Phosphenic chloride
- Formula: ClO2P
- Molecular weight: 98.426
- IUPAC Standard InChI: InChI=1S/ClO2P/c1-4(2)3
- IUPAC Standard InChIKey: OSUKSSHOHKZSJC-UHFFFAOYSA-N
- CAS Registry Number: 12591-02-5
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias and Joel F. Liebman
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.9 | PE | Bock, Kremer, et al., 1992 | Vertical value |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a1 | 1 | PO2 s-stretch | 1122 | Ar | IR | Ahlrichs, Ehrhard, et al., 1986 | |
| 2 | PCl stretch | 586 | Ar | IR | Ahlrichs, Ehrhard, et al., 1986 | ||
| b2 | 5 | PO2 a-stretch | 1429 | Ar | IR | Ahlrichs, Ehrhard, et al., 1986 | |
Additional references: Jacox, 1994, page 213; Jacox, 2003, page 240; Brupbacher-Gatehouse, 2000
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bock, Kremer, et al., 1992
Bock, H.; Kremer, M.; Solouki, B.; Binnewies, M.; Meisel, M.,
Gas phase reactions. FPS2 and FPS,
J. Chem. Soc., Chem. Commun., 1992, 1992, 9. [all data]
Ahlrichs, Ehrhard, et al., 1986
Ahlrichs, R.; Ehrhard, C.; Lakenbrink, M.; Schunck, S.; Schnockel, H.,
Molecular PO2Cl: matrix IR investigations and ab initio SCF calculations,
J. Am. Chem. Soc., 1986, 108, 13, 3596, https://doi.org/10.1021/ja00273a008
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Brupbacher-Gatehouse, 2000
Brupbacher-Gatehouse, B.,
Fourier Transform Microwave Spectroscopic Study of Gas-Phase ClPO,
J. Am. Chem. Soc., 2000, 122, 17, 4171, https://doi.org/10.1021/ja9938534
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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