Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Nitrogen oxide anion


Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Nitrogen oxide anion + Water = (Nitrogen oxide anion bullet Water)

By formula: NO2- + H2O = (NO2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar65. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KPHPMSSieck, 1985gas phase; M
Deltar83.7J/mol*KFABohringer, Fahey, et al., 1984gas phase; switching reaction(NO2-)H2O; Lee, Keesee, et al., 1980; M
Deltar99.6J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Deltar88.J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar35.6 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Deltar35.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar34. ± 24.kJ/molEndoPaulson and Dale, 1982gas phase; B
Deltar33.9 ± 0.84kJ/molTDAsLee, Keesee, et al., 1980gas phase; B
Deltar33.5kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
33.296.FAFehsenfeld and Ferguson, 1974gas phase; M
35.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(Nitrogen oxide anion bullet Water) + Water = (Nitrogen oxide anion bullet 2Water)

By formula: (NO2- bullet H2O) + H2O = (NO2- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Deltar54.0 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Deltar54.0 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar56.9kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Deltar99.2J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar25.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar24. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar24.3kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar26. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
25.296.FAFehsenfeld and Ferguson, 1974gas phase; M
24.300.SAMSPayzant, Cunningham, et al., 1972gas phase; M

(Nitrogen oxide anion bullet 2Water) + Water = (Nitrogen oxide anion bullet 3Water)

By formula: (NO2- bullet 2H2O) + H2O = (NO2- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar48.1 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Deltar43.5 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Deltar43.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar49.0kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M
Deltar88.7J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar17. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar17.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar19. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

Nitrogen oxide anion + Sulfur dioxide = (Nitrogen oxide anion bullet Sulfur dioxide)

By formula: NO2- + O2S = (NO2- bullet O2S)

Quantity Value Units Method Reference Comment
Deltar108.4 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Deltar102. ± 4.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO2-, Keesee, Lee, et al., 1980; B,M
Quantity Value Units Method Reference Comment
Deltar154.J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Deltar132.J/mol*KN/ABohringer, Fahey, et al., 1984gas phase; switching reaction(NO2-)H2O, Entropy change calculated or estimated; Lee, Keesee, et al., 1980; M
Quantity Value Units Method Reference Comment
Deltar62.3 ± 1.3kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

Nitrogen oxide anion + Carbon dioxide = (Nitrogen oxide anion bullet Carbon dioxide)

By formula: NO2- + CO2 = (NO2- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar30.5 ± 0.84kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Deltar38.9 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar72.0J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Deltar101.J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.8 ± 8.4kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B
Deltar8.37 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

Nitrogen oxide anion + Dimethyl Sulfoxide = (Nitrogen oxide anion bullet Dimethyl Sulfoxide)

By formula: NO2- + C2H6OS = (NO2- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar80.3 ± 4.2kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/ASieck, 1985gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsSieck, 1985gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
36.420.PHPMSSieck, 1985gas phase; Entropy change calculated or estimated; M

(Nitrogen oxide anion bullet Sulfur dioxide) + Sulfur dioxide = (Nitrogen oxide anion bullet 2Sulfur dioxide)

By formula: (NO2- bullet O2S) + O2S = (NO2- bullet 2O2S)

Quantity Value Units Method Reference Comment
Deltar37.7 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Deltar41.kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.0J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; M
Deltar70.3J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.7kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

Nitrogen oxide anion + Methane, nitro- = (Nitrogen oxide anion bullet Methane, nitro-)

By formula: NO2- + CH3NO2 = (NO2- bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar60.7 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Deltar59.83 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar64.9J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.6kJ/molTDAsWincel, 2003gas phase; B
Deltar40.6 ± 0.84kJ/molTDAsSieck, 1985gas phase; B

(Nitrogen oxide anion bullet 4294967295Nitrogen dioxide) + Nitrogen dioxide = Nitrogen oxide anion

