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Methyl Alcohol

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 100

(Bromine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 10Methyl Alcohol)

By formula: (Br- bullet 9CH4O) + CH4O = (Br- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar33. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar4.6 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Iodide bullet 7Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 8Methyl Alcohol)

By formula: (I- bullet 7CH4O) + CH4O = (I- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar3. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

(Bromine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 9Methyl Alcohol)

By formula: (Br- bullet 8CH4O) + CH4O = (Br- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar34. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar5.4 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

C2H- + Methyl Alcohol = C3H5O-

By formula: C2H- + CH4O = C3H5O-

Quantity Value Units Method Reference Comment
Deltar90.4 ± 8.4kJ/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B
Quantity Value Units Method Reference Comment
Deltar45.61kJ/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar48.5 ± 8.4kJ/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B

C9H7- + Methyl Alcohol = C10H11O-

By formula: C9H7- + CH4O = C10H11O-

Quantity Value Units Method Reference Comment
Deltar90.4 ± 8.4kJ/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B
Quantity Value Units Method Reference Comment
Deltar42.68kJ/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar46.4 ± 8.4kJ/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B

C6H9- + Methyl Alcohol = C7H13O-

By formula: C6H9- + CH4O = C7H13O-

Quantity Value Units Method Reference Comment
Deltar87.0 ± 8.4kJ/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B
Quantity Value Units Method Reference Comment
Deltar48.12kJ/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
Deltar44.8 ± 8.4kJ/molIMREChabinyc and Brauman, 1999gas phase; Anchored to MeOH «DELTA»Gacid=375.2; B

C7H4N2O2- + Methyl Alcohol = (C7H4N2O2- bullet Methyl Alcohol)

By formula: C7H4N2O2- + CH4O = (C7H4N2O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar58.2 ± 8.4kJ/molN/AChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B,M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSChowdhury, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar17. ± 8.4kJ/molTDAsChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C6H4FNO2- + Methyl Alcohol = (C6H4FNO2- bullet Methyl Alcohol)

By formula: C6H4FNO2- + CH4O = (C6H4FNO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar66.1 ± 8.4kJ/molN/AChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B,M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KPHPMSChowdhury, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar23. ± 8.4kJ/molTDAsChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

C7H7NO3- + Methyl Alcohol = (C7H7NO3- bullet Methyl Alcohol)

By formula: C7H7NO3- + CH4O = (C7H7NO3- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar59.8 ± 8.4kJ/molN/AChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B,M
Quantity Value Units Method Reference Comment
Deltar97.9J/mol*KPHPMSChowdhury, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar26. ± 8.4kJ/molTDAsChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Tetramethyl orthocarbonate + Water = Carbonic acid, dimethyl ester + 2Methyl Alcohol

By formula: C5H12O4 + H2O = C3H6O3 + 2CH4O

Quantity Value Units Method Reference Comment
Deltar31.47 ± 0.046kJ/molCmWiberg, 1980liquid phase; solvent: Water; Hydroysis; ALS
Deltar-31.466 ± 0.044kJ/molCmWiberg and Squires, 1979liquid phase; solvent: Water; Hydrolysis; ALS
Deltar-31.1 ± 1.7kJ/molCmHine and Klueppet, 1974liquid phase; ALS

Propane, 1,1,1-trimethoxy- + Water = Methyl propionate + 2Methyl Alcohol

By formula: C6H14O3 + H2O = C4H8O2 + 2CH4O

Quantity Value Units Method Reference Comment
Deltar-26.12 ± 0.067kJ/molCmWiberg, Martin, et al., 1985liquid phase; solvent: Aqueous dioxane; ALS
Deltar-51.76 ± 0.54kJ/molEqkGuthrie and Cullimore, 1980liquid phase; ALS
Deltar-26.28 ± 0.071kJ/molCmWiberg, 1980liquid phase; solvent: Water; Hydrolysis; ALS

(CH5O+ bullet 10Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 11Methyl Alcohol)

By formula: (CH5O+ bullet 10CH4O) + CH4O = (CH5O+ bullet 11CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
16.184.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 11Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 12Methyl Alcohol)

By formula: (CH5O+ bullet 11CH4O) + CH4O = (CH5O+ bullet 12CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.184.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 12Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 13Methyl Alcohol)

By formula: (CH5O+ bullet 12CH4O) + CH4O = (CH5O+ bullet 13CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
16.184.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 9Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 10Methyl Alcohol)

