Strontium monohydroxide

• Formula: HOSr
• Molecular weight: 104.63
• IUPAC Standard InChI: InChI=1S/H2O.Sr/h1H2;/q;+1/p-1 Copy

  
• IUPAC Standard InChIKey: HGDJQLJUGUXYKQ-UHFFFAOYSA-M Copy
• CAS Registry Number: 12141-14-9
• Chemical structure:
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• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
• Data at other public NIST sites:
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Gas phase ion energetics data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F

State:   E

State:   D

State:   C

State:   B'

State:   B

State:   A

State:   X

Additional references: Jacox, 1994, page 29; Jacox, 1998, page 140; Jacox, 2003, page 23; James and Sugden, 1955; Anderson, Barclay, et al., 1992; Fletcher, Jung, et al., 1993; Zhao, Hajigeorgiou, et al., 1996; Yu, Wang, et al., 2006

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Murad, 1983
Murad, E., Abstraction reactions of Ca⁺ and Sr⁺ ions, J. Chem. Phys., 1983, 78, 6611. [all data]

Murad, 1981
Murad, E., Thermochemical properties of the gaseous alkaline earth monohydroxides, J. Chem. Phys., 1981, 75, 4080. [all data]

Kelly and Padley, 1970
Kelly, R.; Padley, P.J., Ionization potentials of alkaline-earth monohydroxides, Chem. Commun., 1970, 1606. [all data]

Beardah and Ellis, 1999
Beardah, M.S.; Ellis, A.M., Observation of several new electronic transitions of the SrOH free radical, J. Chem. Phys., 1999, 110, 23, 11244, https://doi.org/10.1063/1.479065 . [all data]

Wang, Dick, et al., 2007
Wang, J.-G.; Dick, M.J.; Sheridan, P.M.; Yu, S.; Bernath, P.F., Further spectroscopic investigations of the high energy electronic states of SrOH: The and the transitions, J. Mol. Spectrosc., 2007, 245, 1, 26, https://doi.org/10.1016/j.jms.2007.06.005 . [all data]

Wang, Sheridan, et al., 2006
Wang, J.-G.; Sheridan, P.M.; Dick, M.J.; Bernath, P.F., Optical--optical double-resonance spectroscopy of SrOH: The transition, J. Mol. Spectrosc., 2006, 236, 1, 21, https://doi.org/10.1016/j.jms.2005.12.002 . [all data]

Beardah and Ellis, 2003
Beardah, M.S.; Ellis, A.M., Observation of a new transition of the SrOH free radical, J. Mol. Spectrosc., 2003, 218, 1, 80, https://doi.org/10.1016/S0022-2852(02)00040-1 . [all data]

Wormsbecher, Trkula, et al., 1983
Wormsbecher, R.F.; Trkula, M.; Martner, C.; Penn, R.E.; Harris, D.O., Chemiluminescent reactions of alkaline-earth metals with water and hydrazine, J. Mol. Spectrosc., 1983, 97, 1, 29, https://doi.org/10.1016/0022-2852(83)90335-1 . [all data]

Nakagawa, Wormsbecher, et al., 1983
Nakagawa, J.; Wormsbecher, R.F.; Harris, D.O., High-resolution laser excitation spectra of linear triatomic molecules: Analysis of the B2Σ+-X2Σ+ system of SrOH and SrOD, J. Mol. Spectrosc., 1983, 97, 1, 37, https://doi.org/10.1016/0022-2852(83)90336-3 . [all data]

Steimle, Fletcher, et al., 1992
Steimle, T.C.; Fletcher, D.A.; Jung, K.Y.; Scurlock, C.T., A supersonic molecular beam optical Stark study of CaOH and SrOH, J. Chem. Phys., 1992, 96, 4, 2556, https://doi.org/10.1063/1.462007 . [all data]