By formula: (NO2- bullet 4294967295NO2) + NO2 = NO2-

Quantity Value Units Method Reference Comment
Deltar449.0 ± 1.3kJ/molN/ADavidson, Fehsenfeld, et al., 1977gas phase; Relative to HBr, reevaluated with current HBr acidity. Excited state at 3.0 eV,81WU /TIE.; B
Deltar<192.9kJ/molPDisSmith, Lee, et al., 1979gas phase; Isomer: O4- + NO ->.; B
Deltar276. ± 21.kJ/molPDisSmith, Lee, et al., 1978gas phase; B

(Nitrogen oxide anion bullet 2Sulfur dioxide) + Sulfur dioxide = (Nitrogen oxide anion bullet 3Sulfur dioxide)

By formula: (NO2- bullet 2O2S) + O2S = (NO2- bullet 3O2S)

Quantity Value Units Method Reference Comment
Deltar27.6 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar56.1J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar10.9 ± 3.3kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

Nitrogen oxide anion + Hydrogen peroxide = (Nitrogen oxide anion bullet Hydrogen peroxide)

By formula: NO2- + H2O2 = (NO2- bullet H2O2)

Quantity Value Units Method Reference Comment
Deltar84.5 ± 4.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO2-, Keesee, Lee, et al., 1980; B
Quantity Value Units Method Reference Comment
Deltar59.8 ± 4.2kJ/molTDEqBohringer, Fahey, et al., 1984gas phase; Relative to HOH..NO2-, Keesee, Lee, et al., 1980; B

(Nitrogen oxide anion bullet 2Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 3Carbon dioxide)

By formula: (NO2- bullet 2CO2) + CO2 = (NO2- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar26. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.5J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-3. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet 3Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 4Carbon dioxide)

By formula: (NO2- bullet 3CO2) + CO2 = (NO2- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar25. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-7.1 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet 4Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 5Carbon dioxide)

By formula: (NO2- bullet 4CO2) + CO2 = (NO2- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar22. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.5J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-7.5 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet 5Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 6Carbon dioxide)

By formula: (NO2- bullet 5CO2) + CO2 = (NO2- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar21. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-8.4 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet 6Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 7Carbon dioxide)

By formula: (NO2- bullet 6CO2) + CO2 = (NO2- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar18. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-8.8 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet 7Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 8Carbon dioxide)

By formula: (NO2- bullet 7CO2) + CO2 = (NO2- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar18. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-9.6 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 2Carbon dioxide)

By formula: (NO2- bullet CO2) + CO2 = (NO2- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar28. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.2 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

Nitrogen oxide anion + Nitric acid, ethyl ester = (Nitrogen oxide anion bullet Nitric acid, ethyl ester)

By formula: NO2- + C2H5NO3 = (NO2- bullet C2H5NO3)

Quantity Value Units Method Reference Comment
Deltar87.4kJ/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; switching reaction(NO2-)SO2; Keesee, Lee, et al., 1980; M
Quantity Value Units Method Reference Comment
Deltar148.J/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; switching reaction(NO2-)SO2; Keesee, Lee, et al., 1980; M

Nitrogen oxide anion + Benzonitrile, 3,5-dinitro- = (Nitrogen oxide anion bullet Benzonitrile, 3,5-dinitro-)

By formula: NO2- + C7H3N3O4 = (NO2- bullet C7H3N3O4)

Quantity Value Units Method Reference Comment
Deltar98.3 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar99.2J/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar68.6 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzonitrile, 3-nitro- = (Nitrogen oxide anion bullet Benzonitrile, 3-nitro-)

By formula: NO2- + C7H4N2O2 = (NO2- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar83.7 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar58.6 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzonitrile, 4-nitro- = (Nitrogen oxide anion bullet Benzonitrile, 4-nitro-)

By formula: NO2- + C7H4N2O2 = (NO2- bullet C7H4N2O2)

Quantity Value Units Method Reference Comment
Deltar78.7 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.0J/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar51.9 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzene, 1-fluoro-4-nitro- = (Nitrogen oxide anion bullet Benzene, 1-fluoro-4-nitro-)

