Formamide, N,N-dimethyl-

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Condensed phase thermochemistry data

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-57.21 ± 0.29kcal/molCcbVasil'eva, Zhil'tsova, et al., 1972ALS
Δfliquid-57.13kcal/molCcbMedard and Thomas, 1957Heat of combustion corrected for pressure; ALS
Quantity Value Units Method Reference Comment
Δcliquid-464.06 ± 0.29kcal/molCcbVasil'eva, Zhil'tsova, et al., 1972ALS
Δcliquid-464.13kcal/molCcbMedard and Thomas, 1957Heat of combustion corrected for pressure; ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
34.907298.15Grolier, Roux-Desgranges, et al., 1993DH
35.411298.15Kolker, Kulikov, et al., 1992T = 283 to 323 K.; DH
35.679308.Kulikov, Krestov, et al., 1989DH
35.85298.15Petrov, Peshekhodov, et al., 1989T = 258.15, 278.15, 298.15, 318.15 K.; DH
35.459298.15Zegers and Somsen, 1984DH
35.97298.15Vorob'ev and Yakovlev, 1982T = 297.15 to 299.15 K. Cp given as 2.059 J/g*K.; DH
36.04298.15de Visser and Somsen, 1979DH
28.80298.Marchidan and Ciopec, 1978T = 298 to 427 K. Mean value over range.; DH
35.4298.15De Visser, Perron, et al., 1977DH
35.4298.De Visser, Perron, et al., 1977One temperature only.; DH
36.04298.15De Visser, Perron, et al., 1977, 2DH
34.9298.15Bonner and Cerutti, 1976DH
36.33298.15de Visser and Somsen, 1974DH
37.450298.Geller, 1961T = 273 to 323 K.; DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil426. ± 1.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus212.7KN/ADreisbach, 1955Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc649.6KN/ATeja and Anselme, 1990Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
ρc3.82mol/lN/ATeja and Anselme, 1990Uncertainty assigned by TRC = 0.08 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap11.2 ± 0.1kcal/molCGCPanneerselvam, Antony, et al., 2009Based on data from 463. to 513. K.; AC
Δvap11.2kcal/molABarone, Castronuovo, et al., 1985See also Majer and Svoboda, 1985.; AC
Δvap11.37kcal/molEGeller, 1961, 2ALS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
10.3361.N/AMuñoz, Montón, et al., 2005Based on data from 346. to 425. K.; AC
9.99392.N/ABlanco, Beltrán, et al., 1997Based on data from 377. to 426. K.; AC
10.4353.N/AMarzal, Gabaldon, et al., 1995Based on data from 338. to 425. K.; AC
11.8316.AStephenson and Malanowski, 1987Based on data from 301. to 426. K.; AC
10.2370.N/ABludilina, Baev, et al., 1979Based on data from 318. to 423. K.; AC
13.6346.N/AMyasinkova, Schmelev, et al., 1974Based on data from 331. to 425. K. See also Boublik, Fried, et al., 1984.; AC
11.2318.N/AGopal and Rizvi, 1968Based on data from 303. to 363. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
303. to 363.3.924971337.716-82.648Gopal and Rizvi, 1968, 2Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
2.139212.85N/AKaryakin, Rabinovich, et al., 1978DH
2.14212.9ACSmirnova, Tsvetkova, et al., 2007AC
2.14212.9N/ADomalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
9.99212.85Karyakin, Rabinovich, et al., 1978DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C7H7NO3- + Formamide, N,N-dimethyl- = (C7H7NO3- • Formamide, N,N-dimethyl-)

By formula: C7H7NO3- + C3H7NO = (C7H7NO3- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr5.9 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.9343.PHPMSChowdhury, 1987gas phase; M
5.9343.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Formamide, N,N-dimethyl- = (C6H5NO2- • Formamide, N,N-dimethyl-)

By formula: C6H5NO2- + C3H7NO = (C6H5NO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr6.2 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- • Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr3.9 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.9343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- • Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr5.9 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.9343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- • Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr5.9 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.9343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- • Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr5.6 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.6343.PHPMSChowdhury, 1987gas phase; M

C7H7NO3- + Formamide, N,N-dimethyl- = (C7H7NO3- • Formamide, N,N-dimethyl-)

By formula: C7H7NO3- + C3H7NO = (C7H7NO3- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr6.2 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Formamide, N,N-dimethyl- = (C7H7NO2- • Formamide, N,N-dimethyl-)

By formula: C7H7NO2- + C3H7NO = (C7H7NO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr6.2 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Formamide, N,N-dimethyl- = (C6H4N2O4- • Formamide, N,N-dimethyl-)

By formula: C6H4N2O4- + C3H7NO = (C6H4N2O4- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr2.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.5343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Formamide, N,N-dimethyl- = (C6H4N2O4- • Formamide, N,N-dimethyl-)

By formula: C6H4N2O4- + C3H7NO = (C6H4N2O4- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Formamide, N,N-dimethyl- = (C7H7NO2- • Formamide, N,N-dimethyl-)