Presunka and Coxon, 1993
Presunka, P.I.; Coxon, J.A., High-resolution laser spectroscopy of excited bending vibrations (υ, Can. J. Chem., 1993, 71, 10, 1689, https://doi.org/10.1139/v93-211 . [all data]

Douglas, Hauge, et al., 1984
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., Electronic Matrix Isolation Spectroscopic Studies of the Group IIA Metal---Water Photochemistry, High Temp. Sci., 1984, 17, 201. [all data]

Oberlander and Parson, 1996
Oberlander, M.D.; Parson, J.M., Laser excited fluorescence study of reactions of excited Ca and Sr with water and alcohols: Product selectivity and energy disposal, J. Chem. Phys., 1996, 105, 14, 5806, https://doi.org/10.1063/1.472457 . [all data]

Brazier and Bernath, 1985
Brazier, C.R.; Bernath, P.F., Laser and fourier transform spectroscopy of the transition of SrOH, J. Mol. Spectrosc., 1985, 114, 1, 163, https://doi.org/10.1016/0022-2852(85)90345-5 . [all data]

Presunka and Coxon, 1994
Presunka, P.I.; Coxon, J.A., Laser spectroscopy of the A 2Π--X 2Σ+ transition of SrOH: Deperturbation analysis of K-resonance in the v2=1 level of the A 2Π state, J. Chem. Phys., 1994, 101, 1, 201, https://doi.org/10.1063/1.468171 . [all data]

Presunka and Coxon, 1995
Presunka, P.I.; Coxon, J.A., Laser excitation and dispersed fluorescence investigations of the system of SrOH, Chem. Phys., 1995, 190, 1, 97, https://doi.org/10.1016/0301-0104(94)00330-D . [all data]

Jarman and Bernath, 1992
Jarman, C.N.; Bernath, P.F., High resolution laser spectroscopy of the C 2Δ--X 2Σ+ transition of CaOH and CaOD: Vibronic coupling and the Renner--Teller effect, J. Chem. Phys., 1992, 97, 3, 1711, https://doi.org/10.1063/1.463158 . [all data]

Kauffman, Hauge, et al., 1984
Kauffman, J.W.; Hauge, R.H.; Margrave, J.L., High Temp. Sci., 1984, 18, 97. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

James and Sugden, 1955
James, C.G.; Sugden, T.M., A New Identification of the Flame Spectra of the Alkaline-Earth Metals, Nature, 1955, 175, 4451, 333, https://doi.org/10.1038/175333a0 . [all data]

Anderson, Barclay, et al., 1992
Anderson, M.A.; Barclay, W.L., Jr.; Ziurys, L.M., The millimeter-wave spectrum of the SrOH and SrOD radicals, Chem. Phys. Lett., 1992, 196, 1-2, 166, https://doi.org/10.1016/0009-2614(92)85948-A . [all data]

Fletcher, Jung, et al., 1993
Fletcher, D.A.; Jung, K.Y.; Scurlock, C.T.; Steimle, T.C., Molecular beam pump/probe microwave-optical double resonance using a laser ablation source, J. Chem. Phys., 1993, 98, 3, 1837, https://doi.org/10.1063/1.464218 . [all data]

Zhao, Hajigeorgiou, et al., 1996
Zhao, C.; Hajigeorgiou, P.G.; Bernath, P.F.; Hepburn, J.W., High-Resolution Laser Excitation Spectroscopy of theB2Σ+--X2Σ+System of Jet-Cooled SrOD, J. Mol. Spectrosc., 1996, 176, 2, 268, https://doi.org/10.1006/jmsp.1996.0086 . [all data]

Yu, Wang, et al., 2006
Yu, S.; Wang, J.-G.; Sheridan, P.M.; Dick, M.J.; Bernath, P.F., Laser spectroscopy of the and transitions of SrOD, J. Mol. Spectrosc., 2006, 240, 1, 26, https://doi.org/10.1016/j.jms.2006.08.004 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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