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Nitrogen

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Ar+ + Nitrogen = (Ar+ bullet Nitrogen)

By formula: Ar+ + N2 = (Ar+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar164.kJ/molFAShul, Passarella, et al., 1987gas phase; switching reaction(Ar+)Ar, «DELTA»rH>; Dehmer and Pratt, 1982; M

Trifluoromethyl cation + Nitrogen = (Trifluoromethyl cation bullet Nitrogen)

By formula: CF3+ + N2 = (CF3+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar29.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation bullet Nitrogen) + Nitrogen = (Trifluoromethyl cation bullet 2Nitrogen)

By formula: (CF3+ bullet N2) + N2 = (CF3+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation bullet 2Nitrogen) + Nitrogen = (Trifluoromethyl cation bullet 3Nitrogen)

By formula: (CF3+ bullet 2N2) + N2 = (CF3+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar8.4kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar54.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation bullet 3Nitrogen) + Nitrogen = (Trifluoromethyl cation bullet 4Nitrogen)

By formula: (CF3+ bullet 3N2) + N2 = (CF3+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar7.5kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation bullet 4Nitrogen) + Nitrogen = (Trifluoromethyl cation bullet 5Nitrogen)

By formula: (CF3+ bullet 4N2) + N2 = (CF3+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar6.3kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar50.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

CH2N+ + Nitrogen = (CH2N+ bullet Nitrogen)

By formula: CH2N+ + N2 = (CH2N+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar32.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar92.9J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; M

(CH2N+ bullet Nitrogen) + Nitrogen = (CH2N+ bullet 2Nitrogen)

By formula: (CH2N+ bullet N2) + N2 = (CH2N+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar83.3J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; M

(CH2N+ bullet 2Nitrogen) + Nitrogen = (CH2N+ bullet 3Nitrogen)

By formula: (CH2N+ bullet 2N2) + N2 = (CH2N+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar54.8J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ bullet 3Nitrogen) + Nitrogen = (CH2N+ bullet 4Nitrogen)

By formula: (CH2N+ bullet 3N2) + N2 = (CH2N+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar57.7J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ bullet 4Nitrogen) + Nitrogen = (CH2N+ bullet 5Nitrogen)

By formula: (CH2N+ bullet 4N2) + N2 = (CH2N+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar63.6J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

Methyl cation + Nitrogen = (Methyl cation bullet Nitrogen)

By formula: CH3+ + N2 = (CH3+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar203.kJ/molPDissFoster, Williamson, et al., 1974gas phase; M

CH5+ + Nitrogen = (CH5+ bullet Nitrogen)

By formula: CH5+ + N2 = (CH5+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar28.kJ/molHPMSSpeller, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KHPMSSpeller, 1983gas phase; M

C2H5+ + Nitrogen = (C2H5+ bullet Nitrogen)

By formula: C2H5+ + N2 = (C2H5+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar29.kJ/molHPMSSpeller, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KHPMSSpeller, 1983gas phase; M

(C2H5+ bullet Nitrogen) + Nitrogen = (C2H5+ bullet 2Nitrogen)

By formula: (C2H5+ bullet N2) + N2 = (C2H5+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar45.6J/mol*KHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M

Calcium ion (1+) + Nitrogen = (Calcium ion (1+) bullet Nitrogen)

By formula: Ca+ + N2 = (Ca+ bullet N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.296.FASpears and Fehsenfeld, 1972gas phase; M

Copper ion (1+) + Nitrogen = (Copper ion (1+) bullet Nitrogen)

By formula: Cu+ + N2 = (Cu+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar26.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
Deltar67.J/mol*KHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
Deltar5.9kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M

(Copper ion (1+) bullet Nitrogen) + Nitrogen = (Copper ion (1+) bullet 2Nitrogen)

By formula: (Cu+ bullet N2) + N2 = (Cu+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar12.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desorption, equilibrium?; M

