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Methyl Alcohol

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Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Deltafgas (kJ/mol) Method Reference Comment
-201.EqkHine and Arata, 1976ALS
-200.6N/ABaroody and Carpenter, 1972Value computed using «DELTA»fHliquid° value of -238.4 kj/mol from Baroody and Carpenter, 1972 and «DELTA»vapH° value of 37.8 kj/mol from Green, 1960.; DRB
-201.1 ± 5.0CcrBaroody and Carpenter, 1972Value computed using «DELTA»fHliquid° from Baroody and Carpenter, 1972 and «DELTA»vapH° value of 37.3 kJ/mol from Wadso, 1966. estimated uncertainty; DRB
-201.7N/AChao and Rossini, 1965Value computed using «DELTA»fHliquid° value of -239.5±0.2 kj/mol from Chao and Rossini, 1965 and «DELTA»vapH° value of 37.8 kj/mol from Green, 1960.; DRB
-202.2 ± 0.2CcbChao and Rossini, 1965Value computed using «DELTA»fHliquid° from Chao and Rossini, 1965 and «DELTA»vapH° value of 37.3 kJ/mol from Wadso, 1966.; DRB
-201.1 ± 0.2CcbGreen, 1960ALS
-212.8N/AParks, 1925Value computed using «DELTA»fHliquid° value of -250.6 kj/mol from Parks, 1925 and «DELTA»vapH° value of 37.8 kj/mol from Green, 1960.; DRB
-213.3 ± 2.0CcbParks, 1925Value computed using «DELTA»fHliquid° from Parks, 1925 and «DELTA»vapH° value of 37.3 kJ/mol from Wadso, 1966. estimated uncertainty; DRB
-214.0 ± 5.0CcbRichards and Davis, 1920Value computed using «DELTA»fHliquid° from Richards and Davis, 1920 and «DELTA»vapH° value of 37.3 kJ/mol from Wadso, 1966. estimated uncertainty; DRB

References

Go To: Top, Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hine and Arata, 1976
Hine, J.; Arata, K., Keto-Enol tautomerism. II. The calorimetrical determination of the equilibrium constants for keto-enol tautomerism for cyclohexanone, Bull. Chem. Soc. Jpn., 1976, 49, 3089-3092. [all data]

Baroody and Carpenter, 1972
Baroody, E.E.; Carpenter, G.A., Heats of formation of propellant compounds (U), Rpt. Naval Ordnance Systems Command Task No. 331-003/067-1/UR2402-001 for Naval Ordance Station, Indian Head, MD, 1972, 1-9. [all data]

Green, 1960
Green, J.H.S., Revision of the values of the heats of formation of normal alcohols, Chem. Ind. (London), 1960, 1215-1216. [all data]

Wadso, 1966
Wadso, I., Acta Chem. Scand., 1966, 20, 544. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Parks, 1925
Parks, G.S., Thermal data on organic compounds I. The heat capacities and free energies of methyl, ethyl and normal-butyl alcohols, J. Am. Chem. Soc., 1925, 47, 338-345. [all data]

Richards and Davis, 1920
Richards, T.W.; Davis, H.S., The heats of combustion of benzene, toluene, aliphatic alcohols, cyclohexanol, and other carbon compounds, J. Am. Chem. Soc., 1920, 42, 1599-1617. [all data]


Notes

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