By formula: NO2- + C6H4FNO2 = (NO2- bullet C6H4FNO2)

Quantity Value Units Method Reference Comment
Deltar62.8 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar38. ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzene, 1,3-dinitro- = (Nitrogen oxide anion bullet Benzene, 1,3-dinitro-)

By formula: NO2- + C6H4N2O4 = (NO2- bullet C6H4N2O4)

Quantity Value Units Method Reference Comment
Deltar88.7 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar60.2 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Benzene, nitro- = (Nitrogen oxide anion bullet Benzene, nitro-)

By formula: NO2- + C6H5NO2 = (NO2- bullet C6H5NO2)

Quantity Value Units Method Reference Comment
Deltar59.4 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar73.2J/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar37. ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + 2-Propanol, 2-methyl- = (Nitrogen oxide anion bullet 2-Propanol, 2-methyl-)

By formula: NO2- + C4H10O = (NO2- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar82.01 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar45.2 ± 1.3kJ/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Methyl Alcohol = (Nitrogen oxide anion bullet Methyl Alcohol)

By formula: NO2- + CH4O = (NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar72.80 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar40.6 ± 1.7kJ/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Acetone = (Nitrogen oxide anion bullet Acetone)

By formula: NO2- + C3H6O = (NO2- bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar66.53 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar34.3 ± 0.84kJ/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Acetonitrile = (Nitrogen oxide anion bullet Acetonitrile)

By formula: NO2- + C2H3N = (NO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar56.07 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar64.0J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar36.8 ± 0.84kJ/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + dihydrogen selenide = (Nitrogen oxide anion bullet dihydrogen selenide)

By formula: NO2- + H2Se = (NO2- bullet H2Se)

Quantity Value Units Method Reference Comment
Deltar87.4 ± 4.2kJ/molTDEqWlodek, Luczynski, et al., 1983, 2gas phase; Equilibration with SO2..NO2-; B
Quantity Value Units Method Reference Comment
Deltar43. ± 15.kJ/molTDEqWlodek, Luczynski, et al., 1983, 2gas phase; Equilibration with SO2..NO2-; B

(Nitrogen oxide anion bullet Sulfur dioxide) + Nitric acid, ethyl ester = (Nitrogen oxide anion bullet Nitric acid, ethyl ester bullet Sulfur dioxide)

By formula: (NO2- bullet O2S) + C2H5NO3 = (NO2- bullet C2H5NO3 bullet O2S)

Quantity Value Units Method Reference Comment
Deltar31.kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar43.5J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

(Nitrogen oxide anion bullet 2Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (Nitrogen oxide anion bullet 3Nitric acid, ethyl ester)

By formula: (NO2- bullet 2C2H5NO3) + C2H5NO3 = (NO2- bullet 3C2H5NO3)

Quantity Value Units Method Reference Comment
Deltar31.kJ/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar59.0J/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M

(Nitrogen oxide anion bullet Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (Nitrogen oxide anion bullet 2Nitric acid, ethyl ester)

By formula: (NO2- bullet C2H5NO3) + C2H5NO3 = (NO2- bullet 2C2H5NO3)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar53.6J/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M

(Nitrogen oxide anion bullet 2dihydrogen selenide) + dihydrogen selenide = (Nitrogen oxide anion bullet 3dihydrogen selenide)

By formula: (NO2- bullet 2H2Se) + H2Se = (NO2- bullet 3H2Se)

Quantity Value Units Method Reference Comment
Deltar30.5 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

(Nitrogen oxide anion bullet dihydrogen selenide) + dihydrogen selenide = (Nitrogen oxide anion bullet 2dihydrogen selenide)

By formula: (NO2- bullet H2Se) + H2Se = (NO2- bullet 2H2Se)

Quantity Value Units Method Reference Comment
Deltar35.6 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B
Quantity Value Units Method Reference Comment
Deltar19.7 ± 1.3kJ/molTDAsWlodek, Luczynski, et al., 1983, 2gas phase; B