(Copper ion (1+) bullet 2Nitrogen) + Nitrogen = (Copper ion (1+) bullet 3Nitrogen)

By formula: (Cu+ bullet 2N2) + N2 = (Cu+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar10.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desorption; M

Iron ion (1+) + Nitrogen = (Iron ion (1+) bullet Nitrogen)

By formula: Fe+ + N2 = (Fe+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar54.0 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet Nitrogen) + Nitrogen = (Iron ion (1+) bullet 2Nitrogen)

By formula: (Fe+ bullet N2) + N2 = (Fe+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar82.8 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet 2Nitrogen) + Nitrogen = (Iron ion (1+) bullet 3Nitrogen)

By formula: (Fe+ bullet 2N2) + N2 = (Fe+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar45. ± 3.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet 3Nitrogen) + Nitrogen = (Iron ion (1+) bullet 4Nitrogen)

By formula: (Fe+ bullet 3N2) + N2 = (Fe+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar54.0 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet 4Nitrogen) + Nitrogen = (Iron ion (1+) bullet 5Nitrogen)

By formula: (Fe+ bullet 4N2) + N2 = (Fe+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar61.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

HN2+ + Nitrogen = (HN2+ bullet Nitrogen)

By formula: HN2+ + N2 = (HN2+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar66.9kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Deltar60.7kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Deltar85.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M

(HN2+ bullet Nitrogen) + Nitrogen = (HN2+ bullet 2Nitrogen)

By formula: (HN2+ bullet N2) + N2 = (HN2+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar15. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Deltar17.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar80.3J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Deltar75.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ bullet 2Nitrogen) + Nitrogen = (HN2+ bullet 3Nitrogen)

By formula: (HN2+ bullet 2N2) + N2 = (HN2+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Deltar16.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Deltar84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ bullet 3Nitrogen) + Nitrogen = (HN2+ bullet 4Nitrogen)

By formula: (HN2+ bullet 3N2) + N2 = (HN2+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Deltar15.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Deltar84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ bullet 4Nitrogen) + Nitrogen = (HN2+ bullet 5Nitrogen)

By formula: (HN2+ bullet 4N2) + N2 = (HN2+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar12. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Deltar13.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
Deltar84.J/mol*KN/AHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
5.992.PHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

(HN2+ bullet 5Nitrogen) + Nitrogen = (HN2+ bullet 6Nitrogen)

By formula: (HN2+ bullet 5N2) + N2 = (HN2+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ bullet 6Nitrogen) + Nitrogen = (HN2+ bullet 7Nitrogen)

By formula: (HN2+ bullet 6N2) + N2 = (HN2+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ bullet 7Nitrogen) + Nitrogen = (HN2+ bullet 8Nitrogen)

By formula: (HN2+ bullet 7N2) + N2 = (HN2+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.0J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ bullet 8Nitrogen) + Nitrogen = (HN2+ bullet 9Nitrogen)

By formula: (HN2+ bullet 8N2) + N2 = (HN2+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ bullet 9Nitrogen) + Nitrogen = (HN2+ bullet 10Nitrogen)

By formula: (HN2+ bullet 9N2) + N2 = (HN2+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ bullet 10Nitrogen) + Nitrogen = (HN2+ bullet 11Nitrogen)

By formula: (HN2+ bullet 10N2) + N2 = (HN2+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar7.20kJ/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M

(Hydronium cation bullet Water) + Nitrogen = (Hydronium cation bullet Nitrogen bullet Water)

By formula: (H3O+ bullet H2O) + N2 = (H3O+ bullet N2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar22.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar58.2J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation bullet 2Water) + Nitrogen = (Hydronium cation bullet Nitrogen bullet 2Water)

By formula: (H3O+ bullet 2H2O) + N2 = (H3O+ bullet N2 bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.8J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation bullet Nitrogen bullet Water) + Nitrogen = (Hydronium cation bullet 2Nitrogen bullet Water)

