lias, Liebman, et al., 1984; M
Δr117.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2O)2H+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Yamdagni and Kebarle, 1976, Wolf, Staley, et al., 1977; M
Δr119.kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr120.kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr120.kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KN/ABerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr113.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr112.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr85.4kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr85.8kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

Hydronium cation + Water = (Hydronium cation • Water)

By formula: H3O+ + H2O = (H3O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr136. ± 9.kJ/molAVGN/AAverage of 7 out of 14 values; Individual data points
Quantity Value Units Method Reference Comment
Δr120. ± 30.J/mol*KAVGN/AAverage of 5 out of 7 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.300.HPMSArifov, Pozharov, et al., 1971gas phase; M

(Hydronium cation • Water) + Water = (Hydronium cation • 2Water)

By formula: (H3O+ • H2O) + H2O = (H3O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr84. ± 5.kJ/molAVGN/AAverage of 7 out of 14 values; Individual data points
Quantity Value Units Method Reference Comment
Δr94. ± 20.J/mol*KAVGN/AAverage of 5 out of 7 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
36.300.HPMSArifov, Pozharov, et al., 1971gas phase; M

(Hydronium cation • 3Water) + Water = (Hydronium cation • 4Water)

By formula: (H3O+ • 3H2O) + H2O = (H3O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56. ± 20.kJ/molAVGN/AAverage of 6 out of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Δr100. ± 20.J/mol*KAVGN/AAverage of 5 out of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr23.kJ/molFABierbaum, Golde, et al., 1976gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
24.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M
23.296.SAMSPuckett and Teague, 1971gas phase; M
21.300.PHPMSGood, Durden, et al., 1970gas phase; M
21.307.PHPMSGood, Durden, et al., 1970, 2gas phase; M
29.300.HPMSArifov, Pozharov, et al., 1971gas phase; M

NO3 anion + Water = (NO3 anion • Water)

By formula: NO3- + H2O = (NO3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.09 ± 0.84kJ/molN/ALee, Keesee, et al., 1980gas phase; B,M
Δr59.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr51.88kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr61.9kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr80.3kJ/molFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr89.1J/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Δr79.9J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr30.1 ± 1.3kJ/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr30.5 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
Δr28.0kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
37.250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
28.296.FAFehsenfeld and Ferguson, 1974gas phase; M
29.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

Nitrogen oxide anion + Water = (Nitrogen oxide anion • Water)

By formula: NO2- + H2O = (NO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr65. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr84.9J/mol*KPHPMSSieck, 1985gas phase; M
Δr83.7J/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO2-)H2O; Lee, Keesee, et al., 1980; M
Δr99.6J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr88.J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr35.6 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Δr35.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr34. ± 24.kJ/molEndoPaulson and Dale, 1982gas phase; B
Δr33.9 ± 0.84kJ/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr33.5kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.296.FAFehsenfeld and Ferguson, 1974gas phase; M
35.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(Sodium ion (1+) • 3Water) + Water = (Sodium ion (1+) • 4Water)

By formula: (Na+ • 3H2O) + H2O = (Na+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr55. ± 4.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr99. ± 10.J/mol*KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
54.8 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M
27.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Chlorine anion • 2Water) + Water = (Chlorine anion • 3Water)

By formula: (Cl- • 2H2O) + H2O = (Cl- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr93.7J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr97.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr21. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Iodide + Water = (Iodide • Water)

By formula: I- + H2O = (I- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43. ± 3.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr64.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr80.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr68.2J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr23. ± 1.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • Water) + Water = (Iodide • 2Water)

By formula: (I- • H2O) + H2O = (I- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.4 ± 0.84kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Δr39.7kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr39.7 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr41. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr41. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr73.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr84.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr79.5J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr17. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Chlorine anion • Water) + Water = (Chlorine anion • 2Water)

By formula: (Cl- • H2O) + H2O = (Cl- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr53. ± 5.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr85.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr87.0J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr27.2kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr27. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr27.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr28.kJ/molFAFehsenfeld and Ferguson, 1974gas phase; M

(CH2OH+ • Water) + Water = (CH2OH+ • 2Water)

By formula: (CH3O+ • H2O) + H2O = (CH3O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr90.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr83.3kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr82.8kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr110.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr110.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr50.6kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2OH+ • 2Water) + Water = (CH2OH+ • 3Water)

By formula: (CH3O+ • 2H2O) + H2O = (CH3O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr73.6kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr70.7kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr71.1kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr109.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr109.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr38.kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(Hydronium cation • 4Water) + Water = (Hydronium cation • 5Water)

By formula: (H3O+ • 4H2O) + H2O = (H3O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr50. ± 8.kJ/molAVGN/AAverage of 5 out of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr102. ± 20.J/mol*KAVGN/AAverage of 4 out of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(Sodium ion (1+) • Water) + Water = (Sodium ion (1+) • 2Water)

By formula: (Na+ • H2O) + H2O = (Na+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr79. ± 8.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
82.0 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 2Water) + Water = (Sodium ion (1+) • 3Water)

By formula: (Na+ • 2H2O) + H2O = (Na+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr62.3kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Δr66.1kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr69.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr67.4kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KHPMSTang, Lian, et al., 1976gas phase; M
Δr91.6J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr92.0J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr40.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
70.3 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
39.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Chlorine anion • 3Water) + Water = (Chlorine anion • 4Water)

By formula: (Cl- • 3H2O) + H2O = (Cl- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr40.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr44. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr45.6 ± 2.9kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Δr46.4 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr104.J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr108.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr16. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr14.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr14.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr17. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Nitrogen oxide anion • Water) + Water = (Nitrogen oxide anion • 2Water)

By formula: (NO2- • H2O) + H2O = (NO2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr54.0 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr54.0 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr56.9kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr99.2J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr25.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr24. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr24.3kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr26. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.296.FAFehsenfeld and Ferguson, 1974gas phase; M
24.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(NH4+ • Water) + Water = (NH4+ • 2Water)

By formula: (H4N+ • H2O) + H2O = (H4N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.8kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; ΔrH?, Entropy change is questionable, appear out of line; M
Δr57.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small; M
Δr61.5kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; ΔrH?, Entropy change is questionable, appear out of line; M
Δr92.0J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small; M
Δr91.6J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr37.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.414.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small; M

C16H34OP2Ru (solution) + Diphenylamine (solution) = C28H43NP2Ru (solution) + Water (solution)

By formula: C16H34OP2Ru (solution) + C12H11N (solution) = C28H43NP2Ru (solution) + H2O (solution)

Quantity Value Units Method Reference Comment
Δr5.0 ± 0.4kJ/molEqSBryndza, Fong, et al., 1987solvent: Tetrahydrofuran; In a series of reactions involving similar ruthenium complexes, the reaction enthalpy was identified with the reaction Gibbs energy, since the entropy values are expected to be small Bryndza, Fong, et al., 1987. For this reaction, however a van't Hoff plot could be used. Temperature range: 293-328 K; MS
Δr19.7kJ/molEqSBryndza, Fong, et al., 1987solvent: Benzene; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987; MS

MeCO2 anion + Water = (MeCO2 anion • Water)

By formula: C2H3O2- + H2O = (C2H3O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.6 ± 3.3kJ/molTDAsWincel, 2008gas phase; B
Δr66.5 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Δr66.9 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Δr68.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr66.1kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.9J/mol*KPHPMSMeot-ner, 1988gas phase; M
Δr94.1J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; ion given as C2H3COO- in paper by error; M
Quantity Value Units Method Reference Comment
Δr38. ± 5.9kJ/molN/AWincel, 2008gas phase; B
Δr39.8kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Δr39. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B
Δr39.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(Iodide • 2Water) + Water = (Iodide • 3Water)

By formula: (I- • 2H2O) + H2O = (I- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.9 ± 1.3kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Δr36. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr38.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr39. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr39. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr87.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr89.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr12.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr13.0 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

C2H5NaO (cr) + 0.5(Sulfuric Acid • 1100Water) (solution) = Ethanol (solution) + 0.5sodium sulphate (solution)

By formula: C2H5NaO (cr) + 0.5(H2O4S • 1100H2O) (solution) = C2H6O (solution) + 0.5Na2O4S (solution)

Quantity Value Units Method Reference Comment
Δr-118.4 ± 3.8kJ/molRSCBlanchard, Joly, et al., 1974solvent: Sulphuric acid aqueous solution; The reaction enthalpy relies on -10.6 kJ/mol for the enthalpy of solution of EtOH(l) and on 9.97±0.04 for the enthalpy of solution of Na2SO4(cr) Blanchard, Joly, et al., 1974. A value of -490.8 ± 5.9 kJ/mol was derived in Blanchard, Joly, et al., 1974 for the enthalpy of formation. However, this value is affected by a calculation error. Also, the authors have not accounted for the acid dilution (this correction could not be made in the present database, due to lack of information). These problems were also noted in the data compilations Tel'noi and Rabinovich, 1980 and Wagman, Evans W.H., et al., 1982, where the values quoted for the enthalpy of formation, which rely on the experimental data reported in Blanchard, Joly, et al., 1974, are -410.0 ± 4.2 kJ/mol and -413.8 kJ/mol, respectively. See also comments in Liebman, Martinho Simões, et al., 1995; MS

Potassium ion (1+) + Water = (Potassium ion (1+) • Water)

By formula: K+ + H2O = (K+ • H2O)

Quantity Value Units Method Reference Comment
Δr70.7kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr81. ± 10.kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Δr74.9kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr83.3J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr89.1J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Δr90.4J/mol*KHPMSSearles and Kebarle, 1969gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
38.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
2.840.MSChupka, 1959gas phase; Knudsen cell, 840+-50K; M

(Bromine anion • Water) + Water = (Bromine anion • 2Water)

By formula: (Br- • H2O) + H2O = (Br- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.5 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr51.04kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr51.5 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr51.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr75.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr95.8J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr26. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr23. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr22.6kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr24. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

CN- + Water = (CN- • Water)

By formula: CN- + H2O = (CN- • H2O)

Quantity Value Units Method Reference Comment
Δr53.1 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Δr61.1 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B,B,M,M
Δr57.74kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr61.1kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr75.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Δr82.0J/mol*KPHPMSMeot-ner, 1988gas phase; M
Δr82.0J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Δr82.8J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr30.5 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Δr36. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Δr36. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B
Δr33.1kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

(Bromine anion • 2Water) + Water = (Bromine anion • 3Water)

By formula: (Br- • 2H2O) + H2O = (Br- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.7 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr28.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr48.1 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr48.1 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr104.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr20. ± 4.6kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr17. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr17.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr18. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Nitrogen oxide anion • 2Water) + Water = (Nitrogen oxide anion • 3Water)

By formula: (NO2- • 2H2O) + H2O = (NO2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.1 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr43.5 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr43.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr49.0kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr88.7J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr18.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr17. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr17.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr19. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Bromine anion + Water = (Bromine anion • Water)

By formula: Br- + H2O = (Br- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr53.14kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr49.0 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr52.72kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Δr53.1kJ/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr61.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr77.0J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Δr82.8J/mol*KMSBurdett and Hayhurst, 1982gas phase; FLAME SOURCE, 1600 K; M
Quantity Value Units Method Reference Comment
Δr30.5 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr29. ± 12.kJ/molTDAsBurdett and Hayhurst, 1982gas phase; B
Δr29. ± 8.4kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

CH2N+ + Water = (CH2N+ • Water)

By formula: CH2N+ + H2O = (CH2N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr115.kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr124.kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr120.J/mol*KN/ABerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
87.9300.ICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

Hydroxyl anion + Water = (Hydroxyl anion • Water)

By formula: HO- + H2O = (HO- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr113. ± 4.kJ/molAVGN/AAverage of 3 out of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr118.J/mol*KPHPMSPaul and Kebarle, 1990gas phase; M
Δr91.2J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr87.0J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Δr79.9J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M

HO- + Water = (HO- • Water)

By formula: HO- + H2O = (HO- • H2O)

Quantity Value Units Method Reference Comment
Δr120. ± 30.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr80.3 ± 4.2kJ/molTDAsPaul and Kebarle, 1990gas phase; B
Δr84.1 ± 6.7kJ/molTDEqMeot-Ner and Sieck, 1986gas phase; B
Δr83.7 ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; B
Δr77.82kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

(Fluorine anion • Water) + Water = (Fluorine anion • 2Water)

By formula: (F- • H2O) + H2O = (F- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr80.3 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Stated electron affinity is the Vertical Detachment Energy; B,M
Δr69.5 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr69.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr78.2J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr52.3 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Stated electron affinity is the Vertical Detachment Energy; B
Δr46.0 ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr46.02kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

(MeCO2 anion • 2Water) + Water = (MeCO2 anion • 3Water)

By formula: (C2H3O2- • 2H2O) + H2O = (C2H3O2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.4 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Δr51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr49.4kJ/molPHPMSMeot-ner, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AMeot-ner, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr24.4kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr25.kJ/molPHPMSMeot-ner, 1988gas phase; Entropy change calculated or estimated; M

(Bromine anion • 3Water) + Water = (Bromine anion • 4Water)

By formula: (Br- • 3H2O) + H2O = (Br- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.02 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr26. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr45.6 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr112.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr13.0 ± 2.9kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr12.1kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

O3P- + Water = (O3P- • Water)

By formula: O3P- + H2O = (O3P- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0 ± 1.3kJ/molTDAsKeesee and Castleman Jr., 1989gas phase; Not (HO)2PO2-. See also Blades, Ho, et al., 1996 : (HO)2PO2- -> PO3- + HOH, Eact ca. 55 kcal/mol.; B,M,M
Δr52.7kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Δr92.9J/mol*KHPMSKeesee and Castleman Jr., 1989gas phase; M
Δr87.0J/mol*KHPMSKeesee and Castleman Jr., 1989gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr26. ± 5.0kJ/molTDAsKeesee and Castleman Jr., 1989gas phase; Not (HO)2PO2-. See also Blades, Ho, et al., 1996 : (HO)2PO2- -> PO3- + HOH, Eact ca. 55 kcal/mol.; B
Δr27.kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M

Sodium ion (1+) + Water = (Sodium ion (1+) • Water)

By formula: Na+ + H2O = (Na+ • H2O)

Quantity Value Units Method Reference Comment
Δr100.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr87.9 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Δr82.0 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Δr95.0 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr111.kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr92.J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
94.6 (+7.5,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
65.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Potassium ion (1+) • 2Water) + Water = (Potassium ion (1+) • 3Water)

By formula: (K+ • 2H2O) + H2O = (K+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr55.2kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr96.2J/mol*KHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(MeCO2 anion • Water) + Water = (MeCO2 anion • 2Water)

By formula: (C2H3O2- • H2O) + H2O = (C2H3O2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Δr57.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr53.6kJ/molPHPMSMeot-ner, 1988gas phase; M
Δr54.0kJ/molPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr79.9J/mol*KPHPMSMeot-ner, 1988gas phase; M
Δr85.8J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr29.3kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Δr28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(Chlorine anion • 6Water) + Water = (Chlorine anion • 7Water)

By formula: (Cl- • 6H2O) + H2O = (Cl- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B
Δr28.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr34.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr8.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Rubidium ion (1+) + Water = (Rubidium ion (1+) • Water)

By formula: Rb+ + H2O = (Rb+ • H2O)

Quantity Value Units Method Reference Comment
Δr66.5kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr66.9kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr84.1J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
39.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(NO3 anion • Water) + Water = (NO3 anion • 2Water)

By formula: (NO3- • H2O) + H2O = (NO3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr59.8kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr127.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr21.8 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M
21.296.FAFehsenfeld and Ferguson, 1974gas phase; M

C4H6N+ + Water = (C4H6N+ • Water)

By formula: C4H6N+ + H2O = (C4H6N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr58.6kJ/molPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr57.7kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Δr67.kJ/molPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr97.5J/mol*KPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr92.0J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Δr130.J/mol*KN/AMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.344.PHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M

C2H2F3O2+ + Water = (C2H2F3O2+ • Water)

By formula: C2H2F3O2+ + H2O = (C2H2F3O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr118.kJ/molICRLarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr97.5J/mol*KN/ALarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
89.5309.ICRLarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C4H5O+ + Water = (C4H5O+ • Water)

By formula: C4H5O+ + H2O = (C4H5O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr42.7kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Δr67.kJ/molPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr82.4J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Δr130.J/mol*KN/AMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.382.PHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M

(Fluorine anion • 2Water) + Water = (Fluorine anion • 3Water)

By formula: (F- • 2H2O) + H2O = (F- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr64.0 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr57.3 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr57.3 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr85.4J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr35. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr32. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr31.8kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

(Hydroxyl anion • Water) + Water = (Hydroxyl anion • 2Water)

By formula: (HO- • H2O) + H2O = (HO- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr73.6kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr75.kJ/molCIDHierl and Paulson, 1984gas phase; M
Δr74.9kJ/molHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Δr68.6kJ/molPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Δr96.kJ/molCIDDePaz, Giardini, et al., 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr88.7J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Δr80.8J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M

C2H4F3O+ + Water = (C2H4F3O+ • Water)

By formula: C2H4F3O+ + H2O = (C2H4F3O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr128.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
97.9309.ICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to H2O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)12.621 ± 0.002eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)691.kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity660.0kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
12.65 ± 0.05EISnow and Thomas, 1990LL
12.6188 ± 0.0009PIPage, Larkin, et al., 1988LL
12.6223 ± 0.0003PEReutt, Wang, et al., 1986LBLHLM
12.6 ± 0.1EIGrade, Wienecke, et al., 1983LBLHLM
12.63 ± 0.03EILefaivre and Marmet, 1978LLK
12.612SGurtler, Saile, et al., 1977LLK
12.627PEBotter and Carlier, 1977LLK
12.616PEKronebusch and Berkowitz, 1976LLK
12.624PEDixon, Duxbury, et al., 1976LLK
12.615 ± 0.001PEKarlsson, Mattson, et al., 1975LLK
12.6PEDebies and Rabalais, 1975LLK
12.6PIRabalais, Debies, et al., 1974LLK
12.615 ± 0.001PEBergmark, Karlsson, et al., 1974LLK
12.619PERobin and Kuebler, 1973LLK
12.7EIMorrison and Traeger, 1973LLK
12.619 ± 0.006SKatayama, Huffman, et al., 1973LLK
12.62PEPotts and Price, 1972LLK
12.624PEAsbrink and Rabalais, 1971LLK
12.65CICermak, 1968RDSH
12.62 ± 0.01PEBrundle and Turner, 1968RDSH
12.59 ± 0.01PIDibeler, Walker, et al., 1966RDSH
12.614 ± 0.005PIBrehm, 1966RDSH
12.597 ± 0.010PINicholson, 1965RDSH
12.60 ± 0.01EIFrost and McDowell, 1958RDSH
12.62 ± 0.02SPrice, 1936RDSH
12.62PEKimura, Katsumata, et al., 1981Vertical value; LLK
11.8PECampbell, Liesegang, et al., 1979Vertical value; LLK
12.61PEBenoit and Harrison, 1977Vertical value; LLK
12.61PEWieczorek, Koenig, et al., 1975Vertical value; LLK
12.60 ± 0.02PEBanna and Shirley, 1975Vertical value; LLK
12.62PESchweig and Thiel, 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
H+16.95 ± 0.05OHEILefaivre and Marmet, 1978LLK
H+18.7 ± 0.05OH(X2P)EIAppell and Durup, 1973LLK
H+16.0 ± 0.3OH-EICottin, 1959RDSH
H+19.6 ± 0.25OHEICottin, 1959RDSH
HO+18.08 ± 0.05HEILefaivre and Marmet, 1978LLK
HO+18.115 ± 0.008HPIMcCulloh, 1976LLK
HO+18.2HEIMorrison and Traeger, 1973LLK
HO+18.05HPIDibeler, Walker, et al., 1966RDSH
HO+18.2 ± 0.1HEIFoner and Hudson, 1956RDSH
H2+20.7 ± 0.4OEIEhrhardt and Kresling, 1967RDSH
O+19.0H2EIMorrison and Traeger, 1973LLK
O+26.82HEIMorrison and Traeger, 1973LLK
O+19.0 ± 0.2H2EIEhrhardt and Kresling, 1967RDSH
O+26.5 ± 0.32H?EIEhrhardt and Kresling, 1967RDSH
O+29.15 ± 0.252H?EICottin, 1959RDSH

De-protonation reactions

HO- + Hydrogen cation = Water

By formula: HO- + H+ = H2O

Quantity Value Units Method Reference Comment
Δr1633.141 ± 0.042kJ/molD-EASmith, Kim, et al., 1997gas phase; Given: 14741.02(3) cm-1. dHacid(0K) = 389.11±0.014; B
Δr1622.1kJ/molN/ACheck, Faust, et al., 2001gas phase; MnBr3-; ; ΔS(EA)=1.7; B
Quantity Value Units Method Reference Comment
Δr1605.57 ± 0.25kJ/molH-TSSmith, Kim, et al., 1997gas phase; Given: 14741.02(3) cm-1. dHacid(0K) = 389.11±0.014; B
Δr1594.5kJ/molN/ACheck, Faust, et al., 2001gas phase; MnBr3-; ; ΔS(EA)=1.7; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Silver ion (1+) + Water = (Silver ion (1+) • Water)

By formula: Ag+ + H2O = (Ag+ • H2O)

Quantity Value Units Method Reference Comment
Δr139.kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr119.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • Water) + Water = (Silver ion (1+) • 2Water)

By formula: (Ag+ • H2O) + H2O = (Ag+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr106.kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 2Water) + Water = (Silver ion (1+) • 3Water)

By formula: (Ag+ • 2H2O) + H2O = (Ag+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr62.8kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 3Water) + Water = (Silver ion (1+) • 4Water)

By formula: (Ag+ • 3H2O) + H2O = (Ag+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr62.3kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr123.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 4Water) + Water = (Silver ion (1+) • 5Water)

By formula: (Ag+ • 4H2O) + H2O = (Ag+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr57.3kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr127.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) • 5Water) + Water = (Silver ion (1+) • 6Water)

By formula: (Ag+ • 5H2O) + H2O = (Ag+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr55.6kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr135.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

Aluminum ion (1+) + Water = (Aluminum ion (1+) • Water)

By formula: Al+ + H2O = (Al+ • H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
104. (+15.,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) • Water) + Water = (Aluminum ion (1+) • 2Water)

By formula: (Al+ • H2O) + H2O = (Al+ • 2H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.4 (+5.0,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) • 2Water) + Water = (Aluminum ion (1+) • 3Water)

By formula: (Al+ • 2H2O) + H2O = (Al+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
63.6 (+7.5,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) • 3Water) + Water = (Aluminum ion (1+) • 4Water)

By formula: (Al+ • 3H2O) + H2O = (Al+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
52.3 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

Bismuth ion (1+) + Water = (Bismuth ion (1+) • Water)

By formula: Bi+ + H2O = (Bi+ • H2O)

Quantity Value Units Method Reference Comment
Δr95.4kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • Water) + Water = (Bismuth ion (1+) • 2Water)

By formula: (Bi+ • H2O) + H2O = (Bi+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr74.1kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 2Water) + Water = (Bismuth ion (1+) • 3Water)

By formula: (Bi+ • 2H2O) + H2O = (Bi+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr58.6kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 3Water) + Water = (Bismuth ion (1+) • 4Water)

By formula: (Bi+ • 3H2O) + H2O = (Bi+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr50.2kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr98.3J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 4Water) + Water = (Bismuth ion (1+) • 5Water)

By formula: (Bi+ • 4H2O) + H2O = (Bi+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr43.9kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) • 5Water) + Water = (Bismuth ion (1+) • 6Water)

By formula: (Bi+ • 5H2O) + H2O = (Bi+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr41.kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr98.7J/mol*KHPMSTang and Castleman, 1974gas phase; M

Bromine anion + Water = (Bromine anion • Water)

By formula: Br- + H2O = (Br- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr53.14kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr49.0 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr52.72kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Δr53.1kJ/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr61.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr77.0J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Δr82.8J/mol*KMSBurdett and Hayhurst, 1982gas phase; FLAME SOURCE, 1600 K; M
Quantity Value Units Method Reference Comment
Δr30.5 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr29. ± 12.kJ/molTDAsBurdett and Hayhurst, 1982gas phase; B
Δr29. ± 8.4kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

(Bromine anion • Water) + Water = (Bromine anion • 2Water)

By formula: (Br- • H2O) + H2O = (Br- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.5 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr51.04kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr51.5 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr51.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr75.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr95.8J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr26. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr23. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr22.6kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr24. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion • 2Water) + Water = (Bromine anion • 3Water)

By formula: (Br- • 2H2O) + H2O = (Br- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.7 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr28.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr48.1 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr48.1 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr104.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr20. ± 4.6kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr17. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr17.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr18. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion • 3Water) + Water = (Bromine anion • 4Water)

By formula: (Br- • 3H2O) + H2O = (Br- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.02 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr26. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr45.6 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr112.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr13.0 ± 2.9kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr12.1kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion • 4Water) + Water = (Bromine anion • 5Water)

By formula: (Br- • 4H2O) + H2O = (Br- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.2 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr26. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr119.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr9.6 ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion • 5Water) + Water = (Bromine anion • 6Water)

By formula: (Br- • 5H2O) + H2O = (Br- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr25. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr118.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr7.5 ± 8.8kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion • 6Water) + Water = (Bromine anion • 7Water)

By formula: (Br- • 6H2O) + H2O = (Br- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Δr10. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr5.44kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Bromine anion • 7Water) + Water = (Bromine anion • 8Water)

By formula: (Br- • 7H2O) + H2O = (Br- • 8H2O)

Quantity Value Units Method Reference Comment
Δr6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion • 8Water) + Water = (Bromine anion • 9Water)

By formula: (Br- • 8H2O) + H2O = (Br- • 9H2O)

Quantity Value Units Method Reference Comment
Δr3. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion • 9Water) + Water = (Bromine anion • 10Water)

By formula: (Br- • 9H2O) + H2O = (Br- • 10H2O)

Quantity Value Units Method Reference Comment
Δr6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion • 10Water) + Water = (Bromine anion • 11Water)

By formula: (Br- • 10H2O) + H2O = (Br- • 11H2O)

Quantity Value Units Method Reference Comment
Δr6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion • 11Water) + Water = (Bromine anion • 12Water)

By formula: (Br- • 11H2O) + H2O = (Br- • 12H2O)

Quantity Value Units Method Reference Comment
Δr10. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion • 12Water) + Water = (Bromine anion • 13Water)

By formula: (Br- • 12H2O) + H2O = (Br- • 13H2O)

Quantity Value Units Method Reference Comment
Δr7.5 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion • 13Water) + Water = (Bromine anion • 14Water)

By formula: (Br- • 13H2O) + H2O = (Br- • 14H2O)

Quantity Value Units Method Reference Comment
Δr13. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion • 14Water) + Water = (Bromine anion • 15Water)

By formula: (Br- • 14H2O) + H2O = (Br- • 15H2O)

Quantity Value Units Method Reference Comment
Δr-2. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion • 15Water) + Water = (Bromine anion • 16Water)

By formula: (Br- • 15H2O) + H2O = (Br- • 16H2O)

Quantity Value Units Method Reference Comment
Δr9.6 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

Trifluoromethyl cation + Water = (Trifluoromethyl cation • Water)

By formula: CF3+ + H2O = (CF3+ • H2O)

Quantity Value Units Method Reference Comment
Δr19.kJ/molHPMSBennet and Field, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr78.7J/mol*KHPMSBennet and Field, 1972gas phase; M

CF3O- + Water = CH2F3O2-

By formula: CF3O- + H2O = CH2F3O2-

Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molN/AAmelynck, Van Bavel, et al., 2000gas phase; B

CF3O3S- + Water = (CF3O3S- • Water)

By formula: CF3O3S- + H2O = (CF3O3S- • H2O)

Quantity Value Units Method Reference Comment
Δr48.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr19.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

(CF3O3S- • Water) + Water = (CF3O3S- • 2Water)

By formula: (CF3O3S- • H2O) + H2O = (CF3O3S- • 2H2O)

Quantity Value Units Method Reference Comment
Δr45.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr15.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

HCO2 anion + Water = (HCO2 anion • Water)

By formula: CHO2- + H2O = (CHO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr66.9 ± 4.2kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr38. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B
Δr35.1 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B
Δr38.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(HCO2 anion • Water) + Water = (HCO2 anion • 2Water)

By formula: (CHO2- • H2O) + H2O = (CHO2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr28.9 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

(HCO2 anion • 2Water) + Water = (HCO2 anion • 3Water)

