Butane, 2-methyl-
- Formula: C5H12
- Molecular weight: 72.1488
- IUPAC Standard InChIKey: QWTDNUCVQCZILF-UHFFFAOYSA-N
- CAS Registry Number: 78-78-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: iso-Pentane; 1,1,2-Trimethylethane; 2-Methylbutane; iso-C5H12; Ethyldimethylmethane; Isoamylhydride; Exxsol isopentane S; 1,1-Dimethylpropane; Methylbutane; NSC 119476
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Normal boiling point
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Tboil (K) | Reference | Comment |
---|---|---|
303.2 | Aldrich Chemical Company Inc., 1990 | BS; Data excluded from overall average |
301.0 | Weast and Grasselli, 1989 | BS |
301. | Majer and Svoboda, 1985 | |
301.2 | Usov, Skvortsova, et al., 1967 | Uncertainty assigned by TRC = 1.5 K; TRC |
302.1 | Le Fevre, Sundaram, et al., 1963 | Uncertainty assigned by TRC = 3. K; TRC; Data excluded from overall average |
300.2 | Freidlin, Nazarova, et al., 1961 | Uncertainty assigned by TRC = 0.6 K; TRC; Data excluded from overall average |
300. | Freidlin, Nazarova, et al., 1961 | Uncertainty assigned by TRC = 4. K; TRC; Data excluded from overall average |
301. | Desty and Whyman, 1957 | Uncertainty assigned by TRC = 0.2 K; TRC |
301.05 | Lichtenfels, Fleck, et al., 1955 | Uncertainty assigned by TRC = 0.5 K; TRC |
300.9 | Slobodin, Grigor'eva, et al., 1953 | Uncertainty assigned by TRC = 1. K; TRC |
301.1 | Anonymous, 1951 | Uncertainty assigned by TRC = 0.1 K; TRC |
301.15 | Obolentsev, 1950 | Uncertainty assigned by TRC = 1. K; TRC |
301.05 | Denyer, Fidler, et al., 1949 | Uncertainty assigned by TRC = 0.5 K; TRC |
300.86 | Foehr and Fenske, 1949 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.1 | Lecat, 1949 | Uncertainty assigned by TRC = 0.07 K; TRC |
301.1 | Lecat, 1949, 2 | Uncertainty assigned by TRC = 0.07 K; TRC |
301.05 | Paushkin and Topchiev, 1949 | Uncertainty assigned by TRC = 0.7 K; TRC |
301.05 | Pichler, Ziesecke, et al., 1949 | Uncertainty assigned by TRC = 0.5 K; TRC |
300.95 | Topchiev and Paushkin, 1949 | Uncertainty assigned by TRC = 0.7 K; TRC |
301.1 | Lecat, 1948 | Uncertainty assigned by TRC = 0.07 K; TRC |
301. | LeTourneau and Matteson, 1948 | Uncertainty assigned by TRC = 0.7 K; TRC |
301.05 | Paushkin and Topchiev, 1948 | Uncertainty assigned by TRC = 0.7 K; TRC |
301.1 | Rossini, 1948 | Uncertainty assigned by TRC = 0.2 K; TRC |
301.15 | Rust, Seubold, et al., 1948 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.04 | Thornton and Herald, 1948 | Uncertainty assigned by TRC = 0.06 K; TRC |
300.95 | Topchiev and Paushkin, 1948 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.05 | Fenske, Braun, et al., 1947 | Uncertainty assigned by TRC = 0.3 K; TRC |
301.1 | Hooper, 1947 | Uncertainty assigned by TRC = 0.1 K; TRC |
301. | Howard, Mears, et al., 1947 | Uncertainty assigned by TRC = 0.02 K; TRC |
301.1 | Lecat, 1947 | Uncertainty assigned by TRC = 0.07 K; TRC |
301.10 | Lecat, 1947, 2 | Uncertainty assigned by TRC = 0.3 K; TRC |
301.1 | Lecat, 1947, 3 | Uncertainty assigned by TRC = 0.07 K; TRC |
300.15 | Slabey, 1947 | Uncertainty assigned by TRC = 2. K; TRC; Data excluded from overall average |
301.1 | Fidler, 1945 | Uncertainty assigned by TRC = 0.1 K; TRC |
301.6 | Grummitt, Sensel, et al., 1945 | Uncertainty assigned by TRC = 0.6 K; TRC; Data excluded from overall average |
301.25 | Maslyanskii, 1944 | Uncertainty assigned by TRC = 0.7 K; TRC |
301.15 | Moldavskii, Nebylova, et al., 1944 | Uncertainty assigned by TRC = 1. K; TRC |
301.1 | Anonymous, 1943 | Uncertainty assigned by TRC = 0.1 K; TRC |
301. | Anonymous, 1943, 2 | Uncertainty assigned by TRC = 0.02 K; TRC |
301.07 | Guthrie and Huffman, 1943 | Uncertainty assigned by TRC = 0.05 K; TRC |
301.15 | McArdle and Robertson, 1943 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.0 | Rossini, 1943 | Uncertainty assigned by TRC = 0.3 K; TRC |
