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Iron ion (1+)


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Iron ion (1+) + Argon = (Iron ion (1+) bullet Argon)

By formula: Fe+ + Ar = (Fe+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar11. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Formaldehyde = (Iron ion (1+) bullet Formaldehyde)

By formula: Fe+ + CH2O = (Fe+ bullet CH2O)

Quantity Value Units Method Reference Comment
Deltar138. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet Formaldehyde) + Formaldehyde = (Iron ion (1+) bullet 2Formaldehyde)

By formula: (Fe+ bullet CH2O) + CH2O = (Fe+ bullet 2CH2O)

Quantity Value Units Method Reference Comment
Deltar164. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet 2Formaldehyde) + Formaldehyde = (Iron ion (1+) bullet 3Formaldehyde)

By formula: (Fe+ bullet 2CH2O) + CH2O = (Fe+ bullet 3CH2O)

Quantity Value Units Method Reference Comment
Deltar76.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet 3Formaldehyde) + Formaldehyde = (Iron ion (1+) bullet 4Formaldehyde)

By formula: (Fe+ bullet 3CH2O) + CH2O = (Fe+ bullet 4CH2O)

Quantity Value Units Method Reference Comment
Deltar50.2 ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Methyl radical = (Iron ion (1+) bullet Methyl radical)

By formula: Fe+ + CH3 = (Fe+ bullet CH3)

Quantity Value Units Method Reference Comment
Deltar240. ± 13.kJ/molCIDTFisher, Schultz, et al., 1989RCD
Deltar238. ± 6.7kJ/molCIDTFisher, Schultz, et al., 1989RCD
Deltar242. ± 10.kJ/molCIDTSchultz, Elkind, et al., 1988RCD

Iron ion (1+) + CH4Si = (Iron ion (1+) bullet CH4Si)

By formula: Fe+ + CH4Si = (Fe+ bullet CH4Si)

Quantity Value Units Method Reference Comment
Deltar262. ± 31.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + CH4Si = (Iron ion (1+) bullet CH4Si)

By formula: Fe+ + CH4Si = (Fe+ bullet CH4Si)

Quantity Value Units Method Reference Comment
Deltar280. ± 46.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + Methane = (Iron ion (1+) bullet Methane)

By formula: Fe+ + CH4 = (Fe+ bullet CH4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
57. (+3.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet Methane) + Methane = (Iron ion (1+) bullet 2Methane)

By formula: (Fe+ bullet CH4) + CH4 = (Fe+ bullet 2CH4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
97.1 (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 2Methane) + Methane = (Iron ion (1+) bullet 3Methane)

By formula: (Fe+ bullet 2CH4) + CH4 = (Fe+ bullet 3CH4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
99.2 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 3Methane) + Methane = (Iron ion (1+) bullet 4Methane)

By formula: (Fe+ bullet 3CH4) + CH4 = (Fe+ bullet 4CH4)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
74.1 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + Carbon monoxide = (Iron ion (1+) bullet Carbon monoxide)

By formula: Fe+ + CO = (Fe+ bullet CO)

Quantity Value Units Method Reference Comment
Deltar129. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar130. ± 10.kJ/molMKERCarpenter, van Koppen, et al., 1995gas phase; determined from MKER and theory; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
131. (+7.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Iron ion (1+) bullet 2Carbon monoxide)

By formula: (Fe+ bullet CO) + CO = (Fe+ bullet 2CO)

Quantity Value Units Method Reference Comment
Deltar148. ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
151. (+14.,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Iron ion (1+) bullet 3Carbon monoxide)

By formula: (Fe+ bullet 2CO) + CO = (Fe+ bullet 3CO)

Quantity Value Units Method Reference Comment
Deltar69.0 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
66.1 (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 3Carbon monoxide) + Carbon monoxide = (Iron ion (1+) bullet 4Carbon monoxide)

By formula: (Fe+ bullet 3CO) + CO = (Fe+ bullet 4CO)

Quantity Value Units Method Reference Comment
Deltar97.9 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
103. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 4Carbon monoxide) + Carbon monoxide = (Iron ion (1+) bullet 5Carbon monoxide)