By formula: (CHO2- • 2H2O) + H2O = (CHO2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr50.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr21.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr21.8 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

CHO3- + Water = CH3O4-

By formula: CHO3- + H2O = CH3O4-

Quantity Value Units Method Reference Comment
Δr65.69 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Δr35.6 ± 1.7kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

(CH2N+ • Hydrogen cyanide) + Water = (CH2N+ • Water • Hydrogen cyanide)

By formula: (CH2N+ • CHN) + H2O = (CH2N+ • H2O • CHN)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr84.1kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

CH2N+ + Water = (CH2N+ • Water)

By formula: CH2N+ + H2O = (CH2N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr115.kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr124.kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr120.J/mol*KN/ABerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
87.9300.ICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2N+ • Water • Hydrogen cyanide) + Water = (CH2N+ • 2Water • Hydrogen cyanide)

By formula: (CH2N+ • H2O • CHN) + H2O = (CH2N+ • 2H2O • CHN)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr70.7kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CH2N+ • Water) + Water = (CH2N+ • 2Water)

By formula: (CH2N+ • H2O) + H2O = (CH2N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr89.5kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CH2N+ • 2Water) + Water = (CH2N+ • 3Water)

By formula: (CH2N+ • 2H2O) + H2O = (CH2N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.0kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

CH2NO5- + Water + Formic acid = CH4NO6-

By formula: CH2NO5- + H2O + CH2O2 = CH4NO6-

Quantity Value Units Method Reference Comment
Δr18.4 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

CH2O2S- + 2Water = CH4O3S-

By formula: CH2O2S- + 2H2O = CH4O3S-

Quantity Value Units Method Reference Comment
Δr44.8 ± 8.4kJ/molN/ASurber and Sanov, 2002gas phase; Stated electron affinity is the Vertical Detachment Energy; B

CH2O4- + 2Water = CH4O5-

By formula: CH2O4- + 2H2O = CH4O5-

Quantity Value Units Method Reference Comment
Δr56.9 ± 2.1kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Δr20. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

CH2OH+ + Water = (CH2OH+ • Water)

By formula: CH3O+ + H2O = (CH3O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr119.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; switching reaction(H3O+)H2O; Davidson, Sunner J., et al., 1979, Lias, Liebman, et al., 1984; M
Δr117.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2O)2H+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Yamdagni and Kebarle, 1976, Wolf, Staley, et al., 1977; M
Δr119.kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr120.kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr120.kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KN/ABerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr113.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr112.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr85.4kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr85.8kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2OH+ • Water) + Water = (CH2OH+ • 2Water)

By formula: (CH3O+ • H2O) + H2O = (CH3O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr90.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr83.3kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr82.8kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr110.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr110.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr50.6kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2OH+ • 2Water) + Water = (CH2OH+ • 3Water)

By formula: (CH3O+ • 2H2O) + H2O = (CH3O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr73.6kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr70.7kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr71.1kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr109.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Δr109.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Δr38.kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2OH+ • 3Water) + Water = (CH2OH+ • 4Water)

By formula: (CH3O+ • 3H2O) + H2O = (CH3O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH2OH+ • 4Water) + Water = (CH2OH+ • 5Water)

By formula: (CH3O+ • 4H2O) + H2O = (CH3O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.4kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH2OH+ • 5Water) + Water = (CH2OH+ • 6Water)

By formula: (CH3O+ • 5H2O) + H2O = (CH3O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH2OH+ • 6Water) + Water = (CH2OH+ • 7Water)

By formula: (CH3O+ • 6H2O) + H2O = (CH3O+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH3O- • Methyl Alcohol) + Water = (CH3O- • Water • Methyl Alcohol)

By formula: (CH3O- • CH4O) + H2O = (CH3O- • H2O • CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr74.5kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH3O- • 2Methyl Alcohol) + Water = (CH3O- • Water • 2Methyl Alcohol)

By formula: (CH3O- • 2CH4O) + H2O = (CH3O- • H2O • 2CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.7kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

CH3O- + Water = (CH3O- • Water)

By formula: CH3O- + H2O = (CH3O- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr106. ± 9.2kJ/molCIDTDeTuri and Ervin, 1999gas phase; B
Δr100.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M,B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSMeot-ner and Sieck, 1986gas phase; M
Δr95.8J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr71.1 ± 1.3kJ/molTDAsMeot-ner and Sieck, 1986gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
64.4296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(OH-)H2O, DG>; Meot-Ner(Mautner), 1986; M

(CH3O- • Water • Methyl Alcohol) + Water = (CH3O- • 2Water • Methyl Alcohol)

By formula: (CH3O- • H2O • CH4O) + H2O = (CH3O- • 2H2O • CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.6kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr116.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH3O- • Water) + Water = (CH3O- • 2Water)

By formula: (CH3O- • H2O) + H2O = (CH3O- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr80.3kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(OH-)2H2O; Meot-Ner(Mautner), 1986; M

(CH3O- • 2Water) + Water = (CH3O- • 3Water)

By formula: (CH3O- • 2H2O) + H2O = (CH3O- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.9kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(OH-)3H2O; Meot-Ner(Mautner), 1986; M

(CH3O- • 3Water) + Water = (CH3O- • 4Water)

By formula: (CH3O- • 3H2O) + H2O = (CH3O- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.0kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr83.7J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

CH3O3S- + Water = (CH3O3S- • Water)

By formula: CH3O3S- + H2O = (CH3O3S- • H2O)

Quantity Value Units Method Reference Comment
Δr58.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr28.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

(CH3O3S- • Water) + Water = (CH3O3S- • 2Water)

By formula: (CH3O3S- • H2O) + H2O = (CH3O3S- • 2H2O)

Quantity Value Units Method Reference Comment
Δr51.9 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr22.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

(CH3O3S- • 2Water) + Water = (CH3O3S- • 3Water)

By formula: (CH3O3S- • 2H2O) + H2O = (CH3O3S- • 3H2O)

Quantity Value Units Method Reference Comment
Δr47.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr18.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

CH3O4- + 2Water = CH5O5-

By formula: CH3O4- + 2H2O = CH5O5-

Quantity Value Units Method Reference Comment
Δr62.34 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Δr26. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

MeS anion + Water = (MeS anion • Water)

By formula: CH3S- + H2O = (CH3S- • H2O)

Quantity Value Units Method Reference Comment
Δr62.76 ± 0.84kJ/molTDAsSieck and Meot-ner, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr36.4 ± 2.9kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

(MeS anion • Water) + Water = (MeS anion • 2Water)

By formula: (CH3S- • H2O) + H2O = (CH3S- • 2H2O)

Quantity Value Units Method Reference Comment
Δr56.5kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr98.3J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

(MeS anion • 2Water) + Water = (MeS anion • 3Water)

By formula: (CH3S- • 2H2O) + H2O = (CH3S- • 3H2O)

Quantity Value Units Method Reference Comment
Δr46.4kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr85.8J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

(MeS anion • 3Water) + Water = (MeS anion • 4Water)

By formula: (CH3S- • 3H2O) + H2O = (CH3S- • 4H2O)

Quantity Value Units Method Reference Comment
Δr40.kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

CH4NO+ + Water = (CH4NO+ • Water)

By formula: CH4NO+ + H2O = (CH4NO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr88.7kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr89.1kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr114.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr114.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(CH4NO+ • Water) + Water = (CH4NO+ • 2Water)

By formula: (CH4NO+ • H2O) + H2O = (CH4NO+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr58.6kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr58.6kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr95.0J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(CH4NO+ • 2Water) + Water = (CH4NO+ • 3Water)

By formula: (CH4NO+ • 2H2O) + H2O = (CH4NO+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.4kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr49.4kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr87.9J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(CH4NO+ • 3Water) + Water = (CH4NO+ • 4Water)

By formula: (CH4NO+ • 3H2O) + H2O = (CH4NO+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr41.kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr84.5J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(CH4NO+ • 4Water) + Water = (CH4NO+ • 5Water)

By formula: (CH4NO+ • 4H2O) + H2O = (CH4NO+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr41.kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr107.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

CH4O5- + 3Water = CH6O6-

By formula: CH4O5- + 3H2O = CH6O6-

Quantity Value Units Method Reference Comment
Δr54.8 ± 3.3kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Δr14. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

(CH5O+ • Methyl Alcohol) + Water = (CH5O+ • Water • Methyl Alcohol)

By formula: (CH5O+ • CH4O) + H2O = (CH5O+ • H2O • CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr77.0kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ • 3Methyl Alcohol) + Water = (CH5O+ • Water • 3Methyl Alcohol)

By formula: (CH5O+ • 3CH4O) + H2O = (CH5O+ • H2O • 3CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr50.6kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ • 4Methyl Alcohol) + Water = (CH5O+ • Water • 4Methyl Alcohol)

By formula: (CH5O+ • 4CH4O) + H2O = (CH5O+ • H2O • 4CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.8kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

CH5O+ + Water = (CH5O+ • Water)

By formula: CH5O+ + H2O = (CH5O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr115.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr100.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr123.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr96.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ • Water • 2Methyl Alcohol) + Water = (CH5O+ • 2Water • 2Methyl Alcohol)

By formula: (CH5O+ • H2O • 2CH4O) + H2O = (CH5O+ • 2H2O • 2CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.4kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ • Water • 3Methyl Alcohol) + Water = (CH5O+ • 2Water • 3Methyl Alcohol)

By formula: (CH5O+ • H2O • 3CH4O) + H2O = (CH5O+ • 2H2O • 3CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr36.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr79.5J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ • 2Water • Methyl Alcohol) + Water = (CH5O+ • 3Water • Methyl Alcohol)

By formula: (CH5O+ • 2H2O • CH4O) + H2O = (CH5O+ • 3H2O • CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.9kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ • 2Water • 2Methyl Alcohol) + Water = (CH5O+ • 3Water • 2Methyl Alcohol)

By formula: (CH5O+ • 2H2O • 2CH4O) + H2O = (CH5O+ • 3H2O • 2CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ • 2Water • 3Methyl Alcohol) + Water = (CH5O+ • 3Water • 3Methyl Alcohol)

By formula: (CH5O+ • 2H2O • 3CH4O) + H2O = (CH5O+ • 3H2O • 3CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.272.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ • 3Water • Methyl Alcohol) + Water = (CH5O+ • 4Water • Methyl Alcohol)

By formula: (CH5O+ • 3H2O • CH4O) + H2O = (CH5O+ • 4H2O • CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr98.3J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ • 3Water • 2Methyl Alcohol) + Water = (CH5O+ • 4Water • 2Methyl Alcohol)

By formula: (CH5O+ • 3H2O • 2CH4O) + H2O = (CH5O+ • 4H2O • 2CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr39.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.272.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ • 4Water • Methyl Alcohol) + Water = (CH5O+ • 5Water • Methyl Alcohol)

By formula: (CH5O+ • 4H2O • CH4O) + H2O = (CH5O+ • 5H2O • CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr39.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.269.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ • Water) + Water = (CH5O+ • 2Water)

By formula: (CH5O+ • H2O) + H2O = (CH5O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr82.8kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr87.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr114.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr121.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ • 2Water) + Water = (CH5O+ • 3Water)

By formula: (CH5O+ • 2H2O) + H2O = (CH5O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr59.0kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr61.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr108.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ • 3Water) + Water = (CH5O+ • 4Water)

By formula: (CH5O+ • 3H2O) + H2O = (CH5O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.5kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr48.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr92.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ • 4Water) + Water = (CH5O+ • 5Water)

By formula: (CH5O+ • 4H2O) + H2O = (CH5O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr38.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr86.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr77.4J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ • 5Water) + Water = (CH5O+ • 6Water)

By formula: (CH5O+ • 5H2O) + H2O = (CH5O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr39.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr92.9J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ • 6Water) + Water = (CH5O+ • 7Water)

By formula: (CH5O+ • 6H2O) + H2O = (CH5O+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.269.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

CH5O2- + 2Water = CH7O3-

By formula: CH5O2- + 2H2O = CH7O3-

Quantity Value Units Method Reference Comment
Δr80.3 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr49.0 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

CH5O5- + 3Water = CH7O6-

By formula: CH5O5- + 3H2O = CH7O6-

Quantity Value Units Method Reference Comment
Δr56.9 ± 1.3kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Δr19. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

CH5S+ + Water = (CH5S+ • Water)

By formula: CH5S+ + H2O = (CH5S+ • H2O)

Quantity Value Units Method Reference Comment
Δr64.9kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated; M
Δr56.5kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.476.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated; M

CH6N+ + Water = (CH6N+ • Water)

By formula: CH6N+ + H2O = (CH6N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr70.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr78.7kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Δr78.7kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Δr110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr44.8kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(CH6N+ • Water) + Water = (CH6N+ • 2Water)

By formula: (CH6N+ • H2O) + H2O = (CH6N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr61.1kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Δr61.1kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr112.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Δr112.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr31.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(CH6N+ • 2Water) + Water = (CH6N+ • 3Water)

By formula: (CH6N+ • 2H2O) + H2O = (CH6N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr51.9kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Δr51.9kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Δr110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr22.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(CH6N+ • 3Water) + Water = (CH6N+ • 4Water)

By formula: (CH6N+ • 3H2O) + H2O = (CH6N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr92.0J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH6N+ • 4Water) + Water = (CH6N+ • 5Water)

By formula: (CH6N+ • 4H2O) + H2O = (CH6N+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.269.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

(CH6N+ • 5Water) + Water = (CH6N+ • 6Water)

By formula: (CH6N+ • 5H2O) + H2O = (CH6N+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr36.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.259.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

CH7O3- + 3Water = CH9O4-

By formula: CH7O3- + 3H2O = CH9O4-

Quantity Value Units Method Reference Comment
Δr61.9 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr31.4 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

CH7O6- + 4Water = CH9O7-

By formula: CH7O6- + 4H2O = CH9O7-

Quantity Value Units Method Reference Comment
Δr56.1 ± 3.8kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Δr14. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

CH9O4- + 4Water = CH11O5-

By formula: CH9O4- + 4H2O = CH11O5-

Quantity Value Units Method Reference Comment
Δr46.0 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr21.3 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

(CN- • Hydrogen cyanide) + Water = (CN- • Water • Hydrogen cyanide)

By formula: (CN- • CHN) + H2O = (CN- • H2O • CHN)

Quantity Value Units Method Reference Comment
Δr51.9 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr27. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- • 2Hydrogen cyanide) + Water = (CN- • Water • 2Hydrogen cyanide)

By formula: (CN- • 2CHN) + H2O = (CN- • H2O • 2CHN)

Quantity Value Units Method Reference Comment
Δr32. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Δr52.3J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr17. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- • 3Hydrogen cyanide) + Water = (CN- • Water • 3Hydrogen cyanide)

By formula: (CN- • 3CHN) + H2O = (CN- • H2O • 3CHN)

Quantity Value Units Method Reference Comment
Δr39. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr14. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

CN- + Water = (CN- • Water)

By formula: CN- + H2O = (CN- • H2O)

Quantity Value Units Method Reference Comment
Δr53.1 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Δr61.1 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B,B,M,M
Δr57.74kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr61.1kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr75.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Δr82.0J/mol*KPHPMSMeot-ner, 1988gas phase; M
Δr82.0J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Δr82.8J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr30.5 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Δr36. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Δr36. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B
Δr33.1kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

(CN- • Water • Hydrogen cyanide) + Water = (CN- • 2Water • Hydrogen cyanide)

By formula: (CN- • H2O • CHN) + H2O = (CN- • 2H2O • CHN)

Quantity Value Units Method Reference Comment
Δr40. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Δr73.2J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr18. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- • Water • 2Hydrogen cyanide) + Water = (CN- • 2Water • 2Hydrogen cyanide)

By formula: (CN- • H2O • 2CHN) + H2O = (CN- • 2H2O • 2CHN)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Δr12. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- • 2Water • Hydrogen cyanide) + Water = (CN- • 3Water • Hydrogen cyanide)

By formula: (CN- • 2H2O • CHN) + H2O = (CN- • 3H2O • CHN)

Quantity Value Units Method Reference Comment
Δr36. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
Δr10. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

(CN- • Water) + Water = (CN- • 2Water)

By formula: (CN- • H2O) + H2O = (CN- • 2H2O)

Quantity Value Units Method Reference Comment
Δr49.0 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Δr49.0kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr75.7J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr75.7J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr26. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- • 2Water) + Water = (CN- • 3Water)

By formula: (CN- • 2H2O) + H2O = (CN- • 3H2O)

Quantity Value Units Method Reference Comment
Δr44.8 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B,M
Δr44.8kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr82.8J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Δr82.8J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr33. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B

(CN- • 3Water) + Water = (CN- • 4Water)

By formula: (CN- • 3H2O) + H2O = (CN- • 4H2O)

Quantity Value Units Method Reference Comment
Δr41. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr16. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M

CO3- + Water = CH2O4-

By formula: CO3- + H2O = CH2O4-

Quantity Value Units Method Reference Comment
Δr58.99 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Δr48.1 ± 4.2kJ/molIMREFehsenfeld and Ferguson, 1974gas phase; B
Δr<161.1kJ/molPDisSmith, Lee, et al., 1978gas phase; B
Quantity Value Units Method Reference Comment
Δr27.6 ± 1.7kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Δr28.0 ± 1.7kJ/molIMREFehsenfeld and Ferguson, 1974gas phase; B

CO3- + Water = (CO3- • Water)

By formula: CO3- + H2O = (CO3- • H2O)

Quantity Value Units Method Reference Comment
Δr59.0kJ/molHPMSKeesee, Lee, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KHPMSKeesee, Lee, et al., 1979gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(CO3- • Water) + Water = (CO3- • 2Water)

By formula: (CO3- • H2O) + H2O = (CO3- • 2H2O)

Quantity Value Units Method Reference Comment
Δr56.9kJ/molHPMSKeesee, Lee, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr124.J/mol*KHPMSKeesee, Lee, et al., 1979gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(CO3- • 2Water) + Water = (CO3- • 3Water)

By formula: (CO3- • 2H2O) + H2O = (CO3- • 3H2O)

Quantity Value Units Method Reference Comment
Δr54.8kJ/molHPMSKeesee, Lee, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr136.J/mol*KHPMSKeesee, Lee, et al., 1979gas phase; M

C2Cl3O2- + Water = (C2Cl3O2- • Water)

By formula: C2Cl3O2- + H2O = (C2Cl3O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr24.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

CF3CO2 anion + Water = (CF3CO2 anion • Water)

By formula: C2F3O2- + H2O = (C2F3O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.7 ± 6.3kJ/molN/ABlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr57.3 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr27. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B

(CF3CO2 anion • Water) + Water = (CF3CO2 anion • 2Water)

By formula: (C2F3O2- • H2O) + H2O = (C2F3O2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr19.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

C2H- + Water = (C2H- • Water)

By formula: C2H- + H2O = (C2H- • H2O)

Quantity Value Units Method Reference Comment
Δr67.8 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr77.8J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr44.4 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B

C2HCl2O2- + Water = (C2HCl2O2- • Water)

By formula: C2HCl2O2- + H2O = (C2HCl2O2- • H2O)

Quantity Value Units Method Reference Comment
Δr57.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

(C2HCl2O2- • Water) + Water = (C2HCl2O2- • 2Water)

By formula: (C2HCl2O2- • H2O) + H2O = (C2HCl2O2- • 2H2O)

Quantity Value Units Method Reference Comment
Δr49.8 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr20.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

C2HF2O2- + Water = (C2HF2O2- • Water)

By formula: C2HF2O2- + H2O = (C2HF2O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr60.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(C2HF2O2- • Water) + Water = (C2HF2O2- • 2Water)

By formula: (C2HF2O2- • H2O) + H2O = (C2HF2O2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

C2HO4- + Water = (C2HO4- • Water)

By formula: C2HO4- + H2O = (C2HO4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

ClCH2CO2 anion + Water = (ClCH2CO2 anion • Water)

By formula: C2H2ClO2- + H2O = (C2H2ClO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr32.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

FCH2CO2 anion + Water = (FCH2CO2 anion • Water)

By formula: C2H2FO2- + H2O = (C2H2FO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr64.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr34.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(FCH2CO2 anion • Water) + Water = (FCH2CO2 anion • 2Water)

By formula: (C2H2FO2- • H2O) + H2O = (C2H2FO2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(FCH2CO2 anion • 2Water) + Water = (FCH2CO2 anion • 3Water)

By formula: (C2H2FO2- • 2H2O) + H2O = (C2H2FO2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr19.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

C2H2F3O2+ + Water = (C2H2F3O2+ • Water)

By formula: C2H2F3O2+ + H2O = (C2H2F3O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr118.kJ/molICRLarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr97.5J/mol*KN/ALarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
89.5309.ICRLarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

ICH2CO2 anion + Water = (ICH2CO2 anion • Water)

By formula: C2H2IO2- + H2O = (C2H2IO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr59.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr30.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(ICH2CO2 anion • Water) + Water = (ICH2CO2 anion • 2Water)

By formula: (C2H2IO2- • H2O) + H2O = (C2H2IO2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(ICH2CO2 anion • 2Water) + Water = (ICH2CO2 anion • 3Water)

By formula: (C2H2IO2- • 2H2O) + H2O = (C2H2IO2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.3 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr18.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

C2H2N- + Water = (C2H2N- • Water)

By formula: C2H2N- + H2O = (C2H2N- • H2O)

Quantity Value Units Method Reference Comment
Δr55.2 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr73.6J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr33. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B

C2H2O+ + Water = (C2H2O+ • Water)

By formula: C2H2O+ + H2O = (C2H2O+ • H2O)

Quantity Value Units Method Reference Comment
Δr48.5kJ/molEIPostma, Ruttink, et al., 1986gas phase; based on AE(CH2CO+)H2O from (HOCH2)2CO+; M

C2H3O+ + Water = (C2H3O+ • Water)

By formula: C2H3O+ + H2O = (C2H3O+ • H2O)

Quantity Value Units Method Reference Comment
Δr103.kJ/molHPMSDavidson, Lau, et al., 1978gas phase; forms CH3COOH2+; M
Quantity Value Units Method Reference Comment
Δr138.J/mol*KHPMSDavidson, Lau, et al., 1978gas phase; forms CH3COOH2+; M

C2H3O- + Water = (C2H3O- • Water)

By formula: C2H3O- + H2O = (C2H3O- • H2O)

Quantity Value Units Method Reference Comment
Δr64.4 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr40. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B

(MeCO2 anion • CH3CONHCH(CH3)COOCH3) + Water = (MeCO2 anion • Water • CH3CONHCH(CH3)COOCH3)

By formula: (C2H3O2- • C6H11NO3) + H2O = (C2H3O2- • H2O • C6H11NO3)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr55.2kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

MeCO2 anion + Water = (MeCO2 anion • Water)

By formula: C2H3O2- + H2O = (C2H3O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.6 ± 3.3kJ/molTDAsWincel, 2008gas phase; B
Δr66.5 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Δr66.9 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Δr68.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr66.1kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr84.9J/mol*KPHPMSMeot-ner, 1988gas phase; M
Δr94.1J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; ion given as C2H3COO- in paper by error; M
Quantity Value Units Method Reference Comment
Δr38. ± 5.9kJ/molN/AWincel, 2008gas phase; B
Δr39.8kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Δr39. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B
Δr39.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(MeCO2 anion • Water) + Water = (MeCO2 anion • 2Water)

By formula: (C2H3O2- • H2O) + H2O = (C2H3O2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Δr57.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr53.6kJ/molPHPMSMeot-ner, 1988gas phase; M
Δr54.0kJ/molPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr79.9J/mol*KPHPMSMeot-ner, 1988gas phase; M
Δr85.8J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr29.3kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Δr28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(MeCO2 anion • 2Water) + Water = (MeCO2 anion • 3Water)

By formula: (C2H3O2- • 2H2O) + H2O = (C2H3O2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.4 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Δr51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr49.4kJ/molPHPMSMeot-ner, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AMeot-ner, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr24.4kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr25.kJ/molPHPMSMeot-ner, 1988gas phase; Entropy change calculated or estimated; M

C2H4F3O+ + Water = (C2H4F3O+ • Water)

By formula: C2H4F3O+ + H2O = (C2H4F3O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr128.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
97.9309.ICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

(C2H4N+ • Acetonitrile) + Water = (C2H4N+ • Water • Acetonitrile)

By formula: (C2H4N+ • C2H3N) + H2O = (C2H4N+ • H2O • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr66.5kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

C2H4N+ + Water = (C2H4N+ • Water)

By formula: C2H4N+ + H2O = (C2H4N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr92.5 ± 5.9kJ/molCIDHonma, Sunderlin, et al., 1993gas phase; guided ion beam CID; M
Δr95.4kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Δr104.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Δr119.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • Water • Acetonitrile) + Water = (C2H4N+ • 2Water • Acetonitrile)

By formula: (C2H4N+ • H2O • C2H3N) + H2O = (C2H4N+ • 2H2O • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr64.0kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

(C2H4N+ • Water • 2Acetonitrile) + Water = (C2H4N+ • 2Water • 2Acetonitrile)

By formula: (C2H4N+ • H2O • 2C2H3N) + H2O = (C2H4N+ • 2H2O • 2C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ADeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
12.316.PHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n, Entropy change calculated or estimated; M

(C2H4N+ • 2Water • Acetonitrile) + Water = (C2H4N+ • 3Water • Acetonitrile)

By formula: (C2H4N+ • 2H2O • C2H3N) + H2O = (C2H4N+ • 3H2O • C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

(C2H4N+ • Water) + Water = (C2H4N+ • 2Water)

By formula: (C2H4N+ • H2O) + H2O = (C2H4N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr62.8 ± 7.1kJ/molCIDHonma, Sunderlin, et al., 1993gas phase; guided ion beam CID; M
Δr73.2kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • 2Water) + Water = (C2H4N+ • 3Water)

By formula: (C2H4N+ • 2H2O) + H2O = (C2H4N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr65.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • 3Water) + Water = (C2H4N+ • 4Water)

By formula: (C2H4N+ • 3H2O) + H2O = (C2H4N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • 4Water) + Water = (C2H4N+ • 5Water)

By formula: (C2H4N+ • 4H2O) + H2O = (C2H4N+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr97.9J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ • 5Water) + Water = (C2H4N+ • 6Water)

By formula: (C2H4N+ • 5H2O) + H2O = (C2H4N+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr42.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C2H4NO2- + Water = C2H6NO3-

By formula: C2H4NO2- + H2O = C2H6NO3-

Quantity Value Units Method Reference Comment
Δr72.5 ± 2.1kJ/molTDAsNieckarz, Atkins, et al., 2008gas phase; B
Δr66.9 ± 1.3kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr39. ± 4.2kJ/molTDAsNieckarz, Atkins, et al., 2008gas phase; B
Δr34.3 ± 1.7kJ/molTDAsWincel, 2008gas phase; B

C2H4NO5- + Water + Acetic acid = C2H6NO6-

By formula: C2H4NO5- + H2O + C2H4O2 = C2H6NO6-

Quantity Value Units Method Reference Comment
Δr19.2 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

C2H5F2O+ + Water = (C2H5F2O+ • Water)

By formula: C2H5F2O+ + H2O = (C2H5F2O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr100.kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984; M

C2H5F3N+ + Water = (C2H5F3N+ • Water)

By formula: C2H5F3N+ + H2O = (C2H5F3N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr88.3kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr126.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H5F3N+ • Water) + Water = (C2H5F3N+ • 2Water)

By formula: (C2H5F3N+ • H2O) + H2O = (C2H5F3N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.4kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr125.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H5F3N+ • 2Water) + Water = (C2H5F3N+ • 3Water)

By formula: (C2H5F3N+ • 2H2O) + H2O = (C2H5F3N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr59.4kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr122.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

C2H5O+ + Water = (C2H5O+ • Water)

By formula: C2H5O+ + H2O = (C2H5O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr105.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr115.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • Water) + Water = (C2H5O+ • 2Water)

By formula: (C2H5O+ • H2O) + H2O = (C2H5O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr70.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 2Water) + Water = (C2H5O+ • 3Water)

By formula: (C2H5O+ • 2H2O) + H2O = (C2H5O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr71.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr117.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 3Water) + Water = (C2H5O+ • 4Water)

By formula: (C2H5O+ • 3H2O) + H2O = (C2H5O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 4Water) + Water = (C2H5O+ • 5Water)

By formula: (C2H5O+ • 4H2O) + H2O = (C2H5O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr39.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr78.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 5Water) + Water = (C2H5O+ • 6Water)

