Magnesium monohydroxide
- Formula: HMgO
- Molecular weight: 41.3123
- IUPAC Standard InChI: InChI=1S/Mg.H2O/h;1H2/q+1;/p-1
- IUPAC Standard InChIKey: UNYOJUYSNFGNDV-UHFFFAOYSA-M
- CAS Registry Number: 12141-11-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
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Gas phase thermochemistry data
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -39.379 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1975 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 54.120 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1975 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. to 6000. |
|---|---|
| A | 11.44060 |
| B | 2.022441 |
| C | -0.440268 |
| D | 0.034037 |
| E | -0.153830 |
| F | -43.39130 |
| G | 66.51621 |
| H | -39.37739 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in December, 1975 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.5 ± 0.3 | EI | Murad, 1981 | LLK |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Π | 2 | Bend | 188 ± 2 | H | gas | LF | Bunker, Kolbuszewski, et al., 1995 |
| Σ+ | 3 | MgO stretch | 750 ± 3 | gas | LF | Bunker, Kolbuszewski, et al., 1995 | |
Additional references: Jacox, 1998, page 138; Jacox, 2003, page 23; Barclay, Anderson, et al., 1992; Nuccio, Apponi, et al., 1995; Apponi, Anderson, et al., 1999
Notes
| H | (1/2)(2ν) |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Murad, 1981
Murad, E.,
Thermochemical properties of the gaseous alkaline earth monohydroxides,
J. Chem. Phys., 1981, 75, 4080. [all data]
Bunker, Kolbuszewski, et al., 1995
Bunker, P.R.; Kolbuszewski, M.; Jensen, P.; Brumm, M.; Anderson, M.A.; Barclay, W.L., Jr.; Ziurys, L.M.; Ni, Y.; Harris, D.O.,
New rovibrational data for MgOH and MgOD and the internuclear potential function of the ground electronic state,
Chem. Phys. Lett., 1995, 239, 4-6, 217, https://doi.org/10.1016/0009-2614(95)00479-N
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Barclay, Anderson, et al., 1992
Barclay, W.L., Jr.; Anderson, M.A.; Ziurys, L.M.,
The millimeter-wave spectrum of the MgOH radical (X 2Σ+),
Chem. Phys. Lett., 1992, 196, 3-4, 225, https://doi.org/10.1016/0009-2614(92)85959-E
. [all data]
Nuccio, Apponi, et al., 1995
Nuccio, B.P.; Apponi, A.J.; Ziurys, L.M.,
Millimeter-wave rotational spectroscopy of MgOD and CaOD (X 2Σ+),
J. Chem. Phys., 1995, 103, 21, 9193, https://doi.org/10.1063/1.470030
. [all data]
Apponi, Anderson, et al., 1999
Apponi, A.J.; Anderson, M.A.; Ziurys, L.M.,
High resolution spectroscopy of MgOH (X [sup 2]Σ[sup +]) in its V[sub 2] mode: Further evidence for quasilinearity,
J. Chem. Phys., 1999, 111, 24, 10919, https://doi.org/10.1063/1.480455
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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