(dimethylamino)borane
- Formula: C2H8BN
- Molecular weight: 56.903
- CAS Registry Number: 1838-13-7
- Information on this page:
- Options:
Gas phase ion energetics data
Go To: Top, UV/Visible spectrum, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference |
|---|---|---|
| 9.51 | PE | Bock and Fuss, 1971 |
UV/Visible spectrum
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.
Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
View spectrum image in SVG format.
Download spectrum in JCAMP-DX format.
| Source | Fuss, 1974 |
|---|---|
| Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
| Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
| Source reference | RAS UV No. 14085 |
| Instrument | McPherson 225 |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| BH a-stretch | 2560 | Ar | IR | Carpenter and Ault, 1991 | |||
| BH s-stretch | 2502 | Ar | IR | Carpenter and Ault, 1991 | |||
| 1523 | Ar | IR | Carpenter and Ault, 1991 | ||||
| CH3 deform. | 1420 | Ar | IR | Carpenter and Ault, 1991 | |||
| B=N stretch | 1224 | Ar | IR | Carpenter and Ault, 1991 | |||
| BH2 deform. | 1104 | Ar | IR | Carpenter and Ault, 1991 | |||
| CN stretch | 1052 | Ar | IR | Carpenter and Ault, 1991 | |||
| CN stretch | 984 | Ar | IR | Carpenter and Ault, 1991 | |||
Additional references: Jacox, 1994, page 399
References
Go To: Top, Gas phase ion energetics data, UV/Visible spectrum, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bock and Fuss, 1971
Bock, H.; Fuss, W.,
Ionisierungsenergien und geometrie von aminoboranen,
Chem. Ber., 1971, 104, 1687. [all data]
Fuss, 1974
Fuss, W.,
Z. Naturforsch., 1974, 29b, 514. [all data]
Carpenter and Ault, 1991
Carpenter, J.D.; Ault, B.S.,
Infrared matrix isolation characterization of aminoborane and related compounds,
J. Phys. Chem., 1991, 95, 9, 3502, https://doi.org/10.1021/j100162a013
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Notes
Go To: Top, Gas phase ion energetics data, UV/Visible spectrum, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.