By formula: (C2H5O+ • 5H2O) + H2O = (C2H5O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr39.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 6Water) + Water = (C2H5O+ • 7Water)

By formula: (C2H5O+ • 6H2O) + H2O = (C2H5O+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C2H5O+ + Water = (C2H5O+ • Water)

By formula: C2H5O+ + H2O = (C2H5O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr84.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr91.6kJ/molHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • Water) + Water = (C2H5O+ • 2Water)

By formula: (C2H5O+ • H2O) + H2O = (C2H5O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr74.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 2Water) + Water = (C2H5O+ • 3Water)

By formula: (C2H5O+ • 2H2O) + H2O = (C2H5O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ • 3Water) + Water = (C2H5O+ • 4Water)

By formula: (C2H5O+ • 3H2O) + H2O = (C2H5O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.2kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C2H5O2+ + Water = (C2H5O2+ • Water)

By formula: C2H5O2+ + H2O = (C2H5O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr90.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O2+ • Water) + Water = (C2H5O2+ • 2Water)

By formula: (C2H5O2+ • H2O) + H2O = (C2H5O2+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr67.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr111.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O2+ • 2Water) + Water = (C2H5O2+ • 3Water)

By formula: (C2H5O2+ • 2H2O) + H2O = (C2H5O2+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O2+ • 3Water) + Water = (C2H5O2+ • 4Water)

By formula: (C2H5O2+ • 3H2O) + H2O = (C2H5O2+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
16.334.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

(C2H5O2+ • 4Water) + Water = (C2H5O2+ • 5Water)

By formula: (C2H5O2+ • 4H2O) + H2O = (C2H5O2+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.280.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

C2H5O4- + 2Water = C2H7O5-

By formula: C2H5O4- + 2H2O = C2H7O5-

Quantity Value Units Method Reference Comment
Δr54.8 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

C2H6NO2+ + Water = (C2H6NO2+ • Water)

By formula: C2H6NO2+ + H2O = (C2H6NO2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C2H6NO2+ • Water) + Water = (C2H6NO2+ • 2Water)

By formula: (C2H6NO2+ • H2O) + H2O = (C2H6NO2+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C2H6NO2+ • 2Water) + Water = (C2H6NO2+ • 3Water)

By formula: (C2H6NO2+ • 2H2O) + H2O = (C2H6NO2+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C2H7O+ • Dimethyl ether) + Water = (C2H7O+ • Water • Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + H2O = (C2H7O+ • H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.2kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr162.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

C2H7O+ + Water = (C2H7O+ • Water)

By formula: C2H7O+ + H2O = (C2H7O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.9kJ/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Δr100.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr94.6kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr114.J/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M
Δr121.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr111.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; M

(C2H7O+ • Water • Dimethyl ether) + Water = (C2H7O+ • 2Water • Dimethyl ether)

By formula: (C2H7O+ • H2O • C2H6O) + H2O = (C2H7O+ • 2H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.9kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water • 2Dimethyl ether) + Water = (C2H7O+ • 2Water • 2Dimethyl ether)

By formula: (C2H7O+ • H2O • 2C2H6O) + H2O = (C2H7O+ • 2H2O • 2C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Δr127.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water • 3Dimethyl ether) + Water = (C2H7O+ • 2Water • 3Dimethyl ether)

By formula: (C2H7O+ • H2O • 3C2H6O) + H2O = (C2H7O+ • 2H2O • 3C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Δr127.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Water • Dimethyl ether) + Water = (C2H7O+ • 3Water • Dimethyl ether)

By formula: (C2H7O+ • 2H2O • C2H6O) + H2O = (C2H7O+ • 3H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.5kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Δr112.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water) + Water = (C2H7O+ • 2Water)

By formula: (C2H7O+ • H2O) + H2O = (C2H7O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr64.0kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Water) + Water = (C2H7O+ • 3Water)

By formula: (C2H7O+ • 2H2O) + H2O = (C2H7O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0kJ/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Δr57.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M
Δr106.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Water) + Water = (C2H7O+ • 4Water)

By formula: (C2H7O+ • 3H2O) + H2O = (C2H7O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr42.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Δr79.5J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C2H7O+ + Water = (C2H7O+ • Water)

By formula: C2H7O+ + H2O = (C2H7O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr111.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr100.kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr128.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr110.J/mol*KPHPMSKebarle, 1977gas phase; M

(C2H7O+ • Water) + Water = (C2H7O+ • 2Water)

By formula: (C2H7O+ • H2O) + H2O = (C2H7O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr78.2kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr80.3kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr120.J/mol*KPHPMSKebarle, 1977gas phase; M

(C2H7O+ • 2Water) + Water = (C2H7O+ • 3Water)

By formula: (C2H7O+ • 2H2O) + H2O = (C2H7O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.1kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr59.4kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr110.J/mol*KPHPMSKebarle, 1977gas phase; M

(C2H7O+ • 3Water) + Water = (C2H7O+ • 4Water)

By formula: (C2H7O+ • 3H2O) + H2O = (C2H7O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.3kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr52.3kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr110.J/mol*KPHPMSKebarle, 1977gas phase; M

(C2H7O+ • 4Water) + Water = (C2H7O+ • 5Water)

By formula: (C2H7O+ • 4H2O) + H2O = (C2H7O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C2H7O+ • 5Water) + Water = (C2H7O+ • 6Water)

By formula: (C2H7O+ • 5H2O) + H2O = (C2H7O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.8kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSKebarle, 1977gas phase; M

C2H7O2- + Water + Methyl Alcohol = C2H9O3-

By formula: C2H7O2- + H2O + CH4O = C2H9O3-

Quantity Value Units Method Reference Comment
Δr74.5 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr42.3 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C2H7O5- + 3Water = C2H9O6-

By formula: C2H7O5- + 3H2O = C2H9O6-

Quantity Value Units Method Reference Comment
Δr48.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr19.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

C2H7O5S- + 2Water = C2H9O6S-

By formula: C2H7O5S- + 2H2O = C2H9O6S-

Quantity Value Units Method Reference Comment
Δr48.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr19.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

C2H7S+ + Water = (C2H7S+ • Water)

By formula: C2H7S+ + H2O = (C2H7S+ • H2O)

Quantity Value Units Method Reference Comment
Δr50.kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984; M
Δr54.8kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

(C2H7S+ • Water) + Water = (C2H7S+ • 2Water)

By formula: (C2H7S+ • H2O) + H2O = (C2H7S+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr48.5kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C2H7S+ + Water = (C2H7S+ • Water)

By formula: C2H7S+ + H2O = (C2H7S+ • H2O)

Quantity Value Units Method Reference Comment
Δr61.5kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C2H8N+ + Water = (C2H8N+ • Water)

By formula: C2H8N+ + H2O = (C2H8N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr62.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr38.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C2H8N+ • Water) + Water = (C2H8N+ • 2Water)

By formula: (C2H8N+ • H2O) + H2O = (C2H8N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr26.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C2H8N+ • 2Water) + Water = (C2H8N+ • 3Water)

By formula: (C2H8N+ • 2H2O) + H2O = (C2H8N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr18.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C2H8N+ • 3Water) + Water = (C2H8N+ • 4Water)

By formula: (C2H8N+ • 3H2O) + H2O = (C2H8N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H8N+ • 4Water) + Water = (C2H8N+ • 5Water)

By formula: (C2H8N+ • 4H2O) + H2O = (C2H8N+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr39.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H8N+ • 5Water) + Water = (C2H8N+ • 6Water)

By formula: (C2H8N+ • 5H2O) + H2O = (C2H8N+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr35.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.255.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

C2H8N+ + Water = (C2H8N+ • Water)

By formula: C2H8N+ + H2O = (C2H8N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr73.2kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H8N+ • Water) + Water = (C2H8N+ • 2Water)

By formula: (C2H8N+ • H2O) + H2O = (C2H8N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.5kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr124.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H8N+ • 2Water) + Water = (C2H8N+ • 3Water)

By formula: (C2H8N+ • 2H2O) + H2O = (C2H8N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr55.2kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Δr129.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

C2H8O8S2-2 + 3Water = C2H10O9S2-2

By formula: C2H8O8S2-2 + 3H2O = C2H10O9S2-2

Quantity Value Units Method Reference Comment
Δr31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H9N+ + Water = (C2H9N+ • Water)

By formula: C2H9N+ + H2O = (C2H9N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

C2H9O3- + 2Water + Methyl Alcohol = C2H11O4-

By formula: C2H9O3- + 2H2O + CH4O = C2H11O4-

Quantity Value Units Method Reference Comment
Δr63.6 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr28.9 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C2H10O9S2-2 + 4Water = C2H12O10S2-2

By formula: C2H10O9S2-2 + 4H2O = C2H12O10S2-2

Quantity Value Units Method Reference Comment
Δr27.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H12O10S2-2 + 5Water = C2H14O11S2-2

By formula: C2H12O10S2-2 + 5H2O = C2H14O11S2-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H14O11S2-2 + 6Water = C2H16O12S2-2

By formula: C2H14O11S2-2 + 6H2O = C2H16O12S2-2

Quantity Value Units Method Reference Comment
Δr22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C3H2F3O- + Water = (C3H2F3O- • Water)

By formula: C3H2F3O- + H2O = (C3H2F3O- • H2O)

Quantity Value Units Method Reference Comment
Δr53.6 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr32. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B

C3H2F3O- + Water = (C3H2F3O- • Water)

By formula: C3H2F3O- + H2O = (C3H2F3O- • H2O)

Quantity Value Units Method Reference Comment
Δr53.6kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr72.4J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M

C3H2N+ + Water = (C3H2N+ • Water)

By formula: C3H2N+ + H2O = (C3H2N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr97.5kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C3H2NO2- + Water = (C3H2NO2- • Water)

By formula: C3H2NO2- + H2O = (C3H2NO2- • H2O)

Quantity Value Units Method Reference Comment
Δr59.83kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

(C3H2NO2- • Water) + Water = (C3H2NO2- • 2Water)

By formula: (C3H2NO2- • H2O) + H2O = (C3H2NO2- • 2H2O)

Quantity Value Units Method Reference Comment
Δr51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

imidazolide anion + Water = (imidazolide anion • Water)

By formula: C3H3N2- + H2O = (C3H3N2- • H2O)

Quantity Value Units Method Reference Comment
Δr63.6kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(imidazolide anion • Water) + Water = (imidazolide anion • 2Water)

By formula: (C3H3N2- • H2O) + H2O = (C3H3N2- • 2H2O)

Quantity Value Units Method Reference Comment
Δr49.4kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(imidazolide anion • 2Water) + Water = (imidazolide anion • 3Water)

By formula: (C3H3N2- • 2H2O) + H2O = (C3H3N2- • 3H2O)

Quantity Value Units Method Reference Comment
Δr54.0kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr122.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

C3H3O4- + Water = (C3H3O4- • Water)

By formula: C3H3O4- + H2O = (C3H3O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr22.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C3H3O4- • Water) + Water = (C3H3O4- • 2Water)

By formula: (C3H3O4- • H2O) + H2O = (C3H3O4- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr17.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C3H4N2+ + Water = (C3H4N2+ • Water)

By formula: C3H4N2+ + H2O = (C3H4N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.9kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(C3H4N2+ • Water) + Water = (C3H4N2+ • 2Water)

By formula: (C3H4N2+ • H2O) + H2O = (C3H4N2+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr52.7kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr97.5J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(C3H4N2+ • 2Water) + Water = (C3H4N2+ • 3Water)

By formula: (C3H4N2+ • 2H2O) + H2O = (C3H4N2+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr125.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

C3H4O5- + Water + Acetic acid = C3H6O6-

By formula: C3H4O5- + H2O + C2H4O2 = C3H6O6-

Quantity Value Units Method Reference Comment
Δr19.2 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

C3H5O+ + Water = (C3H5O+ • Water)

By formula: C3H5O+ + H2O = (C3H5O+ • H2O)

Quantity Value Units Method Reference Comment
Δr66.1kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr84.9J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M

(C3H5O+ • Water) + Water = (C3H5O+ • 2Water)

By formula: (C3H5O+ • H2O) + H2O = (C3H5O+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr58.2kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M

(C3H5O+ • 2Water) + Water = (C3H5O+ • 3Water)

By formula: (C3H5O+ • 2H2O) + H2O = (C3H5O+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr115.J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M

(C3H5O+ • 3Water) + Water = (C3H5O+ • 4Water)

By formula: (C3H5O+ • 3H2O) + H2O = (C3H5O+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr45.2kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M

C3H5O+ + Water = (C3H5O+ • Water)

By formula: C3H5O+ + H2O = (C3H5O+ • H2O)

Quantity Value Units Method Reference Comment
Δr99.2kJ/molPHPMSDavidson, Meza-Hojer, et al., 1979gas phase; forms protonated propanoic acid; M
Quantity Value Units Method Reference Comment
Δr147.J/mol*KPHPMSDavidson, Meza-Hojer, et al., 1979gas phase; forms protonated propanoic acid; M

(C3H5O+ • 2Water) + Water = (C3H5O+ • 3Water)

By formula: (C3H5O+ • 2H2O) + H2O = (C3H5O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.6kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M

(C3H5O+ • 3Water) + Water = (C3H5O+ • 4Water)

By formula: (C3H5O+ • 3H2O) + H2O = (C3H5O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr53.1kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M

C3H5O- + Water = (C3H5O- • Water)

By formula: C3H5O- + H2O = (C3H5O- • H2O)

Quantity Value Units Method Reference Comment
Δr66.1 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B
Quantity Value Units Method Reference Comment
Δr41. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B

EtCO2 anion + Water = (EtCO2 anion • Water)

By formula: C3H5O2- + H2O = (C3H5O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr38.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr35.1 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

(EtCO2 anion • Water) + Water = (EtCO2 anion • 2Water)

By formula: (C3H5O2- • H2O) + H2O = (C3H5O2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.9 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr27.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr28.9 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

(EtCO2 anion • 2Water) + Water = (EtCO2 anion • 3Water)

By formula: (C3H5O2- • 2H2O) + H2O = (C3H5O2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr50.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr21.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr21.3 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

MeCH(OH)CO2 anion + Water = (MeCH(OH)CO2 anion • Water)

By formula: C3H5O3- + H2O = (C3H5O3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr32.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(MeCH(OH)CO2 anion • Water) + Water = (MeCH(OH)CO2 anion • 2Water)

By formula: (C3H5O3- • H2O) + H2O = (C3H5O3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

MeOCH2CO2 anion + Water = (MeOCH2CO2 anion • Water)

By formula: C3H5O3- + H2O = (C3H5O3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr65.3 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr36.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(MeOCH2CO2 anion • Water) + Water = (MeOCH2CO2 anion • 2Water)

By formula: (C3H5O3- • H2O) + H2O = (C3H5O3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.8 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(MeOCH2CO2 anion • 2Water) + Water = (MeOCH2CO2 anion • 3Water)

By formula: (C3H5O3- • 2H2O) + H2O = (C3H5O3- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr20.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

C3H5O5- + 2Water = C3H7O6-

By formula: C3H5O5- + 2H2O = C3H7O6-

Quantity Value Units Method Reference Comment
Δr16.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C3H6+ + Water = (C3H6+ • Water)

By formula: C3H6+ + H2O = (C3H6+ • H2O)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molCIDHolmes, Mommers, et al., 1984gas phase; structure confirmed as ion-dipole complex in Shao, Baer, et al., 1987; M

C3H6NO2- + Water = C3H8NO3-

By formula: C3H6NO2- + H2O = C3H8NO3-

Quantity Value Units Method Reference Comment
Δr64.0 ± 1.7kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr32.6 ± 3.3kJ/molTDAsWincel, 2008gas phase; B

C3H7+ + Water = (C3H7+ • Water)

By formula: C3H7+ + H2O = (C3H7+ • H2O)

Quantity Value Units Method Reference Comment
Δr73.6kJ/molHPMSBeggs and Field, 1971gas phase; ΔrH inconsistent with (CH3)2CHOH2+ product; M
Quantity Value Units Method Reference Comment
Δr116.J/mol*KHPMSBeggs and Field, 1971gas phase; ΔrH inconsistent with (CH3)2CHOH2+ product; M

C3H7O+ + Water = (C3H7O+ • Water)

By formula: C3H7O+ + H2O = (C3H7O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr85.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ • Water) + Water = (C3H7O+ • 2Water)

By formula: (C3H7O+ • H2O) + H2O = (C3H7O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ • 2Water) + Water = (C3H7O+ • 3Water)

By formula: (C3H7O+ • 2H2O) + H2O = (C3H7O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr53.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr91.6J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ • 3Water) + Water = (C3H7O+ • 4Water)

By formula: (C3H7O+ • 3H2O) + H2O = (C3H7O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ • 4Water) + Water = (C3H7O+ • 5Water)

By formula: (C3H7O+ • 4H2O) + H2O = (C3H7O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr98.3J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C3H7O+ + Water = (C3H7O+ • Water)

By formula: C3H7O+ + H2O = (C3H7O+ • H2O)

Quantity Value Units Method Reference Comment
Δr46.9kJ/molPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr78.7J/mol*KPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; M

C3H9O+ + Water = (C3H9O+ • Water)

By formula: C3H9O+ + H2O = (C3H9O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr100.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr117.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • Water) + Water = (C3H9O+ • 2Water)

By formula: (C3H9O+ • H2O) + H2O = (C3H9O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr74.9kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • 2Water) + Water = (C3H9O+ • 3Water)

By formula: (C3H9O+ • 2H2O) + H2O = (C3H9O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • 3Water) + Water = (C3H9O+ • 4Water)

By formula: (C3H9O+ • 3H2O) + H2O = (C3H9O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.0kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • 4Water) + Water = (C3H9O+ • 5Water)

By formula: (C3H9O+ • 4H2O) + H2O = (C3H9O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr86.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • 5Water) + Water = (C3H9O+ • 6Water)

By formula: (C3H9O+ • 5H2O) + H2O = (C3H9O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

C3H9O+ + Water = (C3H9O+ • Water)

By formula: C3H9O+ + H2O = (C3H9O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.2kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; unusually small ΔrH and ΔrS; M
Δr56.5kJ/molHPMSBeggs and Field, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr57.3J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; unusually small ΔrH and ΔrS; M
Δr53.1J/mol*KHPMSBeggs and Field, 1971gas phase; M

(C3H9O+ • Water) + Water = (C3H9O+ • 2Water)

By formula: (C3H9O+ • H2O) + H2O = (C3H9O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.6kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr62.3kJ/molHPMSBeggs and Field, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr90.0J/mol*KHPMSBeggs and Field, 1971gas phase; M

(C3H9O+ • 2Water) + Water = (C3H9O+ • 3Water)

By formula: (C3H9O+ • 2H2O) + H2O = (C3H9O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr52.3kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr98.7J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • 3Water) + Water = (C3H9O+ • 4Water)

By formula: (C3H9O+ • 3H2O) + H2O = (C3H9O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.9kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • 4Water) + Water = (C3H9O+ • 5Water)

By formula: (C3H9O+ • 4H2O) + H2O = (C3H9O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr91.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • 5Water) + Water = (C3H9O+ • 6Water)

By formula: (C3H9O+ • 5H2O) + H2O = (C3H9O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr89.1J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ • 6Water) + Water = (C3H9O+ • 7Water)

By formula: (C3H9O+ • 6H2O) + H2O = (C3H9O+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr33.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AHiraoka, Takimoto, et al., 1986gas phase; Entropy change calculated or estimated; M

C3H9S+ + Water = (C3H9S+ • Water)

By formula: C3H9S+ + H2O = (C3H9S+ • H2O)

Quantity Value Units Method Reference Comment
Δr52.7kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.347.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C3H9S+ + Water = (C3H9S+ • Water)

By formula: C3H9S+ + H2O = (C3H9S+ • H2O)

Quantity Value Units Method Reference Comment
Δr60.2kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.446.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C3H9S+ + Water = (C3H9S+ • Water)

By formula: C3H9S+ + H2O = (C3H9S+ • H2O)

Quantity Value Units Method Reference Comment
Δr58.2kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.418.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C3H9Si+ + Water = (C3H9Si+ • Water)

By formula: C3H9Si+ + H2O = (C3H9Si+ • H2O)

Quantity Value Units Method Reference Comment
Δr126. ± 7.9kJ/molPHPMSStone and Wojtyniak, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSStone and Wojtyniak, 1986gas phase; M

(C3H9Si+ • Water) + Water = (C3H9Si+ • 2Water)

By formula: (C3H9Si+ • H2O) + H2O = (C3H9Si+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr83.3kJ/molPHPMSStone and Wytenberg, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr118.J/mol*KPHPMSStone and Wytenberg, 1987gas phase; M

C3H9Sn+ + Water = (C3H9Sn+ • Water)

By formula: C3H9Sn+ + H2O = (C3H9Sn+ • H2O)

Quantity Value Units Method Reference Comment
Δr108.kJ/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr115.J/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
46.9525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M

(C3H10N+ • 2Methylamine, N,N-dimethyl-) + Water = (C3H10N+ • Water • 2Methylamine, N,N-dimethyl-)

By formula: (C3H10N+ • 2C3H9N) + H2O = (C3H10N+ • H2O • 2C3H9N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.kJ/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M

C3H10N+ + Water = (C3H10N+ • Water)

By formula: C3H10N+ + H2O = (C3H10N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr60.7kJ/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Δr60.7kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr60.7kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Δr101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr101.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr32.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C3H10N+ • Water • Methylamine, N,N-dimethyl-) + Water = (C3H10N+ • 2Water • Methylamine, N,N-dimethyl-)

By formula: (C3H10N+ • H2O • C3H9N) + H2O = (C3H10N+ • 2H2O • C3H9N)

Quantity Value Units Method Reference Comment
Δr34.kJ/molPHPMSEl-Shall, Daly, et al., 1992gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AEl-Shall, Daly, et al., 1992gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
10.225.PHPMSEl-Shall, Daly, et al., 1992gas phase; Entropy change calculated or estimated; M

(C3H10N+ • Water) + Water = (C3H10N+ • 2Water)

By formula: (C3H10N+ • H2O) + H2O = (C3H10N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.7kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr18.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C3H10N+ • 2Water) + Water = (C3H10N+ • 3Water)

By formula: (C3H10N+ • 2H2O) + H2O = (C3H10N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr14.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C3H10N+ • 3Water) + Water = (C3H10N+ • 4Water)

By formula: (C3H10N+ • 3H2O) + H2O = (C3H10N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr35.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated, attributed to MeNH3+.4H2O by error in footnote; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated, attributed to MeNH3+.4H2O by error in footnote; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.254.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated, attributed to MeNH3+.4H2O by error in footnote; M

C3H10N+ + Water = (C3H10N+ • Water)

By formula: C3H10N+ + H2O = (C3H10N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr65.3kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr63.2kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr90.0J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr37.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C3H10N+ • Water) + Water = (C3H10N+ • 2Water)

By formula: (C3H10N+ • H2O) + H2O = (C3H10N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr89.1J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
27.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C3H10N+ • 2Water) + Water = (C3H10N+ • 3Water)

By formula: (C3H10N+ • 2H2O) + H2O = (C3H10N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr96.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C3H10N+ • 3Water) + Water = (C3H10N+ • 4Water)

By formula: (C3H10N+ • 3H2O) + H2O = (C3H10N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C3H11N2+ + Water = (C3H11N2+ • Water)

By formula: C3H11N2+ + H2O = (C3H11N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C3H11O3- + Water + 2Methyl Alcohol = C3H13O4-

By formula: C3H11O3- + H2O + 2CH4O = C3H13O4-

Quantity Value Units Method Reference Comment
Δr57.7 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr26.8 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C4H3O4- + Water = (C4H3O4- • Water)

By formula: C4H3O4- + H2O = (C4H3O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr21.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C4H3O4- + Water = (C4H3O4- • Water)

By formula: C4H3O4- + H2O = (C4H3O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr31.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

pyrrolide anion + Water = (pyrrolide anion • Water)

By formula: C4H4N- + H2O = (C4H4N- • H2O)

Quantity Value Units Method Reference Comment
Δr65.7 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.7J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B

(pyrrolide anion • Water) + Water = (pyrrolide anion • 2Water)

By formula: (C4H4N- • H2O) + H2O = (C4H4N- • 2H2O)

Quantity Value Units Method Reference Comment
Δr50.6kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M

C4H4O+ + Water = (C4H4O+ • Water)

By formula: C4H4O+ + H2O = (C4H4O+ • H2O)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr74.5J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H4S+ + Water = (C4H4S+ • Water)

By formula: C4H4S+ + H2O = (C4H4S+ • H2O)

Quantity Value Units Method Reference Comment
Δr40.kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr74.1J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H5N+ + Water = (C4H5N+ • Water)

By formula: C4H5N+ + H2O = (C4H5N+ • H2O)

Quantity Value Units Method Reference Comment
Δr49.0kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr64.9J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

(C4H5N+ • Water) + Water = (C4H5N+ • 2Water)

By formula: (C4H5N+ • H2O) + H2O = (C4H5N+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr36.kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr63.J/mol*KN/AHiraoka, Takimoto, et al., 1987gas phase; Entropy change calculated or estimated; M

C4H5O+ + Water = (C4H5O+ • Water)

By formula: C4H5O+ + H2O = (C4H5O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr42.7kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Δr67.kJ/molPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr82.4J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Δr130.J/mol*KN/AMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.382.PHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M

C4H5O4- + Water = (C4H5O4- • Water)

By formula: C4H5O4- + H2O = (C4H5O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr23.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C4H5O4- • Water) + Water = (C4H5O4- • 2Water)

By formula: (C4H5O4- • H2O) + H2O = (C4H5O4- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr17.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C4H5O5- + 2Water = C4H7O6-

By formula: C4H5O5- + 2H2O = C4H7O6-

Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C4H5S+ + Water = (C4H5S+ • Water)

By formula: C4H5S+ + H2O = (C4H5S+ • H2O)

Quantity Value Units Method Reference Comment
Δr41.8kJ/molPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr42.7kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr86.2J/mol*KPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr83.3J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H6N+ + Water = (C4H6N+ • Water)

By formula: C4H6N+ + H2O = (C4H6N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr58.6kJ/molPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr57.7kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Δr67.kJ/molPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M
Quantity Value Units Method Reference Comment
Δr97.5J/mol*KPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr92.0J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Δr130.J/mol*KN/AMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.344.PHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; Entropy change calculated or estimated, ΔrH<; M

(C4H6N+ • Water) + Water = (C4H6N+ • 2Water)

By formula: (C4H6N+ • H2O) + H2O = (C4H6N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr45.6kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KPHPMSNicol, Sunner, et al., 1988gas phase; M
Δr99.2J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H7N2O3- + Water = C4H9N2O4-

By formula: C4H7N2O3- + H2O = C4H9N2O4-

Quantity Value Units Method Reference Comment
Δr51.5 ± 2.1kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr18. ± 4.6kJ/molTDAsWincel, 2008gas phase; B

C4H7O2- + Water = C4H9O3-

By formula: C4H7O2- + H2O = C4H9O3-

Quantity Value Units Method Reference Comment
Δr36.0 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

iPrCO2 anion + Water = (iPrCO2 anion • Water)

By formula: C4H7O2- + H2O = (C4H7O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr65.7 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/AMeot-Ner and Sieck, 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr37. ± 6.7kJ/molIMREMeot-Ner and Sieck, 1986gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
16.514.PHPMSMeot-Ner and Sieck, 1986gas phase; Entropy change calculated or estimated; M

C4H7O4- + Water + 2Water = C4H9O5-

By formula: C4H7O4- + H2O + 2H2O = C4H9O5-

Quantity Value Units Method Reference Comment
Δr49.4 ± 2.9kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Δr21.7kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B

C4H7O5- + 2Water = C4H9O6-

By formula: C4H7O5- + 2H2O = C4H9O6-

Quantity Value Units Method Reference Comment
Δr16.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C4H8N+ + Water = (C4H8N+ • Water)

By formula: C4H8N+ + H2O = (C4H8N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr80.3kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C4H8N+ + Water = (C4H8N+ • Water)

By formula: C4H8N+ + H2O = (C4H8N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr100.kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr131.J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C4H8S+ + Water = (C4H8S+ • Water)

By formula: C4H8S+ + H2O = (C4H8S+ • H2O)

Quantity Value Units Method Reference Comment
Δr42.kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; ΔrH<; M

C4H9+ + Water = (C4H9+ • Water)

By formula: C4H9+ + H2O = (C4H9+ • H2O)

Quantity Value Units Method Reference Comment
Δr46.9kJ/molPHPMSHiraoka and Kebarle, 1977, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSHiraoka and Kebarle, 1977, 2gas phase; M

