dithallium oxide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.02 ± 0.10EIBagarat'yan, Il'in, et al., 1973LLK
7.5 ± 0.3EICubicciotti, 1969RDSH
8.8 ± 0.5EIShchukarev, Semenov, et al., 1962RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Tl+12. ± 1.?EICubicciotti, 1969RDSH
Tl2+11.97 ± 0.09?EIBagarat'yan, Il'in, et al., 1973LLK
Tl2+9.7 ± 0.5OEIShchukarev, Semenov, et al., 1962RDSH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

3 Asym. stretch 643.6 Ar IR Brom, Devore, et al., 1971
Andrews, Kushto, et al., 1997
3 Asym. stretch 634.6 Kr IR Brom, Devore, et al., 1971
3 Asym. stretch 625.3 N2 IR Hinchcliffe and Ogden, 1969
Brom, Devore, et al., 1971
Makowiecki, Lynch, et al., 1971

Additional references: Jacox, 1994, page 65; Jacox, 2003, page 81


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bagarat'yan, Il'in, et al., 1973
Bagarat'yan, N.V.; Il'in, M.K.; Nikitin, O.T., Mass-spectrometric study of thallium metaborate, High Temp., 1973, 11, 888, In original 995. [all data]

Cubicciotti, 1969
Cubicciotti, D., Some thermodynamic properties of the thallium oxides, High Temp. Sci., 1969, 1, 11. [all data]

Shchukarev, Semenov, et al., 1962
Shchukarev, S.A.; Semenov, G.A.; Rat'kovskii, I.A., Study of the evaporation of gallium, indium, and thallium with the aid of the mass spectrometer, Zh. Prikl. Khim., 1962, 35, 1454, In original 1401. [all data]

Brom, Devore, et al., 1971
Brom, J.M., Jr.; Devore, T.; Franzen, H.F., Infrared Spectrum and Structure of Matrix Isolated Thallous Oxide, J. Chem. Phys., 1971, 54, 6, 2742, https://doi.org/10.1063/1.1675239 . [all data]

Andrews, Kushto, et al., 1997
Andrews, L.; Kushto, G.P.; Yustein, J.T.; Archibong, E.; Sullivan, R.; Leszczynski, J., Reactions of Pulsed-Laser-Evaporated Thallium Atoms with O, J. Phys. Chem. A, 1997, 101, 48, 9077, https://doi.org/10.1021/jp9723325 . [all data]

Hinchcliffe and Ogden, 1969
Hinchcliffe, A.J.; Ogden, J.S., Chem. Commun., 1969, 1053. [all data]

Makowiecki, Lynch, et al., 1971
Makowiecki, D.M.; Lynch, D.A.; Carlson, K.D., Infrared spectra of the aluminum family suboxides, J. Phys. Chem., 1971, 75, 1963. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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