Phosphine, (fluoromethylidyne)-

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference
10.57 ± 0.01PEKroto, Nixon, et al., 1978

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 CP stretch 1670.84 gas IR Ohno, Matsuura, et al., 1983
2 Bend 375.43 gas IR Ohno, Matsuura, et al., 1983
3 CF stretch 780.1 ± 0.2 gas IR Ohno, Matsuura, et al., 1983

Additional references: Jacox, 1998, page 190; Kroto, Nixon, et al., 1980; Bizzocchi, Degli Esposti, et al., 2006

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kroto, Nixon, et al., 1978
Kroto, H.W.; Nixon, J.F.; Simmons, N.P.C.; Westwood, N.P.C., FC≡P, C-fluorophosphaethyne: Preparation and detection by photoelectron and microwave spectroscopy, J. Am. Chem. Soc., 1978, 100, 446. [all data]

Ohno, Matsuura, et al., 1983
Ohno, K.; Matsuura, H.; Murata, H.; Kroto, H.W., The vibration-rotation spectrum of C-fluorophosphaethyne FC«58876»P: Fermi resonance and harmonic force field, J. Mol. Spectrosc., 1983, 100, 2, 403, https://doi.org/10.1016/0022-2852(83)90097-8 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Kroto, Nixon, et al., 1980
Kroto, H.W.; Nixon, J.F.; Simmons, N.P.C., The microwave spectrum of C-fluorophosphaethyne FC«58876»P: Structure determination, dipole moment, and vibration-rotation data, J. Mol. Spectrosc., 1980, 82, 1, 185, https://doi.org/10.1016/0022-2852(80)90108-3 . [all data]

Bizzocchi, Degli Esposti, et al., 2006
Bizzocchi, L.; Degli Esposti, C.; Puzzarini, C., Millimetre-wave spectroscopy and, Mol. phys., 2006, 104, 16-17, 2627, https://doi.org/10.1080/00268970600688437 . [all data]

Notes

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