Dibromosilylene

• Formula: Br₂Si
• Molecular weight: 187.893
• IUPAC Standard InChI: InChI=1S/Br2Si/c1-3-2 Copy

  
• IUPAC Standard InChIKey: KBDJQNUZLNUGDS-UHFFFAOYSA-N Copy
• CAS Registry Number: 14877-32-8
• Chemical structure:
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• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

View reactions leading to Br₂Si⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A ?

State:   X

Additional references: Jacox, 1994, page 101

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pabst, Margrave, et al., 1977
Pabst, R.E.; Margrave, J.L.; Franklin, J.L., Electron impact studies of the tetrachlorides and tetrabromides of silicon and germanium, Int. J. Mass Spectrom. Ion Phys., 1977, 25, 361. [all data]

Creasey, Lambert, et al., 1991
Creasey, J.C.; Lambert, I.R.; Tuckett, R.P.; Codling, K.; Leszek, J.F.; Hatherly, P.A.; Stankiewicz, M., Photoionization mass-spectrometric study of fragmentation of SiBr₄ and GeBr₄ in the range 400-1220 A, J. Chem. Soc. Faraday Trans., 1991, 87, 3717. [all data]

Farber and Srivastava, 1980
Farber, M.; Srivastava, R.D., Mass spectrometric determination of the heats of formation of the silicon bromides SiBr(g), SiBr₂(g), and SiBr₃(g)., High Temp. Sci., 1980, 12, 21. [all data]

Ruzsicska, Jodhan, et al., 1987
Ruzsicska, B.; Jodhan, A.; Safarik, I.; Strausz, O.P.; Bell, T.N., Flash photolysis of SiBr4: the UV spectrum of SiBr2, Chem. Phys. Lett., 1987, 139, 1, 72, https://doi.org/10.1016/0009-2614(87)80153-7 . [all data]

Maass, Hauge, et al., 1972
Maass, G.; Hauge, R.H.; Margrave, J.L., The I.R. Spectra of Matrix-isolated SiBr2 and SiCl2, Z. Anorg. Allg. Chem., 1972, 392, 3, 295, https://doi.org/10.1002/zaac.19723920314 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  EA	Electron affinity

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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