By formula: (Fe+ bullet 4CO) + CO = (Fe+ bullet 5CO)

Quantity Value Units Method Reference Comment
Deltar97.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
112. (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 3Carbon monoxide bullet 2iron) + Carbon monoxide = (Iron ion (1+) bullet 4Carbon monoxide bullet 2iron)

By formula: (Fe+ bullet 3CO bullet 2Fe) + CO = (Fe+ bullet 4CO bullet 2Fe)

Quantity Value Units Method Reference Comment
Deltar238.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH<; M

Iron ion (1+) + Carbon dioxide = (Iron ion (1+) bullet Carbon dioxide)

By formula: Fe+ + CO2 = (Fe+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar59.8 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) bullet Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ bullet CS)

Quantity Value Units Method Reference Comment
Deltar207. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD
Deltar231. ± 12.kJ/molCIDTSchroeder, Kretzschmar, et al., 1999RCD

Iron ion (1+) + Carbon disulfide = (Iron ion (1+) bullet Carbon disulfide)

By formula: Fe+ + CS2 = (Fe+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar166. ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet Carbon disulfide) + Carbon disulfide = (Iron ion (1+) bullet 2Carbon disulfide)

By formula: (Fe+ bullet CS2) + CS2 = (Fe+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar188. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Acetylene = (Iron ion (1+) bullet Acetylene)

By formula: Fe+ + C2H2 = (Fe+ bullet C2H2)

Quantity Value Units Method Reference Comment
Deltar151. ± 7.9kJ/molIRMPDSurya, Ranatunga, et al., 1997RCD

Iron ion (1+) + Ethylene = (Iron ion (1+) bullet Ethylene)

By formula: Fe+ + C2H4 = (Fe+ bullet C2H4)

Quantity Value Units Method Reference Comment
Deltar145. ± 11.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
145. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet Ethylene) + Ethylene = (Iron ion (1+) bullet 2Ethylene)

By formula: (Fe+ bullet C2H4) + C2H4 = (Fe+ bullet 2C2H4)

Quantity Value Units Method Reference Comment
Deltar151. ± 15.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

Iron ion (1+) + C2H6Si = (Iron ion (1+) bullet C2H6Si)

By formula: Fe+ + C2H6Si = (Fe+ bullet C2H6Si)

Quantity Value Units Method Reference Comment
Deltar287. ± 36.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + C2H6Si = (Iron ion (1+) bullet C2H6Si)

By formula: Fe+ + C2H6Si = (Fe+ bullet C2H6Si)

Quantity Value Units Method Reference Comment
Deltar260. ± 30.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + Ethane = (Iron ion (1+) bullet Ethane)

By formula: Fe+ + C2H6 = (Fe+ bullet C2H6)

Quantity Value Units Method Reference Comment
Deltar70. ± 10.kJ/molMKERCarpenter, van Koppen, et al., 1995gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
64.0 (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + Propene = (Iron ion (1+) bullet Propene)

By formula: Fe+ + C3H6 = (Fe+ bullet C3H6)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
145. (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + 2-Silaisobutene = (Iron ion (1+) bullet 2-Silaisobutene)

By formula: Fe+ + C3H8Si = (Fe+ bullet C3H8Si)

Quantity Value Units Method Reference Comment
Deltar270. ± 40.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + Propane = (Iron ion (1+) bullet Propane)

By formula: Fe+ + C3H8 = (Fe+ bullet C3H8)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
74.9 (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + 1,3-Diazine = (Iron ion (1+) bullet 1,3-Diazine)

By formula: Fe+ + C4H4N2 = (Fe+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
Deltar199. ± 7.9kJ/molCIDTAmunugama and Rodgers, 2001RCD

Iron ion (1+) + Pyrrole = (Iron ion (1+) bullet Pyrrole)

By formula: Fe+ + C4H5N = (Fe+ bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar226.kJ/molRAKGapeev and Yang, 2000RCD