(Nitrogen oxide anion bullet 3Water) + Water = (Nitrogen oxide anion bullet 4Water)

By formula: (NO2- bullet 3H2O) + H2O = (NO2- bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar48.5kJ/molHPMSLee, Keesee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar121.J/mol*KHPMSLee, Keesee, et al., 1980gas phase; M

Nitrogen oxide anion + Benzene, 1-methoxy-4-nitro- = (Nitrogen oxide anion bullet Benzene, 1-methoxy-4-nitro-)

By formula: NO2- + C7H7NO3 = (NO2- bullet C7H7NO3)

Quantity Value Units Method Reference Comment
Deltar85.8 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar52.7 ± 8.4kJ/molTDAsGrimsrud, Chowdhury, et al., 1986gas phase; B

Nitrogen oxide anion + Hydrogen cation = Nitrous acid

By formula: NO2- + H+ = HNO2

Quantity Value Units Method Reference Comment
Deltar1423.5 ± 0.88kJ/molD-EAErvin, Ho, et al., 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar1396.3 ± 1.3kJ/molH-TSErvin, Ho, et al., 1988gas phase; B

Nitrogen oxide anion + Ethane, nitro- = C2H5N2O4-

By formula: NO2- + C2H5NO2 = C2H5N2O4-

Quantity Value Units Method Reference Comment
Deltar66.1 ± 2.1kJ/molTDAsWincel, 2004gas phase; B
Quantity Value Units Method Reference Comment
Deltar37.2kJ/molTDAsWincel, 2004gas phase; B

Nitrogen oxide anion + Benzene, 1-methoxy-3-nitro- = (Nitrogen oxide anion bullet Benzene, 1-methoxy-3-nitro-)

By formula: NO2- + C7H7NO3 = (NO2- bullet C7H7NO3)

Quantity Value Units Method Reference Comment
Deltar85.8kJ/molPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSGrimsrud, Chowdhury, et al., 1986gas phase; M

Nitrogen oxide anion + Nitrous acid = (Nitrogen oxide anion bullet Nitrous acid)

By formula: NO2- + HNO2 = (NO2- bullet HNO2)

Quantity Value Units Method Reference Comment
Deltar136. ± 4.2kJ/molTDAsLee, Keesee, et al., 1980gas phase; B

Nitrogen oxide anion + Butanoic acid = C4H8NO4-

By formula: NO2- + C4H8O2 = C4H8NO4-

Quantity Value Units Method Reference Comment
Deltar55.65 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

Nitrogen oxide anion + Propanoic acid = C3H6NO4-

By formula: NO2- + C3H6O2 = C3H6NO4-

Quantity Value Units Method Reference Comment
Deltar52.30 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

Nitrogen oxide anion + Acetic acid = C2H4NO4-

By formula: NO2- + C2H4O2 = C2H4NO4-

Quantity Value Units Method Reference Comment
Deltar51.04 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 1998gas phase; B

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sieck, 1985
Sieck, L.W., Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure., J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049 . [all data]

Bohringer, Fahey, et al., 1984
Bohringer, H.; Fahey, D.W.; Fehsenfeld, F.C.; Ferguson, E.E., Bond energies of the molecules H2O, SO2, H2O2, and HCl to various atmospheric negative ions, J. Chem. Phys., 1984, 81, 2805. [all data]

Lee, Keesee, et al., 1980
Lee, N.; Keesee, R.G.; Castleman, A.W., Jr., The properties of clusters in the gas phase. IV. Complexes of H2O and HNOx clustering on NOx-, J. Chem. Phys., 1980, 72, 1089. [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]

Paulson and Dale, 1982
Paulson, J.F.; Dale, J., Reactions of OH-.H2O with NO2, J. Chem. Phys., 1982, 77, 4006. [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]

Payzant, Cunningham, et al., 1972
Payzant, J.D.; Cunningham, A.J.; Kebarle, P., Kinetics and Rate Constants of Reactions Leading to Hydration of NO2- and NO3- in Gaseous Oxygen, Argon, and Helium Containing Traces of Water, Can. J. Chem., 1972, 50, 14, 2230, https://doi.org/10.1139/v72-358 . [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]

