Monofluoroamine

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

IE (eV) Method Reference Comment
10.83PEBaumgartel, Jochims, et al., 1989 
11.62PEBaumgartel, Jochims, et al., 1989Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FHN+15.2HPEBaumgartel, Jochims, et al., 1989 
FN+14.85H2PEBaumgartel, Jochims, et al., 1989 

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NH2 s-stretch 3269 H Ar IR Andrews and Lascola, 1987
1 NH2 s-stretch 3234 N2 IR Baumgartel, Jochims, et al., 1989
2 NH2 scissors 1568 H Ar IR Andrews and Lascola, 1987
2 NH2 scissors 1564 N2 IR Baumgartel, Jochims, et al., 1989
3 NH2 wag 1244 H Ar IR Andrews and Lascola, 1987
3 NH2 wag 1241 N2 IR Baumgartel, Jochims, et al., 1989
3 NH2 wag 1233 N2 IR Baumgartel, Jochims, et al., 1989
4 NF stretch 934 H Ar IR Andrews and Lascola, 1987
4 NF stretch 891 N2 IR Baumgartel, Jochims, et al., 1989
a 5 NH2 a-stretch 3346 N2 IR Baumgartel, Jochims, et al., 1989

Additional references: Jacox, 1994, page 153; Christen, Minkwitz, et al., 1987

Notes

H(1/2)(2ν)

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baumgartel, Jochims, et al., 1989
Baumgartel, H.; Jochims, H.-W.; Ruhl, E.; Bock, H.; Dammel, R.; Minkwitz, J.; Nass, R., Photoelectron and photoionization mass spectra of the fluoramines NH3-nFn1, Inorg. Chem., 1989, 28, 943. [all data]

Andrews and Lascola, 1987
Andrews, L.; Lascola, R., Infrared spectra of the ammonia-fluorine and fluoramide-hydrogen fluoride complexes in solid argon, J. Am. Chem. Soc., 1987, 109, 21, 6243, https://doi.org/10.1021/ja00255a004 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Christen, Minkwitz, et al., 1987
Christen, D.; Minkwitz, R.; Nass, R., Microwave spectrum, inversion, and molecular structure of monofluoramine, FNH2, J. Am. Chem. Soc., 1987, 109, 23, 7020, https://doi.org/10.1021/ja00257a019 . [all data]


Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References