Ethenamine, N-methylene-
- Formula: C3H5N
- Molecular weight: 55.0785
- IUPAC Standard InChI: InChI=1S/C3H5N/c1-3-4-2/h3H,1-2H2
- IUPAC Standard InChIKey: TUVFMMNANXKTRP-UHFFFAOYSA-N
- CAS Registry Number: 38239-27-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: N-Methyleneethenamine
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Mass spectrum (electron ionization)
Go To: Top, Vibrational and/or electronic energy levels, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY |
| NIST MS number | 60636 |
Vibrational and/or electronic energy levels
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a' | 2 | CH2 a-stretch | 3035 | gas | IR | Amatatsu, Hamada, et al., 1987 | |
| 4 | CH stretch | 2871 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 5 | CH2 s-stretch | 2832 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 6 | C=N stretch | 1635 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 7 | C=C stretch | 1618 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 8 | CH2 scissors | 1452 | w T | gas | IR | Amatatsu, Hamada, et al., 1987 | |
| 9 | CH2 scissors | 1382 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 10 | CH bend | 1298 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 11 | CH2 rock | 1233 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 14 | CNC bend | 523 | w T | gas | IR | Amatatsu, Hamada, et al., 1987 | |
| a | 16 | CH2 OPLA | 1015 | gas | IR | Amatatsu, Hamada, et al., 1987 | |
| 17 | CH OPLA | 965 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 18 | CH2 OPLA | 913 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
| 20 | C=C torsion | 585 | gas | IR | Amatatsu, Hamada, et al., 1987 | ||
Additional references: Jacox, 1994, page 409
Notes
| w | Weak |
| T | Tentative assignment or approximate value |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | CP-Sil 8CB-MS | 727. | Elmore, Mottram, et al., 2000 | 60. m/0.25 mm/0.25 μm, He; Program: 0C(5min) => 40C/min => 40C (2min) => 4C/min => 280C |
References
Go To: Top, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Amatatsu, Hamada, et al., 1987
Amatatsu, Y.; Hamada, Y.; Tsuboi, M.,
FTIR detection of unstable molecules: Infrared spectrum of 2-azabutadiene,
J. Mol. Spectrosc., 1987, 123, 2, 276, https://doi.org/10.1016/0022-2852(87)90278-5
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Elmore, Mottram, et al., 2000
Elmore, J.S.; Mottram, D.S.; Enser, M.; Wood, J.D.,
The effects of diet and breed on the volatile compounds of cooked lamb,
Meat Sci., 2000, 55, 2, 149-159, https://doi.org/10.1016/S0309-1740(99)00137-0
. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, References
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