Monofluoroamine
- Formula: FH2N
- Molecular weight: 35.0210
- IUPAC Standard InChIKey: MDQRDWAGHRLBPA-UHFFFAOYSA-N
- CAS Registry Number: 15861-05-9
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias and Joel F. Liebman
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.83 | PE | Baumgartel, Jochims, et al., 1989 | |
11.62 | PE | Baumgartel, Jochims, et al., 1989 | Vertical value |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
FHN+ | 15.2 | H | PE | Baumgartel, Jochims, et al., 1989 | |
FN+ | 14.85 | H2 | PE | Baumgartel, Jochims, et al., 1989 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | NH2 s-stretch | 3269 | H | Ar | IR | Andrews and Lascola, 1987 |
1 | NH2 s-stretch | 3234 | N2 | IR | Baumgartel, Jochims, et al., 1989 | ||
2 | NH2 scissors | 1568 | H | Ar | IR | Andrews and Lascola, 1987 | |
2 | NH2 scissors | 1564 | N2 | IR | Baumgartel, Jochims, et al., 1989 | ||
3 | NH2 wag | 1244 | H | Ar | IR | Andrews and Lascola, 1987 | |
3 | NH2 wag | 1241 | N2 | IR | Baumgartel, Jochims, et al., 1989 | ||
3 | NH2 wag | 1233 | N2 | IR | Baumgartel, Jochims, et al., 1989 | ||
4 | NF stretch | 934 | H | Ar | IR | Andrews and Lascola, 1987 | |
4 | NF stretch | 891 | N2 | IR | Baumgartel, Jochims, et al., 1989 | ||
a | 5 | NH2 a-stretch | 3346 | N2 | IR | Baumgartel, Jochims, et al., 1989 | |
Additional references: Jacox, 1994, page 153; Christen, Minkwitz, et al., 1987
Notes
H | (1/2)(2ν) |
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Baumgartel, Jochims, et al., 1989
Baumgartel, H.; Jochims, H.-W.; Ruhl, E.; Bock, H.; Dammel, R.; Minkwitz, J.; Nass, R.,
Photoelectron and photoionization mass spectra of the fluoramines NH3-nFn1,
Inorg. Chem., 1989, 28, 943. [all data]
Andrews and Lascola, 1987
Andrews, L.; Lascola, R.,
Infrared spectra of the ammonia-fluorine and fluoramide-hydrogen fluoride complexes in solid argon,
J. Am. Chem. Soc., 1987, 109, 21, 6243, https://doi.org/10.1021/ja00255a004
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Christen, Minkwitz, et al., 1987
Christen, D.; Minkwitz, R.; Nass, R.,
Microwave spectrum, inversion, and molecular structure of monofluoramine, FNH2,
J. Am. Chem. Soc., 1987, 109, 23, 7020, https://doi.org/10.1021/ja00257a019
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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