(C4H9+ • 2Water) + Water = (C4H9+ • 3Water)

By formula: (C4H9+ • 2H2O) + H2O = (C4H9+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr74.1kJ/molPHPMSHiraoka and Kebarle, 1977, 2gas phase; may form ((CH3)3COH2+) 2H2O; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSHiraoka and Kebarle, 1977, 2gas phase; may form ((CH3)3COH2+) 2H2O; M

(C4H9+ • 3Water) + Water = (C4H9+ • 4Water)

By formula: (C4H9+ • 3H2O) + H2O = (C4H9+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr59.kJ/molPHPMSHiraoka and Kebarle, 1977, 3gas phase; may form ((CH3)3COH2+) 3H2O; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSHiraoka and Kebarle, 1977, 3gas phase; may form ((CH3)3COH2+) 3H2O; M

C4H9O+ + Water = (C4H9O+ • Water)

By formula: C4H9O+ + H2O = (C4H9O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr82.8kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

(C4H9O+ • Water) + Water = (C4H9O+ • 2Water)

By formula: (C4H9O+ • H2O) + H2O = (C4H9O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.8kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H9O- + Water = (C4H9O- • Water)

By formula: C4H9O- + H2O = (C4H9O- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr97.9 ± 4.2kJ/molIMREMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner and Sieck, 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr62.8 ± 7.9kJ/molIMREMeot-Ner and Sieck, 1986gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
39.505.PHPMSMeot-Ner and Sieck, 1986gas phase; Entropy change calculated or estimated; M

C4H9O3- + 3Water = C4H11O4-

By formula: C4H9O3- + 3H2O = C4H11O4-

Quantity Value Units Method Reference Comment
Δr27.6 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

C4H9O5- + Water + 3Water = C4H11O6-

By formula: C4H9O5- + H2O + 3H2O = C4H11O6-

Quantity Value Units Method Reference Comment
Δr46.4 ± 2.5kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Δr16.4kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B

C4H9S+ + Water = (C4H9S+ • Water)

By formula: C4H9S+ + H2O = (C4H9S+ • H2O)

Quantity Value Units Method Reference Comment
Δr48.1kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr81.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

(C4H9S+ • Water) + Water = (C4H9S+ • 2Water)

By formula: (C4H9S+ • H2O) + H2O = (C4H9S+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H10N+ + Water = (C4H10N+ • Water)

By formula: C4H10N+ + H2O = (C4H10N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.3kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr88.3J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

(C4H10N+ • Water) + Water = (C4H10N+ • 2Water)

By formula: (C4H10N+ • H2O) + H2O = (C4H10N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H10NO+ + Water = (C4H10NO+ • Water)

By formula: C4H10NO+ + H2O = (C4H10NO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr69.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr69.0kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr110.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(C4H10NO+ • Water) + Water = (C4H10NO+ • 2Water)

By formula: (C4H10NO+ • H2O) + H2O = (C4H10NO+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr51.5kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr110.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(C4H10NO+ • 2Water) + Water = (C4H10NO+ • 3Water)

By formula: (C4H10NO+ • 2H2O) + H2O = (C4H10NO+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr39.kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(C4H10NO+ • 3Water) + Water = (C4H10NO+ • 4Water)

By formula: (C4H10NO+ • 3H2O) + H2O = (C4H10NO+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
14.268.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

(C4H11O2+ • Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ • Water • Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ • C4H10O2) + H2O = (C4H11O2+ • H2O • C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.3kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr115.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C4H11O2+ + Water = (C4H11O2+ • Water)

By formula: C4H11O2+ + H2O = (C4H11O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.6kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ • Water • Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ • 2Water • Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ • H2O • C4H10O2) + H2O = (C4H11O2+ • 2H2O • C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ • Water • 2Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ • 2Water • 2Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ • H2O • 2C4H10O2) + H2O = (C4H11O2+ • 2H2O • 2C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ • 2Water • Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ • 3Water • Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ • 2H2O • C4H10O2) + H2O = (C4H11O2+ • 3H2O • C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr42.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ • 2Water • 2Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ • 3Water • 2Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ • 2H2O • 2C4H10O2) + H2O = (C4H11O2+ • 3H2O • 2C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.225.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

(C4H11O2+ • 3Water • Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ • 4Water • Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ • 3H2O • C4H10O2) + H2O = (C4H11O2+ • 4H2O • C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
16.225.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

(C4H11O2+ • Water) + Water = (C4H11O2+ • 2Water)

By formula: (C4H11O2+ • H2O) + H2O = (C4H11O2+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr65.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ • 2Water) + Water = (C4H11O2+ • 3Water)

By formula: (C4H11O2+ • 2H2O) + H2O = (C4H11O2+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.3kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ • 3Water) + Water = (C4H11O2+ • 4Water)

By formula: (C4H11O2+ • 3H2O) + H2O = (C4H11O2+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.2kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ • 4Water) + Water = (C4H11O2+ • 5Water)

By formula: (C4H11O2+ • 4H2O) + H2O = (C4H11O2+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr42.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C4H11O4- + 3Water = C4H13O5-

By formula: C4H11O4- + 3H2O = C4H13O5-

Quantity Value Units Method Reference Comment
Δr21.3 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

C4H11O6- + Water + 3Water = C4H13O7-

By formula: C4H11O6- + H2O + 3H2O = C4H13O7-

Quantity Value Units Method Reference Comment
Δr46.0 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Δr18.6kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B

C4H13N2+ + Water = (C4H13N2+ • Water)

By formula: C4H13N2+ + H2O = (C4H13N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

cyclopentadienide anion + Water = (cyclopentadienide anion • Water)

By formula: C5H5- + H2O = (C5H5- • H2O)

Quantity Value Units Method Reference Comment
Δr46.0 ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr67.4J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr26. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B

(cyclopentadienide anion • Water) + Water = (cyclopentadienide anion • 2Water)

By formula: (C5H5- • H2O) + H2O = (C5H5- • 2H2O)

Quantity Value Units Method Reference Comment
Δr41.8kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr72.8J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M

C5H5ClN+ + Water = (C5H5ClN+ • Water)

By formula: C5H5ClN+ + H2O = (C5H5ClN+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.400.PHPMSDavidson, Sunner J., et al., 1979gas phase; M

C5H5N2O2+ + Water = (C5H5N2O2+ • Water)

By formula: C5H5N2O2+ + H2O = (C5H5N2O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.400.PHPMSDavidson, Sunner J., et al., 1979gas phase; M

C5H6N+ + Water = (C5H6N+ • Water)

By formula: C5H6N+ + H2O = (C5H6N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr67.4kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Δr62.8kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Δr107.J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(C5H6N+ • Water) + Water = (C5H6N+ • 2Water)

By formula: (C5H6N+ • H2O) + H2O = (C5H6N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(C5H6N+ • 2Water) + Water = (C5H6N+ • 3Water)

By formula: (C5H6N+ • 2H2O) + H2O = (C5H6N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr35.kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

C5H6O4-2 + Water = (C5H6O4-2 • Water)

By formula: C5H6O4-2 + H2O = (C5H6O4-2 • H2O)

Quantity Value Units Method Reference Comment
Δr34. ± 18.kJ/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

(C5H6O4-2 • Water) + Water = (C5H6O4-2 • 2Water)

By formula: (C5H6O4-2 • H2O) + H2O = (C5H6O4-2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr53. ± 18.kJ/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

C5H7O4- + Water = (C5H7O4- • Water)

By formula: C5H7O4- + H2O = (C5H7O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr35.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C5H7O4- • Water) + Water = (C5H7O4- • 2Water)

By formula: (C5H7O4- • H2O) + H2O = (C5H7O4- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C5H7O4- • Water) + Water = (C5H7O4- • 2Water)

By formula: (C5H7O4- • H2O) + H2O = (C5H7O4- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr18.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C5H7O4-2 + Water = C5H9O5-

By formula: C5H7O4-2 + H2O = C5H9O5-

Quantity Value Units Method Reference Comment
Δr23.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C5H8NO2- + Water = C5H10NO3-

By formula: C5H8NO2- + H2O = C5H10NO3-

Quantity Value Units Method Reference Comment
Δr64.4 ± 2.1kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr31.8 ± 3.8kJ/molTDAsWincel, 2008gas phase; B

C5H9N2O3- + Water = C5H11N2O4-

By formula: C5H9N2O3- + H2O = C5H11N2O4-

Quantity Value Units Method Reference Comment
Δr60.2 ± 1.7kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr22.6 ± 3.3kJ/molTDAsWincel, 2008gas phase; B

C5H9O+ + Water = (C5H9O+ • Water)

By formula: C5H9O+ + H2O = (C5H9O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr76.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr112.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C5H9O+ • Water) + Water = (C5H9O+ • 2Water)

By formula: (C5H9O+ • H2O) + H2O = (C5H9O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.4kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C5H9O+ • 2Water) + Water = (C5H9O+ • 3Water)

By formula: (C5H9O+ • 2H2O) + H2O = (C5H9O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr42.7kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr80.8J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C5H9O+ • 3Water) + Water = (C5H9O+ • 4Water)

By formula: (C5H9O+ • 3H2O) + H2O = (C5H9O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr88.3J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.284.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

(C5H9O+ • 4Water) + Water = (C5H9O+ • 5Water)

By formula: (C5H9O+ • 4H2O) + H2O = (C5H9O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.281.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

C5H9O5- + 2Water = C5H11O6-

By formula: C5H9O5- + 2H2O = C5H11O6-

Quantity Value Units Method Reference Comment
Δr25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C5H9O5- + 2Water = C5H11O6-

By formula: C5H9O5- + 2H2O = C5H11O6-

Quantity Value Units Method Reference Comment
Δr17.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C5H10NO2+ + Water = (C5H10NO2+ • Water)

By formula: C5H10NO2+ + H2O = (C5H10NO2+ • H2O)

Quantity Value Units Method Reference Comment
Δr79.1kJ/molPHPMSMeot-Ner and Field, 1974gas phase; Entropy change is questionable; M
Δr79.1kJ/molPHPMSMeot-Ner and Field, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr154.J/mol*KPHPMSMeot-Ner and Field, 1974gas phase; Entropy change is questionable; M
Δr154.J/mol*KPHPMSMeot-Ner and Field, 1974gas phase; Entropy change is questionable; M

C5H10NO2- + Water = C5H12NO3-

By formula: C5H10NO2- + H2O = C5H12NO3-

Quantity Value Units Method Reference Comment
Δr59.8 ± 1.7kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr30.1 ± 2.9kJ/molTDAsWincel, 2008gas phase; B

L-Methionine anion + Water = C5H12NO3S-

By formula: C5H10NO2S- + H2O = C5H12NO3S-

Quantity Value Units Method Reference Comment
Δr60.7 ± 2.1kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr29.7 ± 3.3kJ/molTDAsWincel, 2008gas phase; B

C5H11O+ + Water = (C5H11O+ • Water)

By formula: C5H11O+ + H2O = (C5H11O+ • H2O)

Quantity Value Units Method Reference Comment
Δr77.4kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

(C5H11O+ • Water) + Water = (C5H11O+ • 2Water)

By formula: (C5H11O+ • H2O) + H2O = (C5H11O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.8kJ/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C5H12NO2+ + Water = (C5H12NO2+ • Water)

By formula: C5H12NO2+ + H2O = (C5H12NO2+ • H2O)

Quantity Value Units Method Reference Comment
Δr80.8kJ/molPHPMSMeot-Ner and Field, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr152.J/mol*KPHPMSMeot-Ner and Field, 1974gas phase; Entropy change is questionable; M

C5H15N2+ + Water = (C5H15N2+ • Water)

By formula: C5H15N2+ + H2O = (C5H15N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C5H16N2+2 + Water = (C5H16N2+2 • Water)

By formula: C5H16N2+2 + H2O = (C5H16N2+2 • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr77.8kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KN/ABlades, Klassen, et al., 1996gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr51.0kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; Entropy change calculated or estimated; M

(C5H16N2+2 • Water) + Water = (C5H16N2+2 • 2Water)

By formula: (C5H16N2+2 • H2O) + H2O = (C5H16N2+2 • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr77.0kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/ABlades, Klassen, et al., 1996gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr47.3kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; Entropy change calculated or estimated; M

C6F6- + Water = C6H2F6O-

By formula: C6F6- + H2O = C6H2F6O-

Quantity Value Units Method Reference Comment
Δr22.2kJ/molN/AEustis, Wang, et al., 2007gas phase; Vertical Detachment Energy: 1.78±0.02 eV. EA is not adiabatic, just threshhold; B

C6H2F6O- + 2Water = C6H4F6O2-

By formula: C6H2F6O- + 2H2O = C6H4F6O2-

Quantity Value Units Method Reference Comment
Δr14.5kJ/molN/AEustis, Wang, et al., 2007gas phase; Vertical Detachment Energy: 1.93±0.03 eV. EA is not adiabatic, just threshhold; B

C6H5NO2- + Water = (C6H5NO2- • Water)

By formula: C6H5NO2- + H2O = (C6H5NO2- • H2O)

Quantity Value Units Method Reference Comment
Δr56.48 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr91.6J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr29.3 ± 0.84kJ/molTDAsSieck, 1985gas phase; B

(C6H5NO2- • Water) + Water = (C6H5NO2- • 2Water)

By formula: (C6H5NO2- • H2O) + H2O = (C6H5NO2- • 2H2O)

Quantity Value Units Method Reference Comment
Δr51.88 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr20.9 ± 1.7kJ/molTDAsSieck, 1985gas phase; B

C6H5N2+ + Water = (C6H5N2+ • Water)

By formula: C6H5N2+ + H2O = (C6H5N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.400.PHPMSDavidson, Sunner J., et al., 1979gas phase; M

C6H5N2+ + Water = (C6H5N2+ • Water)

By formula: C6H5N2+ + H2O = (C6H5N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(C6H5N2+ • Water) + Water = (C6H5N2+ • 2Water)

By formula: (C6H5N2+ • H2O) + H2O = (C6H5N2+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(C6H5N2+ • 2Water) + Water = (C6H5N2+ • 3Water)

By formula: (C6H5N2+ • 2H2O) + H2O = (C6H5N2+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

(C6H5N2+ • 3Water) + Water = (C6H5N2+ • 4Water)

By formula: (C6H5N2+ • 3H2O) + H2O = (C6H5N2+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr34.kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

phenoxide anion + Water = (phenoxide anion • Water)

By formula: C6H5O- + H2O = (C6H5O- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr64.4kJ/molPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M

phenoxide anion + Water = C6H7O2-

By formula: C6H5O- + H2O = C6H7O2-

Quantity Value Units Method Reference Comment
Δr64.4 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr34. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B

thiophenoxide anion + Water = (thiophenoxide anion • Water)

By formula: C6H5S- + H2O = (C6H5S- • H2O)

Quantity Value Units Method Reference Comment
Δr47.7kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

thiophenoxide anion + Water = C6H7OS-

By formula: C6H5S- + H2O = C6H7OS-

Quantity Value Units Method Reference Comment
Δr47.70 ± 0.84kJ/molTDAsSieck and Meot-ner, 1989gas phase; B
Quantity Value Units Method Reference Comment
Δr23.4 ± 2.9kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

C6H6ClO+ + Water = (C6H6ClO+ • Water)

By formula: C6H6ClO+ + H2O = (C6H6ClO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
12.436.PHPMSMartinsen and Buttrill, 1978gas phase; M

C6H6ClO+ + Water = (C6H6ClO+ • Water)

By formula: C6H6ClO+ + H2O = (C6H6ClO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
20.443.PHPMSMartinsen and Buttrill, 1978gas phase; M

C6H6ClO+ + Water = (C6H6ClO+ • Water)

By formula: C6H6ClO+ + H2O = (C6H6ClO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.453.PHPMSMartinsen and Buttrill, 1978gas phase; M

C6H6NO3+ + Water = (C6H6NO3+ • Water)

By formula: C6H6NO3+ + H2O = (C6H6NO3+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.427.PHPMSMartinsen and Buttrill, 1978gas phase; M

C6H6NO3+ + Water = (C6H6NO3+ • Water)

By formula: C6H6NO3+ + H2O = (C6H6NO3+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.427.PHPMSMartinsen and Buttrill, 1978gas phase; M

C6H6NO3+ + Water = (C6H6NO3+ • Water)

By formula: C6H6NO3+ + H2O = (C6H6NO3+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.427.PHPMSMartinsen and Buttrill, 1978gas phase; M

C6H7+ + Water = (C6H7+ • Water)

By formula: C6H7+ + H2O = (C6H7+ • H2O)

Quantity Value Units Method Reference Comment
Δr71.kJ/molICRBerman and Beauchamp, 1986gas phase; switching reaction(H3O+)H2O, ΔrH<; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984; M

C6H7ClN+ + Water = (C6H7ClN+ • Water)

By formula: C6H7ClN+ + H2O = (C6H7ClN+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.9kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

C6H7FN+ + Water = (C6H7FN+ • Water)

By formula: C6H7FN+ + H2O = (C6H7FN+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.9kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

C6H7O2+ + Water = (C6H7O2+ • Water)

By formula: C6H7O2+ + H2O = (C6H7O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
12.454.PHPMSMartinsen and Buttrill, 1978gas phase; M

C6H7O2+ + Water = (C6H7O2+ • Water)

By formula: C6H7O2+ + H2O = (C6H7O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.454.PHPMSMartinsen and Buttrill, 1978gas phase; M

C6H7O4S- + 2Water = C6H9O5S-

By formula: C6H7O4S- + 2H2O = C6H9O5S-

Quantity Value Units Method Reference Comment
Δr47.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr18.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

C6H8N+ + Water = (C6H8N+ • Water)

By formula: C6H8N+ + H2O = (C6H8N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.5kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr111.J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

C6H8N+ + Water = (C6H8N+ • Water)

By formula: C6H8N+ + H2O = (C6H8N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.2kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.434.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

C6H8NO+ + Water = (C6H8NO+ • Water)

By formula: C6H8NO+ + H2O = (C6H8NO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
14.400.PHPMSDavidson, Sunner J., et al., 1979gas phase; M

C6H8NO+ + Water = (C6H8NO+ • Water)

By formula: C6H8NO+ + H2O = (C6H8NO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr52.3kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

C6H8O4-2 + Water = (C6H8O4-2 • Water)

By formula: C6H8O4-2 + H2O = (C6H8O4-2 • H2O)

Quantity Value Units Method Reference Comment
Δr30. ± 18.kJ/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

(C6H8O4-2 • Water) + Water = (C6H8O4-2 • 2Water)

By formula: (C6H8O4-2 • H2O) + H2O = (C6H8O4-2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr56. ± 18.kJ/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

(C6H8O4-2 • 2Water) + Water = (C6H8O4-2 • 3Water)

By formula: (C6H8O4-2 • 2H2O) + H2O = (C6H8O4-2 • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr35.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C6H8O4-2 • 3Water) + Water = (C6H8O4-2 • 4Water)

By formula: (C6H8O4-2 • 3H2O) + H2O = (C6H8O4-2 • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C6H8O4-2 • 4Water) + Water = (C6H8O4-2 • 5Water)

By formula: (C6H8O4-2 • 4H2O) + H2O = (C6H8O4-2 • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr26.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C6H8O4-2 • 5Water) + Water = (C6H8O4-2 • 6Water)

By formula: (C6H8O4-2 • 5H2O) + H2O = (C6H8O4-2 • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr24.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

C6H9N2+ + Water = (C6H9N2+ • Water)

By formula: C6H9N2+ + H2O = (C6H9N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.5kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

C6H9N2+ + Water = (C6H9N2+ • Water)

By formula: C6H9N2+ + H2O = (C6H9N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring protonated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring protonated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring protonated; M

C6H9N2+ + Water = (C6H9N2+ • Water)

By formula: C6H9N2+ + H2O = (C6H9N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr58.2kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

C6H9O4- + Water = (C6H9O4- • Water)

By formula: C6H9O4- + H2O = (C6H9O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr24.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C6H9O4- • Water) + Water = (C6H9O4- • 2Water)

By formula: (C6H9O4- • H2O) + H2O = (C6H9O4- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr18.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C6H9O4-2 + Water = C6H11O5-

By formula: C6H9O4-2 + H2O = C6H11O5-

Quantity Value Units Method Reference Comment
Δr23.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C6H11O5- + 2Water = C6H13O6-

By formula: C6H11O5- + 2H2O = C6H13O6-

Quantity Value Units Method Reference Comment
Δr18.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C6H11O6- + 2Water + 2Water = C6H13O7-

By formula: C6H11O6- + 2H2O + 2H2O = C6H13O7-

Quantity Value Units Method Reference Comment
Δr38.1 ± 1.7kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Δr11.6kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B

C6H12NO3+ + Water = (C6H12NO3+ • Water)

By formula: C6H12NO3+ + H2O = (C6H12NO3+ • H2O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr54.4kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(C6H12NO3+ • Water) + Water = (C6H12NO3+ • 2Water)

By formula: (C6H12NO3+ • H2O) + H2O = (C6H12NO3+ • 2H2O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr51.9kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(C6H12NO3+ • 2Water) + Water = (C6H12NO3+ • 3Water)

By formula: (C6H12NO3+ • 2H2O) + H2O = (C6H12NO3+ • 3H2O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr40.kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KPHPMSMeot-Ner, 1984gas phase; M

C6H12N3O4+ + Water = (C6H12N3O4+ • Water)

By formula: C6H12N3O4+ + H2O = (C6H12N3O4+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C6H12N3O4+ • Water) + Water = (C6H12N3O4+ • 2Water)

By formula: (C6H12N3O4+ • H2O) + H2O = (C6H12N3O4+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
24.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C6H13N2O2- + Water = C6H15N2O3-

By formula: C6H13N2O2- + H2O = C6H15N2O3-

Quantity Value Units Method Reference Comment
Δr60.7 ± 2.5kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr30. ± 4.2kJ/molTDAsWincel, 2008gas phase; B

C6H13N4O2- + Water = C6H15N4O3-

By formula: C6H13N4O2- + H2O = C6H15N4O3-

Quantity Value Units Method Reference Comment
Δr63.2 ± 2.1kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr22.6 ± 3.8kJ/molTDAsWincel, 2008gas phase; B

C6H13O7- + 2Water + 2Water = C6H15O8-

By formula: C6H13O7- + 2H2O + 2H2O = C6H15O8-

Quantity Value Units Method Reference Comment
Δr33.9 ± 0.42kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Δr9.83kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B

C6H15Ge+ + Water = (C6H15Ge+ • Water)

By formula: C6H15Ge+ + H2O = (C6H15Ge+ • H2O)

Quantity Value Units Method Reference Comment
Δr104.kJ/molPHPMSStone and Wytenberg, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr132.J/mol*KPHPMSStone and Wytenberg, 1987gas phase; M

(C6H15Ge+ • Water) + Water = (C6H15Ge+ • 2Water)

By formula: (C6H15Ge+ • H2O) + H2O = (C6H15Ge+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr77.0kJ/molPHPMSStone and Wytenberg, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr137.J/mol*KPHPMSStone and Wytenberg, 1987gas phase; M

C6H15N2O2+ + Water = (C6H15N2O2+ • Water)

By formula: C6H15N2O2+ + H2O = (C6H15N2O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C6H15O+ + Water = (C6H15O+ • Water)

By formula: C6H15O+ + H2O = (C6H15O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr78.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr119.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O+ • Water) + Water = (C6H15O+ • 2Water)

By formula: (C6H15O+ • H2O) + H2O = (C6H15O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr55.2kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O+ • 2Water) + Water = (C6H15O+ • 3Water)

By formula: (C6H15O+ • 2H2O) + H2O = (C6H15O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr52.3kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O+ • 3Water) + Water = (C6H15O+ • 4Water)

By formula: (C6H15O+ • 3H2O) + H2O = (C6H15O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.9kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr99.2J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O+ • 4Water) + Water = (C6H15O+ • 5Water)

By formula: (C6H15O+ • 4H2O) + H2O = (C6H15O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr42.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O+ • 5Water) + Water = (C6H15O+ • 6Water)

By formula: (C6H15O+ • 5H2O) + H2O = (C6H15O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr39.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.234.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

(C6H15O3+ • Ethane, 1,1'-oxybis[2-methoxy-) + Water = (C6H15O3+ • Water • Ethane, 1,1'-oxybis[2-methoxy-)

By formula: (C6H15O3+ • C6H14O3) + H2O = (C6H15O3+ • H2O • C6H14O3)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr86.2kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr145.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C6H15O3+ + Water = (C6H15O3+ • Water)

By formula: C6H15O3+ + H2O = (C6H15O3+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr73.6kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr146.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O3+ • Water) + Water = (C6H15O3+ • 2Water)

By formula: (C6H15O3+ • H2O) + H2O = (C6H15O3+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.8kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C6H15O3+ • 2Water) + Water = (C6H15O3+ • 3Water)

By formula: (C6H15O3+ • 2H2O) + H2O = (C6H15O3+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr42.7kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; DG<=, ΔrH<=, (ΔrS); M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; DG<=, ΔrH<=, (ΔrS); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
16.257.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; DG<=, ΔrH<=, (ΔrS); M

C6H15S+ + Water = (C6H15S+ • Water)

By formula: C6H15S+ + H2O = (C6H15S+ • H2O)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C6H16N+ + Water = (C6H16N+ • Water)

By formula: C6H16N+ + H2O = (C6H16N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr55.2kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr114.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C6H16N+ + Water = (C6H16N+ • Water)

By formula: C6H16N+ + H2O = (C6H16N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.6kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr35.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

C6H17N2+ + Water = (C6H17N2+ • Water)

By formula: C6H17N2+ + H2O = (C6H17N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C6H18N2+2 + Water = (C6H18N2+2 • Water)

By formula: C6H18N2+2 + H2O = (C6H18N2+2 • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr74.5kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr48.1kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C6H18N2+2 • Water) + Water = (C6H18N2+2 • 2Water)

By formula: (C6H18N2+2 • H2O) + H2O = (C6H18N2+2 • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.0kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr96.7J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr43.5kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

benzoate anion + Water = (benzoate anion • Water)

By formula: C7H5O2- + H2O = (C7H5O2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr33.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(benzoate anion • Water) + Water = (benzoate anion • 2Water)

By formula: (C7H5O2- • H2O) + H2O = (C7H5O2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr53.1 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr23.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(benzoate anion • 2Water) + Water = (benzoate anion • 3Water)

By formula: (C7H5O2- • 2H2O) + H2O = (C7H5O2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.1 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr18.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

C7H6N+ + Water = (C7H6N+ • Water)

By formula: C7H6N+ + H2O = (C7H6N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr79.1kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr96.7J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C7H6NO+ + Water = (C7H6NO+ • Water)

By formula: C7H6NO+ + H2O = (C7H6NO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.426.PHPMSMartinsen and Buttrill, 1978gas phase; M

C7H7F3N+ + Water = (C7H7F3N+ • Water)

By formula: C7H7F3N+ + H2O = (C7H7F3N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr67.4kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

C7H7N2+ + Water = (C7H7N2+ • Water)

By formula: C7H7N2+ + H2O = (C7H7N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.4kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

C7H7O2+ + Water = (C7H7O2+ • Water)

By formula: C7H7O2+ + H2O = (C7H7O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr78.2kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; data from graph; M

C7H7O3+ + Water = (C7H7O3+ • Water)

By formula: C7H7O3+ + H2O = (C7H7O3+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.452.PHPMSMartinsen and Buttrill, 1978gas phase; M

C7H9O+ + Water = (C7H9O+ • Water)

By formula: C7H9O+ + H2O = (C7H9O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.454.PHPMSMartinsen and Buttrill, 1978gas phase; M

C7H9O+ + Water = (C7H9O+ • Water)

By formula: C7H9O+ + H2O = (C7H9O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.447.PHPMSMartinsen and Buttrill, 1978gas phase; M

C7H9O+ + Water = (C7H9O+ • Water)

By formula: C7H9O+ + H2O = (C7H9O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.447.PHPMSMartinsen and Buttrill, 1978gas phase; M

C7H10N+ + Water = (C7H10N+ • Water)

By formula: C7H10N+ + H2O = (C7H10N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr55.2kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C7H10N+ + Water = (C7H10N+ • Water)

By formula: C7H10N+ + H2O = (C7H10N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.5kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; ring to N proton shift on hydration; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; ring to N proton shift on hydration; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; ring to N proton shift on hydration; M

C7H10NO+ + Water = (C7H10NO+ • Water)

By formula: C7H10NO+ + H2O = (C7H10NO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.433.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