By formula: (H3O+ bullet N2 bullet H2O) + N2 = (H3O+ bullet 2N2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar54.8J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation bullet Nitrogen bullet 2Water) + Nitrogen = (Hydronium cation bullet 2Nitrogen bullet 2Water)

By formula: (H3O+ bullet N2 bullet 2H2O) + N2 = (H3O+ bullet 2N2 bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar22.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar69.5J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation bullet Nitrogen bullet 3Water) + Nitrogen = (Hydronium cation bullet 2Nitrogen bullet 3Water)

By formula: (H3O+ bullet N2 bullet 3H2O) + N2 = (H3O+ bullet 2N2 bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar18.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar65.7J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation bullet 2Nitrogen bullet Water) + Nitrogen = (Hydronium cation bullet 3Nitrogen bullet Water)

By formula: (H3O+ bullet 2N2 bullet H2O) + N2 = (H3O+ bullet 3N2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar33. ± 8.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation bullet 2Nitrogen bullet 2Water) + Nitrogen = (Hydronium cation bullet 3Nitrogen bullet 2Water)

By formula: (H3O+ bullet 2N2 bullet 2H2O) + N2 = (H3O+ bullet 3N2 bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar38. ± 11.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar119.J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation bullet 2Nitrogen bullet 3Water) + Nitrogen = (Hydronium cation bullet 3Nitrogen bullet 3Water)

By formula: (H3O+ bullet 2N2 bullet 3H2O) + N2 = (H3O+ bullet 3N2 bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar5.0kJ/molDTGheno and Fitaire, 1987gas phase; «DELTA»rH, «DELTA»rS approximate; M
Quantity Value Units Method Reference Comment
Deltar27.J/mol*KDTGheno and Fitaire, 1987gas phase; «DELTA»rH, «DELTA»rS approximate; M

(Hydronium cation bullet 3Nitrogen bullet 2Water) + Nitrogen = (Hydronium cation bullet 4Nitrogen bullet 2Water)

By formula: (H3O+ bullet 3N2 bullet 2H2O) + N2 = (H3O+ bullet 4N2 bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar10.kJ/molDTGheno and Fitaire, 1987gas phase; «DELTA»rH, «DELTA»rS approximate; M
Quantity Value Units Method Reference Comment
Deltar50.J/mol*KDTGheno and Fitaire, 1987gas phase; «DELTA»rH, «DELTA»rS approximate; M

NH4+ + Nitrogen = (NH4+ bullet Nitrogen)

By formula: H4N+ + N2 = (H4N+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar50. ± 20.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KDTGheno and Fitaire, 1987gas phase; M

Potassium ion (1+) + Nitrogen = (Potassium ion (1+) bullet Nitrogen)

By formula: K+ + N2 = (K+ bullet N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
4.2310.DTBeyer and Keller, 1971gas phase; low E/N; M

Lithium ion (1+) + Nitrogen = (Lithium ion (1+) bullet Nitrogen)

By formula: Li+ + N2 = (Li+ bullet N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

(Lithium ion (1+) bullet Nitrogen) + Nitrogen = (Lithium ion (1+) bullet 2Nitrogen)

By formula: (Li+ bullet N2) + N2 = (Li+ bullet 2N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

N+ + Nitrogen = (N+ bullet Nitrogen)

By formula: N+ + N2 = (N+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar249.kJ/molN/ANational Bureau of Standards, 1968gas phase; from «DELTA»rH(f); M
Deltar250.kJ/molEISaporoschenko, 1965gas phase; M
Deltar250.kJ/molEIFranklin, Dibeler, et al., 1958gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
361. (+7.5,-0.) CIDHaynes, Freysinger, et al., 1995gas phase; guided ion beam CID; M

Nitric oxide anion + Nitrogen = (Nitric oxide anion bullet Nitrogen)