By formula: C7H7NO2- + C3H7NO = (C7H7NO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

C6F4O2- + Formamide, N,N-dimethyl- = (C6F4O2- • Formamide, N,N-dimethyl-)

By formula: C6F4O2- + C3H7NO = (C6F4O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr2.7 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.7343.PHPMSChowdhury, 1987gas phase; M

p-Benzoquinone anion + Formamide, N,N-dimethyl- = (p-Benzoquinone anion • Formamide, N,N-dimethyl-)

By formula: C6H4O2- + C3H7NO = (C6H4O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.3343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- • Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.8343.PHPMSChowdhury, 1987gas phase; M

Potassium ion (1+) + Formamide, N,N-dimethyl- = (Potassium ion (1+) • Formamide, N,N-dimethyl-)

By formula: K+ + C3H7NO = (K+ • C3H7NO)

Quantity Value Units Method Reference Comment
Δr29.5kcal/molCIDTKlassen, Anderson, et al., 1996RCD
Δr31.kcal/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr26.cal/mol*KHPMSSunner, 1984gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- • Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5343.PHPMSChowdhury, 1987gas phase; M

C7H4F3NO2- + Formamide, N,N-dimethyl- = (C7H4F3NO2- • Formamide, N,N-dimethyl-)

By formula: C7H4F3NO2- + C3H7NO = (C7H4F3NO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.8343.PHPMSChowdhury, 1987gas phase; M

Sodium ion (1+) + Formamide, N,N-dimethyl- = (Sodium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Na+ + C3H7NO = (Na+ • C3H7NO)

Quantity Value Units Method Reference Comment
Δr37.4 ± 0.9kcal/molCIDTArmentrout and Rodgers, 2000See 96KLA/AND?; RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
30.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

C3H6NO- + Hydrogen cation = Formamide, N,N-dimethyl-

By formula: C3H6NO- + H+ = C3H7NO

Quantity Value Units Method Reference Comment
Δr399.1 ± 4.1kcal/molG+TSDePuy, Grabowski, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Δr392.0 ± 4.0kcal/molIMRBDePuy, Grabowski, et al., 1985gas phase; B

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ • C3H7NO)

Quantity Value Units Method Reference Comment
Δr50.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

(Potassium ion (1+) • 2Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) • 3Formamide, N,N-dimethyl-)

By formula: (K+ • 2C3H7NO) + C3H7NO = (K+ • 3C3H7NO)

Quantity Value Units Method Reference Comment
Δr15.kcal/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr18.cal/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) • 3Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) • 4Formamide, N,N-dimethyl-)

By formula: (K+ • 3C3H7NO) + C3H7NO = (K+ • 4C3H7NO)

Quantity Value Units Method Reference Comment
Δr13.kcal/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr24.cal/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) • Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) • 2Formamide, N,N-dimethyl-)

By formula: (K+ • C3H7NO) + C3H7NO = (K+ • 2C3H7NO)

Quantity Value Units Method Reference Comment
Δr21.kcal/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KHPMSSunner, 1984gas phase; M

Gas phase ion energetics data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C3H7NO+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)9.13eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)212.1kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity204.7kcal/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Reference Comment
0.01362Desfrancois, Periquet, et al., 1999B

Ionization energy determinations

IE (eV) Method Reference Comment
9.45 ± 0.05EIBaldwin, Loudon, et al., 1977LLK
9.14PEBrundle, Turner, et al., 1969RDSH
9.12 ± 0.02PIWatanabe, Nakayama, et al., 1962RDSH
9.14PEBieri, Asbrink, et al., 1982Vertical value; LBLHLM
9.25PEHenriksen, Isaksson, et al., 1981Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+14.50?EILoudon and Webb, 1977LLK
CHO+14.3 ± 0.1?EIGowenlock, Jones, et al., 1961RDSH
C2H6N+11.60?EILoudon and Webb, 1977LLK
C2H6N+11.6 ± 0.1?EIGowenlock, Jones, et al., 1961RDSH
C3H6NO+11.35?EILoudon and Webb, 1977LLK

De-protonation reactions

C3H6NO- + Hydrogen cation = Formamide, N,N-dimethyl-

By formula: C3H6NO- + H+ = C3H7NO

Quantity Value Units Method Reference Comment
Δr399.1 ± 4.1kcal/molG+TSDePuy, Grabowski, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Δr392.0 ± 4.0kcal/molIMRBDePuy, Grabowski, et al., 1985gas phase; B

Ion clustering data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C6F4O2- + Formamide, N,N-dimethyl- = (C6F4O2- • Formamide, N,N-dimethyl-)

By formula: C6F4O2- + C3H7NO = (C6F4O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr2.7 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.7343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- • Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr5.9 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.9343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- • Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr5.9 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.9343.PHPMSChowdhury, 1987gas phase; M

