dithallium oxide
- Formula: OTl2
- Molecular weight: 424.7660
- CAS Registry Number: 1314-12-1
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Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.02 ± 0.10 | EI | Bagarat'yan, Il'in, et al., 1973 | LLK |
7.5 ± 0.3 | EI | Cubicciotti, 1969 | RDSH |
8.8 ± 0.5 | EI | Shchukarev, Semenov, et al., 1962 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
Tl+ | 12. ± 1. | ? | EI | Cubicciotti, 1969 | RDSH |
Tl2+ | 11.97 ± 0.09 | ? | EI | Bagarat'yan, Il'in, et al., 1973 | LLK |
Tl2+ | 9.7 ± 0.5 | O | EI | Shchukarev, Semenov, et al., 1962 | RDSH |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
3 | Asym. stretch | 643.6 | Ar | IR | Brom, Devore, et al., 1971 Andrews, Kushto, et al., 1997 | ||
3 | Asym. stretch | 634.6 | Kr | IR | Brom, Devore, et al., 1971 | ||
3 | Asym. stretch | 625.3 | N2 | IR | Hinchcliffe and Ogden, 1969 Brom, Devore, et al., 1971 Makowiecki, Lynch, et al., 1971 | ||
Additional references: Jacox, 1994, page 65; Jacox, 2003, page 81
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bagarat'yan, Il'in, et al., 1973
Bagarat'yan, N.V.; Il'in, M.K.; Nikitin, O.T.,
Mass-spectrometric study of thallium metaborate,
High Temp., 1973, 11, 888, In original 995. [all data]
Cubicciotti, 1969
Cubicciotti, D.,
Some thermodynamic properties of the thallium oxides,
High Temp. Sci., 1969, 1, 11. [all data]
Shchukarev, Semenov, et al., 1962
Shchukarev, S.A.; Semenov, G.A.; Rat'kovskii, I.A.,
Study of the evaporation of gallium, indium, and thallium with the aid of the mass spectrometer,
Zh. Prikl. Khim., 1962, 35, 1454, In original 1401. [all data]
Brom, Devore, et al., 1971
Brom, J.M., Jr.; Devore, T.; Franzen, H.F.,
Infrared Spectrum and Structure of Matrix Isolated Thallous Oxide,
J. Chem. Phys., 1971, 54, 6, 2742, https://doi.org/10.1063/1.1675239
. [all data]
Andrews, Kushto, et al., 1997
Andrews, L.; Kushto, G.P.; Yustein, J.T.; Archibong, E.; Sullivan, R.; Leszczynski, J.,
Reactions of Pulsed-Laser-Evaporated Thallium Atoms with O,
J. Phys. Chem. A, 1997, 101, 48, 9077, https://doi.org/10.1021/jp9723325
. [all data]
Hinchcliffe and Ogden, 1969
Hinchcliffe, A.J.; Ogden, J.S.,
Chem. Commun., 1969, 1053. [all data]
Makowiecki, Lynch, et al., 1971
Makowiecki, D.M.; Lynch, D.A.; Carlson, K.D.,
Infrared spectra of the aluminum family suboxides,
J. Phys. Chem., 1971, 75, 1963. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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