By formula: NO- + N2 = (NO- bullet N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Deltar20.kJ/molDTGheno and Fitaire, 1987gas phase; «DELTA»rS+-12. J/mol*K; M
Deltar18.kJ/molHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
Deltar22.kJ/molHPMSTurner and Conway, 1976gas phase; M
Deltar19.kJ/molDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
Deltar57.7J/mol*KDTGheno and Fitaire, 1987gas phase; «DELTA»rS+-12. J/mol*K; M
Deltar55.6J/mol*KHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
Deltar79.1J/mol*KHPMSTurner and Conway, 1976gas phase; M
Deltar65.7J/mol*KDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
2.200.FADunkin, Fehsenfeld, et al., 1971gas phase; M

(Nitric oxide anion bullet Nitrogen) + Nitrogen = (Nitric oxide anion bullet 2Nitrogen)

By formula: (NO- bullet N2) + N2 = (NO- bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Deltar16.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar72.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
Deltar52.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Nitric oxide anion bullet 2Nitrogen) + Nitrogen = (Nitric oxide anion bullet 3Nitrogen)

By formula: (NO- bullet 2N2) + N2 = (NO- bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar70.3J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
4.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion bullet 3Nitrogen) + Nitrogen = (Nitric oxide anion bullet 4Nitrogen)

By formula: (NO- bullet 3N2) + N2 = (NO- bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
2.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion bullet 4Nitrogen) + Nitrogen = (Nitric oxide anion bullet 5Nitrogen)

By formula: (NO- bullet 4N2) + N2 = (NO- bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar13. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion bullet 5Nitrogen) + Nitrogen = (Nitric oxide anion bullet 6Nitrogen)

By formula: (NO- bullet 5N2) + N2 = (NO- bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar13. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion bullet 6Nitrogen) + Nitrogen = (Nitric oxide anion bullet 7Nitrogen)

By formula: (NO- bullet 6N2) + N2 = (NO- bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar12. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion bullet 7Nitrogen) + Nitrogen = (Nitric oxide anion bullet 8Nitrogen)

By formula: (NO- bullet 7N2) + N2 = (NO- bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar11. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.5J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion bullet 8Nitrogen) + Nitrogen = (Nitric oxide anion bullet 9Nitrogen)

By formula: (NO- bullet 8N2) + N2 = (NO- bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion bullet 9Nitrogen) + Nitrogen = (Nitric oxide anion bullet 10Nitrogen)

By formula: (NO- bullet 9N2) + N2 = (NO- bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar7.03kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KN/AHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M

NO2+ + Nitrogen = (NO2+ bullet Nitrogen)

By formula: NO2+ + N2 = (NO2+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet Nitrogen) + Nitrogen = (NO2+ bullet 2Nitrogen)

By formula: (NO2+ bullet N2) + N2 = (NO2+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 2Nitrogen) + Nitrogen = (NO2+ bullet 3Nitrogen)

By formula: (NO2+ bullet 2N2) + N2 = (NO2+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar18. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 3Nitrogen) + Nitrogen = (NO2+ bullet 4Nitrogen)

By formula: (NO2+ bullet 3N2) + N2 = (NO2+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 4Nitrogen) + Nitrogen = (NO2+ bullet 5Nitrogen)

By formula: (NO2+ bullet 4N2) + N2 = (NO2+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 5Nitrogen) + Nitrogen = (NO2+ bullet 6Nitrogen)

By formula: (NO2+ bullet 5N2) + N2 = (NO2+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 6Nitrogen) + Nitrogen = (NO2+ bullet 7Nitrogen)

By formula: (NO2+ bullet 6N2) + N2 = (NO2+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 7Nitrogen) + Nitrogen = (NO2+ bullet 8Nitrogen)

By formula: (NO2+ bullet 7N2) + N2 = (NO2+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 8Nitrogen) + Nitrogen = (NO2+ bullet 9Nitrogen)

By formula: (NO2+ bullet 8N2) + N2 = (NO2+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 9Nitrogen) + Nitrogen = (NO2+ bullet 10Nitrogen)