(Iron ion (1+) bullet Pyrrole) + Pyrrole = (Iron ion (1+) bullet 2Pyrrole)

By formula: (Fe+ bullet C4H5N) + C4H5N = (Fe+ bullet 2C4H5N)

Quantity Value Units Method Reference Comment
Deltar174.kJ/molRAKGapeev and Yang, 2000RCD

Iron ion (1+) + Pyridine = (Iron ion (1+) bullet Pyridine)

By formula: Fe+ + C5H5N = (Fe+ bullet C5H5N)

Quantity Value Units Method Reference Comment
Deltar223. ± 9.2kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Iron ion (1+) + Adenine = (Iron ion (1+) bullet Adenine)

By formula: Fe+ + C5H5N5 = (Fe+ bullet C5H5N5)

Quantity Value Units Method Reference Comment
Deltar259. ± 8.8kJ/molCIDTRodgers and Armentrout, 2002RCD

Iron ion (1+) + Benzene = (Iron ion (1+) bullet Benzene)

By formula: Fe+ + C6H6 = (Fe+ bullet C6H6)

Quantity Value Units Method Reference Comment
Deltar197.kJ/molRAKGapeev and Dunbar, 2002RCD
Deltar207. ± 12.kJ/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
208. (+9.6,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

(Iron ion (1+) bullet Benzene) + Benzene = (Iron ion (1+) bullet 2Benzene)

By formula: (Fe+ bullet C6H6) + C6H6 = (Fe+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
Deltar187. ± 16.kJ/molCIDTMeyer, Khan, et al., 1995RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
187. (+16.,-0.) CIDMeyer, Khan, et al., 1995gas phase; guided ion beam CID; M

Iron ion (1+) + iron = (Iron ion (1+) bullet iron)

By formula: Fe+ + Fe = (Fe+ bullet Fe)

Quantity Value Units Method Reference Comment
Deltar260.kJ/molCIDLoh, Lian, et al., 1988gas phase; M
Deltar261.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH>; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
268. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet iron) + Carbon monoxide = (Iron ion (1+) bullet Carbon monoxide bullet iron)

By formula: (Fe+ bullet Fe) + CO = (Fe+ bullet CO bullet Fe)

Quantity Value Units Method Reference Comment
Deltar245.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH<; M

(Iron ion (1+) bullet iron) + iron = (Iron ion (1+) bullet 2iron)

By formula: (Fe+ bullet Fe) + Fe = (Fe+ bullet 2Fe)

Quantity Value Units Method Reference Comment
Deltar233.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; «DELTA»rH<; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
169. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 2iron) + iron = (Iron ion (1+) bullet 3iron)

By formula: (Fe+ bullet 2Fe) + Fe = (Fe+ bullet 3Fe)

Quantity Value Units Method Reference Comment
Deltar174.kJ/molCIDLoh, Lian, et al., 1988gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
216. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 3iron) + iron = (Iron ion (1+) bullet 4iron)

By formula: (Fe+ bullet 3Fe) + Fe = (Fe+ bullet 4Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
260. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 4iron) + iron = (Iron ion (1+) bullet 5iron)

By formula: (Fe+ bullet 4Fe) + Fe = (Fe+ bullet 5Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
315. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 5iron) + iron = (Iron ion (1+) bullet 6iron)

By formula: (Fe+ bullet 5Fe) + Fe = (Fe+ bullet 6Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
320. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 6iron) + iron = (Iron ion (1+) bullet 7iron)

By formula: (Fe+ bullet 6Fe) + Fe = (Fe+ bullet 7Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
252. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 7iron) + iron = (Iron ion (1+) bullet 8iron)

By formula: (Fe+ bullet 7Fe) + Fe = (Fe+ bullet 8Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 8iron) + iron = (Iron ion (1+) bullet 9iron)

By formula: (Fe+ bullet 8Fe) + Fe = (Fe+ bullet 9Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
284. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 9iron) + iron = (Iron ion (1+) bullet 10iron)

By formula: (Fe+ bullet 9Fe) + Fe = (Fe+ bullet 10Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
308. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 10iron) + iron = (Iron ion (1+) bullet 11iron)

