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Trifluoromethyl cation


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Trifluoromethyl cation + Tetrafluoromethane = (Trifluoromethyl cation bullet Tetrafluoromethane)

By formula: CF3+ + CF4 = (CF3+ bullet CF4)

Quantity Value Units Method Reference Comment
Deltar28.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar79.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet Tetrafluoromethane) + Tetrafluoromethane = (Trifluoromethyl cation bullet 2Tetrafluoromethane)

By formula: (CF3+ bullet CF4) + CF4 = (CF3+ bullet 2CF4)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 2Tetrafluoromethane) + Tetrafluoromethane = (Trifluoromethyl cation bullet 3Tetrafluoromethane)

By formula: (CF3+ bullet 2CF4) + CF4 = (CF3+ bullet 3CF4)

Quantity Value Units Method Reference Comment
Deltar12.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 3Tetrafluoromethane) + Tetrafluoromethane = (Trifluoromethyl cation bullet 4Tetrafluoromethane)

By formula: (CF3+ bullet 3CF4) + CF4 = (CF3+ bullet 4CF4)

Quantity Value Units Method Reference Comment
Deltar12.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

Trifluoromethyl cation + Methane = (Trifluoromethyl cation bullet Methane)

By formula: CF3+ + CH4 = (CF3+ bullet CH4)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molHPMSBennet and Field, 1972gas phase
Quantity Value Units Method Reference Comment
Deltar78.7J/mol*KHPMSBennet and Field, 1972gas phase

Trifluoromethyl cation + Carbon monoxide = (Trifluoromethyl cation bullet Carbon monoxide)

By formula: CF3+ + CO = (CF3+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar66.9kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation bullet 2Carbon monoxide)

By formula: (CF3+ bullet CO) + CO = (CF3+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar26.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 2Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation bullet 3Carbon monoxide)

By formula: (CF3+ bullet 2CO) + CO = (CF3+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar24.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 3Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation bullet 4Carbon monoxide)

By formula: (CF3+ bullet 3CO) + CO = (CF3+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar23.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 4Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation bullet 5Carbon monoxide)

By formula: (CF3+ bullet 4CO) + CO = (CF3+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar13.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 5Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation bullet 6Carbon monoxide)

By formula: (CF3+ bullet 5CO) + CO = (CF3+ bullet 6CO)

Quantity Value Units Method Reference Comment
Deltar12.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 6Carbon monoxide) + Carbon monoxide = (Trifluoromethyl cation bullet 7Carbon monoxide)

By formula: (CF3+ bullet 6CO) + CO = (CF3+ bullet 7CO)

Quantity Value Units Method Reference Comment
Deltar11.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

Trifluoromethyl cation + Water = (Trifluoromethyl cation bullet Water)

By formula: CF3+ + H2O = (CF3+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molHPMSBennet and Field, 1972gas phase
Quantity Value Units Method Reference Comment
Deltar78.7J/mol*KHPMSBennet and Field, 1972gas phase

Trifluoromethyl cation + Nitrogen = (Trifluoromethyl cation bullet Nitrogen)

By formula: CF3+ + N2 = (CF3+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar29.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet Nitrogen) + Nitrogen = (Trifluoromethyl cation bullet 2Nitrogen)

By formula: (CF3+ bullet N2) + N2 = (CF3+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 2Nitrogen) + Nitrogen = (Trifluoromethyl cation bullet 3Nitrogen)

By formula: (CF3+ bullet 2N2) + N2 = (CF3+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar8.4kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar54.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 3Nitrogen) + Nitrogen = (Trifluoromethyl cation bullet 4Nitrogen)

By formula: (CF3+ bullet 3N2) + N2 = (CF3+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar7.5kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar59.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

(Trifluoromethyl cation bullet 4Nitrogen) + Nitrogen = (Trifluoromethyl cation bullet 5Nitrogen)

By formula: (CF3+ bullet 4N2) + N2 = (CF3+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar6.3kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase
Quantity Value Units Method Reference Comment
Deltar50.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Nasu, et al., 1996
Hiraoka, K.; Nasu, M.; Fujimaki, S.; Ignacio, E.W.; Yamabe, S., Gas-Phase Stability and Structure of the Cluster Ions CF3+(CO)n, CF3+(N2)n, CF3+((CF4)n, and CF4H+(CF4)n, J. Phys. Chem., 1996, 100, 13, 5245, https://doi.org/10.1021/jp9530010 . [all data]

Bennet and Field, 1972
Bennet, S.L.; Field, F.H., Reversible Reactions of Gaseous Ions. VI. The NH3 - CH4, H2S - CH4 and CF4 - CH4 Systems at Low Temperatures, J. Am. Chem. Soc., 1972, 94, 18, 6305, https://doi.org/10.1021/ja00773a009 . [all data]


Notes

Go To: Top, Ion clustering data, References