By formula: (NO2+ bullet 9N2) + N2 = (NO2+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar86.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 10Nitrogen) + Nitrogen = (NO2+ bullet 11Nitrogen)

By formula: (NO2+ bullet 10N2) + N2 = (NO2+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar77.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ bullet 11Nitrogen) + Nitrogen = (NO2+ bullet 12Nitrogen)

By formula: (NO2+ bullet 11N2) + N2 = (NO2+ bullet 12N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Nitrogen cation + Nitrogen = (Nitrogen cation bullet Nitrogen)

By formula: N2+ + N2 = (N2+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar102. - 102.kJ/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Deltar67.8J/mol*KPHPMSTeng and Conway, 1973gas phase; M
Deltar81.6J/mol*KPHPMSPayzant and Kebarle, 1970gas phase; M
Deltar46.J/mol*KDTVarney, 1968gas phase; Entropy change is questionable; M
Deltar-4.J/mol*KDTVarney, 1959gas phase; Entropy change is questionable; M

(Nitrogen cation bullet Nitrogen) + Nitrogen = (Nitrogen cation bullet 2Nitrogen)

By formula: (N2+ bullet N2) + N2 = (N2+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Deltar5.9kJ/molPILinn, Ono, et al., 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar62.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 2Nitrogen) + Nitrogen = (Nitrogen cation bullet 3Nitrogen)

By formula: (N2+ bullet 2N2) + N2 = (N2+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar66.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 3Nitrogen) + Nitrogen = (Nitrogen cation bullet 4Nitrogen)

By formula: (N2+ bullet 3N2) + N2 = (N2+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar10.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar69.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 4Nitrogen) + Nitrogen = (Nitrogen cation bullet 5Nitrogen)

By formula: (N2+ bullet 4N2) + N2 = (N2+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar10.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 5Nitrogen) + Nitrogen = (Nitrogen cation bullet 6Nitrogen)

By formula: (N2+ bullet 5N2) + N2 = (N2+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar9.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 6Nitrogen) + Nitrogen = (Nitrogen cation bullet 7Nitrogen)

By formula: (N2+ bullet 6N2) + N2 = (N2+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar8.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 7Nitrogen) + Nitrogen = (Nitrogen cation bullet 8Nitrogen)

By formula: (N2+ bullet 7N2) + N2 = (N2+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar7.8 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar80.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 8Nitrogen) + Nitrogen = (Nitrogen cation bullet 9Nitrogen)

By formula: (N2+ bullet 8N2) + N2 = (N2+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 9Nitrogen) + Nitrogen = (Nitrogen cation bullet 10Nitrogen)

By formula: (N2+ bullet 9N2) + N2 = (N2+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar86.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation bullet 10Nitrogen) + Nitrogen = (Nitrogen cation bullet 11Nitrogen)

By formula: (N2+ bullet 10N2) + N2 = (N2+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

N3+ + Nitrogen = (N3+ bullet Nitrogen)

By formula: N3+ + N2 = (N3+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet Nitrogen) + Nitrogen = (N3+ bullet 2Nitrogen)

By formula: (N3+ bullet N2) + N2 = (N3+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 2Nitrogen) + Nitrogen = (N3+ bullet 3Nitrogen)

By formula: (N3+ bullet 2N2) + N2 = (N3+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 3Nitrogen) + Nitrogen = (N3+ bullet 4Nitrogen)

By formula: (N3+ bullet 3N2) + N2 = (N3+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar15. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 4Nitrogen) + Nitrogen = (N3+ bullet 5Nitrogen)

By formula: (N3+ bullet 4N2) + N2 = (N3+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 5Nitrogen) + Nitrogen = (N3+ bullet 6Nitrogen)

By formula: (N3+ bullet 5N2) + N2 = (N3+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar10. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 6Nitrogen) + Nitrogen = (N3+ bullet 7Nitrogen)

By formula: (N3+ bullet 6N2) + N2 = (N3+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar80.8J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 7Nitrogen) + Nitrogen = (N3+ bullet 8Nitrogen)

