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«alpha»-D-Glucose

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
DH - E.S. Domalski and E.D. Hearing

Quantity Value Units Method Reference Comment
Deltacsolid-2805.0 ± 1.3kJ/molCcbPonomarev and Migarskaya, 1960Reanalyzed by Cox and Pilcher, 1970, Original value = -2806.2 ± 1.3 kJ/mol; Corresponding «DELTA»fsolid = -1271.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar209.19J/mol*KN/ABoerio-Goates, 1991DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
219.19298.15Boerio-Goates, 1991T = 7 to 347 K.; DH
221.300.Finegold, Franks, et al., 1989T(glass) = 312 K.; DH
219.79298.15Lian, Chen, et al., 1982DH
224.303.Kawaizumi, Kushida, et al., 1981T = 300 to 315 K.; DH
218.8298.15Douglas, Ball, et al., 1951T = 273 to 368 K.; DH
218.0298.Nelson and Newton, 1941T = 0 to 60°C. Equation only.; DH
220.9298.Parks and Thomas, 1934T = 273 to 318 K. Curve given also for undercooled liquid.; DH
211.3298.1Parks, Kelley, et al., 1929Extrapolation below 90 K, 55.23 J/mol*K.; DH
229.3300.Simon, 1922T = 20 to 287 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ponomarev and Migarskaya, 1960
Ponomarev, V.V.; Migarskaya, L.B., Heats of combustion of some amino-acids, Russ. J. Phys. Chem. (Engl. Transl.), 1960, 34, 1182-1183. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Boerio-Goates, 1991
Boerio-Goates, J., Heat-capacity measurements and thermodynamic functions of crystalline a-D-glucose at temperatures from 10K to 340K, J. Chem. Thermodynam., 1991, 23, 403-409. [all data]

Finegold, Franks, et al., 1989
Finegold, L.; Franks, F.; Hatley, R.H.M., Glass/rubber transitions and heat capacities of binary sugar blends, J. Chem. Soc., Faraday Trans., 1989, 1 85(9), 2945-2951. [all data]

Lian, Chen, et al., 1982
Lian, Y.N.; Chen, A.T.; Suurkuusk, J.; Wadsoe, I., Polyol-water interactions as reflected by aqueous heat capacity values, Acta Chem. Scand., 1982, A36(9), 735-739. [all data]

Kawaizumi, Kushida, et al., 1981
Kawaizumi, F.; Kushida, S.; Miyahara, Y., Determination of the specific heat capacities of aqueous solutions of pentose, Bull. Chem. Soc. Japan, 1981, 54(8), 2282-2285. [all data]

Douglas, Ball, et al., 1951
Douglas, T.B.; Ball, A.F.; Torgeson, J.L., Heat capacity of crystalline dextrose between 25 and 95°C, J. Am. Chem. Soc., 1951, 73, 1360-1361. [all data]

Nelson and Newton, 1941
Nelson, E.W.; Newton, R.F., The heat capacity of glucose glass, J. Am. Chem. Soc., 1941, 63, 2178-2182. [all data]

Parks and Thomas, 1934
Parks, G.S.; Thomas, S.B., The heat capacities of crystalline, glassy and undercooled liquid glucose, J. Am. Chem. Soc., 1934, 56, 1423. [all data]

Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

Simon, 1922
Simon, F., Untersuchungen über die spezifische Wärme bei tiefen Temperaturen, Ann. Physik. [4], 1922, 68, 241-280. [all data]


Notes

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