By formula: (Fe+ bullet 10Fe) + Fe = (Fe+ bullet 11Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
334. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 11iron) + iron = (Iron ion (1+) bullet 12iron)

By formula: (Fe+ bullet 11Fe) + Fe = (Fe+ bullet 12Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
408. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 12iron) + iron = (Iron ion (1+) bullet 13iron)

By formula: (Fe+ bullet 12Fe) + Fe = (Fe+ bullet 13Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 13iron) + iron = (Iron ion (1+) bullet 14iron)

By formula: (Fe+ bullet 13Fe) + Fe = (Fe+ bullet 14Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
377. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 14iron) + iron = (Iron ion (1+) bullet 15iron)

By formula: (Fe+ bullet 14Fe) + Fe = (Fe+ bullet 15Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
319. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 15iron) + iron = (Iron ion (1+) bullet 16iron)

By formula: (Fe+ bullet 15Fe) + Fe = (Fe+ bullet 16Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
323. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 16iron) + iron = (Iron ion (1+) bullet 17iron)

By formula: (Fe+ bullet 16Fe) + Fe = (Fe+ bullet 17Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
311. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 17iron) + iron = (Iron ion (1+) bullet 18iron)

By formula: (Fe+ bullet 17Fe) + Fe = (Fe+ bullet 18Fe)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
373. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + Water = (Iron ion (1+) bullet Water)

By formula: Fe+ + H2O = (Fe+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar120. ± 10.kJ/molCIDMagnera, David, et al., 1989gas phase; M
Deltar137.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
128. (+5.0,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet Water) + Water = (Iron ion (1+) bullet 2Water)

By formula: (Fe+ bullet H2O) + H2O = (Fe+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar171.kJ/molCIDMarinelli and Squires, 1989gas phase; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
164. (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 2Water) + Water = (Iron ion (1+) bullet 3Water)

By formula: (Fe+ bullet 2H2O) + H2O = (Fe+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
76.1 (+4.2,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) bullet 3Water) + Water = (Iron ion (1+) bullet 4Water)

By formula: (Fe+ bullet 3H2O) + H2O = (Fe+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
82.0 (+7.1,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Iron ion (1+) + Silylene = (Iron ion (1+) bullet Silylene)

By formula: Fe+ + H2Si = (Fe+ bullet H2Si)

Quantity Value Units Method Reference Comment
Deltar280. ± 50.kJ/molICRJacobson and Bakhtiar, 1993gas phase; M

Iron ion (1+) + Hydrogen = (Iron ion (1+) bullet Hydrogen)

By formula: Fe+ + H2 = (Fe+ bullet H2)

Quantity Value Units Method Reference Comment
Deltar52.3 ± 0.8kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 45.2 kJ/mol; M
Quantity Value Units Method Reference Comment
Deltar90.0J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 45.2 kJ/mol; M

(Iron ion (1+) bullet Hydrogen) + Hydrogen = (Iron ion (1+) bullet 2Hydrogen)

By formula: (Fe+ bullet H2) + H2 = (Fe+ bullet 2H2)

Quantity Value Units Method Reference Comment
Deltar71.1 ± 0.8kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 65.7 kJ/mol; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 65.7 kJ/mol; M

(Iron ion (1+) bullet 2Hydrogen) + Hydrogen = (Iron ion (1+) bullet 3Hydrogen)

By formula: (Fe+ bullet 2H2) + H2 = (Fe+ bullet 3H2)

Quantity Value Units Method Reference Comment
Deltar35. ± 0.4kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 31. kJ/mol; M
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 31. kJ/mol; M

(Iron ion (1+) bullet 3Hydrogen) + Hydrogen = (Iron ion (1+) bullet 4Hydrogen)

By formula: (Fe+ bullet 3H2) + H2 = (Fe+ bullet 4H2)

Quantity Value Units Method Reference Comment
Deltar41. ± 0.4kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 36. kJ/mol; M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 36. kJ/mol; M

(Iron ion (1+) bullet 4Hydrogen) + Hydrogen = (Iron ion (1+) bullet 5Hydrogen)

