Boron monofluoride monosulfide

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
10.91PESuffolk, Cooper, et al., 1988LL
10.90 ± 0.01PECooper, Kroto, et al., 1984LBLHLM

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 1 B=S stretch 1644.38 gas IR McNaughton and Tay-Lim, 2001
Π 2 Bend 370 ± 50 gas MW Cooper, Firth, et al., 1991
Bizzocchi and Degli Esposti, 2001

Additional references: Jacox, 1994, page 85; Jacox, 2003, page 130

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Suffolk, Cooper, et al., 1988
Suffolk, R.J.; Cooper, T.A.; Pantelides, E.; Watts, J.D.; Kroto, H.W., Photoelectron spectra of sulphidoborons XBS where X = H, F, Cl, or Br, J. Chem. Soc. Dalton Trans., 1988, 2041. [all data]

Cooper, Kroto, et al., 1984
Cooper, T.A.; Kroto, H.W.; Kirby, C.; Westwood, N.P.C., A photoelectron spectroscopic study of the (FBS)n system (n = 1-3), J. Chem. Soc. Dalton Trans., 1984, 1047. [all data]

McNaughton and Tay-Lim, 2001
McNaughton, D.; Tay-Lim, R., The High-Resolution FTIR Spectrum of Fluoro(sulfido)boron, F«58872»B«58875»S, J. Mol. Spectrosc., 2001, 209, 2, 280, https://doi.org/10.1006/jmsp.2001.8428 . [all data]

Cooper, Firth, et al., 1991
Cooper, T.A.; Firth, S.; Kroto, H.W., J. Chem. Soc., 1991, Faraday Trans. 87, 1499. [all data]

Bizzocchi and Degli Esposti, 2001
Bizzocchi, L.; Degli Esposti, C., Pyrolysis of sulfur tetrafluoride over boron: Excited-state rotational spectra and equilibrium structure of fluorothioborine (FBS), J. Chem. Phys., 2001, 115, 15, 7041, https://doi.org/10.1063/1.1402990 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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