Ethyl Acetate

• Formula: C₄H₈O₂
• Molecular weight: 88.1051
• IUPAC Standard InChI: InChI=1S/C4H8O2/c1-3-6-4(2)5/h3H2,1-2H3 Copy

  
• IUPAC Standard InChIKey: XEKOWRVHYACXOJ-UHFFFAOYSA-N Copy
• CAS Registry Number: 141-78-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Acetic acid, ethyl ester; Acetic ether; Acetidin; Acetoxyethane; Ethyl acetic ester; Ethyl ethanoate; Vinegar naphtha; CH3COOC2H5; Aethylacetat; Essigester; Ethyle (acetate d'); Etile (acetato di); Ethylacetaat; Ethylester kyseliny octove; Rcra waste number U112; UN 1173; Ethyl ester of acetic acid; 1-Acetoxyethane; NSC 70930; ac. acetic ethyl ester
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• Information on this page:
  • Normal boiling point
  • References
  • Notes
• Other data available:
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  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
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  • Gas Chromatography
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Normal boiling point

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein

References

Go To: Top, Normal boiling point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blanco and Ortega, 1998
Blanco, A.M.; Ortega, J., Densities and Vapor-Liquid Equilibrium Values for Binary Mixtures Composed of Methanol + an Ethyl Ester 1t 141.3 kPa with Application of an Extended Correlation Equation for Isobaric VLE Data, J. Chem. Eng. Data, 1998, 43, 638-645. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Kato, 1988
Kato, M., Vapor-Liquid Equilibrium Mewasurements for Binary Systems of Acetic Acid with Ethyl Acetate and Vinyl Acetate by the Dew-Bubble Point Temperature Method, J. Chem. Eng. Data, 1988, 33, 499. [all data]

Manjeshwar and Aminabhavi, 1988
Manjeshwar, L.S.; Aminabhavi, T.M., Densities and Viscosities of Binary Liquid Mixtures Containing Bromoform at 45 deg C, J. Chem. Eng. Data, 1988, 33, 184-5. [all data]

Aminabhavi, Manjeshwar, et al., 1987
Aminabhavi, T.M.; Manjeshwar, L.S.; Balundgi, R.H., Viscosities of Binary Liquid Mixtures, J. Chem. Eng. Data, 1987, 32, 50-2. [all data]

Manjeshwar and Aminabhavi, 1987
Manjeshwar, L.S.; Aminabhavi, T.M., Densities and Viscosities of Binary Liquid Mixtures at 45 deg. C, J. Chem. Eng. Data, 1987, 32, 409-12. [all data]

Ortega, Pena, et al., 1986
Ortega, J.; Pena, J.A.; de Alfonso, C., Isobaric Vapor-Liquid Equilibria of Ethyl Acetate + Ethanol Mixtures at 760 +- 0.5mmHg, J. Chem. Eng. Data, 1986, 31, 339. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Aminabhavi, Patel, et al., 1982
Aminabhavi, T.M.; Patel, R.C.; Bridger, K.; Jayadevappa, E.S.; Prasad, B.R., Viscosity studies of some binary liquid systems., J. Chem. Eng. Data, 1982, 27, 125-8. [all data]

Ohta and Nagata, 1980
Ohta, T.; Nagata, I., Thermodynamic properties of four ester + hydrocarbon mixtures, J. Chem. Eng. Data, 1980, 25, 283-6. [all data]

Gil'burd, Yurkevich, et al., 1979
Gil'burd, M.M.; Yurkevich, B.P.; Politanskaya, T.I., Liquid-vapor phase equilibria in ethyl acetate + acetone and ethyl acetate + allyl alcohol systems., Zh. Prikl. Khim. (Leningrad), 1979, 52, 2372-74. [all data]

Thorat, Nageshwar, et al., 1979
Thorat, R.T.; Nageshwar, G.D.; Mene, P.S., Excess thermodynamic properties of the ternary system ethyl acetate + ethanol + 2-ethoxyethanol, J. Chem. Eng. Data, 1979, 24, 270-2. [all data]

