Dimethylgermathione


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
8.6PEGarcia, Gonbeau, et al., 1985 
8.60PEPfister-Guillouzo and Guimon, 1985Vertical value
8.6PEGuimon, Pfister-Guillouzo, et al., 1983Vertical value

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CH3 deform. 1407 Ar IR Khabashesku, Boganov, et al., 1991
4 CH3 deform. 1237 Ar IR Khabashesku, Boganov, et al., 1991
5 CH3 rock 850 s Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
6 Ge=S stretch 605 vs Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
7 GeC s-stretch 516 m Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
b1 14 CH3 a-deform. 1390 m Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
15 CH3 deform 761 m Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
b2 21 CH3 deform 1229 m Ar IR Barrau, Balaji, et al., 1989
Khabashesku, Boganov, et al., 1991
22 CH3 rock 809 Ar IR Khabashesku, Boganov, et al., 1991
23 GeC a-stretch 574 Ar IR Khabashesku, Boganov, et al., 1991

Additional references: Jacox, 2003, page 391

Notes

mMedium
sStrong
vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Garcia, Gonbeau, et al., 1985
Garcia, J.-L.; Gonbeau, D.; Pfister-Guillouzo, G.; Roch, M.; Weber, J., Germathione - silathione spectres photoelectroniques et structures electroniques par la methode MS Xα, Can. J. Chem., 1985, 63, 1518. [all data]

Pfister-Guillouzo and Guimon, 1985
Pfister-Guillouzo, G.; Guimon, C., Studies by P.E.S. of highly reactive sulfur species, Phosphorus Sulfur, 1985, 23, 197. [all data]

Guimon, Pfister-Guillouzo, et al., 1983
Guimon, G.; Pfister-Guillouzo, G.; Lavayssiere, H.; Dousse, G.; Barrau, J.; Satge, J., Generation of dimethylgermathione and dimethylsilathione and their detection in the gas phase by photoelectron spectroscopy, J. Organomet. Chem., 1983, 249, 17. [all data]

Khabashesku, Boganov, et al., 1991
Khabashesku, V.N.; Boganov, S.E.; Zuev, P.S.; Nefedov, O.M., et al., Direct study of unstable dimethylgermathione, Me2Ge«58875»S, by vacuum pyrolysis-MS and low temperature matrix IR spectroscopy, J. Organomet. Chem., 1991, 402, 2, 161, https://doi.org/10.1016/0022-328X(91)83060-H . [all data]

Barrau, Balaji, et al., 1989
Barrau, J.; Balaji, V.; Michl, J., Matrix isolation and IR spectroscopy of germanethione Me2Ge:S, Organomet., 1989, 8, 8, 2034, https://doi.org/10.1021/om00110a033 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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