By formula: (N3+ bullet 7N2) + N2 = (N3+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar69.9J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 8Nitrogen) + Nitrogen = (N3+ bullet 9Nitrogen)

By formula: (N3+ bullet 8N2) + N2 = (N3+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar68.2J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 9Nitrogen) + Nitrogen = (N3+ bullet 10Nitrogen)

By formula: (N3+ bullet 9N2) + N2 = (N3+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar69.0J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ bullet 10Nitrogen) + Nitrogen = (N3+ bullet 11Nitrogen)

By formula: (N3+ bullet 10N2) + N2 = (N3+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar70.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) bullet Nitrogen)

By formula: Na+ + N2 = (Na+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar33.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar77.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
9.2310.FAPerry, Rowe, et al., 1980gas phase; M
8.4310.DTBeyer and Keller, 1971gas phase; low E/N; M

(Sodium ion (1+) bullet Nitrogen) + Nitrogen = (Sodium ion (1+) bullet 2Nitrogen)

By formula: (Na+ bullet N2) + N2 = (Na+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar22.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar70.3J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
-1.310.FAPerry, Rowe, et al., 1980gas phase; M

Nickel ion (1+) + Nitrogen = (Nickel ion (1+) bullet Nitrogen)

By formula: Ni+ + N2 = (Ni+ bullet N2)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
111. (+10.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) bullet Nitrogen) + Nitrogen = (Nickel ion (1+) bullet 2Nitrogen)

By formula: (Ni+ bullet N2) + N2 = (Ni+ bullet 2N2)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
111. (+10.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) bullet 2Nitrogen) + Nitrogen = (Nickel ion (1+) bullet 3Nitrogen)

By formula: (Ni+ bullet 2N2) + N2 = (Ni+ bullet 3N2)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
56. (+4.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) bullet 3Nitrogen) + Nitrogen = (Nickel ion (1+) bullet 4Nitrogen)

By formula: (Ni+ bullet 3N2) + N2 = (Ni+ bullet 4N2)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
42.3 (+9.6,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

Oxygen cation + Nitrogen = (Oxygen cation bullet Nitrogen)

By formula: O2+ + N2 = (O2+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar21. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Deltar22.kJ/molHPMSSpeller and Fitaire, 1983gas phase; M
Deltar24.kJ/molPHPMSJanik and Conway, 1967gas phase; M
Quantity Value Units Method Reference Comment
Deltar72.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Deltar66.1J/mol*KHPMSSpeller and Fitaire, 1983gas phase; M
Deltar79.1J/mol*KPHPMSJanik and Conway, 1967gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
0.0296.FAHoward, Bierbaum, et al., 1972gas phase; M

(Oxygen cation bullet Nitrogen) + Nitrogen = (Oxygen cation bullet 2Nitrogen)

By formula: (O2+ bullet N2) + N2 = (O2+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar19. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Deltar18.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Deltar57.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation bullet 2Nitrogen) + Nitrogen = (Oxygen cation bullet 3Nitrogen)

By formula: (O2+ bullet 2N2) + N2 = (O2+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar18. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Deltar15.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
Deltar50.6J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation bullet 3Nitrogen) + Nitrogen = (Oxygen cation bullet 4Nitrogen)

By formula: (O2+ bullet 3N2) + N2 = (O2+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar17. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
3.204.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation bullet 4Nitrogen) + Nitrogen = (Oxygen cation bullet 5Nitrogen)

By formula: (O2+ bullet 4N2) + N2 = (O2+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar67.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
3.184.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation bullet 5Nitrogen) + Nitrogen = (Oxygen cation bullet 6Nitrogen)

By formula: (O2+ bullet 5N2) + N2 = (O2+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar10.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar67.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation bullet 6Nitrogen) + Nitrogen = (Oxygen cation bullet 7Nitrogen)