C6H4FNO2- + Formamide, N,N-dimethyl- = (C6H4FNO2- • Formamide, N,N-dimethyl-)

By formula: C6H4FNO2- + C3H7NO = (C6H4FNO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr5.6 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.6343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Formamide, N,N-dimethyl- = (C6H4N2O4- • Formamide, N,N-dimethyl-)

By formula: C6H4N2O4- + C3H7NO = (C6H4N2O4- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr2.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
2.5343.PHPMSChowdhury, 1987gas phase; M

C6H4N2O4- + Formamide, N,N-dimethyl- = (C6H4N2O4- • Formamide, N,N-dimethyl-)

By formula: C6H4N2O4- + C3H7NO = (C6H4N2O4- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5343.PHPMSChowdhury, 1987gas phase; M

p-Benzoquinone anion + Formamide, N,N-dimethyl- = (p-Benzoquinone anion • Formamide, N,N-dimethyl-)

By formula: C6H4O2- + C3H7NO = (C6H4O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.3343.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Formamide, N,N-dimethyl- = (C6H5NO2- • Formamide, N,N-dimethyl-)

By formula: C6H5NO2- + C3H7NO = (C6H5NO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr6.2 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2343.PHPMSChowdhury, 1987gas phase; M

C7H4F3NO2- + Formamide, N,N-dimethyl- = (C7H4F3NO2- • Formamide, N,N-dimethyl-)

By formula: C7H4F3NO2- + C3H7NO = (C7H4F3NO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.8343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- • Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.5 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- • Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr4.8 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.8343.PHPMSChowdhury, 1987gas phase; M

C7H4N2O2- + Formamide, N,N-dimethyl- = (C7H4N2O2- • Formamide, N,N-dimethyl-)

By formula: C7H4N2O2- + C3H7NO = (C7H4N2O2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr3.9 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.9343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Formamide, N,N-dimethyl- = (C7H7NO2- • Formamide, N,N-dimethyl-)

By formula: C7H7NO2- + C3H7NO = (C7H7NO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr6.2 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2343.PHPMSChowdhury, 1987gas phase; M

C7H7NO2- + Formamide, N,N-dimethyl- = (C7H7NO2- • Formamide, N,N-dimethyl-)

By formula: C7H7NO2- + C3H7NO = (C7H7NO2- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

C7H7NO3- + Formamide, N,N-dimethyl- = (C7H7NO3- • Formamide, N,N-dimethyl-)

By formula: C7H7NO3- + C3H7NO = (C7H7NO3- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr5.9 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
5.9343.PHPMSChowdhury, 1987gas phase; M
5.9343.PHPMSChowdhury, 1987gas phase; M

C7H7NO3- + Formamide, N,N-dimethyl- = (C7H7NO3- • Formamide, N,N-dimethyl-)

By formula: C7H7NO3- + C3H7NO = (C7H7NO3- • C3H7NO)

Quantity Value Units Method Reference Comment
Δr6.2 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2343.PHPMSChowdhury, 1987gas phase; M

Potassium ion (1+) + Formamide, N,N-dimethyl- = (Potassium ion (1+) • Formamide, N,N-dimethyl-)

By formula: K+ + C3H7NO = (K+ • C3H7NO)

Quantity Value Units Method Reference Comment
Δr29.5kcal/molCIDTKlassen, Anderson, et al., 1996RCD
Δr31.kcal/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr26.cal/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) • Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) • 2Formamide, N,N-dimethyl-)

By formula: (K+ • C3H7NO) + C3H7NO = (K+ • 2C3H7NO)

Quantity Value Units Method Reference Comment
Δr21.kcal/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr20.cal/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) • 2Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) • 3Formamide, N,N-dimethyl-)

By formula: (K+ • 2C3H7NO) + C3H7NO = (K+ • 3C3H7NO)

Quantity Value Units Method Reference Comment
Δr15.kcal/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr18.cal/mol*KHPMSSunner, 1984gas phase; M

(Potassium ion (1+) • 3Formamide, N,N-dimethyl-) + Formamide, N,N-dimethyl- = (Potassium ion (1+) • 4Formamide, N,N-dimethyl-)

By formula: (K+ • 3C3H7NO) + C3H7NO = (K+ • 4C3H7NO)

Quantity Value Units Method Reference Comment
Δr13.kcal/molHPMSSunner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr24.cal/mol*KHPMSSunner, 1984gas phase; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ • C3H7NO)

Quantity Value Units Method Reference Comment
Δr50.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Sodium ion (1+) + Formamide, N,N-dimethyl- = (Sodium ion (1+) • Formamide, N,N-dimethyl-)

By formula: Na+ + C3H7NO = (Na+ • C3H7NO)

Quantity Value Units Method Reference Comment
Δr37.4 ± 0.9kcal/molCIDTArmentrout and Rodgers, 2000See 96KLA/AND?; RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
30.1298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vasil'eva, Zhil'tsova, et al., 1972
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Bludilina, Baev, et al., 1979
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Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References