osmium tetraoxide

• Formula: O₄Os
• Molecular weight: 254.23
• IUPAC Standard InChI: InChI=1S/4O.Os/q4*-2;+8 Copy

  
• IUPAC Standard InChIKey: ZEWCIYALLCXNSS-UHFFFAOYSA-N Copy
• CAS Registry Number: 20816-12-0
• Chemical structure:
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• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Green, Kaltsoyannis, et al., 1990
Green, J.C.; Kaltsoyannis, N.; Sze, K.H., An investigation of the electronic structure of osmium tetroxide by photoelectron spectroscopy with variable photon energy, Chem. Phys. Lett., 1990, 175, 359. [all data]

Evans, Hamnett, et al., 1974
Evans, S.; Hamnett, A.; Orchard, A.F., Concerning the ultraviolet photoelectron spectra of osmium and ruthenium tetroxide, J. Am. Chem. Soc., 1974, 96, 6221. [all data]

Foster, Felps, et al., 1973
Foster, S.; Felps, S.; Cusachs, L.C.; McGlynn, S.P., Photoelectron spectra of osmium and ruthenium tetroxides, J. Am. Chem. Soc., 1973, 95, 5521. [all data]

Diemann and Muller, 1973
Diemann, E.; Muller, A., The He(I) photoelectron spectra of OsO₄ and RuO₄, Chem. Phys. Lett., 1973, 19, 538. [all data]

Dillard and Kiser, 1965
Dillard, J.G.; Kiser, R.W., Ionization and dissociation of ruthenium and osmium tetroxides, J. Phys. Chem., 1965, 69, 3893. [all data]

Grimley, Burns, et al., 1960
Grimley, R.T.; Burns, R.P.; Inghram, M.G., Mass spectrometric study of the osmium-oxygen system, J. Chem. Phys., 1960, 33, 308. [all data]

Burroughs, Evans, et al., 1974
Burroughs, P.; Evans, S.; Hamnett, A.; Orchard, A.F.; Richardson, N.V., He-I photoelectron spectra of some d (0) transition metal compounds, J. Chem. Soc. Faraday Trans. 2, 1974, 70, 1895. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  IE (evaluated)	Recommended ionization energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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