Svoboda, Vesely, et al., 1977
Svoboda, V.; Vesely, F.; Holub, R.; Pick, J., Heats of vaporization of alkyl acetates and propionates, Collect. Czech. Chem. Commun., 1977, 42, 943-51. [all data]

Kato, Konishi, et al., 1970
Kato, M.; Konishi, H.; Hirata, M., New apparatus for isobaric dew and bubble point method methanol + water, ethyl acetate + ethanol, water + 1-butanol, and ethyl acetate + water systems, J. Chem. Eng. Data, 1970, 15, 435-9. [all data]

Ogata and Aoki, 1969
Ogata, Y.; Aoki, K., Reaction of Alkyl Iodides with Peracetic Acid in the Presence of Aromatic Compounds, J. Org. Chem., 1969, 34, 3974. [all data]

Nakanishi, Nakasato, et al., 1967
Nakanishi, K.; Nakasato, K.; Toba, R.; Shirai, H., Vapor-Liquid Equilibria of Binary Systems Containing Alcohols. Methanol-Ethyl Acetate and Methanol-Isopropyl Ether, J. Chem. Eng. Data, 1967, 12, 440-2. [all data]

Polak and Mertl, 1965
Polak, J.; Mertl, I., Saturated vapor pressure of methyl acetate, ethyl acetate, n-propyl acetate, methyl propionate and ethyl propionate, Collect. Czech. Chem. Commun., 1965, 30, 3526-8. [all data]

Agarwal and Mene, 1963
Agarwal, M.M.; Mene, P.S., Studies in Binary Vapor-Liquid Equilibria, Indian Chem. Eng., 1963, 5, 71. [all data]

Akita and Yoshida, 1963
Akita, K.; Yoshida, F., Phase-Equilibria in Methanol-Ethyl Acetate-Water System, J. Chem. Eng. Data, 1963, 8, 484. [all data]

Scheer, Koogman, et al., 1963
Scheer, J.C.; Koogman, E.C.; Sixma, F.L.J., Gas Phase Pyrolysis of Alkyl Acetates, Recl. Trav. Chim. Pays-Bas, 1963, 82, 1123. [all data]

Carr and Kropholler, 1962
Carr, A.D.; Kropholler, H.W., Vapor Liquid Equilibria at Atmospheric Pressure. Binary Systems of Ethyl Acetate-Benzene, Ethyl Acetate-Toluene, and Ethyl Acetate-p-Xyle, J. Chem. Eng. Data, 1962, 7, 26. [all data]

Fish and Waris, 1962
Fish; Waris, J. Chem. Soc., 1962, 1962, 4513. [all data]

Nagata, 1962
Nagata, I., Isobaric Vapor-Liquid Equilibria for the Ternary System Chloroform- Methanol-Ethyl Acetate, J. Chem. Eng. Data, 1962, 7, 367-73. [all data]

Ratnam, Rao, et al., 1962
Ratnam, A.V.; Rao, C.V.; Murti, P.S., Thermodynamic Proerties of Liquid Mixtures - Heats of Mixing at 35 deg C, Chem. Eng. Sci., 1962, 17, 392. [all data]

Miller, 1958
Miller, K.J., Boiling Point-Composition Diagrams for the Systems 2-Ethoxyethanol- Ethyl Acetate and 2-Ethoxyethanol-Propyl Acetate, Chem. Eng. Data Ser., 1958, 3, 239-40. [all data]

Murti and Van Winkle, 1958
Murti, P.S.; Van Winkle, M., Vapor-Liquid Equilibria for Binary Systems of Methanol, Ethyl Alcohol, 1-Propanol, and 2-Propanol with Ethyl Acetate and 1-Propanol-Water, Chem. Eng. Data Ser., 1958, 3, 72-81. [all data]

Hoffmann and Weiss, 1957
Hoffmann, F.W.; Weiss, J.M., J. Am. Chem. Soc., 1957, 79, 4759. [all data]

