Methyl hypofluorite

• Formula: CH₃FO
• Molecular weight: 50.0323
• IUPAC Standard InChI: InChI=1S/CH3FO/c1-3-2/h1H3 Copy

  
• IUPAC Standard InChIKey: XMSZANIMCDLNKA-UHFFFAOYSA-N Copy
• CAS Registry Number: 36336-08-0
• Chemical structure:
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• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LL - Sharon G. Lias and Joel F. Liebman

Gas basicity at 298K

Ionization energy determinations

Appearance energy determinations

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 322

Notes

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Attina, Cacace, et al., 2001
Attina, M.; Cacace, F.; Cartoni, A.; Rosi, M., Gas-phase electrophilic fluorination of methanol by XeF+. Formation and characterization of protonated methyl hypofluorite and hypoxenite, J. Mass Spectrom., 2001, 36, 392. [all data]

Ruscic, Appelman, et al., 1991
Ruscic, B.; Appelman, E.H.; Berkowitz, J., Photoionization mass spectrometric study of CH₃OF, J. Chem. Phys., 1991, 95, 7957. [all data]

Kol, Rozen, et al., 1991
Kol, M.; Rozen, S.; Appelman, E., Isolation and characterization of methyl hypofluorite (CH3OF), J. Am. Chem. Soc., 1991, 113, 7, 2648, https://doi.org/10.1021/ja00007a043 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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