By formula: (Fe+ bullet 4H2) + H2 = (Fe+ bullet 5H2)

Quantity Value Units Method Reference Comment
Deltar11. ± 0.4kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 9.2 kJ/mol; M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 9.2 kJ/mol; M

(Iron ion (1+) bullet 5Hydrogen) + Hydrogen = (Iron ion (1+) bullet 6Hydrogen)

By formula: (Fe+ bullet 5H2) + H2 = (Fe+ bullet 6H2)

Quantity Value Units Method Reference Comment
Deltar11. ± 0.4kJ/molSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 9.6 kJ/mol; M
Quantity Value Units Method Reference Comment
Deltar75.7J/mol*KSIDTBushnell, Kemper, et al., 1995gas phase; «DELTA»rH(0K) = 9.6 kJ/mol; M

Iron ion (1+) + Ammonia = (Iron ion (1+) bullet Ammonia)

By formula: Fe+ + H3N = (Fe+ bullet H3N)

Quantity Value Units Method Reference Comment
Deltar183. ± 12.kJ/molCIDTWalter and Armentrout, 1998RCD
Deltar161.kJ/molCIDMarinelli and Squires, 1989gas phase; M

(Iron ion (1+) bullet Ammonia) + Ammonia = (Iron ion (1+) bullet 2Ammonia)

By formula: (Fe+ bullet H3N) + H3N = (Fe+ bullet 2H3N)

Quantity Value Units Method Reference Comment
Deltar225. ± 12.kJ/molCIDTWalter and Armentrout, 1998RCD
Deltar204.kJ/molCIDMarinelli and Squires, 1989gas phase; M

(Iron ion (1+) bullet 2Ammonia) + Ammonia = (Iron ion (1+) bullet 3Ammonia)

By formula: (Fe+ bullet 2H3N) + H3N = (Fe+ bullet 3H3N)

Quantity Value Units Method Reference Comment
Deltar68. ± 13.kJ/molCIDTWalter and Armentrout, 1998RCD

(Iron ion (1+) bullet 3Ammonia) + Ammonia = (Iron ion (1+) bullet 4Ammonia)

By formula: (Fe+ bullet 3H3N) + H3N = (Fe+ bullet 4H3N)

Quantity Value Units Method Reference Comment
Deltar41.8 ± 7.1kJ/molCIDTWalter and Armentrout, 1998RCD

Iron ion (1+) + Krypton = (Iron ion (1+) bullet Krypton)

By formula: Fe+ + Kr = (Fe+ bullet Kr)

Quantity Value Units Method Reference Comment
Deltar30. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Nitrogen = (Iron ion (1+) bullet Nitrogen)

By formula: Fe+ + N2 = (Fe+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar54.0 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet Nitrogen) + Nitrogen = (Iron ion (1+) bullet 2Nitrogen)

By formula: (Fe+ bullet N2) + N2 = (Fe+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar82.8 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet 2Nitrogen) + Nitrogen = (Iron ion (1+) bullet 3Nitrogen)

By formula: (Fe+ bullet 2N2) + N2 = (Fe+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar45. ± 3.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet 3Nitrogen) + Nitrogen = (Iron ion (1+) bullet 4Nitrogen)

By formula: (Fe+ bullet 3N2) + N2 = (Fe+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar54.0 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) bullet 4Nitrogen) + Nitrogen = (Iron ion (1+) bullet 5Nitrogen)

By formula: (Fe+ bullet 4N2) + N2 = (Fe+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar61.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Iron ion (1+) + Xenon = (Iron ion (1+) bullet Xenon)

By formula: Fe+ + Xe = (Fe+ bullet Xe)

Quantity Value Units Method Reference Comment
Deltar41.8 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Fisher, Schultz, et al., 1989
Fisher, E.R.; Schultz, r.H.; Armentrout, P.B., Guided Ion Beam Studies of the State - Specific Reactions of Fe+(6D,4F) with CH3X (X = Cl, Br, I), J. Phys. Chem., 1989, 93, 21, 7382, https://doi.org/10.1021/j100358a027 . [all data]

