Chlorine nitrate

• Formula: ClNO₃
• Molecular weight: 97.458
• IUPAC Standard InChI: InChI=1S/ClNO3/c1-5-2(3)4 Copy

  
• IUPAC Standard InChIKey: XYLGPCWDPLOBGP-UHFFFAOYSA-N Copy
• CAS Registry Number: 14545-72-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Information on this page:
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Ion clustering data
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  = ClN₂O₆^-

By formula: NO₃^- + ClNO₃ = ClN₂O₆^-

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

Appearance energy determinations

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?

State:   X

Additional references: Jacox, 1994, page 288; Jacox, 1998, page 302; Jacox, 2003, page 301; Illies and Takacs, 1976; Suenram and Johnson, 1977; Suenram and Lovas, 1984; Davidson, Cantrell, et al., 1987; Casper, Lambotte, et al., 1993; Muller, Helminger, et al., 1997

Notes

References

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schack, 1967
Schack, C.J., New Synthesis of Chlorine Nitrate, Inorg. Chem., 1967, 6, 1938-9. [all data]

Wincel, Mereand, et al., 1997
Wincel, H.; Mereand, E.; Castleman, A.W., Gas-phase reactions of ClONO2 with Cl-(D2O)(n=0-3) and NO2-, J. Phys. Chem. A, 1997, 101, 44, 8248-8254, https://doi.org/10.1021/jp9701146 . [all data]

Wang, Li, et al., 1996
Wang, D.; Li, Y.; Jiang, P.; Wang, X.; Chen, B., The study of HeI photoelectron spectroscopy (PES) of the electronic structure for ClONO₂, Chem. Phys. Lett., 1996, 260, 99. [all data]

Jochims, Denzer, et al., 1992
Jochims, H.-W.; Denzer, W.; Baumgartel, H.; Losking, O.; Willner, H., Photochemical decay reactions of N₂O₅, HNO₃, ClNO₃ and BrNO₃ in the energy range 10-20 eV, Ber. Bunsen-Ges. Phys. Chem., 1992, 96, 573. [all data]

Shamir, Yellin, et al., 1974
Shamir, J.; Yellin, D.; Claassen, H.H., Isr. J. Chem., 1974, 12, 1015. [all data]

Miller, Bernitt, et al., 1967
Miller, R.H.; Bernitt, D.L.; Hisatsune, I.C., Spectrochim. Acta, 1967, 23A, 223. [all data]

Graham, Tuazon, et al., 1977
Graham, R.A.; Tuazon, E.C.; Winer, A.M.; Pitts, J.N., Jr.; Molina, L.T.; Beaman, L.; Molina, M.J., High resolution infrared absorptivities for gaseous chlorine nitrate, Geophys. Res. Lett., 1977, 4, 1, 3, https://doi.org/10.1029/GL004i001p00003 . [all data]

Ballard, Johnston, et al., 1988
Ballard, J.; Johnston, W.B.; Gunson, M.R.; Wassell, P.T., Absolute absorption coefficients of ClONO, J. Geophys. Res., 1988, 93(D), D2, 1659, https://doi.org/10.1029/JD093iD02p01659 . [all data]

Orphal, Morillon-Chapey, et al., 1997
Orphal, J.; Morillon-Chapey, M.; Diallo, A.; Guelachvili, G., High-Resolution Infrared Spectra and Harmonic Force Field of Chlorine Nitrate, J. Phys. Chem. A, 1997, 101, 6, 10062, https://doi.org/10.1021/jp9619595 . [all data]

Bhatia, George-Taylor, et al., 1983
Bhatia, S.C.; George-Taylor, M.; Merideth, C.W.; Hall, J.H., Jr., Low-temperature infrared spectrum of chlorine nitrate and evidence for the existence of chlorine nitrate (ClOONO), J. Phys. Chem., 1983, 87, 7, 1091, https://doi.org/10.1021/j100230a001 . [all data]

Griffith, Tyndall, et al., 1984
Griffith, D.W.T.; Tyndall, G.S.; Burrows, J.P.; Moortgat, G.K., Matrix-isolation spectra of chlorine nitrate, Chem. Phys. Lett., 1984, 107, 3, 341, https://doi.org/10.1016/0009-2614(84)85141-6 . [all data]

De Saxce and Schriver, 1992
De Saxce, A.; Schriver, L., An infrared study of the UV photolysis of chlorine nitrate trapped in various matrices at 11 K, Chem. Phys. Lett., 1992, 199, 6, 596, https://doi.org/10.1016/0009-2614(92)85016-4 . [all data]

Tevault and Smardzewski, 1978
Tevault, D.E.; Smardzewski, R.R., Synthesis of chlorine nitrate by photolysis of nitrosyl chloride in solid oxygen at 10 K, J. Phys. Chem., 1978, 82, 4, 375, https://doi.org/10.1021/j100493a001 . [all data]