Emmons and Lucas, 1955
Emmons, W.D.; Lucas, G.B., Peroxytrifluoroacetic acid: V the oxidation of ketones to esters, J. Am. Chem. Soc., 1955, 77, 2287. [all data]

Pochinok and Shevchenko, 1954
Pochinok, V.Ya.; Shevchenko, O.I., Ukr. Khim. Zh. (Russ. Ed.), 1954, 20, 289. [all data]

Garner and Ellis, 1953
Garner, F.H.; Ellis, S.R.M., Extraction of acetic acid from water: II ethyl acetate + acetic acid + water, Chem. Eng. Sci., 1953, 2, 282. [all data]

McGeer, Curtis, et al., 1952
McGeer, P.L.; Curtis, A.J.; Rathmann, G.B.; Smyth, C.P., Microwave Absorption and Molecular Structure in Liquids VIII. Dielectric Relaxation in Some Long Chain Esters, J. Am. Chem. Soc., 1952, 74, 3541-5. [all data]

Mumford and Phillips, 1950
Mumford, S.A.; Phillips, J.W.C., 19. The Physical Properties of Some Aliphatic Compounds, J. Chem. Soc., 1950, 1950, 75-84. [all data]

Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A., Physical Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 2875-8. [all data]

Patschky and Liermeier, 1949
Patschky, A.; Liermeier, F., Z. Anal. Chem., 1949, 129, 62. [all data]

Vvedenskii, Ivannikov, et al., 1949
Vvedenskii, A.A.; Ivannikov, P.Ya.; Nekrasova, V.A., Thermodynamics of the Dehydration Reactions of Alcohols. The Equilibrium of the Reaction 2C2H5OH = CH3COOC2H5, Zh. Obshch. Khim., 1949, 19, 1094. [all data]

French, 1947
French, C.M., Trans. Faraday Soc., 1947, 43, 356. [all data]

Lecat, 1947
Lecat, M., Orthobaric Azeotropes of Sulfides, Bull. Cl. Sci., Acad. R. Belg., 1947, 33, 160-82. [all data]

Bennewitz and Rossner, 1938
Bennewitz, K.; Rossner, W., The molar heat of organic vapors, Z. Phys. Chem., Abt. B, 1938, 39, 126. [all data]

Whitmore, 1938
Whitmore, F.C., The Reducing Action of Grignard Reagents on Acyl Chlorides, Recl. Trav. Chim. Pays-Bas, 1938, 57, 562. [all data]

Wojciechowski and Smith, 1937
Wojciechowski, M.; Smith, E.R., Boiling Points and Densities of Acetates of Normal Aliphatic Alcohols, J. Res. Natl. Bur. Stand. (U. S.), 1937, 18, 499. [all data]

Butler and Ramchandani, 1935
Butler, J.A.V.; Ramchandani, C.N., The Solubility of Non-electrolytes. Part II. The Influence of the Polar Group on the Free Energy of Hydration of Aliphatic Compounds., J. Chem. Soc., 1935, 1935, 952. [all data]

Gill and Dexter, 1934
Gill, A.H.; Dexter, F.P., Ind. Eng. Chem., 1934, 26, 881. [all data]

Timmermans and Hennaut-Roland, 1930
Timmermans, J.; Hennaut-Roland, M., The Work of the International Bureau of Physical-Chemical Standards IV Study of the Physical Constants of Twenty Organic Compounds, J. Chim. Phys. Phys.-Chim. Biol., 1930, 27, 401-38. [all data]

Hofmann and Reid, 1929
Hofmann, H.E.; Reid, E.W., Ind. Eng. Chem., 1929, 21, 955. [all data]

Krchma and Williams, 1927
Krchma, I.J.; Williams, J.W., J. Am. Chem. Soc., 1927, 49, 2408. [all data]

Lecat, 1927
Lecat, M., New binary azeotropes: 7th list, Ann. Soc. Sci. Bruxelles, Ser. B, 1927, 47, 108-14. [all data]