C7H10O4-2 + Water = (C7H10O4-2 • Water)

By formula: C7H10O4-2 + H2O = (C7H10O4-2 • H2O)

Quantity Value Units Method Reference Comment
Δr25. ± 18.kJ/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

(C7H10O4-2 • Water) + Water = (C7H10O4-2 • 2Water)

By formula: (C7H10O4-2 • H2O) + H2O = (C7H10O4-2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr56. ± 18.kJ/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

(C7H10O4-2 • 2Water) + Water = (C7H10O4-2 • 3Water)

By formula: (C7H10O4-2 • 2H2O) + H2O = (C7H10O4-2 • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr33.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C7H10O4-2 • 3Water) + Water = (C7H10O4-2 • 4Water)

By formula: (C7H10O4-2 • 3H2O) + H2O = (C7H10O4-2 • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr30.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C7H10O4-2 • 4Water) + Water = (C7H10O4-2 • 5Water)

By formula: (C7H10O4-2 • 4H2O) + H2O = (C7H10O4-2 • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr25.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C7H10O4-2 • 5Water) + Water = (C7H10O4-2 • 6Water)

By formula: (C7H10O4-2 • 5H2O) + H2O = (C7H10O4-2 • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr23.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

C7H11N2+ + Water = (C7H11N2+ • Water)

By formula: C7H11N2+ + H2O = (C7H11N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr50.2kJ/molPHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSDavidson, Sunner J., et al., 1979gas phase; M

C7H11O+ + Water = (C7H11O+ • Water)

By formula: C7H11O+ + H2O = (C7H11O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr69.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C7H11O+ • Water) + Water = (C7H11O+ • 2Water)

By formula: (C7H11O+ • H2O) + H2O = (C7H11O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C7H11O+ • 2Water) + Water = (C7H11O+ • 3Water)

By formula: (C7H11O+ • 2H2O) + H2O = (C7H11O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr71.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C7H11O+ • 3Water) + Water = (C7H11O+ • 4Water)

By formula: (C7H11O+ • 3H2O) + H2O = (C7H11O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.269.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

C7H11O4-2 + Water = (C7H11O4-2 • Water)

By formula: C7H11O4-2 + H2O = (C7H11O4-2 • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr23.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C7H11O4-2 + Water = C7H13O5-

By formula: C7H11O4-2 + H2O = C7H13O5-

Quantity Value Units Method Reference Comment
Δr23.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C7H15O2+ + Water = (C7H15O2+ • Water)

By formula: C7H15O2+ + H2O = (C7H15O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.7kJ/molHPMSField, 1969gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr50.J/mol*KHPMSField, 1969gas phase; Entropy change is questionable; M

C7H17O4S- + 2Water = C7H19O5S-

By formula: C7H17O4S- + 2H2O = C7H19O5S-

Quantity Value Units Method Reference Comment
Δr50.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr20.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

C7H19N2+ + Water = (C7H19N2+ • Water)

By formula: C7H19N2+ + H2O = (C7H19N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C7H22+2 + Water = (C7H22+2 • Water)

By formula: C7H22+2 + H2O = (C7H22+2 • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr74.5kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr46.4kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C7H22+2 • Water) + Water = (C7H22+2 • 2Water)

By formula: (C7H22+2 • H2O) + H2O = (C7H22+2 • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.0kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr99.2J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr41.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C7H22+2 • 2Water) + Water = (C7H22+2 • 3Water)

By formula: (C7H22+2 • 2H2O) + H2O = (C7H22+2 • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C7H22+2 • 3Water) + Water = (C7H22+2 • 4Water)

By formula: (C7H22+2 • 3H2O) + H2O = (C7H22+2 • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C7H22+2 • 4Water) + Water = (C7H22+2 • 5Water)

By formula: (C7H22+2 • 4H2O) + H2O = (C7H22+2 • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C7H22+2 • 5Water) + Water = (C7H22+2 • 6Water)

By formula: (C7H22+2 • 5H2O) + H2O = (C7H22+2 • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C8H4O4- + Water = (C8H4O4- • Water)

By formula: C8H4O4- + H2O = (C8H4O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr31.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C8H4O4-2 • 2Water) + Water = (C8H4O4-2 • 3Water)

By formula: (C8H4O4-2 • 2H2O) + H2O = (C8H4O4-2 • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr35.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C8H4O4-2 • 3Water) + Water = (C8H4O4-2 • 4Water)

By formula: (C8H4O4-2 • 3H2O) + H2O = (C8H4O4-2 • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr31.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C8H4O4-2 • 4Water) + Water = (C8H4O4-2 • 5Water)

By formula: (C8H4O4-2 • 4H2O) + H2O = (C8H4O4-2 • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C8H4O4-2 • 5Water) + Water = (C8H4O4-2 • 6Water)

By formula: (C8H4O4-2 • 5H2O) + H2O = (C8H4O4-2 • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr25.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C8H5O4- + Water = (C8H5O4- • Water)

By formula: C8H5O4- + H2O = (C8H5O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr20.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C8H5O4-2 + Water = C8H7O5-

By formula: C8H5O4-2 + H2O = C8H7O5-

Quantity Value Units Method Reference Comment
Δr60.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr31.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

C8H10O7-2 + 4Water = C8H12O8-2

By formula: C8H10O7-2 + 4H2O = C8H12O8-2

Quantity Value Units Method Reference Comment
Δr30.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C8H11O+ + Water = (C8H11O+ • Water)

By formula: C8H11O+ + H2O = (C8H11O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.455.PHPMSMartinsen and Buttrill, 1978gas phase; M

C8H11O+ + Water = (C8H11O+ • Water)

By formula: C8H11O+ + H2O = (C8H11O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
16.453.PHPMSMartinsen and Buttrill, 1978gas phase; M

C8H11O+ + Water = (C8H11O+ • Water)

By formula: C8H11O+ + H2O = (C8H11O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.455.PHPMSMartinsen and Buttrill, 1978gas phase; M

C8H12N+ + Water = (C8H12N+ • Water)

By formula: C8H12N+ + H2O = (C8H12N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr59.4kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C8H12N+ + Water = (C8H12N+ • Water)

By formula: C8H12N+ + H2O = (C8H12N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr55.2kJ/molPHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.434.PHPMSLau, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated, ring to N proton shift on hydration; M

C8H12N+ + Water = (C8H12N+ • Water)

By formula: C8H12N+ + H2O = (C8H12N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.6kJ/molPHPMSButtrill, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr88.J/mol*KPHPMSButtrill, 1983gas phase; M

C8H12O4-2 + Water = (C8H12O4-2 • Water)

By formula: C8H12O4-2 + H2O = (C8H12O4-2 • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr28. ± 18.kJ/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr23.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C8H12O4-2 • Water) + Water = (C8H12O4-2 • 2Water)

By formula: (C8H12O4-2 • H2O) + H2O = (C8H12O4-2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr59. ± 18.kJ/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

(C8H12O4-2 • 2Water) + Water = (C8H12O4-2 • 3Water)

By formula: (C8H12O4-2 • 2H2O) + H2O = (C8H12O4-2 • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr32.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C8H12O4-2 • 3Water) + Water = (C8H12O4-2 • 4Water)

By formula: (C8H12O4-2 • 3H2O) + H2O = (C8H12O4-2 • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C8H12O4-2 • 4Water) + Water = (C8H12O4-2 • 5Water)

By formula: (C8H12O4-2 • 4H2O) + H2O = (C8H12O4-2 • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C8H12O4-2 • 5Water) + Water = (C8H12O4-2 • 6Water)

By formula: (C8H12O4-2 • 5H2O) + H2O = (C8H12O4-2 • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr23.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

C8H12O8-2 + 5Water = C8H14O9-2

By formula: C8H12O8-2 + 5H2O = C8H14O9-2

Quantity Value Units Method Reference Comment
Δr26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C8H13O4-2 + Water = C8H15O5-

By formula: C8H13O4-2 + H2O = C8H15O5-

Quantity Value Units Method Reference Comment
Δr22.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C8H14O9-2 + 6Water = C8H16O10-2

By formula: C8H14O9-2 + 6H2O = C8H16O10-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C8H15O8- + 3Water + Water = C8H17O9-

By formula: C8H15O8- + 3H2O + H2O = C8H17O9-

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Quantity Value Units Method Reference Comment
Δr2.7kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B

C8H18N3O3+ + Water = (C8H18N3O3+ • Water)

By formula: C8H18N3O3+ + H2O = (C8H18N3O3+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C8H20N+ + Water = (C8H20N+ • Water)

By formula: C8H20N+ + H2O = (C8H20N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
36.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C8H20N+ • Water) + Water = (C8H20N+ • 2Water)

By formula: (C8H20N+ • H2O) + H2O = (C8H20N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C8H20N+ • 2Water) + Water = (C8H20N+ • 3Water)

By formula: (C8H20N+ • 2H2O) + H2O = (C8H20N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

C8H21N2+ + Water = (C8H21N2+ • Water)

By formula: C8H21N2+ + H2O = (C8H21N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C8H22N2+2 + Water = (C8H22N2+2 • Water)

By formula: C8H22N2+2 + H2O = (C8H22N2+2 • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr70.7kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr43.9kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C8H22N2+2 • Water) + Water = (C8H22N2+2 • 2Water)

By formula: (C8H22N2+2 • H2O) + H2O = (C8H22N2+2 • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr70.3kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr41.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C8H22N2+2 • 2Water) + Water = (C8H22N2+2 • 3Water)

By formula: (C8H22N2+2 • 2H2O) + H2O = (C8H22N2+2 • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C8H22N2+2 • 3Water) + Water = (C8H22N2+2 • 4Water)

By formula: (C8H22N2+2 • 3H2O) + H2O = (C8H22N2+2 • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
29.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C8H22N2+2 • 4Water) + Water = (C8H22N2+2 • 5Water)

By formula: (C8H22N2+2 • 4H2O) + H2O = (C8H22N2+2 • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
24.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C8H22N2+2 • 5Water) + Water = (C8H22N2+2 • 6Water)

By formula: (C8H22N2+2 • 5H2O) + H2O = (C8H22N2+2 • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C9H10NO2- + Water = C9H12NO3-

By formula: C9H10NO2- + H2O = C9H12NO3-

Quantity Value Units Method Reference Comment
Δr60.7 ± 1.7kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr30.1 ± 3.8kJ/molTDAsWincel, 2008gas phase; B

C9H11O2+ + Water = (C9H11O2+ • Water)

By formula: C9H11O2+ + H2O = (C9H11O2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.3kJ/molHPMSField, 1969gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr50.J/mol*KHPMSField, 1969gas phase; Entropy change is questionable; M

C9H12NO+ + Water = (C9H12NO+ • Water)

By formula: C9H12NO+ + H2O = (C9H12NO+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.2kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

C9H14N+ + Water = (C9H14N+ • Water)

By formula: C9H14N+ + H2O = (C9H14N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr59.4kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr129.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C9H14N+ + Water = (C9H14N+ • Water)

By formula: C9H14N+ + H2O = (C9H14N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), ΔrS should be 113.6 J/mol*K; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), ΔrS should be 113.6 J/mol*K; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
9.6394.PHPMSMeot-Ner M. and Sieck, 1983gas phase; (H), ΔrS should be 113.6 J/mol*K; M

C9H14O4-2 + Water = (C9H14O4-2 • Water)

By formula: C9H14O4-2 + H2O = (C9H14O4-2 • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr22.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C9H14O4-2 • 2Water) + Water = (C9H14O4-2 • 3Water)

By formula: (C9H14O4-2 • 2H2O) + H2O = (C9H14O4-2 • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr32.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C9H14O4-2 • 3Water) + Water = (C9H14O4-2 • 4Water)

By formula: (C9H14O4-2 • 3H2O) + H2O = (C9H14O4-2 • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr29.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C9H14O4-2 • 4Water) + Water = (C9H14O4-2 • 5Water)

By formula: (C9H14O4-2 • 4H2O) + H2O = (C9H14O4-2 • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr25.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C9H14O4-2 • 5Water) + Water = (C9H14O4-2 • 6Water)

By formula: (C9H14O4-2 • 5H2O) + H2O = (C9H14O4-2 • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr22.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C9H20O7-2 + 4Water = C9H22O8-2

By formula: C9H20O7-2 + 4H2O = C9H22O8-2

Quantity Value Units Method Reference Comment
Δr28.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C9H22N+ + Water = (C9H22N+ • Water)

By formula: C9H22N+ + H2O = (C9H22N+ • H2O)

Quantity Value Units Method Reference Comment
Δr52.3kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr126.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C9H22O8-2 + 5Water = C9H24O9-2

By formula: C9H22O8-2 + 5H2O = C9H24O9-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C9H24N2+2 + Water = (C9H24N2+2 • Water)

By formula: C9H24N2+2 + H2O = (C9H24N2+2 • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr69.0kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr43.1kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C9H24N2+2 • Water) + Water = (C9H24N2+2 • 2Water)

By formula: (C9H24N2+2 • H2O) + H2O = (C9H24N2+2 • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr68.2kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr97.9J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr39.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

C9H24O9-2 + 6Water = C9H26O10-2

By formula: C9H24O9-2 + 6H2O = C9H26O10-2

Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H6O6S2-2 + Water = (C10H6O6S2-2 • Water)

By formula: C10H6O6S2-2 + H2O = (C10H6O6S2-2 • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr33.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C10H6O6S2-2 • Water) + Water = (C10H6O6S2-2 • 2Water)

By formula: (C10H6O6S2-2 • H2O) + H2O = (C10H6O6S2-2 • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr29.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C10H6O6S2-2 • 2Water) + Water = (C10H6O6S2-2 • 3Water)

By formula: (C10H6O6S2-2 • 2H2O) + H2O = (C10H6O6S2-2 • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C10H6O6S2-2 • 3Water) + Water = (C10H6O6S2-2 • 4Water)

By formula: (C10H6O6S2-2 • 3H2O) + H2O = (C10H6O6S2-2 • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr23.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C10H8O7S2-2 + 2Water = C10H10O8S2-2

By formula: C10H8O7S2-2 + 2H2O = C10H10O8S2-2

Quantity Value Units Method Reference Comment
Δr29.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H10O8S2-2 + 3Water = C10H12O9S2-2

By formula: C10H10O8S2-2 + 3H2O = C10H12O9S2-2

Quantity Value Units Method Reference Comment
Δr26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H12O9S2-2 + 4Water = C10H14O10S2-2

By formula: C10H12O9S2-2 + 4H2O = C10H14O10S2-2

Quantity Value Units Method Reference Comment
Δr23.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

(C10H16O4-2 • 2Water) + Water = (C10H16O4-2 • 3Water)

By formula: (C10H16O4-2 • 2H2O) + H2O = (C10H16O4-2 • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr31.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C10H16O4-2 • 3Water) + Water = (C10H16O4-2 • 4Water)

By formula: (C10H16O4-2 • 3H2O) + H2O = (C10H16O4-2 • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr28.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C10H16O4-2 • 4Water) + Water = (C10H16O4-2 • 5Water)

By formula: (C10H16O4-2 • 4H2O) + H2O = (C10H16O4-2 • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr24.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C10H16O4-2 • 5Water) + Water = (C10H16O4-2 • 6Water)

By formula: (C10H16O4-2 • 5H2O) + H2O = (C10H16O4-2 • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr21.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C10H17O4- + Water = (C10H17O4- • Water)

By formula: C10H17O4- + H2O = (C10H17O4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr21.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C10H19N5O13P2-2 + 4Water = C10H21N5O14P2-2

By formula: C10H19N5O13P2-2 + 4H2O = C10H21N5O14P2-2

Quantity Value Units Method Reference Comment
Δr25.5 ± 0.84kJ/molIMREBlades, Ho, et al., 1996, 3gas phase; Correction to published article: P. Kebarle; B

C10H21O5+ + Water = (C10H21O5+ • Water)

By formula: C10H21O5+ + H2O = (C10H21O5+ • H2O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr90.4kJ/molPHPMSSharma and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr138.J/mol*KPHPMSSharma and Kebarle, 1984gas phase; M

C10H22O7-2 + 4Water = C10H24O8-2

By formula: C10H22O7-2 + 4H2O = C10H24O8-2

Quantity Value Units Method Reference Comment
Δr28.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H24O8-2 + 5Water = C10H26O9-2

By formula: C10H24O8-2 + 5H2O = C10H26O9-2

Quantity Value Units Method Reference Comment
Δr24.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H25N2+ + Water = (C10H25N2+ • Water)

By formula: C10H25N2+ + H2O = (C10H25N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C10H26N2+2 + Water = (C10H26N2+2 • Water)

By formula: C10H26N2+2 + H2O = (C10H26N2+2 • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr70.3kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr95.4J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr43.1kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C10H26N2+2 • Water) + Water = (C10H26N2+2 • 2Water)

By formula: (C10H26N2+2 • H2O) + H2O = (C10H26N2+2 • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr70.3kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Δr39.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

(C10H26N2+2 • 2Water) + Water = (C10H26N2+2 • 3Water)

By formula: (C10H26N2+2 • 2H2O) + H2O = (C10H26N2+2 • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C10H26N2+2 • 3Water) + Water = (C10H26N2+2 • 4Water)

By formula: (C10H26N2+2 • 3H2O) + H2O = (C10H26N2+2 • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C10H26N2+2 • 4Water) + Water = (C10H26N2+2 • 5Water)

By formula: (C10H26N2+2 • 4H2O) + H2O = (C10H26N2+2 • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
24.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C10H26N2+2 • 5Water) + Water = (C10H26N2+2 • 6Water)

By formula: (C10H26N2+2 • 5H2O) + H2O = (C10H26N2+2 • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C10H26O9-2 + 6Water = C10H28O10-2

By formula: C10H26O9-2 + 6H2O = C10H28O10-2

Quantity Value Units Method Reference Comment
Δr21.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C10H27N5O17P2-2 + 8Water = C10H29N5O18P2-2

By formula: C10H27N5O17P2-2 + 8H2O = C10H29N5O18P2-2

Quantity Value Units Method Reference Comment
Δr18.4 ± 0.84kJ/molIMREBlades, Ho, et al., 1996, 3gas phase; Correction to published article: P. Kebarle; B

L-Tryptophan anion + Water = C11H13N2O3-

By formula: C11H11N2O2- + H2O = C11H13N2O3-

Quantity Value Units Method Reference Comment
Δr61.9 ± 2.1kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Δr28.9 ± 3.8kJ/molTDAsWincel, 2008gas phase; B

C11H18N+ + Water = (C11H18N+ • Water)

By formula: C11H18N+ + H2O = (C11H18N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr53.6kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr134.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C12H25O6+ + Water = (C12H25O6+ • Water)

By formula: C12H25O6+ + H2O = (C12H25O6+ • H2O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr110.kJ/molPHPMSSharma and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr145.J/mol*KPHPMSSharma and Kebarle, 1984gas phase; M

C12H28N+ + Water = (C12H28N+ • Water)

By formula: C12H28N+ + H2O = (C12H28N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56.9kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr152.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

C12H29N2+ + Water = (C12H29N2+ • Water)

By formula: C12H29N2+ + H2O = (C12H29N2+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

C13H9N- + Water = C13H11NO-

By formula: C13H9N- + H2O = C13H11NO-

Quantity Value Units Method Reference Comment
Δr27. ± 6.3kJ/molN/AKokubo, Ando, et al., 2004gas phase; B

C13H22N+ + Water = (C13H22N+ • Water)

By formula: C13H22N+ + H2O = (C13H22N+ • H2O)

Bond type: Hydrogen bonds with steric hindrance in positive ions

Quantity Value Units Method Reference Comment
Δr52.3kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Δr170.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M

Calcium ion (1+) + Water = (Calcium ion (1+) • Water)

By formula: Ca+ + H2O = (Ca+ • H2O)

Quantity Value Units Method Reference Comment
Δr120.kJ/molHPMSKochanski and Constantin, 1987gas phase; M

(Calcium ion (1+) • Water) + Water = (Calcium ion (1+) • 2Water)

By formula: (Ca+ • H2O) + H2O = (Ca+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr100.kJ/molHPMSKochanski and Constantin, 1987gas phase; M

(Calcium ion (1+) • 2Water) + Water = (Calcium ion (1+) • 3Water)

By formula: (Ca+ • 2H2O) + H2O = (Ca+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr90.0kJ/molHPMSKochanski and Constantin, 1987gas phase; M

(Calcium ion (1+) • 3Water) + Water = (Calcium ion (1+) • 4Water)

By formula: (Ca+ • 3H2O) + H2O = (Ca+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr78.2kJ/molHPMSKochanski and Constantin, 1987gas phase; M

(Calcium ion (1+) • 4Water) + Water = (Calcium ion (1+) • 5Water)

By formula: (Ca+ • 4H2O) + H2O = (Ca+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr73.2kJ/molHPMSKochanski and Constantin, 1987gas phase; M

(Ca+2 • 8Water) + Water = (Ca+2 • 9Water)

By formula: (Ca+2 • 8H2O) + H2O = (Ca+2 • 9H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Ca+2 • 9Water) + Water = (Ca+2 • 10Water)

By formula: (Ca+2 • 9H2O) + H2O = (Ca+2 • 10H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Ca+2 • 10Water) + Water = (Ca+2 • 11Water)

By formula: (Ca+2 • 10H2O) + H2O = (Ca+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Ca+2 • 11Water) + Water = (Ca+2 • 12Water)

By formula: (Ca+2 • 11H2O) + H2O = (Ca+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
29.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Chlorine anion • Methyl Alcohol) + Water = (Chlorine anion • Water • Methyl Alcohol)

By formula: (Cl- • CH4O) + H2O = (Cl- • H2O • CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.6kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr70.7J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion • 2Methyl Alcohol) + Water = (Chlorine anion • Water • 2Methyl Alcohol)

By formula: (Cl- • 2CH4O) + H2O = (Cl- • H2O • 2CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr32.kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr46.J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion • Hydrogen chloride) + Water = (Chlorine anion • Water • Hydrogen chloride)

By formula: (Cl- • HCl) + H2O = (Cl- • H2O • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr78.2J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M

(Chlorine anion • 2Hydrogen chloride) + Water = (Chlorine anion • Water • 2Hydrogen chloride)

By formula: (Cl- • 2HCl) + H2O = (Cl- • H2O • 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr32.kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr63.6J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M

Chlorine anion + Water = (Chlorine anion • Water)

By formula: Cl- + H2O = (Cl- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr60. ± 20.kJ/molAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Δr81. ± 10.J/mol*KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr40. ± 20.kJ/molAVGN/AAverage of 9 values; Individual data points

(Chlorine anion • Water • Methyl Alcohol) + Water = (Chlorine anion • 2Water • Methyl Alcohol)

By formula: (Cl- • H2O • CH4O) + H2O = (Cl- • 2H2O • CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr64.9J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion • Water • Hydrogen chloride) + Water = (Chlorine anion • 2Water • Hydrogen chloride)

By formula: (Cl- • H2O • HCl) + H2O = (Cl- • 2H2O • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in 86 KEE/CAS; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in 86 KEE/CAS; M

(Chlorine anion • Water) + Water = (Chlorine anion • 2Water)

By formula: (Cl- • H2O) + H2O = (Cl- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr53. ± 5.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr85.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr87.0J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr27.2kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr27. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr27.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr28.kJ/molFAFehsenfeld and Ferguson, 1974gas phase; M

(Chlorine anion • 2Water) + Water = (Chlorine anion • 3Water)

By formula: (Cl- • 2H2O) + H2O = (Cl- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr93.7J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr97.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr21. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

(Chlorine anion • 3Water) + Water = (Chlorine anion • 4Water)

By formula: (Cl- • 3H2O) + H2O = (Cl- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr40.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr44. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr45.6 ± 2.9kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Δr46.4 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr104.J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr108.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr16. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr14.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr14.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr17. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Chlorine anion • 4Water) + Water = (Chlorine anion • 5Water)

By formula: (Cl- • 4H2O) + H2O = (Cl- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr40. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr28.0kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr40. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr13. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr12. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Chlorine anion • 5Water) + Water = (Chlorine anion • 6Water)

By formula: (Cl- • 5H2O) + H2O = (Cl- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr35.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr37. ± 2.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr10. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 6Water) + Water = (Chlorine anion • 7Water)

By formula: (Cl- • 6H2O) + H2O = (Cl- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B
Δr28.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr34.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr8.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Chlorine anion • Water • Sulfur dioxide) + Water = (Chlorine anion • 2Water • Sulfur dioxide)

By formula: (Cl- • H2O • O2S) + H2O = (Cl- • 2H2O • O2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.9kJ/molTDAsUpschulte, Schelling, et al., 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KHPMSUpschulte, Schelling, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr14.2kJ/molTDAsUpschulte, Schelling, et al., 1984gas phase; B

(Chlorine anion • Sulfur dioxide) + Water = (Chlorine anion • Water • Sulfur dioxide)

By formula: (Cl- • O2S) + H2O = (Cl- • H2O • O2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.51kJ/molTDAsUpschulte, Schelling, et al., 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr81.2J/mol*KHPMSUpschulte, Schelling, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr19.2kJ/molTDAsUpschulte, Schelling, et al., 1984gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.296.FAFehsenfeld and Ferguson, 1974gas phase; From thermochemical cycle,switching reaction(H2O/SO2); M

(Chlorine anion • 2Sulfur dioxide) + Water = (Chlorine anion • Water • 2Sulfur dioxide)

By formula: (Cl- • 2O2S) + H2O = (Cl- • H2O • 2O2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.4kJ/molTDAsUpschulte, Schelling, et al., 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KHPMSUpschulte, Schelling, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr13.0kJ/molTDAsUpschulte, Schelling, et al., 1984gas phase; B

ClO2- + Water = (ClO2- • Water)

By formula: ClO2- + H2O = (ClO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.6 ± 2.1kJ/molTherTschurl and Boesl, 2007gas phase; affinity is difference from ClO2- EA, corrected for calculated neutral BE of 0.09 eV; B
Δr66.9 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr37.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(ClO2- • Water) + Water = (ClO2- • 2Water)

By formula: (ClO2- • H2O) + H2O = (ClO2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.8 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(ClO2- • 2Water) + Water = (ClO2- • 3Water)

By formula: (ClO2- • 2H2O) + H2O = (ClO2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr20.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

ClO3- + Water = (ClO3- • Water)

By formula: ClO3- + H2O = (ClO3- • H2O)

Quantity Value Units Method Reference Comment
Δr55.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr25.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

(ClO3- • Water) + Water = (ClO3- • 2Water)

By formula: (ClO3- • H2O) + H2O = (ClO3- • 2H2O)

Quantity Value Units Method Reference Comment
Δr49.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr19.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

ClO3- + Water = (ClO3- • Water)

By formula: ClO3- + H2O = (ClO3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(ClO3- • Water) + Water = (ClO3- • 2Water)

By formula: (ClO3- • H2O) + H2O = (ClO3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr20.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

ClO4- + Water = (ClO4- • Water)

By formula: ClO4- + H2O = (ClO4- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr20.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

Cobalt ion (1+) + Water = (Cobalt ion (1+) • Water)

By formula: Co+ + H2O = (Co+ • H2O)

Quantity Value Units Method Reference Comment
Δr160. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Δr168.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
161. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • Water) + Water = (Cobalt ion (1+) • 2Water)

By formula: (Co+ • H2O) + H2O = (Co+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr175.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
162. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 2Water) + Water = (Cobalt ion (1+) • 3Water)

By formula: (Co+ • 2H2O) + H2O = (Co+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
64.9 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 3Water) + Water = (Cobalt ion (1+) • 4Water)

By formula: (Co+ • 3H2O) + H2O = (Co+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
58.2 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Co+2 • 9Water) + Water = (Co+2 • 10Water)

By formula: (Co+2 • 9H2O) + H2O = (Co+2 • 10H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
36.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Co+2 • 10Water) + Water = (Co+2 • 11Water)

By formula: (Co+2 • 10H2O) + H2O = (Co+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Co+2 • 11Water) + Water = (Co+2 • 12Water)

By formula: (Co+2 • 11H2O) + H2O = (Co+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Chromium ion (1+) + Water = (Chromium ion (1+) • Water)

By formula: Cr+ + H2O = (Cr+ • H2O)

Quantity Value Units Method Reference Comment
Δr120. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Δr91.6kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
129. (+9.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) • Water) + Water = (Chromium ion (1+) • 2Water)

By formula: (Cr+ • H2O) + H2O = (Cr+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr123.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
142. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) • 2Water) + Water = (Chromium ion (1+) • 3Water)