300.85 | Brown and Groot, 1942 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.05 | McArdle and Robertson, 1942 | Uncertainty assigned by TRC = 0.4 K; TRC |
300.9 | Rank, Scott, et al., 1942 | Uncertainty assigned by TRC = 0.3 K; not clear if this was measured by authors; TRC |
301.04 | Anonymous, 1941 | Uncertainty assigned by TRC = 0.1 K; TRC |
301.15 | Koch and Hilberath, 1941 | Uncertainty assigned by TRC = 0.5 K; TRC |
300.9 | McAllister, Anderson, et al., 1941 | Uncertainty assigned by TRC = 0.8 K; TRC |
301.1 | Oberfell and Frey, 1939 | Uncertainty assigned by TRC = 0.5 K; TRC |
300.95 | Wibaut, Hoog, et al., 1939 | Uncertainty assigned by TRC = 0.3 K; TRC |
300.95 | Smittenberg, Hoog, et al., 1938 | Uncertainty assigned by TRC = 0.3 K; TRC |
301.15 | Hoog, Smittenberg, et al., 1937 | Uncertainty assigned by TRC = 1. K; TRC |
301.25 | Vondracek, 1937 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.25 | Van Wijk and Versteeg, 1937 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.1 | Davydova, Papkina, et al., 1936 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.05 | Schorigin, Issaguljanz, et al., 1933 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.15 | Davis, Thomson, et al., 1932 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.1 | Kolossowsky and Udovenko, 1931 | Uncertainty assigned by TRC = 0.2 K; TRC |
301.1 | Norris and Thomson, 1931 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.15 | Parks, Huffman, et al., 1930 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.15 | Brame and Hunter, 1927 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.1 | Lecat, 1927 | Uncertainty assigned by TRC = 0.05 K; TRC |
303.7 | Brown and Carr, 1926 | Uncertainty assigned by TRC = 1. K; TRC; Data excluded from overall average |
301.1 | Timmermans and Martin, 1926 | Uncertainty assigned by TRC = 0.03 K; TRC |
301.2 | Anderson and Erskine, 1924 | Uncertainty assigned by TRC = 0.2 K; TRC |
301.05 | Calingaert, 1923 | Uncertainty assigned by TRC = 0.5 K; TRC |
301.05 | Timmermans, Van der Horst, et al., 1923 | Uncertainty assigned by TRC = 0.04 K; TRC |
301.15 | Chavanne and Simon, 1920 | Uncertainty assigned by TRC = 1. K; TRC |
301. | Chavanne and Simon, 1919 | Uncertainty assigned by TRC = 2. K; TRC |
301.15 | Chavanne and Simon, 1919, 2 | Uncertainty assigned by TRC = 1. K; TRC |
303.55 | Lagerlof, 1918 | Uncertainty assigned by TRC = 0.5 K; TRC; Data excluded from overall average |
301.1 | Timmermans, 1912 | Uncertainty assigned by TRC = 0.05 K; TRC |
301.10 | Timmermans, 1911 | Uncertainty assigned by TRC = 0.2 K; TRC |
301.1 | Timmermans, 1910 | Uncertainty assigned by TRC = 0.2 K; TRC |
301.15 | Landolt and Jahn, 1892 | Uncertainty assigned by TRC = 1. K; TRC |
303.65 | Perkin, 1884 | Uncertainty assigned by TRC = 2. K; TRC; Data excluded from overall average |
References
Go To: Top, Normal boiling point, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
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Majer and Svoboda, 1985
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Dehydration of Isopentenes and Isopentane on An Alumina-Chromium Oxide -Potassium Oxide Catalyst,
Neftekhimiya, 1967, 7, 341-8. [all data]
Le Fevre, Sundaram, et al., 1963
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Molecular Polarisability: the Anisotropy of the Carbon-Oxygen Link,
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Freidlin, Nazarova, et al., 1961
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Lichtenfels, Fleck, et al., 1955
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Slobodin, Grigor'eva, et al., 1953
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Anonymous, R.,
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Magneto-optic Rotation of Hydrocarbons,
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Lecat, 1949
Lecat, M.,
