Boron hydride sulfide
- Formula: BHS
- Molecular weight: 43.884
- CAS Registry Number: 14457-85-3
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Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.10 ± 0.05 | PE | Suffolk, Cooper, et al., 1988 | LL |
| 11.11 ± 0.03 | PE | Kroto, Suffolk, et al., 1973 | LLK |
| 11.12 | PE | Fehlner and Turner, 1973 | LLK |
| 11.21 ± 0.05 | PE | Suffolk, Cooper, et al., 1988 | Vertical value; LL |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | BH stretch | 2735.80 | gas | IR | Maki and Sams, 1975 | |
| 1 | BH stretch | 2724 | Ar | IR | Carpenter and Ault, 1992 | ||
| 3 | BS stretch | 1172.39 | gas | IR | Turner and Mills, 1982 | ||
| 3 | BS stretch | 1168 | Ar | IR | Carpenter and Ault, 1992 | ||
Additional references: Jacox, 1994, page 35; Pearson and McCormick, 1973; Bizzocchi, Degli Esposti, et al., 2002; Bizzocchi and Degli Esposti, 2007; Bizzocchi, Degli Esposti, et al., 2008
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Suffolk, Cooper, et al., 1988
Suffolk, R.J.; Cooper, T.A.; Pantelides, E.; Watts, J.D.; Kroto, H.W.,
Photoelectron spectra of sulphidoborons XBS where X = H, F, Cl, or Br,
J. Chem. Soc. Dalton Trans., 1988, 2041. [all data]
Kroto, Suffolk, et al., 1973
Kroto, H.W.; Suffolk, R.J.; Westwood, N.P.C.,
The photoelectron spectrum of thioborine, HBS,
Chem. Phys. Lett., 1973, 22, 495. [all data]
Fehlner and Turner, 1973
Fehlner, T.P.; Turner, D.W.,
Photoelectron spectrum of HBS,
J. Am. Chem. Soc., 1973, 95, 7175. [all data]
Maki and Sams, 1975
Maki, A.G.; Sams, R.L.,
High-resolution infrared measurements of v1 and force field calculations for thioborine (HBS),
J. Mol. Struct., 1975, 26, 1, 107, https://doi.org/10.1016/0022-2860(75)80071-8
. [all data]
Carpenter and Ault, 1992
Carpenter, J.D.; Ault, B.S.,
Matrix isolation study of the reaction of diborane with hydrogen sulfide: spectroscopic characterization of mercaptoborane, H2BSH,
J. Phys. Chem., 1992, 96, 20, 7913, https://doi.org/10.1021/j100199a018
. [all data]
Turner and Mills, 1982
Turner, P.; Mills, I.M.,
The infrared spectrum, equilibrium structure and harmonic and anharmonic force field of thioborine, HBS,
Mol. Phys., 1982, 46, 1, 161, https://doi.org/10.1080/00268978200101151
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Pearson and McCormick, 1973
Pearson, E.F.; McCormick, V.,
Rotational spectrum and structure of thioborine: HBS,
J. Chem. Phys., 1973, 58, 4, 1619, https://doi.org/10.1063/1.1679403
. [all data]
Bizzocchi, Degli Esposti, et al., 2002
Bizzocchi, L.; Degli Esposti, C.; Dore, L.,
Rotational Spectroscopy of HB33S: The Quadrupole Coupling Constant of 33S in Thioborine,
J. Mol. Spectrosc., 2002, 215, 2, 228, https://doi.org/10.1006/jmsp.2002.8649
. [all data]
Bizzocchi and Degli Esposti, 2007
Bizzocchi, L.; Degli Esposti, C.,
Millimeter- and submillimeter-wave spectroscopy of HBS and DBS in vibrationally excited states,
J. Mol. Spectrosc., 2007, 241, 1, 67, https://doi.org/10.1016/j.jms.2006.11.002
. [all data]
Bizzocchi, Degli Esposti, et al., 2008
Bizzocchi, L.; Degli Esposti, D.; Dore, L.,
Sub-Doppler millimetre-wave spectroscopy of DBS and HBS: accurate values of nuclear electric and magnetic hyperfine structure constants,
Phys. Chem. Chem. Phys., 2008, 10, 5, 658, https://doi.org/10.1039/b710356e
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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