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Boron monofluoride monoxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Deltafgas-144.00kcal/molReviewChase, 1998Data last reviewed in December, 1965
Quantity Value Units Method Reference Comment
gas,1 bar53.728cal/mol*KReviewChase, 1998Data last reviewed in December, 1965

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. - 800.800. - 6000.
A 6.56966114.06040
B 15.030200.515621
C -11.38740-0.111865
D 3.3488410.008176
E -0.029266-0.934969
F -146.6310-150.6950
G 57.5103067.04510
H -144.0000-144.0000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1965 Data last reviewed in December, 1965

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + BFO = (Fluorine anion bullet BFO)

By formula: F- + BFO = (F- bullet BFO)

Quantity Value Units Method Reference Comment
Deltar48. ± 3.kcal/molICRLarson and McMahon, 1987gas phase; bracketing

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
14. ± 1.EIUy, Srivastava, et al., 1971LLK
13.4 ± 0.5EIHildenbrand, Theard, et al., 1963RDSH

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + BFO = (Fluorine anion bullet BFO)

By formula: F- + BFO = (F- bullet BFO)

Quantity Value Units Method Reference Comment
Deltar48. ± 3.kcal/molICRLarson and McMahon, 1987gas phase; bracketing

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 B=O stretch 2078.87 gas DL Kawashima, Kawaguchi, et al., 1987
1 B=O stretch 2081 Ne IR Snelson, 1972
Jacox and Thompson, 1995
1 B=O stretch 2071 Ar IR Snelson, 1972
Pi 2 Bend 502 Ne IR Snelson, 1972
Jacox and Thompson, 1995
2 Bend 493 Ar IR Snelson, 1972

Additional references: Jacox, 1994, page 84; Jacox, 1998, page 188


References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Trends in Gas Phase Fluoride Ion Affinities of the Main Group Oxyfluorides and Fluoride Sulfides. Fluoride Adducts of FAsO, FPO, FPO2, F2SiO, F4SO, FBO, F2SiS, FPS, FAsS, F2S2, and S2O., Inorg. Chem., 1987, 26, 24, 4018, https://doi.org/10.1021/ic00271a011 . [all data]

Uy, Srivastava, et al., 1971
Uy, O.M.; Srivastava, R.D.; Farber, M., Mass spectrometric determination of the heats of formation of gaseous BO2 BOF2, High Temp. Sci., 1971, 3, 462. [all data]

Hildenbrand, Theard, et al., 1963
Hildenbrand, D.L.; Theard, L.P.; Saul, A.M., Transpiration and mass spectrometric studies of equilibria involving BOF(g) and (BOF)3(g), J. Chem. Phys., 1963, 39, 1973. [all data]

Kawashima, Kawaguchi, et al., 1987
Kawashima, Y.; Kawaguchi, K.; Endo, Y.; Hirota, E., Infrared diode laser and microwave spectra and molecular structure of an unstable molecule, FBO, J. Chem. Phys., 1987, 87, 4, 2006, https://doi.org/10.1063/1.453175 . [all data]

Snelson, 1972
Snelson, A., High Temp. Sci., 1972, 4, 141. [all data]

Jacox and Thompson, 1995
Jacox, M.E.; Thompson, W.E., Matrix isolation study of the interaction of excited neon atoms with BF3: Infrared spectra of BF2, BF+2, BF+3, and BF-3, J. Chem. Phys., 1995, 102, 12, 4747, https://doi.org/10.1063/1.469523 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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