yttrium trifluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
YF+21.5 ± 0.7?EIKent, Zmbov, et al., 1966 
YF2+14.0FEIZmbov and Margrave, 1967 
YF2+13.5 ± 0.7FEIKent, Zmbov, et al., 1966 
Y+28.0 ± 0.7?EIKent, Zmbov, et al., 1966 

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

Fluorine anion + F3Y = (Fluorine anion • F3Y)

By formula: F- + F3Y = (F- • F3Y)

Quantity Value Units Method Reference Comment
Δr477. ± 21.kJ/molTDEqPyatenko, Gusarov, et al., 1981gas phase; F-A at 0 K; ΔHf at 298 K. Equilibrium measured vs. AlF4-; value altered from reference due to conversion from electron convention to ion convention

F4Y- + F3Y = F7Y2-

By formula: F4Y- + F3Y = F7Y2-

Quantity Value Units Method Reference Comment
Δr234. ± 21.kJ/molTDAsPyatenko, Gusarov, et al., 1981gas phase; ΔHf at 298K, fluoride affinity at 0K; value altered from reference due to conversion from electron convention to ion convention

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

e' 3 Asym. stretch 561.0 Ar IR Wang and Andrews, 2010


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kent, Zmbov, et al., 1966
Kent, R.A.; Zmbov, K.F.; Kana'an, A.S.; Besenbruch, G.; McDonald, J.D.; Margrave, J.L., Mass spectrometric studies at high temperatures. X. The sublimation pressures of scandium(III), yttrium(III) and lanthanum(III), trifluorides, J. Inorg. Nucl. Chem., 1966, 28, 1419. [all data]

Zmbov and Margrave, 1967
Zmbov, K.F.; Margrave, J.L., Mass spectrometry at high temperatures. XVIII.The stabilities of the mono- and difluorides of scandium and yttrium, J. Chem. Phys., 1967, 47, 3122. [all data]

Pyatenko, Gusarov, et al., 1981
Pyatenko, A.T.; Gusarov, A.V.; Gorokhov, L.N., Negative Ions in Vapor over Yttrium Trifluoride, High Temp., 1981, 19, 1167. [all data]

Wang and Andrews, 2010
Wang, X.; Andrews, L., