Nitrogen oxide anion


Gas phase thermochemistry data

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar236.60J/mol*KReviewChase, 1998Data last reviewed in June, 1972

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

Nitrogen oxide anion + Hydrogen cation = Nitrous acid

By formula: NO2- + H+ = HNO2

Quantity Value Units Method Reference Comment
Δr1423.5 ± 0.88kJ/molD-EAErvin, Ho, et al., 1988gas phase
Quantity Value Units Method Reference Comment
Δr1396.3 ± 1.3kJ/molH-TSErvin, Ho, et al., 1988gas phase

Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Td = 18340 ± 40 gas Woo, Helmy, et al., 1981
Ervin, Ho, et al., 1988

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 NO stretch 1284 ± 30 gas PE Ervin, Ho, et al., 1988
1 NO stretch 1268.1 T Ne IR Forney, Thompson, et al., 1993
2 Bend 776 ± 30 gas PE Ervin, Ho, et al., 1988
b2 3 NO stretch 1241.5 Ne IR Jacox and Thompson, 1990
Forney, Thompson, et al., 1993
3 NO stretch 1244 Ar IR Milligan, Jacox, et al., 1970
Milligan and Jacox, 1971

Additional references: Jacox, 1994, page 102

Notes

TTentative assignment or approximate value
dPhotodissociation threshold

References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Ervin, Ho, et al., 1988
Ervin, K.M.; Ho, J.; Lineberger, W.C., Ultraviolet Photoelectron Spectrum of NO2-, J. Phys. Chem., 1988, 92, 19, 5405, https://doi.org/10.1021/j100330a017 . [all data]

Woo, Helmy, et al., 1981
Woo, S.B.; Helmy, E.M.; Mauk, P.H.; Paszek, A.P., Wide Range Absolute Photodetachment Spectrum of NO2-, Phys. Rev. A, 1981, 24, 3, 1380, https://doi.org/10.1103/PhysRevA.24.1380 . [all data]

Forney, Thompson, et al., 1993
Forney, D.; Thompson, W.E.; Jacox, M.E., The vibrational spectra of molecular ions isolated in solid neon. XI. NO+2, NO-2, and NO-3, J. Chem. Phys., 1993, 99, 10, 7393, https://doi.org/10.1063/1.465720 . [all data]

Jacox and Thompson, 1990
Jacox, M.E.; Thompson, W.E., The vibrational spectra of molecular ions isolated in solid neon. IV. NO+, NO-, ONNO+, and ONNO-, J. Chem. Phys., 1990, 93, 11, 7609, https://doi.org/10.1063/1.459392 . [all data]

Milligan, Jacox, et al., 1970
Milligan, D.E.; Jacox, M.E.; Guillory, W.A., Infrared Spectrum of the NO2- Ion Isolated in an Argon Matrix, J. Chem. Phys., 1970, 52, 8, 3864, https://doi.org/10.1063/1.1673584 . [all data]

Milligan and Jacox, 1971
Milligan, D.E.; Jacox, M.E., Matrix-Isolation Study of the Interaction of Electrons and Alkali Metal Atoms with Various Nitrogen Oxides. Infrared Spectra of the Species NO-, NO[sub 2]-], and N[sub 2]O[sub 2]-], J. Chem. Phys., 1971, 55, 7, 3404, https://doi.org/10.1063/1.1676592 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References