Chadwell, 1926
Chadwell, H.M., The Viscosities of Several Aqueous Solutions of Organic Substances and the Polymerization of Water, J. Am. Chem. Soc., 1926, 48, 1912. [all data]

Lecat, 1926
Lecat, M., New binary azeotropes second list, Recl. Trav. Chim. Pays-Bas, 1926, 45, 620-627. [all data]

Mathews, 1926
Mathews, J.H., The Accurate Measurement of Heats of Vaporization of Liquids, J. Am. Chem. Soc., 1926, 48, 562. [all data]

Munch, 1926
Munch, J.C., The Refractometric Determination of Alcohols and Esters in Aqueous and in Cottonseed Oil Solutions, J. Am. Chem. Soc., 1926, 48, 994-1003. [all data]

Grimm and Patrick, 1923
Grimm, F.V.; Patrick, W.A., The Dielectric Constastants of Organic Liquids at the Boilin Point, J. Am. Chem. Soc., 1923, 45, 2794. [all data]

Timmermans, Van der Horst, et al., 1923
Timmermans, J.; Van der Horst, H.; Onnes, H.K., Freezing points of pure organic liquids as thermometric reference points at low temperatures, Arch. Neerl. Sci. Exactes Nat., Ser. 3A, 1923, 6, 180. [all data]

Willard and Smith, 1923
Willard, H.H.; Smith, G.F., The Perchalorates of the Alkali and A;kaline Earth Metals and Ammonium. Their Solubility in Water and Other Solvents, J. Am. Chem. Soc., 1923, 45, 286. [all data]

Baudrenghien, 1922
Baudrenghien, Bull. Soc. Chim. Belg., 1922, 31, 160. [all data]

Kendall and Brakeley, 1921
Kendall, J.; Brakeley, E., Compound Formation and Viscosity in Solutions of the Types Acid-ester, Acid-ketone, and Acid-acid, J. Am. Chem. Soc., 1921, 43, 1826-34. [all data]

Kendall and Wright, 1920
Kendall, J.; Wright, A.H., The Viscosity of Liquids. IV. Ideal Mixtures of the Types Ether-Ether and Ester-Ester, J. Am. Chem. Soc., 1920, 42, 1776-9. [all data]

Jaeger, 1917
Jaeger, F.M., Z. Anorg. Allg. Chem., 1917, 101, 130. [all data]

Rosanoff, Bacon, et al., 1914
Rosanoff, M.A.; Bacon, C.W.; White, R.H., A Rapid Laboratory Method of Measuring the Partial Vapor Pressures of Liquid Mixtures, J. Am. Chem. Soc., 1914, 36, 1803-25. [all data]

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Timmermans, J., Experimental Research on the Density of Liquids Below 0 Degrees., Sci. Proc. R. Dublin Soc., 1912, 13, 310. [all data]

Timmermans, 1911
Timmermans, J., Researches on the freezing point of organic liquid compounds, Bull. Soc. Chim. Belg., 1911, 25, 300. [all data]

Timmermans, 1910
Timmermans, J., The Purification and Physical Constants of Several Organic Liquids, Bull. Soc. Chim. Belg., 1910, 24, 244. [all data]

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Young, S.; Thomas, G.L., The vapour pressures, molecular volumes, and critical constants of ten of the lower esters, J. Chem. Soc., 1893, 63, 1191. [all data]

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Perkin, W.H., On the Magnetic Rotary Polarisation of Compounds in Relation to their Chemical Consitution; with Observations on the Preparation and Relative Densities of the Bodies Examined, J. Chem. Soc., 1884, 45, 421-580. [all data]

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Kopp, H., Specific volumes of liquid compounds, Justus Liebigs Ann. Chem., 1854, 92, 1-32. [all data]

Kopp, 1848
Kopp, H., Justus Liebigs Ann. Chem., 1848, 64, 212. [all data]

Notes

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• Symbols used in this document:
  

  Tboil

  Boiling point

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