By formula: (Cr+ • 2H2O) + H2O = (Cr+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
50. (+50.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Chromium ion (1+) • 3Water) + Water = (Chromium ion (1+) • 4Water)

By formula: (Cr+ • 3H2O) + H2O = (Cr+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
51.0 (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cesium ion (1+) + Water = (Cesium ion (1+) • Water)

By formula: Cs+ + H2O = (Cs+ • H2O)

Quantity Value Units Method Reference Comment
Δr49.8kJ/molDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Δr57.3kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr59.8J/mol*KDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Δr81.2J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Cesium ion (1+) • Water) + Water = (Cesium ion (1+) • 2Water)

By formula: (Cs+ • H2O) + H2O = (Cs+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr47.3kJ/molDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Δr52.3kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr69.5J/mol*KDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Δr92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr25.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Cesium ion (1+) • 2Water) + Water = (Cesium ion (1+) • 3Water)

By formula: (Cs+ • 2H2O) + H2O = (Cs+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr41.kJ/molDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Δr46.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr69.5J/mol*KDTMcKnight and Sawina, 1972gas phase; Entropy change is questionable; M
Δr99.2J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr20.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

(Cesium ion (1+) • 3Water) + Water = (Cesium ion (1+) • 4Water)

By formula: (Cs+ • 3H2O) + H2O = (Cs+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr44.4kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Cesium ion (1+) • Water • Sulfur dioxide) + Water = (Cesium ion (1+) • 2Water • Sulfur dioxide)

By formula: (Cs+ • H2O • O2S) + H2O = (Cs+ • 2H2O • O2S)

Quantity Value Units Method Reference Comment
Δr22.kJ/molHPMSBanic and Iribarne, 1985gas phase; electeric fields; M

Copper ion (1+) + Water = (Copper ion (1+) • Water)

By formula: Cu+ + H2O = (Cu+ • H2O)

Quantity Value Units Method Reference Comment
Δr49.8kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Δr150. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Δr150. ± 10.kJ/molCIDMagnera, David, et al., 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Δr18.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
157. (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Copper ion (1+) • Water) + Water = (Copper ion (1+) • 2Water)

By formula: (Cu+ • H2O) + H2O = (Cu+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr58.2kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Δr160. ± 10.kJ/molCIDMagnera, David, et al., 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
Δr27.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
170. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Copper ion (1+) • 2Water) + Water = (Copper ion (1+) • 3Water)

By formula: (Cu+ • 2H2O) + H2O = (Cu+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr70. ± 10.kJ/molCIDMagnera, David, et al., 1989, 2gas phase; M
Δr68.6kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
56.9 (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Copper ion (1+) • 3Water) + Water = (Copper ion (1+) • 4Water)

By formula: (Cu+ • 3H2O) + H2O = (Cu+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molCIDMagnera, David, et al., 1989, 2gas phase; M
Δr69.9kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr126.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
54.0 (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Copper ion (1+) • 4Water) + Water = (Copper ion (1+) • 5Water)

By formula: (Cu+ • 4H2O) + H2O = (Cu+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr58.6kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Δr122.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

Fluorine anion + Water = (Fluorine anion • Water)

By formula: F- + H2O = (F- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr114.6 ± 2.1kJ/molTDAsWeis, Kemper, et al., 1999gas phase; B
Δr97.49kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr72.8J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr91.6 ± 2.1kJ/molTDAsWeis, Kemper, et al., 1999gas phase; B
Δr75.7 ± 8.4kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

(Fluorine anion • Water) + Water = (Fluorine anion • 2Water)

By formula: (F- • H2O) + H2O = (F- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr80.3 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Stated electron affinity is the Vertical Detachment Energy; B,M
Δr69.5 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr69.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr78.2J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr52.3 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Stated electron affinity is the Vertical Detachment Energy; B
Δr46.0 ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr46.02kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

(Fluorine anion • 2Water) + Water = (Fluorine anion • 3Water)

By formula: (F- • 2H2O) + H2O = (F- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr64.0 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr57.3 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr57.3 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr85.4J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr35. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr32. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr31.8kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

(Fluorine anion • 3Water) + Water = (Fluorine anion • 4Water)

By formula: (F- • 3H2O) + H2O = (F- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr58.2 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr56.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr111.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr113.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr25. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr23.0kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr26. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Fluorine anion • 4Water) + Water = (Fluorine anion • 5Water)

By formula: (F- • 4H2O) + H2O = (F- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr55.2 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr128.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr19. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr29.7kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr19. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Fluorine anion • 5Water) + Water = (Fluorine anion • 6Water)

By formula: (F- • 5H2O) + H2O = (F- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.6 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr15. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Fluorine anion • 6Water) + Water = (Fluorine anion • 7Water)

By formula: (F- • 6H2O) + H2O = (F- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr11. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Fluorine anion • 7Water) + Water = (Fluorine anion • 8Water)

By formula: (F- • 7H2O) + H2O = (F- • 8H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.9 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr131.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; 0.4; M
Quantity Value Units Method Reference Comment
Δr7.5 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Fluorine anion • 8Water) + Water = (Fluorine anion • 9Water)

By formula: (F- • 8H2O) + H2O = (F- • 9H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.4 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr137.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr5.4 ± 8.8kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Fluorine anion • 9Water) + Water = (Fluorine anion • 10Water)

By formula: (F- • 9H2O) + H2O = (F- • 10H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.02kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr140.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr4.60kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

Iron ion (1+) + Water = (Iron ion (1+) • Water)

By formula: Fe+ + H2O = (Fe+ • H2O)

Quantity Value Units Method Reference Comment
Δr120. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Δr137.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
128. (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • Water) + Water = (Iron ion (1+) • 2Water)

By formula: (Fe+ • H2O) + H2O = (Fe+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr171.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
164. (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 2Water) + Water = (Iron ion (1+) • 3Water)

By formula: (Fe+ • 2H2O) + H2O = (Fe+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
76.1 (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3Water) + Water = (Iron ion (1+) • 4Water)

By formula: (Fe+ • 3H2O) + H2O = (Fe+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
82.0 (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Hydrogen anion + Water = (Hydrogen anion • Water)

By formula: H- + H2O = (H- • H2O)

Quantity Value Units Method Reference Comment
Δr74.1 ± 8.4kJ/molN/AMiller, Leopold, et al., 1985gas phase; EA given is Vertical Detachment Energy. Est. Adiabatic: 1.40 eV, 32.3 kcal/mol; B
Δr72. ± 15.kJ/molTherPaulson and Henchman, 1984gas phase; HOH..HO- + H2 ->. See also Griffiths and Harris, 1989; B,M
Δr57.74kJ/molCIDTPaulson and Henchman, 1982gas phase; B

HCaO+ + Water = (HCaO+ • Water)

By formula: HCaO+ + H2O = (HCaO+ • H2O)

Quantity Value Units Method Reference Comment
Δr144.kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

HO- + Water = (HO- • Water)

By formula: HO- + H2O = (HO- • H2O)

Quantity Value Units Method Reference Comment
Δr120. ± 30.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr80.3 ± 4.2kJ/molTDAsPaul and Kebarle, 1990gas phase; B
Δr84.1 ± 6.7kJ/molTDEqMeot-Ner and Sieck, 1986gas phase; B
Δr83.7 ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; B
Δr77.82kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

(HO- • Water) + Water = (HO- • 2Water)

By formula: (HO- • H2O) + H2O = (HO- • 2H2O)

Quantity Value Units Method Reference Comment
Δr73.6 ± 4.2kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; B
Δr74.9 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Quantity Value Units Method Reference Comment
Δr46.9 ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; B
Δr48.53kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

(HO- • 2Water) + Water = (HO- • 3Water)

By formula: (HO- • 2H2O) + H2O = (HO- • 3H2O)

Quantity Value Units Method Reference Comment
Δr63.2 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr67.8 ± 4.2kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr38. ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; B

(HO- • 3Water) + Water = (HO- • 4Water)

By formula: (HO- • 3H2O) + H2O = (HO- • 4H2O)

Quantity Value Units Method Reference Comment
Δr50.21kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr24. ± 5.9kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B

(HO- • 4Water) + Water = (HO- • 5Water)

By formula: (HO- • 4H2O) + H2O = (HO- • 5H2O)

Quantity Value Units Method Reference Comment
Δr48.12kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr18. ± 5.9kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B

(HO- • 5Water) + Water = (HO- • 6Water)

By formula: (HO- • 5H2O) + H2O = (HO- • 6H2O)

Quantity Value Units Method Reference Comment
Δr46.86kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr18. ± 5.9kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B

(HO- • 6Water) + Water = (HO- • 7Water)

By formula: (HO- • 6H2O) + H2O = (HO- • 7H2O)

Quantity Value Units Method Reference Comment
Δr43.51kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr13. ± 5.9kJ/molN/AMeot-Ner (Mautner) and Speller, 1986gas phase; B

(HO- • 7Water) + Water = (HO- • 8Water)

By formula: (HO- • 7H2O) + H2O = (HO- • 8H2O)

Quantity Value Units Method Reference Comment
Δr41. ± 4.2kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
Δr11. ± 5.9kJ/molTDAsMeot-Ner (Mautner) and Speller, 1986gas phase; Entropy estimated; B

Hydroxyl anion + Water = (Hydroxyl anion • Water)

By formula: HO- + H2O = (HO- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr113. ± 4.kJ/molAVGN/AAverage of 3 out of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr118.J/mol*KPHPMSPaul and Kebarle, 1990gas phase; M
Δr91.2J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr87.0J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Δr79.9J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M

(Hydroxyl anion • Water) + Water = (Hydroxyl anion • 2Water)

By formula: (HO- • H2O) + H2O = (HO- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr73.6kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr75.kJ/molCIDHierl and Paulson, 1984gas phase; M
Δr74.9kJ/molHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Δr68.6kJ/molPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Δr96.kJ/molCIDDePaz, Giardini, et al., 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr88.7J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Δr80.8J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M

(Hydroxyl anion • 2Water) + Water = (Hydroxyl anion • 3Water)

By formula: (HO- • 2H2O) + H2O = (HO- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr67.8kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr63.2kJ/molPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Δr75.kJ/molCIDDePaz, Giardini, et al., 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr104.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M

(Hydroxyl anion • 3Water) + Water = (Hydroxyl anion • 4Water)

By formula: (HO- • 3H2O) + H2O = (HO- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr50.2kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr59.4kJ/molPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr88.3J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr123.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr23.kJ/molFAFehsenfeld and Ferguson, 1974gas phase; M

(Hydroxyl anion • 4Water) + Water = (Hydroxyl anion • 5Water)

By formula: (HO- • 4H2O) + H2O = (HO- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.1kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr59.0kJ/molPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Δr139.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; deuterated; M

(Hydroxyl anion • 5Water) + Water = (Hydroxyl anion • 6Water)

By formula: (HO- • 5H2O) + H2O = (HO- • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr46.9kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M

(Hydroxyl anion • 6Water) + Water = (Hydroxyl anion • 7Water)

By formula: (HO- • 6H2O) + H2O = (HO- • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M

(Hydroxyl anion • 7Water) + Water = (Hydroxyl anion • 8Water)

By formula: (HO- • 7H2O) + H2O = (HO- • 8H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
16.245.PHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; deuterated; M

HOSr+ + Water = (HOSr+ • Water)

By formula: HOSr+ + H2O = (HOSr+ • H2O)

Quantity Value Units Method Reference Comment
Δr125.kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

(HO4S- • Nitric acid) + Water = (HO4S- • Water • Nitric acid)

By formula: (HO4S- • HNO3) + H2O = (HO4S- • H2O • HNO3)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

HO4S- + Water = (HO4S- • Water)

By formula: HO4S- + H2O = (HO4S- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(HO4S- • Water) + Water = (HO4S- • 2Water)

By formula: (HO4S- • H2O) + H2O = (HO4S- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr19.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(HO4S- • Water • 3Sulfuric Acid) + Water = (HO4S- • 2Water • 3Sulfuric Acid)

By formula: (HO4S- • H2O • 3H2O4S) + H2O = (HO4S- • 2H2O • 3H2O4S)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(HO4S- • 2Sulfuric Acid) + Water = (HO4S- • Water • 2Sulfuric Acid)

By formula: (HO4S- • 2H2O4S) + H2O = (HO4S- • H2O • 2H2O4S)

Quantity Value Units Method Reference Comment
Δr50.6kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(HO4S- • 3Sulfuric Acid) + Water = (HO4S- • Water • 3Sulfuric Acid)

By formula: (HO4S- • 3H2O4S) + H2O = (HO4S- • H2O • 3H2O4S)

Quantity Value Units Method Reference Comment
Δr57.7kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

(HO4S- • 4Sulfuric Acid) + Water = (HO4S- • Water • 4Sulfuric Acid)

By formula: (HO4S- • 4H2O4S) + H2O = (HO4S- • H2O • 4H2O4S)

Quantity Value Units Method Reference Comment
Δr58.2kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

HS- + Water = (HS- • Water)

By formula: HS- + H2O = (HS- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr59.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Δr59.4kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Δr78.2J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M
Δr78.2J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr36. ± 8.4kJ/molTDAsMeot-ner, 1988gas phase; B

(HS- • Water) + Water = (HS- • 2Water)

By formula: (HS- • H2O) + H2O = (HS- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr52.7kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Δr52.7kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M
Δr85.4J/mol*KPHPMSMeot-ner, 1988gas phase; M

(HS- • 2Water) + Water = (HS- • 3Water)

By formula: (HS- • 2H2O) + H2O = (HS- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.0kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Δr49.0kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr98.3J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M
Δr98.3J/mol*KPHPMSMeot-ner, 1988gas phase; M

H2BrO4- + 2Water = H4BrO5-

By formula: H2BrO4- + 2H2O = H4BrO5-

Quantity Value Units Method Reference Comment
Δr50.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr20.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

H2IO4- + 2Water = H4IO5-

By formula: H2IO4- + 2H2O = H4IO5-

Quantity Value Units Method Reference Comment
Δr50.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr20.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

H2N3O- + 2Water = H4N3O2-

By formula: H2N3O- + 2H2O = H4N3O2-

Quantity Value Units Method Reference Comment
Δr40. ± 390.kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 3.78±0.06 eV; B

H2O+ + Water = (H2O+ • Water)

By formula: H2O+ + H2O = (H2O+ • H2O)

Quantity Value Units Method Reference Comment
Δr150.kJ/molPINg, Trevor, et al., 1977gas phase; ΔrH>; M

H2O2- + 2Water = H4O3-

By formula: H2O2- + 2H2O = H4O3-

Quantity Value Units Method Reference Comment
Δr77.0 ± 7.5kJ/molLPESClements, Luong, et al., 2001gas phase; B

H2O3- + Pyridine + Water = C5H7NO3-

By formula: H2O3- + C5H5N + H2O = C5H7NO3-

Quantity Value Units Method Reference Comment
Δr137. ± 9.6kJ/molN/ALe Barbu, Schiedt, et al., 2002gas phase; Affinity is difference in EAs of lesser solvated species; B

H2O3- + Naphthalene + Water = C10H10O3-

By formula: H2O3- + C10H8 + H2O = C10H10O3-

Quantity Value Units Method Reference Comment
Δr158. ± 9.6kJ/molN/ALe Barbu, Schiedt, et al., 2002gas phase; Affinity is difference in EAs of lesser solvated species; B

H2O3P- + Water = (H2O3P- • Water)

By formula: H2O3P- + H2O = (H2O3P- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr33.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(H2O3P- • Water) + Water = (H2O3P- • 2Water)

By formula: (H2O3P- • H2O) + H2O = (H2O3P- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr28.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(H2O3P- • 2Water) + Water = (H2O3P- • 3Water)

By formula: (H2O3P- • 2H2O) + H2O = (H2O3P- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr22.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

H2O4P- + Water = (H2O4P- • Water)

By formula: H2O4P- + H2O = (H2O4P- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr58.6kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr32.kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Δr32.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(H2O4P- • Water) + Water = (H2O4P- • 2Water)

By formula: (H2O4P- • H2O) + H2O = (H2O4P- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(H2O4P- • 2Water) + Water = (H2O4P- • 3Water)

By formula: (H2O4P- • 2H2O) + H2O = (H2O4P- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr20.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

H2O7S4-2 + 2Water = H4O8S4-2

By formula: H2O7S4-2 + 2H2O = H4O8S4-2

Quantity Value Units Method Reference Comment
Δr32.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

Hydronium cation + Water = (Hydronium cation • Water)

By formula: H3O+ + H2O = (H3O+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr136. ± 9.kJ/molAVGN/AAverage of 7 out of 14 values; Individual data points
Quantity Value Units Method Reference Comment
Δr120. ± 30.J/mol*KAVGN/AAverage of 5 out of 7 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.300.HPMSArifov, Pozharov, et al., 1971gas phase; M

(Hydronium cation • Water) + Water = (Hydronium cation • 2Water)

By formula: (H3O+ • H2O) + H2O = (H3O+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr84. ± 5.kJ/molAVGN/AAverage of 7 out of 14 values; Individual data points
Quantity Value Units Method Reference Comment
Δr94. ± 20.J/mol*KAVGN/AAverage of 5 out of 7 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
36.300.HPMSArifov, Pozharov, et al., 1971gas phase; M

(Hydronium cation • 2Water) + Water = (Hydronium cation • 3Water)

By formula: (H3O+ • 2H2O) + H2O = (H3O+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr73. ± 4.kJ/molAVGN/AAverage of 9 out of 16 values; Individual data points
Quantity Value Units Method Reference Comment
Δr118. ± 8.J/mol*KAVGN/AAverage of 6 out of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Δr39.kJ/molFABierbaum, Golde, et al., 1976gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
38.300.HPMSArifov, Pozharov, et al., 1971gas phase; M
38.296.SAMSPuckett and Teague, 1971gas phase; M
35.300.PHPMSGood, Durden, et al., 1970gas phase; M
35.307.PHPMSGood, Durden, et al., 1970, 2gas phase; M

(Hydronium cation • 3Water) + Water = (Hydronium cation • 4Water)

By formula: (H3O+ • 3H2O) + H2O = (H3O+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr56. ± 20.kJ/molAVGN/AAverage of 6 out of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Δr100. ± 20.J/mol*KAVGN/AAverage of 5 out of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr23.kJ/molFABierbaum, Golde, et al., 1976gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
24.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M
23.296.SAMSPuckett and Teague, 1971gas phase; M
21.300.PHPMSGood, Durden, et al., 1970gas phase; M
21.307.PHPMSGood, Durden, et al., 1970, 2gas phase; M
29.300.HPMSArifov, Pozharov, et al., 1971gas phase; M

(Hydronium cation • 4Water) + Water = (Hydronium cation • 5Water)

By formula: (H3O+ • 4H2O) + H2O = (H3O+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr50. ± 8.kJ/molAVGN/AAverage of 5 out of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr102. ± 20.J/mol*KAVGN/AAverage of 4 out of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(Hydronium cation • 5Water) + Water = (Hydronium cation • 6Water)

By formula: (H3O+ • 5H2O) + H2O = (H3O+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.8kJ/molPHPMSLau, Ikuta, et al., 1982gas phase; M
Δr49.0kJ/molHPMSKebarle, Searles, et al., 1967gas phase; M
Δr67.32kJ/molMKERShi, Ford, et al., 1993gas phase; Entropy change is questionable; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSLau, Ikuta, et al., 1982gas phase; M
Δr124.J/mol*KHPMSKebarle, Searles, et al., 1967gas phase; M
Δr346.0J/mol*KMKERShi, Ford, et al., 1993gas phase; Entropy change is questionable; M

(Hydronium cation • 6Water) + Water = (Hydronium cation • 7Water)

By formula: (H3O+ • 6H2O) + H2O = (H3O+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Δr43.1kJ/molHPMSKebarle, Searles, et al., 1967gas phase; M
Δr50.33kJ/molMKERShi, Ford, et al., 1993gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KHPMSKebarle, Searles, et al., 1967gas phase; M
Δr218.9J/mol*KMKERShi, Ford, et al., 1993gas phase; Entropy change is questionable; M

(Hydronium cation • 7Water) + Water = (Hydronium cation • 8Water)

By formula: (H3O+ • 7H2O) + H2O = (H3O+ • 8H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.9kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr21.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr140.0J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 8Water) + Water = (Hydronium cation • 9Water)

By formula: (H3O+ • 8H2O) + H2O = (H3O+ • 9H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr36.7kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr24.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr112.6J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 9Water) + Water = (Hydronium cation • 10Water)

By formula: (H3O+ • 9H2O) + H2O = (H3O+ • 10H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.2kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr107.8J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 10Water) + Water = (Hydronium cation • 11Water)

By formula: (H3O+ • 10H2O) + H2O = (H3O+ • 11H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.9kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr112.6J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 11Water) + Water = (Hydronium cation • 12Water)

By formula: (H3O+ • 11H2O) + H2O = (H3O+ • 12H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.1kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr29.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr140.7J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 12Water) + Water = (Hydronium cation • 13Water)

By formula: (H3O+ • 12H2O) + H2O = (H3O+ • 13H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.10kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr158.7J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 13Water) + Water = (Hydronium cation • 14Water)

By formula: (H3O+ • 13H2O) + H2O = (H3O+ • 14H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.35kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr166.7J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 14Water) + Water = (Hydronium cation • 15Water)

By formula: (H3O+ • 14H2O) + H2O = (H3O+ • 15H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.85kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr168.9J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 15Water) + Water = (Hydronium cation • 16Water)

By formula: (H3O+ • 15H2O) + H2O = (H3O+ • 16H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.27kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr25.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr176.4J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 16Water) + Water = (Hydronium cation • 17Water)

By formula: (H3O+ • 16H2O) + H2O = (H3O+ • 17H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.02kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr173.1J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 17Water) + Water = (Hydronium cation • 18Water)

By formula: (H3O+ • 17H2O) + H2O = (H3O+ • 18H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.98kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr26.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr170.0J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 18Water) + Water = (Hydronium cation • 19Water)

By formula: (H3O+ • 18H2O) + H2O = (H3O+ • 19H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.60kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr29.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr171.5J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 19Water) + Water = (Hydronium cation • 20Water)

By formula: (H3O+ • 19H2O) + H2O = (H3O+ • 20H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.10kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr38.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr165.8J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 20Water) + Water = (Hydronium cation • 21Water)

By formula: (H3O+ • 20H2O) + H2O = (H3O+ • 21H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.64kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr31.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr156.7J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 21Water) + Water = (Hydronium cation • 22Water)

By formula: (H3O+ • 21H2O) + H2O = (H3O+ • 22H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.18kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr25.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr165.1J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 22Water) + Water = (Hydronium cation • 23Water)

By formula: (H3O+ • 22H2O) + H2O = (H3O+ • 23H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.72kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr27.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr162.8J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 23Water) + Water = (Hydronium cation • 24Water)

By formula: (H3O+ • 23H2O) + H2O = (H3O+ • 24H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.01kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr28.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr156.7J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 24Water) + Water = (Hydronium cation • 25Water)

By formula: (H3O+ • 24H2O) + H2O = (H3O+ • 25H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr42.09kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr30.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr151.3J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 25Water) + Water = (Hydronium cation • 26Water)

By formula: (H3O+ • 25H2O) + H2O = (H3O+ • 26H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.7kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr26.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr137.4J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 26Water) + Water = (Hydronium cation • 27Water)

By formula: (H3O+ • 26H2O) + H2O = (H3O+ • 27H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr39.4kJ/molMKERShi, Ford, et al., 1993gas phase; M
Δr34.kJ/molCIDMagnera, David, et al., 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr129.4J/mol*KMKERShi, Ford, et al., 1993gas phase; M

(Hydronium cation • 27Water) + Water = (Hydronium cation • 28Water)

By formula: (H3O+ • 27H2O) + H2O = (H3O+ • 28H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.9kJ/molMKERShi, Ford, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr116.2J/mol*KMKERShi, Ford, et al., 1993gas phase; M

H3S+ + Water = (H3S+ • Water)

By formula: H3S+ + H2O = (H3S+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr88.7kJ/molPHPMSHiraoka and Kebarle, 1977, 2gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSHiraoka and Kebarle, 1977, 2gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976; M

(H3S+ • Water) + Water = (H3S+ • 2Water)

By formula: (H3S+ • H2O) + H2O = (H3S+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr84.9kJ/molPHPMSHiraoka and Kebarle, 1977, 2gas phase; From thermochemical cycle,switching reaction(H3O+ H2O)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSHiraoka and Kebarle, 1977, 2gas phase; From thermochemical cycle,switching reaction(H3O+ H2O)H2O; Cunningham, Payzant, et al., 1972, Yamdagni and Kebarle, 1976; M

(H3S+ • 2Water) + Water = (H3S+ • 3Water)

By formula: (H3S+ • 2H2O) + H2O = (H3S+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr18.kJ/molPIWalters and Blais, 1984gas phase; M

(H3S+ • Hydrogen sulfide) + Water = (H3S+ • Water • Hydrogen sulfide)

By formula: (H3S+ • H2S) + H2O = (H3S+ • H2O • H2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr79.9kJ/molPHPMSHiraoka and Kebarle, 1977, 2gas phase; From thermochemical cycle,switching reaction(H3S+ H2O)H2O; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KPHPMSHiraoka and Kebarle, 1977, 2gas phase; From thermochemical cycle,switching reaction(H3S+ H2O)H2O; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984; M

H4ClO2- + Methyl Alcohol + 2Water = CH8ClO3-

By formula: H4ClO2- + CH4O + 2H2O = CH8ClO3-

Quantity Value Units Method Reference Comment
Δr43.51 ± 0.84kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr47.7 ± 1.3kJ/molTDAsEvans and Keesee, 1991gas phase; For solvation by MeOH of core ion; B
Quantity Value Units Method Reference Comment
Δr24.3kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr25.1kJ/molTDAsEvans and Keesee, 1991gas phase; For solvation by MeOH of core ion; B

H4IO5- + 3Water = H6IO6-

By formula: H4IO5- + 3H2O = H6IO6-

Quantity Value Units Method Reference Comment
Δr46.9 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr17.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

NH4+ + Water = (NH4+ • Water)

By formula: H4N+ + H2O = (H4N+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr86.2kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; M
Δr83.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr72.4kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; M
Δr96.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr82.4J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

(NH4+ • Water) + Water = (NH4+ • 2Water)

By formula: (H4N+ • H2O) + H2O = (H4N+ • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr72.8kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; ΔrH?, Entropy change is questionable, appear out of line; M
Δr57.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small; M
Δr61.5kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; ΔrH?, Entropy change is questionable, appear out of line; M
Δr92.0J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small; M
Δr91.6J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr37.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.414.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; ΔrH of 51.9 kJ/mol from plot is too small; M

(NH4+ • 2Water) + Water = (NH4+ • 3Water)

By formula: (H4N+ • 2H2O) + H2O = (H4N+ • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr57.3kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; M
Δr56.1kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Δr51.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1986gas phase; M
Δr105.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Δr88.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr27.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NH4+ • 3Water) + Water = (NH4+ • 4Water)

By formula: (H4N+ • 3H2O) + H2O = (H4N+ • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.2kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr51.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr114.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr21.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(NH4+ • 4Water) + Water = (NH4+ • 5Water)

By formula: (H4N+ • 4H2O) + H2O = (H4N+ • 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.4kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr41.kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Δr93.7J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

(NH4+ • 5Water) + Water = (NH4+ • 6Water)

By formula: (H4N+ • 5H2O) + H2O = (H4N+ • 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.266.PHPMSMeot-Ner (Mautner), 1984gas phase; M

(NH4+ • 6Water) + Water = (NH4+ • 7Water)

By formula: (H4N+ • 6H2O) + H2O = (H4N+ • 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr35.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
12.254.PHPMSMeot-Ner (Mautner), 1984gas phase; M

(NH4+ • Water • Ammonia) + Water = (NH4+ • 2Water • Ammonia)

By formula: (H4N+ • H2O • H3N) + H2O = (H4N+ • 2H2O • H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr53.1kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

(NH4+ • Water • 2Ammonia) + Water = (NH4+ • 2Water • 2Ammonia)

By formula: (H4N+ • H2O • 2H3N) + H2O = (H4N+ • 2H2O • 2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr116.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

(NH4+ • 2Water • Ammonia) + Water = (NH4+ • 3Water • Ammonia)

By formula: (H4N+ • 2H2O • H3N) + H2O = (H4N+ • 3H2O • H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr119.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

(NH4+ • Water • Sulfur dioxide) + Water = (NH4+ • 2Water • Sulfur dioxide)

