Formaldehyde, seleno-

• Formula: CH₂Se
• Molecular weight: 92.99
• CAS Registry Number: 6596-50-5
• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Options:
  • Switch to SI units

Gas phase ion energetics data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A

State:   a

State:   X

Additional references: Jacox, 1994, page 145; Jacox, 1998, page 226; Jacox, 2003, page 174; Brown, Godfrey, et al., 1985; Brown, Godfrey, et al., 1986; Clouthier, Judge, et al., 1990; Joo, Clouthier, et al., 2000

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Bock, Aygen, et al., 1984
Bock, H.; Aygen, S.; Rosmus, P.; Solouki, B.; Weissflog, E., Gasphasen-reaktionen,40. Selenoformaldehyd: Hochkorrelierte wellenfunktion und photoelektronenspektroskopischer nachweis, Chem. Ber., 1984, 117, 187. [all data]

Clouthier, Judge, et al., 1987
Clouthier, D.J.; Judge, R.H.; Moule, D.C., The laser excitation spectrum of selenoformaldehyde: vibrational analyses of the 1A2 ← 1A1 and 3A2 ← 1A1 electronic transitions, Chem. Phys., 1987, 114, 3, 417, https://doi.org/10.1016/0301-0104(87)85055-3 . [all data]

Judge, Clouthier, et al., 1988
Judge, R.H.; Clouthier, D.J.; Moule, D.C., The laser excitation spectrum of CH2Se and CD2Se in the near infrared, J. Chem. Phys., 1988, 89, 4, 1807, https://doi.org/10.1063/1.455128 . [all data]

Glinski, Taylor, et al., 1991
Glinski, R.J.; Taylor, C.D.; Martin, H.R., Chemiluminescence spectra of thioformaldehyde and selenoformaldehyde, J. Phys. Chem., 1991, 95, 16, 6159, https://doi.org/10.1021/j100169a021 . [all data]

Judge and Moule, 1984
Judge, R.H.; Moule, D.C., Detection of a3A2(n,.pi.*) selenoformaldehyde by flash pyrolysis, J. Am. Chem. Soc., 1984, 106, 19, 5406, https://doi.org/10.1021/ja00331a004 . [all data]

Glinski, Mishalanie, et al., 1986
Glinski, R.J.; Mishalanie, E.A.; Birks, J.W., Selenoformaldehyde phosphorescence observed in the reaction of molecular fluorine with dimethyl diselenide, J. Am. Chem. Soc., 1986, 108, 3, 531, https://doi.org/10.1021/ja00263a042 . [all data]

Joo, Clouthier, et al., 1995
Joo, D.-L.; Clouthier, D.J.; Judge, R.H.; Moule, D.C., Very large zero field splittings in the triplet state of an asymmetric top: Rotational analysis and Zeeman effects in the 820 nm a 3A2-- X 1A1 band system of selenoformaldehyde, J. Chem. Phys., 1995, 102, 19, 7351, https://doi.org/10.1063/1.469047 . [all data]

Beckers, Kim, et al., 2008
Beckers, H.; Kim, Y.S.; Willner, H., Infrared Spectrum of Matrix Isolated Selenoformaldehyde, CH, Inorg. Chem., 2008, 47, 5, 1693, https://doi.org/10.1021/ic702237v . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Brown, Godfrey, et al., 1985
Brown, R.D.; Godfrey, P.D.; McNaughton, D., The microwave spectrum of selenoformaldehyde, Chem. Phys. Lett., 1985, 118, 1, 29, https://doi.org/10.1016/0009-2614(85)85259-3 . [all data]

Brown, Godfrey, et al., 1986
Brown, R.D.; Godfrey, P.D.; McNaughton, D.; Taylor, P.R., The structure of H2CSe from microwave spectroscopy, J. Mol. Spectrosc., 1986, 120, 2, 292, https://doi.org/10.1016/0022-2852(86)90005-6 . [all data]

Clouthier, Judge, et al., 1990
Clouthier, D.J.; Judge, R.H.; Moule, D.C., Selenoformaldehyde: Rotational analysis of the 735 nm band system of H2C78Se, H2C80Se, and D2C80Se from high-resolution laser fluorescence excitation spectra, J. Mol. Spectrosc., 1990, 141, 2, 175, https://doi.org/10.1016/0022-2852(90)90157-L . [all data]

Joo, Clouthier, et al., 2000
Joo, D.-L.; Clouthier, D.J.; Judge, R.H., Experimental proof of the case (ab) coupling hypothesis in the first excited triplet state of selenoformaldehyde (H[sub 2]C[Double Bond]Se), J. Chem. Phys., 2000, 112, 5, 2285, https://doi.org/10.1063/1.480827 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.