Dimethylstannylene radical
- Formula: C2H6Sn
- Molecular weight: 148.779
- CAS Registry Number: 23120-99-2
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Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to C2H6Sn+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference |
|---|---|---|
| 7.95 ± 0.05 | EI | Lampe and Niehaus, 1968 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| CH a-stretch | 2990 | w m | Ar | IR | Bleckmann, Maly, et al., 1982 | ||
| CH s-stretch | 2924 | w m | Ar | IR | Bleckmann, Maly, et al., 1982 | ||
| CH3 deform. | 1187 | w | Ar | IR | Bleckmann, Maly, et al., 1982 | ||
| CH3 deform. | 1182 | s | Ar | IR | Bleckmann, Maly, et al., 1982 | ||
| CH3 rock | 774 | s | Ar | IR | Bleckmann, Maly, et al., 1982 | ||
| 745 | s | Ar | IR | Bleckmann, Maly, et al., 1982 | |||
| CH3 rock | 739 | vs | Ar | IR | Bleckmann, Maly, et al., 1982 | ||
| SnC stretch | 518 | s | Ar | IR | Bleckmann, Maly, et al., 1982 | ||
| SnC stretch | 504 | vs | Ar | IR | Bleckmann, Maly, et al., 1982 | ||
Additional references: Jacox, 1994, page 400
Notes
| w | Weak |
| m | Medium |
| s | Strong |
| vs | Very strong |
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lampe and Niehaus, 1968
Lampe, F.W.; Niehaus, A.,
Ionization potentials of free radicals formed by electron impact. Methylstannyl radicals,
J. Chem. Phys., 1968, 49, 2949. [all data]
Bleckmann, Maly, et al., 1982
Bleckmann, P.; Maly, H.; Minkwitz, R.; Neumann, W.P.; Watta, B.; Olbrich, G.,
Matrix Isolation and IR spectroscopy of stannylenes (CH3)2Sn and (CD3)2Sn,
Tetrahed. Lett., 1982, 23, 45, 4655, https://doi.org/10.1016/S0040-4039(00)85679-8
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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