By formula: (H4N+ • H2O • O2S) + H2O = (H4N+ • 2H2O • O2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr31.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

(NH4+ • 2Water • Sulfur dioxide) + Water = (NH4+ • 3Water • Sulfur dioxide)

By formula: (H4N+ • 2H2O • O2S) + H2O = (H4N+ • 3H2O • O2S)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr22.kJ/molHPMSBanic and Iribarne, 1985gas phase; From thermochemical cycle,switching reaction, electric fields; M

(NH4+ • Ammonia) + Water = (NH4+ • Water • Ammonia)

By formula: (H4N+ • H3N) + H2O = (H4N+ • H2O • H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr84.9J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

(NH4+ • 2Ammonia) + Water = (NH4+ • Water • 2Ammonia)

By formula: (H4N+ • 2H3N) + H2O = (H4N+ • H2O • 2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.9kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

(NH4+ • 3Ammonia) + Water = (NH4+ • Water • 3Ammonia)

By formula: (H4N+ • 3H3N) + H2O = (H4N+ • H2O • 3H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.0kJ/molPHPMSPayzant, Cunningham, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr117.J/mol*KPHPMSPayzant, Cunningham, et al., 1973gas phase; M

H4N3O2- + 3Water = H6N3O3-

By formula: H4N3O2- + 3H2O = H6N3O3-

Quantity Value Units Method Reference Comment
Δr44.35kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 4.25±0.06 eV; B

H4O3P- + 2Water = H6O4P-

By formula: H4O3P- + 2H2O = H6O4P-

Quantity Value Units Method Reference Comment
Δr56.1 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr26.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

H4O4- + Naphthalene + 2Water = C10H12O4-

By formula: H4O4- + C10H8 + 2H2O = C10H12O4-

Quantity Value Units Method Reference Comment
Δr219. ± 9.6kJ/molN/ALe Barbu, Schiedt, et al., 2002gas phase; Affinity is difference in EAs of lesser solvated species; B

H4O4P- + 2Water = H6O5P-

By formula: H4O4P- + 2H2O = H6O5P-

Quantity Value Units Method Reference Comment
Δr56.9 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr27.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

H4O5P- + 2Water = H6O6P-

By formula: H4O5P- + 2H2O = H6O6P-

Quantity Value Units Method Reference Comment
Δr51.5 ± 4.2kJ/molTDAsBlades, Ho, et al., 1996gas phase; B
Δr54.8 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr25.5 ± 2.1kJ/molTDAsBlades, Ho, et al., 1996gas phase; B
Δr25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

H4O8S4-2 + 3Water = H6O9S4-2

By formula: H4O8S4-2 + 3H2O = H6O9S4-2

Quantity Value Units Method Reference Comment
Δr28.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H4O10S2-2 + 3Water = H6O11S2-2

By formula: H4O10S2-2 + 3H2O = H6O11S2-2

Quantity Value Units Method Reference Comment
Δr31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H4P+ + Water = (H4P+ • Water)

By formula: H4P+ + H2O = (H4P+ • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Meot-Ner, 1984, 2, Lias, Liebman, et al., 1984; M

H6N3O3- + 4Water = H8N3O4-

By formula: H6N3O3- + 4H2O = H8N3O4-

Quantity Value Units Method Reference Comment
Δr32.6kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 4.63±0.06 eV; B

H6O4P- + 3Water = H8O5P-

By formula: H6O4P- + 3H2O = H8O5P-

Quantity Value Units Method Reference Comment
Δr49.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr19.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

H6O5P- + 3Water = H8O6P-

By formula: H6O5P- + 3H2O = H8O6P-

Quantity Value Units Method Reference Comment
Δr51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

H6O6P- + 3Water = H8O7P-

By formula: H6O6P- + 3H2O = H8O7P-

Quantity Value Units Method Reference Comment
Δr51.5 ± 4.2kJ/molTDAsBlades, Ho, et al., 1996, 3gas phase; B
Δr49.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Δr26. ± 4.2kJ/molTDAsBlades, Ho, et al., 1996, 3gas phase; B
Δr20.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B

H6O9S2-2 + 4Water = H8O10S2-2

By formula: H6O9S2-2 + 4H2O = H8O10S2-2

Quantity Value Units Method Reference Comment
Δr33.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H6O9S4-2 + 4Water = H8O10S4-2

By formula: H6O9S4-2 + 4H2O = H8O10S4-2

Quantity Value Units Method Reference Comment
Δr25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H6O11S2-2 + 4Water = H8O12S2-2

By formula: H6O11S2-2 + 4H2O = H8O12S2-2

Quantity Value Units Method Reference Comment
Δr28.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H8N3O4- + 5Water = H10N3O5-

By formula: H8N3O4- + 5H2O = H10N3O5-

Quantity Value Units Method Reference Comment
Δr15.5kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change from (H2O)n-1..N3- ion. Vertical Detachment Energy: 4.85±0.06 eV; B

H8O10S2-2 + 5Water = H10O11S2-2

By formula: H8O10S2-2 + 5H2O = H10O11S2-2

Quantity Value Units Method Reference Comment
Δr29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H8O10S4-2 + 5Water = H10O11S4-2

By formula: H8O10S4-2 + 5H2O = H10O11S4-2

Quantity Value Units Method Reference Comment
Δr22.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H8O12S2-2 + 5Water = H10O13S2-2

By formula: H8O12S2-2 + 5H2O = H10O13S2-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H10N3O5- + 6Water = H12N3O6-

By formula: H10N3O5- + 6H2O = H12N3O6-

Quantity Value Units Method Reference Comment
Δr15.5kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.03±0.08 eV; B

H10O8S2-2 + 6Water = H12O9S2-2

By formula: H10O8S2-2 + 6H2O = H12O9S2-2

Quantity Value Units Method Reference Comment
Δr30.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H10O11S2-2 + 6Water = H12O12S2-2

By formula: H10O11S2-2 + 6H2O = H12O12S2-2

Quantity Value Units Method Reference Comment
Δr26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H10O13S2-2 + 6Water = H12O14S2-2

By formula: H10O13S2-2 + 6H2O = H12O14S2-2

Quantity Value Units Method Reference Comment
Δr22.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H12N3O6- + 7Water = H14N3O7-

By formula: H12N3O6- + 7H2O = H14N3O7-

Quantity Value Units Method Reference Comment
Δr13.4kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.25±0.08 eV; B

H12O9S2-2 + 7Water = H14O10S2-2

By formula: H12O9S2-2 + 7H2O = H14O10S2-2

Quantity Value Units Method Reference Comment
Δr27.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H12O10S-2 + 7Water = H14O11S-2

By formula: H12O10S-2 + 7H2O = H14O11S-2

Quantity Value Units Method Reference Comment
Δr58.2 ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Quantity Value Units Method Reference Comment
Δr31. ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Δr31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H12O10Se-2 + 7Water = H14O11Se-2

By formula: H12O10Se-2 + 7H2O = H14O11Se-2

Quantity Value Units Method Reference Comment
Δr29.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H12O12P2-2 + 6Water = H14O13P2-2

By formula: H12O12P2-2 + 6H2O = H14O13P2-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 0.84kJ/molIMREBlades, Ho, et al., 1996, 3gas phase; Correction to published article: P. Kebarle; B

H12O12S2-2 + 7Water = H14O13S2-2

By formula: H12O12S2-2 + 7H2O = H14O13S2-2

Quantity Value Units Method Reference Comment
Δr23.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H14N3O7- + 8Water = H16N3O8-

By formula: H14N3O7- + 8H2O = H16N3O8-

Quantity Value Units Method Reference Comment
Δr13.4kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.42±0.08 eV; B

H14O10S2-2 + 8Water = H16O11S2-2

By formula: H14O10S2-2 + 8H2O = H16O11S2-2

Quantity Value Units Method Reference Comment
Δr24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H14O11S-2 + 8Water = H16O12S-2

By formula: H14O11S-2 + 8H2O = H16O12S-2

Quantity Value Units Method Reference Comment
Δr51.9 ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Quantity Value Units Method Reference Comment
Δr28. ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Δr28.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H14O11Se-2 + 8Water = H16O12Se-2

By formula: H14O11Se-2 + 8H2O = H16O12Se-2

Quantity Value Units Method Reference Comment
Δr26.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H14O13S2-2 + 8Water = H16O14S2-2

By formula: H14O13S2-2 + 8H2O = H16O14S2-2

Quantity Value Units Method Reference Comment
Δr21.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H16N3O8- + 9Water = H18N3O9-

By formula: H16N3O8- + 9H2O = H18N3O9-

Quantity Value Units Method Reference Comment
Δr13.4kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.55±0.08 eV; B

H16O11S2-2 + 9Water = H18O12S2-2

By formula: H16O11S2-2 + 9H2O = H18O12S2-2

Quantity Value Units Method Reference Comment
Δr22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H16O12S-2 + 9Water = H18O13S-2

By formula: H16O12S-2 + 9H2O = H18O13S-2

Quantity Value Units Method Reference Comment
Δr49.4 ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Quantity Value Units Method Reference Comment
Δr26. ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Δr25.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H16O12Se-2 + 9Water = H18O13Se-2

By formula: H16O12Se-2 + 9H2O = H18O13Se-2

Quantity Value Units Method Reference Comment
Δr23.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H18N3O9- + 10Water = H20N3O10-

By formula: H18N3O9- + 10H2O = H20N3O10-

Quantity Value Units Method Reference Comment
Δr12.6kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change from (H2O))n-1..N3- ion. Vertical Detachment Energy: 5.65±0.08 eV; B

H18O12S2-2 + 10Water = H20O13S2-2

By formula: H18O12S2-2 + 10H2O = H20O13S2-2

Quantity Value Units Method Reference Comment
Δr19.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

H18O13S-2 + 10Water = H20O14S-2

By formula: H18O13S-2 + 10H2O = H20O14S-2

Quantity Value Units Method Reference Comment
Δr45.6 ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Quantity Value Units Method Reference Comment
Δr24. ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B

H20N3O10- + 11Water = H22N3O11-

By formula: H20N3O10- + 11H2O = H22N3O11-

Quantity Value Units Method Reference Comment
Δr8.79kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.70±0.08 eV; B

H20O14S-2 + 11Water = H22O15S-2

By formula: H20O14S-2 + 11H2O = H22O15S-2

Quantity Value Units Method Reference Comment
Δr45.6 ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Quantity Value Units Method Reference Comment
Δr22. ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B

H22N3O11- + 12Water = H24N3O12-

By formula: H22N3O11- + 12H2O = H24N3O12-

Quantity Value Units Method Reference Comment
Δr2.9kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.79±0.08 eV; B

H24N3O12- + 13Water = H26N3O13-

By formula: H24N3O12- + 13H2O = H26N3O13-

Quantity Value Units Method Reference Comment
Δr7.53kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.89±0.08 eV; B

H26N3O13- + 14Water = H28N3O14-

By formula: H26N3O13- + 14H2O = H28N3O14-

Quantity Value Units Method Reference Comment
Δr3.8kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 5.95±0.08 eV; B

H28N3O14- + 15Water = H30N3O15-

By formula: H28N3O14- + 15H2O = H30N3O15-

Quantity Value Units Method Reference Comment
Δr8.79kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 6.02±0.08 eV; B

H30N3O15- + 16Water = H32N3O16-

By formula: H30N3O15- + 16H2O = H32N3O16-

Quantity Value Units Method Reference Comment
Δr3.8kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 6.07±0.08 eV; B

Iodide + Water = (Iodide • Water)

By formula: I- + H2O = (I- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43. ± 3.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr64.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr80.8J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr68.2J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr23. ± 1.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • Water) + Water = (Iodide • 2Water)

By formula: (I- • H2O) + H2O = (I- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr41.4 ± 0.84kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Δr39.7kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr39.7 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr41. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr41. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr73.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr84.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr79.5J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr17. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Iodide • 2Water) + Water = (Iodide • 3Water)

By formula: (I- • 2H2O) + H2O = (I- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.9 ± 1.3kJ/molTDAsKeesee and Castleman, 1980gas phase; B,M
Δr36. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr38.5 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr39. ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr39. ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr87.9J/mol*KHPMSKeesee and Castleman, 1980gas phase; M
Δr89.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr12.6kJ/molTDAsKeesee and Castleman, 1980gas phase; B
Δr13.0 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Iodide • 3Water) + Water = (Iodide • 4Water)

By formula: (I- • 3H2O) + H2O = (I- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.5 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr29. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr98.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr8.8 ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr9.2 ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Iodide • 4Water) + Water = (Iodide • 5Water)

By formula: (I- • 4H2O) + H2O = (I- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr37.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Δr17.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr6.28kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Iodide • 5Water) + Water = (Iodide • 6Water)

By formula: (I- • 5H2O) + H2O = (I- • 6H2O)

Quantity Value Units Method Reference Comment
Δr32.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 6Water) + Water = (Iodide • 7Water)

By formula: (I- • 6H2O) + H2O = (I- • 7H2O)

Quantity Value Units Method Reference Comment
Δr7.53kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 7Water) + Water = (Iodide • 8Water)

By formula: (I- • 7H2O) + H2O = (I- • 8H2O)

Quantity Value Units Method Reference Comment
Δr2.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 8Water) + Water = (Iodide • 9Water)

By formula: (I- • 8H2O) + H2O = (I- • 9H2O)

Quantity Value Units Method Reference Comment
Δr16.3kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 9Water) + Water = (Iodide • 10Water)

By formula: (I- • 9H2O) + H2O = (I- • 10H2O)

Quantity Value Units Method Reference Comment
Δr5.86kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 10Water) + Water = (Iodide • 11Water)

By formula: (I- • 10H2O) + H2O = (I- • 11H2O)

Quantity Value Units Method Reference Comment
Δr2.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 11Water) + Water = (Iodide • 12Water)

By formula: (I- • 11H2O) + H2O = (I- • 12H2O)

Quantity Value Units Method Reference Comment
Δr5.86kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 12Water) + Water = (Iodide • 13Water)

By formula: (I- • 12H2O) + H2O = (I- • 13H2O)

Quantity Value Units Method Reference Comment
Δr7.53kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 13Water) + Water = (Iodide • 14Water)

By formula: (I- • 13H2O) + H2O = (I- • 14H2O)

Quantity Value Units Method Reference Comment
Δr0.84kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 14Water) + Water = (Iodide • 15Water)

By formula: (I- • 14H2O) + H2O = (I- • 15H2O)

Quantity Value Units Method Reference Comment
Δr5.02kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • 15Water) + Water = (Iodide • 16Water)

By formula: (I- • 15H2O) + H2O = (I- • 16H2O)

Quantity Value Units Method Reference Comment
Δr5.02kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Iodide • Sulfur dioxide) + Water = (Iodide • Water • Sulfur dioxide)

By formula: (I- • O2S) + H2O = (I- • H2O • O2S)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr14.6 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.300.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

(Potassium ion (1+) • Methyl Alcohol) + Water = (Potassium ion (1+) • Water • Methyl Alcohol)

By formula: (K+ • CH4O) + H2O = (K+ • H2O • CH4O)

Quantity Value Units Method Reference Comment
Δr65.3kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) • 2Methyl Alcohol) + Water = (Potassium ion (1+) • Water • 2Methyl Alcohol)

By formula: (K+ • 2CH4O) + H2O = (K+ • H2O • 2CH4O)

Quantity Value Units Method Reference Comment
Δr47.3kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr75.3J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) • Benzene) + Water = (Potassium ion (1+) • Water • Benzene)

By formula: (K+ • C6H6) + H2O = (K+ • H2O • C6H6)

Quantity Value Units Method Reference Comment
Δr75.7kJ/molHPMSSunner, Nishizawa, et al., 1981gas phase; switching reaction(K+ C6H6)C6H6; Searles and Kebarle, 1969; M
Quantity Value Units Method Reference Comment
Δr125.J/mol*KHPMSSunner, Nishizawa, et al., 1981gas phase; switching reaction(K+ C6H6)C6H6; Searles and Kebarle, 1969; M

(Potassium ion (1+) • 2Benzene) + Water = (Potassium ion (1+) • Water • 2Benzene)

By formula: (K+ • 2C6H6) + H2O = (K+ • H2O • 2C6H6)

Quantity Value Units Method Reference Comment
Δr57.3kJ/molHPMSSunner, Nishizawa, et al., 1981gas phase; switching reaction(K+ 2H2O)C6H6; Searles and Kebarle, 1969; M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KHPMSSunner, Nishizawa, et al., 1981gas phase; switching reaction(K+ 2H2O)C6H6; Searles and Kebarle, 1969; M

Potassium ion (1+) + Water = (Potassium ion (1+) • Water)

By formula: K+ + H2O = (K+ • H2O)

Quantity Value Units Method Reference Comment
Δr70.7kJ/molHPMSDavidson and Kebarle, 1976gas phase; M
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr81. ± 10.kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Δr74.9kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr83.3J/mol*KHPMSDavidson and Kebarle, 1976gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr89.1J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Δr90.4J/mol*KHPMSSearles and Kebarle, 1969gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
38.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
2.840.MSChupka, 1959gas phase; Knudsen cell, 840+-50K; M

(Potassium ion (1+) • Water • Methyl Alcohol) + Water = (Potassium ion (1+) • 2Water • Methyl Alcohol)

By formula: (K+ • H2O • CH4O) + H2O = (K+ • 2H2O • CH4O)

Quantity Value Units Method Reference Comment
Δr54.8kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Potassium ion (1+) • Water • Benzene) + Water = (Potassium ion (1+) • 2Water • Benzene)

By formula: (K+ • H2O • C6H6) + H2O = (K+ • 2H2O • C6H6)

Quantity Value Units Method Reference Comment
Δr53.1kJ/molHPMSSunner, Nishizawa, et al., 1981gas phase; From thermochemical cycle,switching reaction(K+)3H2O; Searles and Kebarle, 1969; M
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KHPMSSunner, Nishizawa, et al., 1981gas phase; From thermochemical cycle,switching reaction(K+)3H2O; Searles and Kebarle, 1969; M

(Potassium ion (1+) • Water • 2Benzene) + Water = (Potassium ion (1+) • 2Water • 2Benzene)

By formula: (K+ • H2O • 2C6H6) + H2O = (K+ • 2H2O • 2C6H6)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molHPMSSunner, Nishizawa, et al., 1981gas phase; From thermochemical cycle(K+ 3H2O)C6H6; Searles and Kebarle, 1969; M
Quantity Value Units Method Reference Comment
Δr123.J/mol*KHPMSSunner, Nishizawa, et al., 1981gas phase; From thermochemical cycle(K+ 3H2O)C6H6; Searles and Kebarle, 1969; M

(Potassium ion (1+) • 2Water • Benzene) + Water = (Potassium ion (1+) • 3Water • Benzene)

By formula: (K+ • 2H2O • C6H6) + H2O = (K+ • 3H2O • C6H6)

Quantity Value Units Method Reference Comment
Δr49.4kJ/molHPMSSunner, Nishizawa, et al., 1981gas phase; From thermochemical cycle,switching reaction(K+)4H2O; Searles and Kebarle, 1969; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KHPMSSunner, Nishizawa, et al., 1981gas phase; From thermochemical cycle,switching reaction(K+)4H2O; Searles and Kebarle, 1969; M

(Potassium ion (1+) • Water) + Water = (Potassium ion (1+) • 2Water)

By formula: (K+ • H2O) + H2O = (K+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr67.4kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr101.J/mol*KHPMSSearles and Kebarle, 1969gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
38.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Potassium ion (1+) • 2Water) + Water = (Potassium ion (1+) • 3Water)

By formula: (K+ • 2H2O) + H2O = (K+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr55.2kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr96.2J/mol*KHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Potassium ion (1+) • 3Water) + Water = (Potassium ion (1+) • 4Water)

By formula: (K+ • 3H2O) + H2O = (K+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr49.4kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr103.J/mol*KHPMSSearles and Kebarle, 1969gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Potassium ion (1+) • 4Water) + Water = (Potassium ion (1+) • 5Water)

By formula: (K+ • 4H2O) + H2O = (K+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr44.8kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KHPMSSearles and Kebarle, 1969gas phase; M

(Potassium ion (1+) • 5Water) + Water = (Potassium ion (1+) • 6Water)

By formula: (K+ • 5H2O) + H2O = (K+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr41.8kJ/molHPMSSearles and Kebarle, 1969gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KHPMSSearles and Kebarle, 1969gas phase; M

Lithium ion (1+) + Water = (Lithium ion (1+) • Water)

By formula: Li+ + H2O = (Li+ • H2O)

Quantity Value Units Method Reference Comment
Δr135. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr140.kJ/molHPMSDzidic and Kebarle, 1970gas phase; interpolated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; interpolated; M

(Lithium ion (1+) • Water) + Water = (Lithium ion (1+) • 2Water)

By formula: (Li+ • H2O) + H2O = (Li+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr113. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr108.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr88.3J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Lithium ion (1+) • 2Water) + Water = (Lithium ion (1+) • 3Water)

By formula: (Li+ • 2H2O) + H2O = (Li+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr94.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Δr86.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
Δr104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

(Lithium ion (1+) • 3Water) + Water = (Lithium ion (1+) • 4Water)

By formula: (Li+ • 3H2O) + H2O = (Li+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr68.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr125.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) • 4Water) + Water = (Lithium ion (1+) • 5Water)

By formula: (Li+ • 4H2O) + H2O = (Li+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr58.2kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr131.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Lithium ion (1+) • 5Water) + Water = (Lithium ion (1+) • 6Water)

By formula: (Li+ • 5H2O) + H2O = (Li+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr59.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr50.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr134.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Magnesium ion (1+) + Water = (Magnesium ion (1+) • Water)

By formula: Mg+ + H2O = (Mg+ • H2O)

Quantity Value Units Method Reference Comment
Δr118. ± 13.kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
119. (+13.,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) • Water) + Water = (Magnesium ion (1+) • 2Water)

By formula: (Mg+ • H2O) + H2O = (Mg+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr93.3 ± 6.7kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
93.7 (+6.7,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) • 2Water) + Water = (Magnesium ion (1+) • 3Water)

By formula: (Mg+ • 2H2O) + H2O = (Mg+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr72.4 ± 8.8kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
72.4 (+8.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Magnesium ion (1+) • 3Water) + Water = (Magnesium ion (1+) • 4Water)

By formula: (Mg+ • 3H2O) + H2O = (Mg+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr48.1 ± 8.8kJ/molCIDTAndersen, Muntean, et al., 2000RCD

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
48.1 (+8.8,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Mg+ (3s1); M

(Mg+2 • 7Water) + Water = (Mg+2 • 8Water)

By formula: (Mg+2 • 7H2O) + H2O = (Mg+2 • 8H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mg+2 • 8Water) + Water = (Mg+2 • 9Water)

By formula: (Mg+2 • 8H2O) + H2O = (Mg+2 • 9H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mg+2 • 9Water) + Water = (Mg+2 • 10Water)

By formula: (Mg+2 • 9H2O) + H2O = (Mg+2 • 10H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mg+2 • 10Water) + Water = (Mg+2 • 11Water)

By formula: (Mg+2 • 10H2O) + H2O = (Mg+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M
31.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mg+2 • 11Water) + Water = (Mg+2 • 12Water)

By formula: (Mg+2 • 11H2O) + H2O = (Mg+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mg+2 • 12Water) + Water = (Mg+2 • 13Water)

By formula: (Mg+2 • 12H2O) + H2O = (Mg+2 • 13H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

(Mg+2 • 13Water) + Water = (Mg+2 • 14Water)

By formula: (Mg+2 • 13H2O) + H2O = (Mg+2 • 14H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

(Mg+2 • 14Water) + Water = (Mg+2 • 15Water)

By formula: (Mg+2 • 14H2O) + H2O = (Mg+2 • 15H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

(Mg+2 • 15Water) + Water = (Mg+2 • 16Water)

By formula: (Mg+2 • 15H2O) + H2O = (Mg+2 • 16H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

Manganese ion (1+) + Water = (Manganese ion (1+) • Water)

By formula: Mn+ + H2O = (Mn+ • H2O)

Quantity Value Units Method Reference Comment
Δr140. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Δr111.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
119. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) • Water) + Water = (Manganese ion (1+) • 2Water)

By formula: (Mn+ • H2O) + H2O = (Mn+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr74.5kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
90.0 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) • 2Water) + Water = (Manganese ion (1+) • 3Water)

By formula: (Mn+ • 2H2O) + H2O = (Mn+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
108. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Manganese ion (1+) • 3Water) + Water = (Manganese ion (1+) • 4Water)

By formula: (Mn+ • 3H2O) + H2O = (Mn+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
50.2 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Mn+2 • 8Water) + Water = (Mn+2 • 9Water)

By formula: (Mn+2 • 8H2O) + H2O = (Mn+2 • 9H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mn+2 • 9Water) + Water = (Mn+2 • 10Water)

By formula: (Mn+2 • 9H2O) + H2O = (Mn+2 • 10H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mn+2 • 10Water) + Water = (Mn+2 • 11Water)

By formula: (Mn+2 • 10H2O) + H2O = (Mn+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Mn+2 • 11Water) + Water = (Mn+2 • 12Water)

By formula: (Mn+2 • 11H2O) + H2O = (Mn+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Nitric oxide anion + Water = (Nitric oxide anion • Water)

By formula: NO- + H2O = (NO- • H2O)

Quantity Value Units Method Reference Comment
Δr77.4kJ/molPHPMSFrench, Hills, et al., 1973gas phase; M
Δr69.5kJ/molPESEaton, Arnold, et al., 1990gas phase; M
Δr95.0kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KPHPMSFrench, Hills, et al., 1973gas phase; M
Δr100.J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
53.1296.SAMSPuckett and Teague, 1971gas phase; switching reaction(NO+)NO; M

(Nitric oxide anion • Water) + Water = (Nitric oxide anion • 2Water)

By formula: (NO- • H2O) + H2O = (NO- • 2H2O)

Quantity Value Units Method Reference Comment
Δr65.69kJ/molN/AEaton, Arnold, et al., 1990gas phase; Vertical Detachment Energy: 1.860±0.020 eV; B,M
Δr67.4kJ/molPHPMSFrench, Hills, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr107.J/mol*KPHPMSFrench, Hills, et al., 1973gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.293.HPMSMcAdams and Bone, 1972gas phase; M
36.296.FAHoward, Rundle, et al., 1971gas phase; M
36.296.SAMSPuckett and Teague, 1971gas phase; M

(Nitric oxide anion • 2Water) + Water = (Nitric oxide anion • 3Water)

By formula: (NO- • 2H2O) + H2O = (NO- • 3H2O)

Quantity Value Units Method Reference Comment
Δr74.5kJ/molPESEaton, Arnold, et al., 1990gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.308.PHPMSFrench, Hills, et al., 1973gas phase; M
25.293.HPMSMcAdams and Bone, 1972gas phase; M
25.296.FAHoward, Rundle, et al., 1971gas phase; M
25.296.SAMSPuckett and Teague, 1971gas phase; M

NO2+ + Water = (NO2+ • Water)

By formula: NO2+ + H2O = (NO2+ • H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.4 (+9.6,-0.) PD/KERDGraul, Kim, et al., 1992gas phase; M

Nitrogen oxide anion + Water = (Nitrogen oxide anion • Water)

By formula: NO2- + H2O = (NO2- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr65. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr84.9J/mol*KPHPMSSieck, 1985gas phase; M
Δr83.7J/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO2-)H2O; Lee, Keesee, et al., 1980; M
Δr99.6J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr88.J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr35.6 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Δr35.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr34. ± 24.kJ/molEndoPaulson and Dale, 1982gas phase; B
Δr33.9 ± 0.84kJ/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr33.5kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.296.FAFehsenfeld and Ferguson, 1974gas phase; M
35.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(Nitrogen oxide anion • Water) + Water = (Nitrogen oxide anion • 2Water)

By formula: (NO2- • H2O) + H2O = (NO2- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr54.0 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr54.0 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr56.9kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr99.2J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr25.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr24. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr24.3kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr26. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.296.FAFehsenfeld and Ferguson, 1974gas phase; M
24.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(Nitrogen oxide anion • 2Water) + Water = (Nitrogen oxide anion • 3Water)

By formula: (NO2- • 2H2O) + H2O = (NO2- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48.1 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr43.5 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr43.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr49.0kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr88.7J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr18.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr17. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr17.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr19. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Nitrogen oxide anion • 3Water) + Water = (Nitrogen oxide anion • 4Water)

By formula: (NO2- • 3H2O) + H2O = (NO2- • 4H2O)

Quantity Value Units Method Reference Comment
Δr48.5kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr121.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M