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Lecat, 1949, 2
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Homofunctional azeotropes of hydrocarbons,
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Pure compounds from petroleum purification and purity of hydrocarbons,
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Dec. of Di-t-Alkyl Peroxides. II. React. of the Resultant Free Radical,
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Fenske, Braun, et al., 1947
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The analysis of hydrocarbon gases by low temperature distillation,
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Azeotropes of sulfides and halides,
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Orthobaric Azeotropes of Sulfides,
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Lecat, 1947, 3
Lecat, M.,
Azeotropes of nitro derivatives,
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Slabey, 1947
Slabey, V.A.,
J. Am. Chem. Soc., 1947, 69, 475. [all data]
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The Action of Aluminum Bromide on Paraffin Hydrocarbons I. n-Hexane and n-Heptane,
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Zh. Obshch. Khim., 1944, 14, 148. [all data]
Moldavskii, Nebylova, et al., 1944
Moldavskii, B.; Nebylova, E.; Nizovkina, T.V.,
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Anonymous, R.,
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Anonymous, X.,
Am. Pet. Inst. Res. Proj. 6, 1943, Unpublished, 1943. [all data]
Guthrie and Huffman, 1943
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Thermal data. XVI. the heat capacity and entropy of isopentane. the absence of a reported anomaly.,
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Rossini, 1943
Rossini, F.D.,
Pet. Eng., 1943, 14, 5, 41-2. [all data]
Brown and Groot, 1942
Brown, H.C.; Groot, C.,
J. Am. Chem. Soc., 1942, 64, 2563. [all data]
McArdle and Robertson, 1942
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Solvent Properties of Isomeric Paraffins,
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Rank, Scott, et al., 1942
Rank, D.H.; Scott, R.W.; Fenske, M.R.,
Qualitive and quantitative analysis of hydrocarbon mixtures,
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Anonymous, 1941
Anonymous, R.,
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Koch and Hilberath, 1941
Koch, H.; Hilberath, F.,
Uber unterhalb 100C siedenden kohlenwassestoffe des synthetischen benzins aus kohlenoxyd und wasserstoff (kogasin),
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McAllister, Anderson, et al., 1941
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J. Org. Chem., 1941, 6, 647. [all data]
Oberfell and Frey, 1939
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Oil & Gas J., 1939, 38, 29, 70. [all data]
Wibaut, Hoog, et al., 1939
Wibaut, J.P.; Hoog, H.; Langedijk, S.L.; Overhoff, J.; Smittenberg, J.; Benninga, N.; Bouman, G.P.; van Dijk, H.; Gaade, W.; Geldof, H.; Hackmann, J.Th.; Jonker, E.W.; Paap, T.; Zuiderweg, F.J.,
Study on the Preparation and the Physical Constants of A Number of Alkanes and Cycloalkanes,
Recl. Trav. Chim. Pays-Bas, 1939, 58, 329. [all data]
Smittenberg, Hoog, et al., 1938
Smittenberg, J.; Hoog, H.; Henkes, R.A.,
Freezing Points of A Number of Pure Hydrocarbons of the Gasoline Boiling Range and of Some of their Binary Mixtures,
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Hoog, Smittenberg, et al., 1937
Hoog, H.; Smittenberg, J.; Visser, G.H.,
Composition of the Primary Polymerization Prod. of Propene and Butenes
in IIe Congr. Mondial Pet. 2, Sect. 2, Phys. Chim. Raffin- age, p 489, 1937. [all data]
Vondracek, 1937
Vondracek, R.,
Binary Systems of Phenol with Some Hydrocarbons,
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Van Wijk and Versteeg, 1937
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Viscosity of pure hydrocarbons.
