BrONO2
- Formula: BrNO3
- Molecular weight: 141.909
- CAS Registry Number: 40423-14-1
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Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias and Joel F. Liebman
Ionization energy determinations
IE (eV) | Method | Reference |
---|---|---|
10.60 | PE | Dianxum and Peng, 1996 |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
BrO+ | 11.62 | NO2 | PI | Jochims, Denzer, et al., 1992 | |
NO+ | 13.1 | BrO+O/Br+O2 | PI | Jochims, Denzer, et al., 1992 | |
NO2+ | 10.6 | BrO | PI | Jochims, Denzer, et al., 1992 | |
NO2+ | 13.2 | Br+O | PI | Jochims, Denzer, et al., 1992 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a' | 1 | NO2 a-stretch | 1714 | vs | gas | IR | Wilson and Christe, 1987 |
1 | NO2 a-stretch | 1709 | vs | Ne | IR | Wilson and Christe, 1987 | |
1 | NO2 a-stretch | 1702 | vs | N2 | IR | Wilson and Christe, 1987 | |
2 | NO2 s-stretch | 1288 | vs | gas | IR | Wilson and Christe, 1987 | |
2 | NO2 s-stretch | 1285 | vs | Ne | IR | Wilson and Christe, 1987 | |
2 | NO2 s-stretch | 1285 | vs | N2 | IR | Wilson and Christe, 1987 | |
3 | NO2 scissors | 806 | vs | gas | IR | Wilson and Christe, 1987 | |
3 | NO2 scissors | 802 | vs | Ne | IR | Wilson and Christe, 1987 | |
3 | NO2 scissors | 805 | vs | N2 | IR | Wilson and Christe, 1987 | |
4 | OBr stretch | 750 | w | Ne | IR | Wilson and Christe, 1987 | |
4 | OBr stretch | 750 | w | N2 | IR | Wilson and Christe, 1987 | |
5 | NO2 rock | 564 | s | gas | IR | Wilson and Christe, 1987 | |
5 | NO2 rock | 563 | s | Ne | IR | Wilson and Christe, 1987 | |
5 | NO2 rock | 574 | s | N2 | IR | Wilson and Christe, 1987 | |
5 | NO2 rock | 569 | s | N2 | IR | Wilson and Christe, 1987 | |
a | 8 | ONO2 OPLA | 728 | w m | gas | IR | Wilson and Christe, 1987 |
8 | ONO2 OPLA | 723 | w | Ne | IR | Wilson and Christe, 1987 | |
8 | ONO2 OPLA | 725 | w m | N2 | IR | Wilson and Christe, 1987 | |
Additional references: Jacox, 1994, page 289; Jacox, 1998, page 303; Casper, Lambotte, et al., 1993
Notes
w | Weak |
m | Medium |
s | Strong |
vs | Very strong |
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dianxum and Peng, 1996
Dianxum, W.; Peng, J.,
He I photoelectron spectroscopy study on the electronic structure of bromine nitrate, BrONO2,
J. Phys. Chem., 1996, 100, 4382. [all data]
Jochims, Denzer, et al., 1992
Jochims, H.-W.; Denzer, W.; Baumgartel, H.; Losking, O.; Willner, H.,
Photochemical decay reactions of N2O5, HNO3, ClNO3 and BrNO3 in the energy range 10-20 eV,
Ber. Bunsen-Ges. Phys. Chem., 1992, 96, 573. [all data]
Wilson and Christe, 1987
Wilson, W.W.; Christe, K.O.,
Bromine nitrates,
Inorg. Chem., 1987, 26, 10, 1573, https://doi.org/10.1021/ic00257a022
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Casper, Lambotte, et al., 1993
Casper, B.; Lambotte, P.; Minkwitz, R.; Oberhammer, H.,
Gas-phase structures of chlorine and bromine nitrate (ClONO2 and BrONO2),
J. Phys. Chem., 1993, 97, 39, 9992, https://doi.org/10.1021/j100141a017
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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