By formula: (CH5O+ bullet 9CH4O) + CH4O = (CH5O+ bullet 10CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.200.PHPMSMeot-Ner (Mautner), 1992gas phase; M

(CH5O+ bullet 8Methyl Alcohol) + Methyl Alcohol = (CH5O+ bullet 9Methyl Alcohol)

By formula: (CH5O+ bullet 8CH4O) + CH4O = (CH5O+ bullet 9CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
16.200.PHPMSMeot-Ner (Mautner), 1992gas phase; M

Fluorine anion + Methyl Alcohol = CH3D4FO-

By formula: F- + CH4O = CH3D4FO-

Quantity Value Units Method Reference Comment
Deltar125. ± 8.4kJ/molTDEqWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B
Quantity Value Units Method Reference Comment
Deltar93.7 ± 8.4kJ/molTDEqWilkinson, Szulejko, et al., 1992gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B

(Oxygen anion bullet 2Methyl Alcohol) + Methyl Alcohol = (Oxygen anion bullet 3Methyl Alcohol)

By formula: (O2- bullet 2CH4O) + CH4O = (O2- bullet 3CH4O)

Quantity Value Units Method Reference Comment
Deltar56.5 ± 2.9kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar21.8 ± 1.3kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Oxygen anion bullet Methyl Alcohol) + Methyl Alcohol = (Oxygen anion bullet 2Methyl Alcohol)

By formula: (O2- bullet CH4O) + CH4O = (O2- bullet 2CH4O)

Quantity Value Units Method Reference Comment
Deltar64.9 ± 3.3kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar33.9 ± 1.7kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Fluorine anion bullet 10Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 11Methyl Alcohol)

By formula: (F- bullet 10CH4O) + CH4O = (F- bullet 11CH4O)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.2 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Chlorine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 10Methyl Alcohol)

By formula: (Cl- bullet 9CH4O) + CH4O = (Cl- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar31. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.1J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Fluorine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 4Methyl Alcohol)

By formula: (F- bullet 3CH4O) + CH4O = (F- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar52.3 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar98.3J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar23. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 5Methyl Alcohol)

By formula: (F- bullet 4CH4O) + CH4O = (F- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar16. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 6Methyl Alcohol)

By formula: (F- bullet 5CH4O) + CH4O = (F- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar11. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 9Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 10Methyl Alcohol)

By formula: (F- bullet 9CH4O) + CH4O = (F- bullet 10CH4O)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.4 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Chlorine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 6Methyl Alcohol)

By formula: (Cl- bullet 5CH4O) + CH4O = (Cl- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar92.9J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 7Methyl Alcohol)

By formula: (Cl- bullet 6CH4O) + CH4O = (Cl- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar33. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar84.1J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 8Methyl Alcohol)

By formula: (Cl- bullet 7CH4O) + CH4O = (Cl- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Chlorine anion bullet 9Methyl Alcohol)

By formula: (Cl- bullet 8CH4O) + CH4O = (Cl- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar86.2J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Fluorine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 7Methyl Alcohol)

By formula: (F- bullet 6CH4O) + CH4O = (F- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.2 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 8Methyl Alcohol)

By formula: (F- bullet 7CH4O) + CH4O = (F- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion bullet 8Methyl Alcohol) + Methyl Alcohol = (Fluorine anion bullet 9Methyl Alcohol)

By formula: (F- bullet 8CH4O) + CH4O = (F- bullet 9CH4O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.3 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 3Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 4Methyl Alcohol)

By formula: (I- bullet 3CH4O) + CH4O = (I- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 4Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 5Methyl Alcohol)

By formula: (I- bullet 4CH4O) + CH4O = (I- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar40. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.3 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 5Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 6Methyl Alcohol)

By formula: (I- bullet 5CH4O) + CH4O = (I- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar40. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.9 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide bullet 6Methyl Alcohol) + Methyl Alcohol = (Iodide bullet 7Methyl Alcohol)

By formula: (I- bullet 6CH4O) + CH4O = (I- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar39. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.6 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 3Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 4Methyl Alcohol)

By formula: (Br- bullet 3CH4O) + CH4O = (Br- bullet 4CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar13. ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 4Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 5Methyl Alcohol)

By formula: (Br- bullet 4CH4O) + CH4O = (Br- bullet 5CH4O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 5Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 6Methyl Alcohol)

By formula: (Br- bullet 5CH4O) + CH4O = (Br- bullet 6CH4O)

Quantity Value Units Method Reference Comment
Deltar38. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar98.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.8 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 6Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 7Methyl Alcohol)