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Davydova, Papkina, et al., 1936
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Chloro Derivatives of Aliphatic Hydrocarbons. IV. Chlorination of Isopentane,
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Davis, Thomson, et al., 1932
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The role of liquid stationary films in batch absorption of gases: III rates of hydrogen absorption and relative rates of catalytic hydrogenation in alcohol,
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Norris and Thomson, 1931
Norris; Thomson,
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Parks, Huffman, et al., 1930
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Thermal Data on Organic Compounds VI. The Heat Capacities, Entropies and Free Energies of Some Saturated, Non-Benzenoid Hydrocarbons,
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Brame and Hunter, 1927
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Composition of Cracked Distillates,
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Lecat, 1927
Lecat, M.,
New binary azeotropes: 6th list,
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Brown and Carr, 1926
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Timmermans and Martin, 1926
Timmermans, J.; Martin, F.,
J. Chim. Phys. Phys.-Chim. Biol., 1926, 23, 747. [all data]
Anderson and Erskine, 1924
Anderson, R.P.; Erskine, A.M.,
Ind. Eng. Chem., 1924, 16, 263. [all data]
Calingaert, 1923
Calingaert, G.,
J. Am. Chem. Soc., 1923, 45, 130. [all data]
Timmermans, Van der Horst, et al., 1923
Timmermans, J.; Van der Horst, H.; Onnes, H.K.,
Freezing points of pure organic liquids as thermometric reference points at low temperatures,
Arch. Neerl. Sci. Exactes Nat., Ser. 3A, 1923, 6, 180. [all data]
Chavanne and Simon, 1920
Chavanne, G.; Simon, L.J.,
Ann. Chim. Anal. Chim. Appl., 1920, 2, 76. [all data]
Chavanne and Simon, 1919
Chavanne, G.; Simon, L.J.,
Critical solution temperatures in aniline of the principal hydrocarbons contained in petroleum,
C. R. Hebd. Seances Acad. Sci., 1919, 168, 1111. [all data]
Chavanne and Simon, 1919, 2
Chavanne, G.; Simon, L.J.,
Preparation of Several Volatile Acyclic Saturated Hydrocarbons Found in Petroleum,
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Lagerlof, 1918
Lagerlof, D.,
Thermodynamic research: reduced formulas for simplified calculations of latent molar heat of evaporation,
J. Prakt. Chem., 1918, 98, 136. [all data]
Timmermans, 1912
Timmermans, J.,
Experimental Research on the Density of Liquids Below 0 Degrees.,
Sci. Proc. R. Dublin Soc., 1912, 13, 310. [all data]
Timmermans, 1911
Timmermans, J.,
Researches on the freezing point of organic liquid compounds,
Bull. Soc. Chim. Belg., 1911, 25, 300. [all data]
Timmermans, 1910
Timmermans, J.,
The Purification and Physical Constants of Several Organic Liquids,
Bull. Soc. Chim. Belg., 1910, 24, 244. [all data]
Landolt and Jahn, 1892
Landolt, H.; Jahn, H.,
The Molecular Refraction of Several Simple Organic Compounds for Rays of Infinitely Great Wave Length.,
Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1892, 10, 289. [all data]
Perkin, 1884
Perkin, W.H.,
On the Magnetic Rotary Polarisation of Compounds in Relation to their Chemical Consitution; with Observations on the Preparation and Relative Densities of the Bodies Examined,
J. Chem. Soc., 1884, 45, 421-580. [all data]
Notes
Go To: Top, Normal boiling point, References
- Symbols used in this document:
Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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