Kebarle, Arshadi, et al., 1968
Kebarle, P.; Arshadi, M.; Scarborough, J., Hydration of Negative Ions in the Gas Phase, J. Chem. Phys., 1968, 49, 2, 817, https://doi.org/10.1063/1.1670145 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Wlodek, Luczynski, et al., 1983
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas phase complexes of NO2- and NO3- with SO2, Int. J. Mass Spectrom. Ion Processes, 1983, 49, 301. [all data]

Wincel, 2003
Wincel, H., Gas-phase Solvation of Cl-, NO2-, CH2NO2-, CH3NO2-, and CH3NO4- by CH3NO2, Int. J. Mass Spectrom., 2003, 226, 3, 341-353, https://doi.org/10.1016/S1387-3806(03)00066-6 . [all data]

Davidson, Fehsenfeld, et al., 1977
Davidson, J.A.; Fehsenfeld, F.C.; Howard, C.J., The heats of formation of NO3- and NO3- association complexes with HNO3 and HBr, Int. J. Chem. Kinet., 1977, 9, 17. [all data]

Smith, Lee, et al., 1979
Smith, G.P.; Lee, L.C.; Moseley, J.T., Photodissociation and photodetachment of molecular negative ions. VIII. Nitrogen oxides and hydrates,3500-8250 Å, J. Chem. Phys., 1979, 71, 4034. [all data]

Smith, Lee, et al., 1978
Smith, G.P.; Lee, L.C.; Cosby, P.C.; Peterson, J.R.; Moseley, J.T., Photodissociation and photodetachment of molecular negative ions. V. Atmospheric ions from 7000 to 8400 A), J. Chem. Phys., 1978, 68, 3818. [all data]

Wlodek, Luczynski, et al., 1983, 2
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas - Phase Solvation of NO2- and NO3- by Ethyl Nitrate, Int. J. Mass Spectrom. Ion Phys., 1983, 52, 2-3, 149, https://doi.org/10.1016/0020-7381(83)85036-0 . [all data]

Grimsrud, Chowdhury, et al., 1986
Grimsrud, E.P.; Chowdhury, S.; Kebarle, P., Gas Phase Reactions of NO2- with Nitrobenzenes and Quinones. Electron Transfer, Clusters, and Formation of Phenoxide and Quinoxide Negative Ions. Use of NO2 as a NICI Reagent Gas., Int. J. Mass Spectrom. Ion Proc., 1986, 68, 1-2, 57, https://doi.org/10.1016/0168-1176(86)87068-9 . [all data]

Ervin, Ho, et al., 1988
Ervin, K.M.; Ho, J.; Lineberger, W.C., Ultraviolet Photoelectron Spectrum of NO2-, J. Phys. Chem., 1988, 92, 19, 5405, https://doi.org/10.1021/j100330a017 . [all data]

Wincel, 2004
Wincel, H., Gas-phase clustering reactions of NO2-, C2H3NO2-, C2H4NO2-C2H5NO2- and C2H5NO4- with C2H5NO2, Int. J. Mass Spectrom., 2004, 232, 2, 185-194, https://doi.org/10.1016/j.ijms.2004.01.003 . [all data]

Viidanoja, Reiner, et al., 2000
Viidanoja, J.; Reiner, T.; Kiendler, A.; Grimm, F.; Arnold, F., Laboratory investigations of negative ion molecule reactions of propionic, butyric, glyoxylic, pyruvic, and pinonic acids, Int. J. Mass Spectrom., 2000, 194, 1, 53-68, https://doi.org/10.1016/S1387-3806(99)00172-4 . [all data]

Viidanoja, Reiner, et al., 1998
Viidanoja, J.; Reiner, T.; Arnold, F., Laboratory Investigations of Negative Ion-Molecule Reactions of Formic and Acetic Acid., Int. J. Mass Spectrom., 1998, 181, 1-3, 31, https://doi.org/10.1016/S1387-3806(98)14151-9 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References