By formula: (Br- bullet 6CH4O) + CH4O = (Br- bullet 7CH4O)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.1 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion bullet 7Methyl Alcohol) + Methyl Alcohol = (Bromine anion bullet 8Methyl Alcohol)

By formula: (Br- bullet 7CH4O) + CH4O = (Br- bullet 8CH4O)

Quantity Value Units Method Reference Comment
Deltar35. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar6.3 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1991gas phase; B

2-Methyl-1-butene + Methyl Alcohol = Butane, 2-methoxy-2-methyl-

By formula: C5H10 + CH4O = C6H14O

Quantity Value Units Method Reference Comment
Deltar-35.8kJ/molEqkSerda, Izquierdo, et al., 1995liquid phase; ALS
Deltar-20.4 ± 0.8kJ/molEqkHwang and Wu, 1994liquid phase; ALS
Deltar-33.6 ± 5.1kJ/molEqkRihko, Linnekoski, et al., 1994liquid phase; solvent: Alcohol/alkane mixture; ALS

(C2H7O+ bullet 2Methyl Alcohol bullet Dimethyl ether) + Methyl Alcohol = (C2H7O+ bullet 3Methyl Alcohol bullet Dimethyl ether)

By formula: (C2H7O+ bullet 2CH4O bullet C2H6O) + CH4O = (C2H7O+ bullet 3CH4O bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar51.0kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar111.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet Methyl Alcohol bullet Dimethyl ether) + Methyl Alcohol = (C2H7O+ bullet 2Methyl Alcohol bullet Dimethyl ether)

By formula: (C2H7O+ bullet CH4O bullet C2H6O) + CH4O = (C2H7O+ bullet 2CH4O bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar63.2kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar128.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C16H34OP2Ru (solution) + Methyl Alcohol (solution) = C17H36OP2Ru (solution) + Water (solution)

By formula: C16H34OP2Ru (solution) + CH4O (solution) = C17H36OP2Ru (solution) + H2O (solution)

Quantity Value Units Method Reference Comment
Deltar0.kJ/molESTBryndza, Fong, et al., 1987solvent: Tetrahydrofuran; The reaction enthalpy was identified with the reaction Gibbs energy, since the the entropy is expected to be small Bryndza, Fong, et al., 1987; MS

Nitrogen oxide anion + Methyl Alcohol = (Nitrogen oxide anion bullet Methyl Alcohol)

By formula: NO2- + CH4O = (NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar72.80 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar40.6 ± 1.7kJ/molTDAsSieck, 1985gas phase; B

Oxygen anion + Methyl Alcohol = (Oxygen anion bullet Methyl Alcohol)

By formula: O2- + CH4O = (O2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar79.91kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar52.30kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

HCO2 anion + Methyl Alcohol = (HCO2 anion bullet Methyl Alcohol)

By formula: CHO2- + CH4O = (CHO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar73.6 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar98.7J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar43.9 ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B

(C2H7O+ bullet 2Methyl Alcohol) + Dimethyl ether = (C2H7O+ bullet Dimethyl ether bullet 2Methyl Alcohol)

By formula: (C2H7O+ bullet 2CH4O) + C2H6O = (C2H7O+ bullet C2H6O bullet 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar69.5kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar133.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 3Methyl Alcohol) + Dimethyl ether = (C2H7O+ bullet Dimethyl ether bullet 3Methyl Alcohol)

By formula: (C2H7O+ bullet 3CH4O) + C2H6O = (C2H7O+ bullet C2H6O bullet 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Chabinyc and Brauman, 1999
Chabinyc, M.L.; Brauman, J.I., Hydrogen bond strength and acidity. Structural and energetic correlations for acetylides and alcohols, J. Phys. Chem. A, 1999, 103, 46, 9163-9166, https://doi.org/10.1021/jp992852v . [all data]

Mustanir, Matsuoka, et al., 2006
Mustanir; Matsuoka, M.; Mishima, M.; Koch, H., Stability of complexes of phenylacetylides and benzyl alkoxides with methanol in the gas phase. Acid-base correlation in the ionic hydrogen-bond strength, Bull. Chem. Soc. Japan, 2006, 79, 7, 1118-1125, https://doi.org/10.1246/bcsj.79.1118 . [all data]