Orphal, Morillon-Chapey, et al., 1994
Orphal, J.; Morillon-Chapey, M.; Guelachvili, G., High-resolution absorption cross sections of chlorine nitrate in the ν, J. Geophys. Res., 1994, 99(D), D7, 14549, https://doi.org/10.1029/94JD00671 . [all data]

Domenech, Flaud, et al., 1997
Domenech, J.L.; Flaud, J.-M.; Fraser, G.T.; Andrews, A.M.; Lafferty, W.J.; Watson, P.L., Infrared Diode-Laser Molecular-Beam Spectrum of the ν2Band of Chlorine Nitrate at 1293 cm-1, J. Mol. Spectrosc., 1997, 183, 2, 228, https://doi.org/10.1006/jmsp.1997.7260 . [all data]

Chiang and Lee, 1991
Chiang, S.-Y.; Lee, Y.-P., Vibronic analysis of the A 2A1--X 2E laser-induced fluorescence of jet-cooled CH3S, J. Chem. Phys., 1991, 95, 1, 66, https://doi.org/10.1063/1.461786 . [all data]

Bell, Duxbury, et al., 1992
Bell, W.; Duxbury, G.; Stuart, D.D., High-resolution spectra of the ν4 band of chlorine nitrate, J. Mol. Spectrosc., 1992, 152, 2, 285, https://doi.org/10.1016/0022-2852(92)90069-Z . [all data]

Xu, Blake, et al., 1996
Xu, S.; Blake, T.A.; Sharpe, S.W., High-Resolution Infrared Spectroscopy of the ν4Fundamental Band of Chlorine Nitrate, J. Mol. Spectrosc., 1996, 175, 2, 303, https://doi.org/10.1006/jmsp.1996.0036 . [all data]

McPheat and Duxbury, 1996
McPheat, R.; Duxbury, G., Absorption coefficients of ClONO, J. Geophys. Res., 1996, 101(D), D3, 6803, https://doi.org/10.1029/95JD02927 . [all data]

Flaud, Lafferty, et al., 2003
Flaud, J.-M.; Lafferty, W.J.; Orphal, J.; Birk, M.; Wagner, G., First high-resolution analyses of the ν, Mol. Phys., 2003, 101, 10, 1527, https://doi.org/10.1080/0026897031000108087 . [all data]

Fleming, 1977
Fleming, J.W., Far infrared rotational and torsional absorption spectra of chlorine nitrate, Chem. Phys. Lett., 1977, 50, 1, 107, https://doi.org/10.1016/0009-2614(77)80690-8 . [all data]

Chance and Traub, 1982
Chance, K.V.; Traub, W.A., The torsional spectrum of chlorine nitrate, J. Mol. Spectrosc., 1982, 95, 2, 306, https://doi.org/10.1016/0022-2852(82)90131-X . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Illies and Takacs, 1976
Illies, A.J.; Takacs, G.A., Gas phase ultra-violet photoabsorption cross-sections for nitrosyl chloride and nitryl chloride, J. Photochem., 1976, 6, 1, 35, https://doi.org/10.1016/0047-2670(76)87005-0 . [all data]

Suenram and Johnson, 1977
Suenram, R.D.; Johnson, D.R., Microwave spectrum of chlorine nitrate (ClNO3), J. Mol. Spectrosc., 1977, 65, 2, 239, https://doi.org/10.1016/0022-2852(77)90191-6 . [all data]

Suenram and Lovas, 1984
Suenram, R.D.; Lovas, F.J., Millimeter wave spectrum of chlorine nitrate, J. Mol. Spectrosc., 1984, 105, 2, 351, https://doi.org/10.1016/0022-2852(84)90225-X . [all data]

Davidson, Cantrell, et al., 1987
Davidson, J.A.; Cantrell, C.A.; Shetter, R.E.; McDaniel, A.H.; Calvert, J.G., Absolute infrared absorption cross sections for ClONO, J. Geophys. Res., 1987, 92(D), D9, 10921, https://doi.org/10.1029/JD092iD09p10921 . [all data]

Casper, Lambotte, et al., 1993
Casper, B.; Lambotte, P.; Minkwitz, R.; Oberhammer, H., Gas-phase structures of chlorine and bromine nitrate (ClONO2 and BrONO2), J. Phys. Chem., 1993, 97, 39, 9992, https://doi.org/10.1021/j100141a017 . [all data]

Muller, Helminger, et al., 1997
Muller, H.S.P.; Helminger, P.; Young, S.H., Millimeter and Submillimeter Spectroscopy of Chlorine Nitrate: The Cl Quadrupole Tensor and the Harmonic Force Field, J. Mol. Spectrosc., 1997, 181, 2, 363, https://doi.org/10.1006/jmsp.1996.7183 . [all data]

Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  AE	Appearance energy
  Tboil	Boiling point
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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