By formula: (O2+ bullet 6N2) + N2 = (O2+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar9.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar77.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation bullet 7Nitrogen) + Nitrogen = (Oxygen cation bullet 8Nitrogen)

By formula: (O2+ bullet 7N2) + N2 = (O2+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar8.8 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar80.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation bullet 8Nitrogen) + Nitrogen = (Oxygen cation bullet 9Nitrogen)

By formula: (O2+ bullet 8N2) + N2 = (O2+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation bullet 9Nitrogen) + Nitrogen = (Oxygen cation bullet 10Nitrogen)

By formula: (O2+ bullet 9N2) + N2 = (O2+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar7.0 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.0J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation bullet 10Nitrogen) + Nitrogen = (Oxygen cation bullet 11Nitrogen)

By formula: (O2+ bullet 10N2) + N2 = (O2+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation bullet Nitrogen bullet Oxygen) + Nitrogen = (Oxygen cation bullet 2Nitrogen bullet Oxygen)

By formula: (O2+ bullet N2 bullet O2) + N2 = (O2+ bullet 2N2 bullet O2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
2.230.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation bullet Oxygen) + Nitrogen = (Oxygen cation bullet Nitrogen bullet Oxygen)

By formula: (O2+ bullet O2) + N2 = (O2+ bullet N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar12.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar42.3J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

Oxygen anion + Nitrogen = (Oxygen anion bullet Nitrogen)

By formula: O2- + N2 = (O2- bullet N2)

Quantity Value Units Method Reference Comment
Deltar25. ± 4.2kJ/molN/APosey and Johnson, 1988gas phase; B
Deltar<56.90kJ/molIMRBAdams and Bohme, 1970gas phase; N2..O2- + O2 -> O4-; B

(Oxygen anion bullet Nitrogen bullet Oxygen) + Nitrogen = (Oxygen anion bullet 2Nitrogen bullet Oxygen)

By formula: (O2- bullet N2 bullet O2) + N2 = (O2- bullet 2N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar11.7 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion bullet 2Nitrogen bullet Oxygen) + Nitrogen = (Oxygen anion bullet 3Nitrogen bullet Oxygen)

By formula: (O2- bullet 2N2 bullet O2) + N2 = (O2- bullet 3N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar10.3 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar76.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion bullet 3Nitrogen bullet Oxygen) + Nitrogen = (Oxygen anion bullet 4Nitrogen bullet Oxygen)

By formula: (O2- bullet 3N2 bullet O2) + N2 = (O2- bullet 4N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar9.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion bullet 4Nitrogen bullet Oxygen) + Nitrogen = (Oxygen anion bullet 5Nitrogen bullet Oxygen)

By formula: (O2- bullet 4N2 bullet O2) + N2 = (O2- bullet 5N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar8.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion bullet 5Nitrogen bullet Oxygen) + Nitrogen = (Oxygen anion bullet 6Nitrogen bullet Oxygen)

By formula: (O2- bullet 5N2 bullet O2) + N2 = (O2- bullet 6N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion bullet 6Nitrogen bullet Oxygen) + Nitrogen = (Oxygen anion bullet 7Nitrogen bullet Oxygen)

By formula: (O2- bullet 6N2 bullet O2) + N2 = (O2- bullet 7N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar7.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar78.7J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion bullet 7Nitrogen bullet Oxygen) + Nitrogen = (Oxygen anion bullet 8Nitrogen bullet Oxygen)

By formula: (O2- bullet 7N2 bullet O2) + N2 = (O2- bullet 8N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Deltar6.40kJ/molPHPMSHiraoka, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka, 1988gas phase; M
Deltar75.3J/mol*KN/AHiraoka, 1988gas phase; Entropy change calculated or estimated; M

(Oxygen anion bullet Oxygen) + Nitrogen = (Oxygen anion bullet Nitrogen bullet Oxygen)

By formula: (O2- bullet O2) + N2 = (O2- bullet N2 bullet O2)