Chowdhury, Grimsrud, et al., 1987
Chowdhury, S.; Grimsrud, E.P.; Kebarle, P., Bonding of Charged Delocalized Anions to Protic and Dipolar Aprotic Solvent Molecules, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Chowdhury, 1987
Chowdhury, S. Grimsrud, Bonding of Charge Delocalized Anions to Protic and Dipolar Aprotic Solvents, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Wiberg, 1980
Wiberg, K.B., Energies of organic compounds, Rept. DOE-E(11-1)4060 Prepared for US Dept. of Energy by Yale Univ., New Haven, CT. Avail. NTIS, 1980, 1-24. [all data]

Wiberg and Squires, 1979
Wiberg, K.B.; Squires, R.R., A microprocessor-controlled system for precise measurement of temperature changes. Determination of the enthalpies of hydrolysis of some polyoxygenated hydrocarbons, J. Chem. Thermodyn., 1979, 11, 773-786. [all data]

Hine and Klueppet, 1974
Hine, J.; Klueppet, A.W., Structural effects on rates and equilibria. XVIII. Thermodynamic stability of ortho esters, J. Am. Chem. Soc., 1974, 96, 2924-2929. [all data]

Wiberg, Martin, et al., 1985
Wiberg, K.B.; Martin, E.J.; Squires, R.R., Thermochemical studies of carbonyl compounds. 3. Enthalpies of hydrolysis of ortho esters, J. Org. Chem., 1985, 50, 4717-4720. [all data]

Guthrie and Cullimore, 1980
Guthrie, J.P.; Cullimore, P.A., Effect of the acyl substituent on the equilibrium constant for hydration of esters, Can. J. Chem., 1980, 58, 1281-1294. [all data]

Meot-Ner (Mautner), 1992
Meot-Ner (Mautner), M., Intermolecular Forces in Organic Clusters, J. Am. Chem. Soc., 1992, 114, 9, 3312, https://doi.org/10.1021/ja00035a024 . [all data]

Wilkinson, Szulejko, et al., 1992
Wilkinson, F.E.; Szulejko, J.E.; Allison, C.E.; Mcmahon, T.B., Fourier Transform Ion Cyclotron Resonance Investigation of the Deuterium Isotope Effect on Gas Phase Ion/Molecule Hydrogen Bonding Interactions in Alcohol-Fluoride Adduct Ions, Int. J. Mass Spectrom., 1992, 117, 487-505, https://doi.org/10.1016/0168-1176(92)80110-M . [all data]

Yamdagni, Payzant, et al., 1973
Yamdagni, R.; Payzant, J.D.; Kebarle, P., Solvation of Cl- and O2- with H2O, CH3OH, and CH3CN in the gas phase, Can. J. Chem., 1973, 51, 2507. [all data]

Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S., Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH, Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4 . [all data]

Serda, Izquierdo, et al., 1995
Serda, J.A.; Izquierdo, J.F.; Tejero, J.; Cunill, F.; Iborra, M., Equilibrium and thermodynamics for 2-methyl-2-methoxybutane liquid-phase decomposition, Thermochim. Acta, 1995, 259, 111-120. [all data]

Hwang and Wu, 1994
Hwang, W.-S.; Wu, J.-C., Kinetics and thermodynamics of synthesis of tertiary-amyl methyl ether catalyzed by ion-exchange resin, J. Chin. Chem. Soc. (Taipei), 1994, 41, 181-186. [all data]

Rihko, Linnekoski, et al., 1994
Rihko, L.K.; Linnekoski, J.A.; Krause, A.O., Reaction equilibria in the synthesis of 2-methoxy-2-methylbutane and 2-ethyoxy-2-methylbutane in the liquid phase, J. Chem. Eng. Data, 1994, 39, 700-704. [all data]

Hiraoka, Grimsrud, et al., 1974
Hiraoka, K.; Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Hydrogen Ion in Water - Dimethyl Ether and Methanol - Dimethyl Ether Mixtures, J. Am. Chem. Soc., 1974, 96, 11, 3359, https://doi.org/10.1021/ja00818a004 . [all data]

Bryndza, Fong, et al., 1987
Bryndza, H.E.; Fong, L.K.; Paciello, R.A.; Tam, W.; Bercaw, J.E., J. Am. Chem. Soc., 1987, 109, 1444. [all data]

Sieck, 1985
Sieck, L.W., Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure., J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049 . [all data]

Meot-Ner and Sieck, 1986
Meot-Ner, M.; Sieck, L.W., The ionic hydrogen bond and ion solvation. 5. OH...O- bonds. Gas phase solvation and clustering of alkoxide and carboxylate anions, J. Am. Chem. Soc., 1986, 108, 7525. [all data]


Notes

Go To: Top, Reaction thermochemistry data, References