Schultz, Elkind, et al., 1988
Schultz, R.H.; Elkind, J.L.; Armentrout, P.B., Electronic Effects in C-H and C-C Bond Activation: State-Specific Reactions of Fe+(6D,4F) with Methane, Ethane and Propane, J. Am. Chem. Soc., 1988, 110, 2, 411, https://doi.org/10.1021/ja00210a017 . [all data]

Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R., Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Carpenter, van Koppen, et al., 1995
Carpenter, C.J.; van Koppen, P.A.M.; Bowers, M.T., Details of Potential Energy Surfaces Involving C-C Bond Activation: Reactions of Fe+, Co+ and Ni+ with Acetone, J. Am. Chem. Soc., 1995, 117, 44, 10976, https://doi.org/10.1021/ja00149a021 . [all data]

Tecklenberg, Bricker, et al., 1988
Tecklenberg, R.E.; Bricker, D.L.; Russel, D.H., Laser - Ion Beam Photodissociation Studies of Ionic Cluster Fragments of Iron Carbonyls: Fe(x)(CO)y+ (x = 1 - 3; y = 0 - 6), Organometallics, 1988, 7, 12, 2506, https://doi.org/10.1021/om00102a013 . [all data]

Schroeder, Kretzschmar, et al., 1999
Schroeder, D.; Kretzschmar, I.; Schwarz; Rue, C.; Armentrout, P.B., On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2, Inorg. Chem., 1999, 38, 15, 3474, https://doi.org/10.1021/ic990241b . [all data]

Surya, Ranatunga, et al., 1997
Surya, P.I.; Ranatunga, D.R.A.; Freiser, B.S., Infrared Multiphoton Dissociation of MC4H6+ [M=Fe, Co or Ni: C4H6=1,3-butadiene or (C2H2)(C2H4), J. Am. Chem. Soc., 1997, 119, 14, 3351, https://doi.org/10.1021/ja963200c . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Gapeev and Dunbar, 2002
Gapeev, A.; Dunbar, R.C., Reactivity and Binding Energies of Transition Metal Halide Ions with Benzene, J. Am. Soc. Mass Spectrom., 2002, 13, 5, 477, https://doi.org/10.1016/S1044-0305(02)00373-2 . [all data]

Meyer, Khan, et al., 1995
Meyer, F.; Khan, F.A.; Armentrout, P.B., Thermochemistry of Transition Metal Benzene complexes: Binding energies of M(C6H6)x+ (x = 1,2) for M = Ti to Cu, J. Am. Chem. Soc., 1995, 117, 38, 9740, https://doi.org/10.1021/ja00143a018 . [all data]

Loh, Lian, et al., 1988
Loh, S.K.; Lian, L.; Hales, D.A.; Armentrout, P.B., Collision - Induced Dissociation Processes of Nb4+ and Fe4+: Fission vs Evaporation, J. Chem. Phys., 1988, 89, 1, 610, https://doi.org/10.1063/1.455455 . [all data]

Magnera, David, et al., 1989
Magnera, T.F.; David, D.E.; Michl, J., Gas -Phase Water and Hydroxyl Binding Energies for Monopoisitive First - Row Transition - Metal Ions, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a051 . [all data]

Marinelli and Squires, 1989
Marinelli, P.J.; Squires, R.R., Sequential Solvation of Atomic Transition Metal Ions: The Second Solvent Molecule Can Bind More Strongly than the First, J. Am. Chem. Soc., 1989, 111, 11, 4101, https://doi.org/10.1021/ja00193a052 . [all data]

Bushnell, Kemper, et al., 1995
Bushnell, J.E.; Kemper, P.R.; Bowers, M.T., Factors Affecting sigma Bond Activation in Simple Systems; Measurement of Experimental Binding energies of Fe+(H2)1-6 Clusters, J. Phys. Chem., 1995, 99, 42, 15602, https://doi.org/10.1021/j100042a040 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]


Notes

Go To: Top, Ion clustering data, References