Quantity Value Units Method Reference Comment
Deltar12.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar69.0J/mol*KPHPMSHiraoka, 1988gas phase; M

O3- + Nitrogen = (O3- bullet Nitrogen)

By formula: O3- + N2 = (O3- bullet N2)

Quantity Value Units Method Reference Comment
Deltar11.3 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar77.0J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar-11.7 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

(O3- bullet Nitrogen) + Nitrogen = (O3- bullet 2Nitrogen)

By formula: (O3- bullet N2) + N2 = (O3- bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar11.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 2Nitrogen) + Nitrogen = (O3- bullet 3Nitrogen)

By formula: (O3- bullet 2N2) + N2 = (O3- bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar10.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 3Nitrogen) + Nitrogen = (O3- bullet 4Nitrogen)

By formula: (O3- bullet 3N2) + N2 = (O3- bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar9.5 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 4Nitrogen) + Nitrogen = (O3- bullet 5Nitrogen)

By formula: (O3- bullet 4N2) + N2 = (O3- bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar8.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 5Nitrogen) + Nitrogen = (O3- bullet 6Nitrogen)

By formula: (O3- bullet 5N2) + N2 = (O3- bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar8.2 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 6Nitrogen) + Nitrogen = (O3- bullet 7Nitrogen)

By formula: (O3- bullet 6N2) + N2 = (O3- bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 7Nitrogen) + Nitrogen = (O3- bullet 8Nitrogen)

By formula: (O3- bullet 7N2) + N2 = (O3- bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar73.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- bullet 8Nitrogen) + Nitrogen = (O3- bullet 9Nitrogen)

By formula: (O3- bullet 8N2) + N2 = (O3- bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar6. ± 2.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar70.7J/mol*KPHPMSHiraoka, 1988gas phase; M

O4- + Nitrogen + Oxygen = N2O4-

By formula: O4- + N2 + O2 = N2O4-

Quantity Value Units Method Reference Comment
Deltar12.1 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar-8.8 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Shul, R.J.; Passarella, R.; Upshulte, B.L.; Keesee, R.G.; Castleman, A.W., Thermal Energy Reactions Invoving Ar+ Monomer and Dimer with N2, H2, Xe, and Kr, J. Chem. Phys., 1987, 86, 8, 4446, https://doi.org/10.1063/1.452718 . [all data]

Dehmer and Pratt, 1982
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Speller, Fitaire, et al., 1982
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Spears and Fehsenfeld, 1972
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El-Shall, M.S.; Schriver, K.E.; Whetten, R.L.; Meot-Ner (Mautner), M., Ion/Molecule Clustering Thermochemistry by Laser Ionization High - Pressure Mass Spectrometry, J. Phys. Chem., 1989, 93, 24, 7969, https://doi.org/10.1021/j100361a002 . [all data]

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Meot-Ner (Mautner) and Field, 1974
Meot-Ner (Mautner), M.; Field, F.H., Kinetics and Thermodynamics of the Association of CO+ with CO and of N2+ with N2 between 120 and 650 K, J. Chem. Phys., 1974, 61, 9, 3742, https://doi.org/10.1063/1.1682560 . [all data]

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Hiraoka, K.; Mori, T., Gas Phase Stabilities of the Cluster Ions H+(CO)2(CO)n, H+(N2)2(N2)n and H+(O2)2(O2)n with n = 1 - 14, Chem. Phys., 1989, 137, 1-3, 345, https://doi.org/10.1016/0301-0104(89)87119-8 . [all data]

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Khan, F.A.; Steele, D.L.; Armentrout, P.B., Ligand effects in organometallic thermochemistry: The sequential bond energies of Ni(CO)x+ and Ni(N2)x+ (x = 1-4) and Ni(NO)x+ (x = 1-3) [Data derived from reported bond energies taking value of 8.273±0.046 eV for IE[Ni(CO)4]], J. Phys. Chem., 1995, 99, 7819. [all data]

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Notes

Go To: Top, Ion clustering data, References