Ethenamine, N-methyl-


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

View reactions leading to C3H7N+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.00PEFang, Sim, et al., 1995Vertical value

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NH stretch 3485 gas IR Amatatsu, Hamada, et al., 1985
2 CH2 a-stretch 3120 gas IR Amatatsu, Hamada, et al., 1985
3 CH2 s-stretch 3037 gas IR Amatatsu, Hamada, et al., 1985
4 CH stretch 2990 gas IR Amatatsu, Hamada, et al., 1985
5 CH3 stretch 2928 T gas IR Amatatsu, Hamada, et al., 1985
6 CH3 s-stretch 2868 T gas IR Amatatsu, Hamada, et al., 1985
7 C=C stretch 1655 s gas IR Amatatsu, Hamada, et al., 1985
8 CH3 deform. 1495 gas IR Amatatsu, Hamada, et al., 1985
9 NH bend 1465 gas IR Amatatsu, Hamada, et al., 1985
10 CH2 scissors 1430 T gas IR Amatatsu, Hamada, et al., 1985
11 CH3 s-deform. 1405 gas IR Amatatsu, Hamada, et al., 1985
12 CCH bend 1315 gas IR Amatatsu, Hamada, et al., 1985
13 CNC a-stretch 1230 gas IR Amatatsu, Hamada, et al., 1985
13 CNC a-stretch 1223 gas IR Amatatsu, Hamada, et al., 1985
14 CH3 rock 1150 gas IR Amatatsu, Hamada, et al., 1985
15 CH2 rock 1029 gas IR Amatatsu, Hamada, et al., 1985
16 CNC s-stretch 920 gas IR Amatatsu, Hamada, et al., 1985
17 CNC bend 527 gas IR Amatatsu, Hamada, et al., 1985
a 19 CH3 stretch 2822 T gas IR Amatatsu, Hamada, et al., 1985
20 CH3 deform. 1445 T gas IR Amatatsu, Hamada, et al., 1985
21 CH3 rock 1063 T gas IR Amatatsu, Hamada, et al., 1985
22 CH OPLA 966 gas IR Amatatsu, Hamada, et al., 1985
23 CH2 OPLA 795 s gas IR Amatatsu, Hamada, et al., 1985
23 CH2 OPLA 788 s gas IR Amatatsu, Hamada, et al., 1985
24 C=C torsion 661 gas IR Amatatsu, Hamada, et al., 1985
25 NH wag 408 gas IR Amatatsu, Hamada, et al., 1985

Additional references: Jacox, 1994, page 409

Notes

sStrong
TTentative assignment or approximate value

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fang, Sim, et al., 1995
Fang, J.; Sim, C.W.; Mok, C.Y.; Huang, H.H.; Novak, I., n,π=Conjugation in N-methylvinylamine. A photoelectron spectroscopic study, J. Chem. Soc. Perkin Trans. 2, 1995, 1995, 1625. [all data]

Amatatsu, Hamada, et al., 1985
Amatatsu, Y.; Hamada, Y.; Tsuboi, M.; Sugie, M., Pyrolysis of amines: Infrared spectrum of N-methylvinylamine, J. Mol. Spectrosc., 1985, 111, 1, 29, https://doi.org/10.1016/0022-2852(85)90065-7 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References