(NO3 anion • Nitric acid) + Water = (NO3 anion • Water • Nitric acid)

By formula: (NO3- • HNO3) + H2O = (NO3- • H2O • HNO3)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.233.ATMArnold, Viggiano, et al., 1982gas phase; Entropy change calculated or estimated; M

NO3 anion + Water = (NO3 anion • Water)

By formula: NO3- + H2O = (NO3- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.09 ± 0.84kJ/molN/ALee, Keesee, et al., 1980gas phase; B,M
Δr59.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr51.88kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Δr61.9kJ/molATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr80.3kJ/molFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Δr100.J/mol*KN/AArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
Δr89.1J/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO3-)H2O; Lee, Keesee, et al., 1980; M
Δr79.9J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr30.1 ± 1.3kJ/molTDAsLee, Keesee, et al., 1980gas phase; B
Δr29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr30.5 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B
Δr28.0kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
37.250.ATMArnold and Qiu, 1984gas phase; Entropy change calculated or estimated; M
28.296.FAFehsenfeld and Ferguson, 1974gas phase; M
29.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

NO3 anion + Water + Propanoic acid = C3H8NO6-

By formula: NO3- + H2O + C3H6O2 = C3H8NO6-

Quantity Value Units Method Reference Comment
Δr16.3 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

NO3 anion + Water + Butanoic acid = C4H10NO6-

By formula: NO3- + H2O + C4H8O2 = C4H10NO6-

Quantity Value Units Method Reference Comment
Δr15.9 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

(NO3 anion • Water) + Water = (NO3 anion • 2Water)

By formula: (NO3- • H2O) + H2O = (NO3- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr59.8kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr127.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M
Δr21.8 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M
21.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(NO3 anion • 2Water) + Water = (NO3 anion • 3Water)

By formula: (NO3- • 2H2O) + H2O = (NO3- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B
Δr57.7kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr139.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr16.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. ΔSaff approx. 24 cal/mol-K; B,M

(NO3 anion • Sulfur dioxide) + Water = (NO3 anion • Water • Sulfur dioxide)

By formula: (NO3- • O2S) + H2O = (NO3- • H2O • O2S)

Quantity Value Units Method Reference Comment
Δr18.0 ± 0.42kJ/molTDAsBanic and Iribarne, 1985gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.299.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Azide anion + Water = H2N3O-

By formula: N3- + H2O = H2N3O-

Quantity Value Units Method Reference Comment
Δr46. ± 75.kJ/molN/AYang, Kiran, et al., 2004gas phase; Affinity: EA change (H2O)n-1..N3- ion. Vertical Detachment Energy: 3.25±0.03 eV; B

(Sodium ion (1+) • Carbon dioxide) + Water = (Sodium ion (1+) • Water • Carbon dioxide)

By formula: (Na+ • CO2) + H2O = (Na+ • H2O • CO2)

Quantity Value Units Method Reference Comment
Δr86.6kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Δr95.8kJ/molFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Δr107.J/mol*KFAPerry, Rowe, et al., 1980gas phase; From thermochemical cycle(Na+) 2H2O; Dzidic and Kebarle, 1970, Peterson, Mark, et al., 1984; M

Sodium ion (1+) + Water = (Sodium ion (1+) • Water)

By formula: Na+ + H2O = (Na+ • H2O)

Quantity Value Units Method Reference Comment
Δr100.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr87.9 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Δr82.0 ± 5.9kJ/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Δr95.0 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr111.kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M
Quantity Value Units Method Reference Comment
Δr90.0J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr92.J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, 1600 K; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
94.6 (+7.5,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
65.7298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Sodium ion (1+) • Water • Carbon dioxide) + Water = (Sodium ion (1+) • 2Water • Carbon dioxide)

By formula: (Na+ • H2O • CO2) + H2O = (Na+ • 2H2O • CO2)

Quantity Value Units Method Reference Comment
Δr72.8kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
Δr98.7J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

(Sodium ion (1+) • 2Water • Carbon dioxide) + Water = (Sodium ion (1+) • 3Water • Carbon dioxide)

By formula: (Na+ • 2H2O • CO2) + H2O = (Na+ • 3H2O • CO2)

Quantity Value Units Method Reference Comment
Δr51.9kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
Δr23.kJ/molHPMSPeterson, Mark, et al., 1984gas phase; From thermochemical cycle; Dzidic and Kebarle, 1970; M

(Sodium ion (1+) • Water) + Water = (Sodium ion (1+) • 2Water)

By formula: (Na+ • H2O) + H2O = (Na+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr79. ± 8.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
82.0 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 2Water) + Water = (Sodium ion (1+) • 3Water)

By formula: (Na+ • 2H2O) + H2O = (Na+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr62.3kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Δr66.1kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr69.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD
Δr67.4kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KHPMSTang, Lian, et al., 1976gas phase; M
Δr91.6J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr92.0J/mol*KES/HPMSBlades, Klassen, et al., 1996gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr40.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
70.3 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
39.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 3Water) + Water = (Sodium ion (1+) • 4Water)

By formula: (Na+ • 3H2O) + H2O = (Na+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr55. ± 4.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr99. ± 10.J/mol*KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr26.kJ/molES/HPMSBlades, Klassen, et al., 1996gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
54.8 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Na+ (3s0); M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M
27.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Sodium ion (1+) • 4Water) + Water = (Sodium ion (1+) • 5Water)

By formula: (Na+ • 4H2O) + H2O = (Na+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr44.8kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Δr48.5kJ/molHPMSTang and Castleman, 1972gas phase; M
Δr51.5kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M
Δr111.J/mol*KHPMSTang and Castleman, 1972gas phase; M
Δr118.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
20.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(Sodium ion (1+) • 5Water) + Water = (Sodium ion (1+) • 6Water)

By formula: (Na+ • 5H2O) + H2O = (Na+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr44.8kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Sodium ion (1+) • Sulfur dioxide) + Water = (Sodium ion (1+) • Water • Sulfur dioxide)

By formula: (Na+ • O2S) + H2O = (Na+ • H2O • O2S)

Quantity Value Units Method Reference Comment
Δr82.8kJ/molHPMSUpschulte, Schelling, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KHPMSUpschulte, Schelling, et al., 1984gas phase; M

Nickel ion (1+) + Water = (Nickel ion (1+) • Water)

By formula: Ni+ + H2O = (Ni+ • H2O)

Quantity Value Units Method Reference Comment
Δr150. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Δr166.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
180. (+3.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • Water) + Water = (Nickel ion (1+) • 2Water)

By formula: (Ni+ • H2O) + H2O = (Ni+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr170.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
168. (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 2Water) + Water = (Nickel ion (1+) • 3Water)

By formula: (Ni+ • 2H2O) + H2O = (Ni+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
68.2 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 3Water) + Water = (Nickel ion (1+) • 4Water)

By formula: (Ni+ • 3H2O) + H2O = (Ni+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
51.9 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Ni+2 • 7Water) + Water = (Ni+2 • 8Water)

By formula: (Ni+2 • 7H2O) + H2O = (Ni+2 • 8H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.300.HPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

(Ni+2 • 8Water) + Water = (Ni+2 • 9Water)

By formula: (Ni+2 • 8H2O) + H2O = (Ni+2 • 9H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
34.300.HPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

(Ni+2 • 9Water) + Water = (Ni+2 • 10Water)

By formula: (Ni+2 • 9H2O) + H2O = (Ni+2 • 10H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

(Ni+2 • 10Water) + Water = (Ni+2 • 11Water)

By formula: (Ni+2 • 10H2O) + H2O = (Ni+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.300.HPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

(Ni+2 • 11Water) + Water = (Ni+2 • 12Water)

By formula: (Ni+2 • 11H2O) + H2O = (Ni+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.300.HPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

(Ni+2 • 12Water) + Water = (Ni+2 • 13Water)

By formula: (Ni+2 • 12H2O) + H2O = (Ni+2 • 13H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.300.HPMSBlades, Jayaweera, et al., 1990, 2gas phase; electrospray, Entropy change calculated or estimated; M

O- + Water = (O- • Water)

By formula: O- + H2O = (O- • H2O)

Quantity Value Units Method Reference Comment
Δr111. ± 7.5kJ/molPDisDeyerl, Clements, et al., 2001gas phase; B
Δr2.2kJ/molN/AArnold, Xu, et al., 1995gas phase; Vertical Detachment Energy: 1.45 eV. Affinity is difference between EA of O-. and HOH..O-.; B
Δr126.kJ/molPDissRoehl, Snodgrass, et al., 1991gas phase; ΔrH<; M
Δr130.kJ/molFAFehsenfeld and Ferguson, 1974gas phase; bracketing, ΔrH<; M

Oxygen cation + Water = (Oxygen cation • Water)

By formula: O2+ + H2O = (O2+ • H2O)

Quantity Value Units Method Reference Comment
Δr67.kJ/molFAAdams and Bohme, 1970gas phase; switching reaction(O2+)SO2, ΔrH>; M

Oxygen anion + Water = (Oxygen anion • Water)

By formula: O2- + H2O = (O2- • H2O)

Quantity Value Units Method Reference Comment
Δr93.3 ± 6.3kJ/molN/ALuong, Clements, et al., 2001gas phase; Vertical Detachment Energy: 2.03±0.05 eV.; B
Δr77.0 ± 8.4kJ/molTDAsArshadi and Kebarle, 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr84.1J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr52.3 ± 8.4kJ/molTDAsArshadi and Kebarle, 1970gas phase; B
Δr49.0 ± 8.4kJ/molIMREParkes, 1971gas phase; B

(Oxygen anion • Water) + Water = (Oxygen anion • 2Water)

By formula: (O2- • H2O) + H2O = (O2- • 2H2O)

Quantity Value Units Method Reference Comment
Δr72.0 ± 4.2kJ/molTDAsArshadi and Kebarle, 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr40.6kJ/molTDAsArshadi and Kebarle, 1970gas phase; B
Δr36. ± 4.2kJ/molIMREPayzant J.D. and Kebarle, 1972gas phase; B
Δr41. ± 4.2kJ/molIMREPack and Phelps, 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.300.PHPMSPayzant J.D. and Kebarle, 1972gas phase; M

(Oxygen anion • 2Water) + Water = (Oxygen anion • 3Water)

By formula: (O2- • 2H2O) + H2O = (O2- • 3H2O)

Quantity Value Units Method Reference Comment
Δr64.4 ± 4.2kJ/molTDAsArshadi and Kebarle, 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr118.J/mol*KPHPMSArshadi and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr29.3kJ/molTDAsArshadi and Kebarle, 1970gas phase; B
Δr26. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.296.FAFehsenfeld and Ferguson, 1974gas phase; M
30.300.PHPMSPayzant J.D. and Kebarle, 1972gas phase; M

(Oxygen anion • 3Water) + Water = (Oxygen anion • 4Water)

By formula: (O2- • 3H2O) + H2O = (O2- • 4H2O)

Quantity Value Units Method Reference Comment
Δr18. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M
Δr14.kJ/molPHPMSArshadi and Kebarle, 1970gas phase; M

(Oxygen anion • 4Water) + Water = (Oxygen anion • 5Water)

By formula: (O2- • 4H2O) + H2O = (O2- • 5H2O)

Quantity Value Units Method Reference Comment
Δr14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B

(O2S- • Water • 3Sulfur dioxide) + Water = (O2S- • 2Water • 3Sulfur dioxide)

By formula: (O2S- • H2O • 3O2S) + H2O = (O2S- • 2H2O • 3O2S)

Quantity Value Units Method Reference Comment
Δr29.7 ± 1.7kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr15.9 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • Water • 4Sulfur dioxide) + Water = (O2S- • 2Water • 4Sulfur dioxide)

By formula: (O2S- • H2O • 4O2S) + H2O = (O2S- • 2H2O • 4O2S)

Quantity Value Units Method Reference Comment
Δr29.7 ± 2.9kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr12.6 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • 2Water • 3Sulfur dioxide) + Water = (O2S- • 3Water • 3Sulfur dioxide)

By formula: (O2S- • 2H2O • 3O2S) + H2O = (O2S- • 3H2O • 3O2S)

Quantity Value Units Method Reference Comment
Δr27.6 ± 1.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr12.6 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • 2Water • 4Sulfur dioxide) + Water = (O2S- • 3Water • 4Sulfur dioxide)

By formula: (O2S- • 2H2O • 4O2S) + H2O = (O2S- • 3H2O • 4O2S)

Quantity Value Units Method Reference Comment
Δr29.7 ± 2.9kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr10.9 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • Sulfur dioxide) + Water = (O2S- • Water • Sulfur dioxide)

By formula: (O2S- • O2S) + H2O = (O2S- • H2O • O2S)

Quantity Value Units Method Reference Comment
Δr37.2 ± 3.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr18.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • 2Sulfur dioxide) + Water = (O2S- • Water • 2Sulfur dioxide)

By formula: (O2S- • 2O2S) + H2O = (O2S- • H2O • 2O2S)

Quantity Value Units Method Reference Comment
Δr31.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr15.1 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • 3Sulfur dioxide) + Water = (O2S- • Water • 3Sulfur dioxide)

By formula: (O2S- • 3O2S) + H2O = (O2S- • H2O • 3O2S)

Quantity Value Units Method Reference Comment
Δr31.8 ± 1.3kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr14.2 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • 4Sulfur dioxide) + Water = (O2S- • Water • 4Sulfur dioxide)

By formula: (O2S- • 4O2S) + H2O = (O2S- • H2O • 4O2S)

Quantity Value Units Method Reference Comment
Δr31.4 ± 1.7kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr13.8 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O2S- • 5Sulfur dioxide) + Water = (O2S- • Water • 5Sulfur dioxide)

By formula: (O2S- • 5O2S) + H2O = (O2S- • H2O • 5O2S)

Quantity Value Units Method Reference Comment
Δr27.2 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Δr13.0 ± 0.84kJ/molTDAsVacher, Leduc, et al., 1994gas phase; B

(O3- • Water) + Water = (O3- • 2Water)

By formula: (O3- • H2O) + H2O = (O3- • 2H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O3- • 2Water) + Water = (O3- • 3Water)

By formula: (O3- • 2H2O) + H2O = (O3- • 3H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.296.FAFehsenfeld and Ferguson, 1974gas phase; M

O3P- + Water = (O3P- • Water)

By formula: O3P- + H2O = (O3P- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.0 ± 1.3kJ/molTDAsKeesee and Castleman Jr., 1989gas phase; Not (HO)2PO2-. See also Blades, Ho, et al., 1996 : (HO)2PO2- -> PO3- + HOH, Eact ca. 55 kcal/mol.; B,M,M
Δr52.7kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Δr92.9J/mol*KHPMSKeesee and Castleman Jr., 1989gas phase; M
Δr87.0J/mol*KHPMSKeesee and Castleman Jr., 1989gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr26. ± 5.0kJ/molTDAsKeesee and Castleman Jr., 1989gas phase; Not (HO)2PO2-. See also Blades, Ho, et al., 1996 : (HO)2PO2- -> PO3- + HOH, Eact ca. 55 kcal/mol.; B
Δr27.kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M

(O3P- • Water) + Water = (O3P- • 2Water)

By formula: (O3P- • H2O) + H2O = (O3P- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr47.7kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Δr47.7kJ/molHPMSKeesee and Castleman Jr., 1989gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr92.0J/mol*KES/HPMSBlades, Ho, et al., 1996, 2gas phase; M
Δr92.0J/mol*KHPMSKeesee and Castleman Jr., 1989gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr21.kJ/molES/HPMSBlades, Ho, et al., 1996, 2gas phase; M

(O3P- • 2Water) + Water = (O3P- • 3Water)

By formula: (O3P- • 2H2O) + H2O = (O3P- • 3H2O)

Quantity Value Units Method Reference Comment
Δr68.2kJ/molHPMSKeesee and Castleman Jr., 1989gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr152.J/mol*KHPMSKeesee and Castleman Jr., 1989gas phase; deuterated; M

(O3P- • 3Water) + Water = (O3P- • 4Water)

By formula: (O3P- • 3H2O) + H2O = (O3P- • 4H2O)

Quantity Value Units Method Reference Comment
Δr46.0kJ/molHPMSKeesee and Castleman Jr., 1989gas phase; deuterated; M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KHPMSKeesee and Castleman Jr., 1989gas phase; deuterated; M

O3S- + Water = (O3S- • Water)

By formula: O3S- + H2O = (O3S- • H2O)

Quantity Value Units Method Reference Comment
Δr23.4 ± 0.84kJ/molIMREMöhler, Reiner, et al., 1992gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.296.FAFehsenfeld and Ferguson, 1974gas phase; M

O4S- + Water = (O4S- • Water)

By formula: O4S- + H2O = (O4S- • H2O)

Quantity Value Units Method Reference Comment
Δr24.7 ± 0.84kJ/molIMREMöhler, Reiner, et al., 1992gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O4S- • Water) + Water = (O4S- • 2Water)

By formula: (O4S- • H2O) + H2O = (O4S- • 2H2O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
6.7296.FAFehsenfeld and Ferguson, 1974gas phase; M

Sulfate + 6Water = H12O10S-2

By formula: O4S-2 + 6H2O = H12O10S-2

Quantity Value Units Method Reference Comment
Δr35.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

Sulfate + 12Water = H24O16S-2

By formula: O4S-2 + 12H2O = H24O16S-2

Quantity Value Units Method Reference Comment
Δr44.8 ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B
Quantity Value Units Method Reference Comment
Δr20. ± 8.4kJ/molTDAsBlades and Kebarle, 2005gas phase; B

Sulfate + 13Water = H26O17S-2

By formula: O4S-2 + 13H2O = H26O17S-2

Quantity Value Units Method Reference Comment
Δr21. ± 8.4kJ/molIMREBlades and Kebarle, 2005gas phase; dGaff at 270K; 298 value probably ca. 0.5 kcal/mole weaker; B

Sulfate + 14Water = H28O18S-2

By formula: O4S-2 + 14H2O = H28O18S-2

Quantity Value Units Method Reference Comment
Δr21. ± 8.4kJ/molIMREBlades and Kebarle, 2005gas phase; dGaff at 270K; 298 value probably ca. 0.5 kcal/mole weaker; B

Sulfate + 15Water = H30O19S-2

By formula: O4S-2 + 15H2O = H30O19S-2

Quantity Value Units Method Reference Comment
Δr19. ± 8.4kJ/molIMREBlades and Kebarle, 2005gas phase; dGaff at 270K; 298 value probably ca. 0.5 kcal/mole weaker; B

Sulfate + 16Water = H32O20S-2

By formula: O4S-2 + 16H2O = H32O20S-2

Quantity Value Units Method Reference Comment
Δr18. ± 8.4kJ/molIMREBlades and Kebarle, 2005gas phase; dGaff at 270K; 298 value probably ca. 0.5 kcal/mole weaker; B

Sulfate + 17Water = H34O21S-2

By formula: O4S-2 + 17H2O = H34O21S-2

Quantity Value Units Method Reference Comment
Δr18. ± 8.4kJ/molIMREBlades and Kebarle, 2005gas phase; dGaff at 270K; 298 value probably ca. 0.5 kcal/mole weaker; B

Sulfate + 18Water = H36O22S-2

By formula: O4S-2 + 18H2O = H36O22S-2

Quantity Value Units Method Reference Comment
Δr16. ± 8.4kJ/molIMREBlades and Kebarle, 2005gas phase; dGaff at 270K; 298 value probably ca. 0.5 kcal/mole weaker; B

Sulfate + 19Water = H38O23S-2

By formula: O4S-2 + 19H2O = H38O23S-2

Quantity Value Units Method Reference Comment
Δr15. ± 8.4kJ/molIMREBlades and Kebarle, 2005gas phase; dGaff at 270K; 298 value probably ca. 0.5 kcal/mole weaker; B

(Sulfate • 5Water) + Water = (Sulfate • 6Water)

By formula: (O4S-2 • 5H2O) + H2O = (O4S-2 • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr36.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(Sulfate • 6Water) + Water = (Sulfate • 7Water)

By formula: (O4S-2 • 6H2O) + H2O = (O4S-2 • 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr31.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(Sulfate • 7Water) + Water = (Sulfate • 8Water)

By formula: (O4S-2 • 7H2O) + H2O = (O4S-2 • 8H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr28.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(Sulfate • 8Water) + Water = (Sulfate • 9Water)

By formula: (O4S-2 • 8H2O) + H2O = (O4S-2 • 9H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr25.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(Sulfate • 9Water) + Water = (Sulfate • 10Water)

By formula: (O4S-2 • 9H2O) + H2O = (O4S-2 • 10H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr23.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(Sulfate • 10Water) + Water = (Sulfate • 11Water)

By formula: (O4S-2 • 10H2O) + H2O = (O4S-2 • 11H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr21.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

Lead ion (1+) + Water = (Lead ion (1+) • Water)

By formula: Pb+ + H2O = (Pb+ • H2O)

Quantity Value Units Method Reference Comment
Δr93.7kJ/molHPMSTang and Castleman, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr149.J/mol*KHPMSTang and Castleman, 1972gas phase; M

(Lead ion (1+) • Water) + Water = (Lead ion (1+) • 2Water)

By formula: (Pb+ • H2O) + H2O = (Pb+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr70.7kJ/molHPMSTang and Castleman, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KHPMSTang and Castleman, 1972gas phase; M

(Lead ion (1+) • 2Water) + Water = (Lead ion (1+) • 3Water)

By formula: (Pb+ • 2H2O) + H2O = (Pb+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molHPMSTang and Castleman, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5J/mol*KHPMSTang and Castleman, 1972gas phase; M

(Lead ion (1+) • 4Water) + Water = (Lead ion (1+) • 5Water)

By formula: (Pb+ • 4H2O) + H2O = (Pb+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr41.8kJ/molHPMSTang and Castleman, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KHPMSTang and Castleman, 1972gas phase; M

(Lead ion (1+) • 5Water) + Water = (Lead ion (1+) • 6Water)

By formula: (Pb+ • 5H2O) + H2O = (Pb+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr40.kJ/molHPMSTang and Castleman, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr98.7J/mol*KHPMSTang and Castleman, 1972gas phase; M

Rubidium ion (1+) + Water = (Rubidium ion (1+) • Water)

By formula: Rb+ + H2O = (Rb+ • H2O)

Quantity Value Units Method Reference Comment
Δr66.5kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr66.9kJ/molMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Δr84.1J/mol*KMSBurdett and Hayhurst, 1982gas phase; flame source, about 1600 K; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
39.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Rubidium ion (1+) • Water) + Water = (Rubidium ion (1+) • 2Water)

By formula: (Rb+ • H2O) + H2O = (Rb+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr56.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.9J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Rubidium ion (1+) • 2Water) + Water = (Rubidium ion (1+) • 3Water)

By formula: (Rb+ • 2H2O) + H2O = (Rb+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Δr50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Rubidium ion (1+) • 3Water) + Water = (Rubidium ion (1+) • 4Water)

By formula: (Rb+ • 3H2O) + H2O = (Rb+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr46.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Rubidium ion (1+) • 4Water) + Water = (Rubidium ion (1+) • 5Water)

By formula: (Rb+ • 4H2O) + H2O = (Rb+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr43.9kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Scandium ion (1+) + Water = (Scandium ion (1+) • Water)

By formula: Sc+ + H2O = (Sc+ • H2O)

Quantity Value Units Method Reference Comment
Δr130. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M

Strontium ion (1+) + Water = (Strontium ion (1+) • Water)

By formula: Sr+ + H2O = (Sr+ • H2O)

Quantity Value Units Method Reference Comment
Δr144.kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M

(Strontium ion (1+) • Water) + Water = (Strontium ion (1+) • 2Water)

By formula: (Sr+ • H2O) + H2O = (Sr+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr128.kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr118.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M

(Strontium ion (1+) • 2Water) + Water = (Strontium ion (1+) • 3Water)

By formula: (Sr+ • 2H2O) + H2O = (Sr+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr108.kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M

(Strontium ion (1+) • 3Water) + Water = (Strontium ion (1+) • 4Water)

By formula: (Sr+ • 3H2O) + H2O = (Sr+ • 4H2O)

Quantity Value Units Method Reference Comment
Δr93.3kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr118.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M

(Strontium ion (1+) • 4Water) + Water = (Strontium ion (1+) • 5Water)

By formula: (Sr+ • 4H2O) + H2O = (Sr+ • 5H2O)

Quantity Value Units Method Reference Comment
Δr86.2kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr128.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M

(Strontium ion (1+) • 5Water) + Water = (Strontium ion (1+) • 6Water)

By formula: (Sr+ • 5H2O) + H2O = (Sr+ • 6H2O)

Quantity Value Units Method Reference Comment
Δr76.6kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr128.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M

(Strontium ion (1+) • 6Water) + Water = (Strontium ion (1+) • 7Water)

By formula: (Sr+ • 6H2O) + H2O = (Sr+ • 7H2O)

Quantity Value Units Method Reference Comment
Δr72.4kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr144.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M

(Strontium ion (1+) • 7Water) + Water = (Strontium ion (1+) • 8Water)

By formula: (Sr+ • 7H2O) + H2O = (Sr+ • 8H2O)

Quantity Value Units Method Reference Comment
Δr68.6kJ/molHPMSTang, Lian, et al., 1976gas phase; M
Quantity Value Units Method Reference Comment
Δr157.J/mol*KHPMSTang, Lian, et al., 1976gas phase; M

(Sr+2 • 8Water) + Water = (Sr+2 • 9Water)

By formula: (Sr+2 • 8H2O) + H2O = (Sr+2 • 9H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Sr+2 • 9Water) + Water = (Sr+2 • 10Water)

By formula: (Sr+2 • 9H2O) + H2O = (Sr+2 • 10H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Sr+2 • 10Water) + Water = (Sr+2 • 11Water)

By formula: (Sr+2 • 10H2O) + H2O = (Sr+2 • 11H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Sr+2 • 11Water) + Water = (Sr+2 • 12Water)

By formula: (Sr+2 • 11H2O) + H2O = (Sr+2 • 12H2O)

Quantity Value Units Method Reference Comment
Δr60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
29.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Titanium ion (1+) + Water = (Titanium ion (1+) • Water)

By formula: Ti+ + H2O = (Ti+ • H2O)

Quantity Value Units Method Reference Comment
Δr160. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
154. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • Water) + Water = (Titanium ion (1+) • 2Water)

By formula: (Ti+ • H2O) + H2O = (Ti+ • 2H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
136. (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 2Water) + Water = (Titanium ion (1+) • 3Water)

By formula: (Ti+ • 2H2O) + H2O = (Ti+ • 3H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
66.9 (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Titanium ion (1+) • 3Water) + Water = (Titanium ion (1+) • 4Water)

By formula: (Ti+ • 3H2O) + H2O = (Ti+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
83.7 (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Vanadium ion (1+) + Water = (Vanadium ion (1+) • Water)

By formula: V+ + H2O = (V+ • H2O)

Quantity Value Units Method Reference Comment
Δr150. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Δr147.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
147. (+35.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • Water) + Water = (Vanadium ion (1+) • 2Water)

By formula: (V+ • H2O) + H2O = (V+ • 2H2O)

Quantity Value Units Method Reference Comment
Δr149.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
151. (+10.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 2Water) + Water = (Vanadium ion (1+) • 3Water)

By formula: (V+ • 2H2O) + H2O = (V+ • 3H2O)

Quantity Value Units Method Reference Comment
Δr51.0kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
68.2 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Vanadium ion (1+) • 3Water) + Water = (Vanadium ion (1+) • 4Water)

By formula: (V+ • 3H2O) + H2O = (V+ • 4H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.8 (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Zinc ion (1+) + Water = (Zinc ion (1+) • Water)

By formula: Zn+ + H2O = (Zn+ • H2O)

Quantity Value Units Method Reference Comment
Δr160. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 7

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Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   C     Symmetry Number σ = 2


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1 1 Sym str 3657  A 3656.65 gas 3654 gas
a1 2 Bend 1595  A 1594.59 gas
b1 3 Anti str 3756  A 3755.79 gas

Source: Shimanouchi, 1972

Notes

A0~1 cm-1 uncertainty

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedApiezon L130.317.Landault and Guiochon, 1964Teflon-Haloport; Column length: 2.26 m

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-101319.Zenkevich, 200525. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryMethyl Silicone327.Zenkevich, Korolenko, et al., 1995Program: not specified

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryPolyethylene Glycol1039.Zenkevich, Korolenko, et al., 1995Program: not specified
CapillaryDB-Wax1066.Peng, Yang, et al., 1991Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

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