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Chlorine difluoride-35cl


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to ClF2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference
12.77 ± 0.05EIDudin, Gorokhov, et al., 1979

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 500 Ar Ra Prochaska and Andrews, 1977
1 Sym. stretch 536 w T N2 IR Mamantov, Vasini, et al., 1971
1 Sym. stretch 500 N2 Ra Prochaska and Andrews, 1977
2 Bend 242 w T N2 IR Mamantov, Vasini, et al., 1971
b2 3 Asym. stretch 574 s Ar IR Mamantov, Vasini, et al., 1971
Prochaska and Andrews, 1977
3 Asym. stretch 578 s N2 IR Mamantov, Vasini, et al., 1971
Prochaska and Andrews, 1977

Additional references: Jacox, 1994, page 116; Galbraith, Vacek, et al., 1993

Notes

wWeak
sStrong
TTentative assignment or approximate value

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dudin, Gorokhov, et al., 1979
Dudin, A.V.; Gorokhov, L.N.; Baluev, A.V., A study of the electron-impact ionization of chlorine trifluoride and its decomposition products by mass spectrometry, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1979, 11, 2408. [all data]

Prochaska and Andrews, 1977
Prochaska, E.S.; Andrews, L., Raman, infrared and ultraviolet spectra of the chlorine difluoride free radical in solid nitrogen, Inorg. Chem., 1977, 16, 2, 339, https://doi.org/10.1021/ic50168a023 . [all data]

Mamantov, Vasini, et al., 1971
Mamantov, G.; Vasini, E.J.; Moulton, M.C.; Vickroy, D.G.; Maekawa, T., Chlorine--Fluorine System at Low Temperatures: Characterization of the ClF2 Radical, J. Chem. Phys., 1971, 54, 8, 3419, https://doi.org/10.1063/1.1675359 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Galbraith, Vacek, et al., 1993
Galbraith, J.M.; Vacek, G.; Schaefer, H.F., III, ClF2: Structure and infrared spectra of a weakly bound triatomic molecule, J. Chem. Phys., 1993, 98, 10, 8051, https://doi.org/10.1063/1.464560 . [all data]


Notes

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