vinylamine

• Formula: C₂H₅N
• Molecular weight: 43.0678
• IUPAC Standard InChI: InChI=1S/C2H5N/c1-2-3/h2H,1,3H2 Copy

  
• IUPAC Standard InChIKey: UYMKPFRHYYNDTL-UHFFFAOYSA-N Copy
• CAS Registry Number: 593-67-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Ethenamine
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Options:
  • Switch to calorie-based units

Gas phase ion energetics data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

View reactions leading to C₂H₅N⁺ (ion structure unspecified)

Ionization energy determinations

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 375; Jacox, 1998, page 336; Jacox, 2003, page 352; Lovas, Clark, et al., 1975; Brown, Godfrey, et al., 1987; McNaughton and Robertson, 1994

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Takhistov and Ponomarev, 1994
Takhistov, V.V.; Ponomarev, D.A., Isodesmic reactions and thermochemistry of ions, Org. Mass Spectrom., 1994, 29, 395. [all data]

Albercht, Allan, et al., 1984
Albercht, B.; Allan, M.; Haselbach, E.; Neuhaus, L.; Carrupt, P.-A., 27. Molecular ions of transient species: Vinylamine-cation, Helv. Chim. Acta, 1984, 67, 220. [all data]

Gonbeau, Lacombe, et al., 1988
Gonbeau, D.; Lacombe, S.; Lasnes, M.; Ripoll, J.; Pfister-Guillouzo, G., Ethenylphosphine. Synthesis by flash-vacuum thermolysis and characterization by photoelectron spectroscopy, J. Am. Chem. Soc., 1988, 110, 2730. [all data]

Hamada, Hashiguchi, et al., 1984
Hamada, Y.; Hashiguchi, K.; Tsuboi, M.; Koga, Y.; Kondo, S., Pyrolysis of amines: Infrared spectrum of vinylamine, J. Mol. Spectrosc., 1984, 105, 1, 93, https://doi.org/10.1016/0022-2852(84)90106-1 . [all data]

Hamada, Sato, et al., 1987
Hamada, Y.; Sato, N.; Tsuboi, M., Amino wagging and torsion vibrations of vinylamine, J. Mol. Spectrosc., 1987, 124, 1, 172, https://doi.org/10.1016/0022-2852(87)90130-5 . [all data]

Brown, Godfrey, et al., 1990
Brown, R.D.; Godfrey, P.D.; Kleibomer, B.; Pierlot, A.P.; McNaughton, D., Submillimeter-wave spectrum, far-infrared spectrum, and inversion potential of vinylamine, J. Mol. Spectrosc., 1990, 142, 2, 195, https://doi.org/10.1016/0022-2852(90)90177-R . [all data]

McNaughton and Evans, 1999
McNaughton, D.; Evans, C.J., The High-Resolution FTIR Far-Infrared Spectrum of Vinylamine, J. Mol. Spectrosc., 1999, 196, 2, 274, https://doi.org/10.1006/jmsp.1999.7861 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Lovas, Clark, et al., 1975
Lovas, F.J.; Clark, F.O.; Tiemann, E., Pyrolysis of ethylamine. I. Microwave spectrum and molecular constants of vinylamine, J. Chem. Phys., 1975, 62, 5, 1925, https://doi.org/10.1063/1.430679 . [all data]

Brown, Godfrey, et al., 1987
Brown, R.D.; Godfrey, P.D.; Kleibomer, B., The inversion-torsion motion in vinylamine, J. Mol. Spectrosc., 1987, 124, 1, 21, https://doi.org/10.1016/0022-2852(87)90117-2 . [all data]

McNaughton and Robertson, 1994
McNaughton, D.; Robertson, E.G., The Far-Infrared Inversion Transition of Vinylamine, J. Mol. Spectrosc., 1994, 163, 1, 80, https://doi.org/10.1006/jmsp.1994.1009 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.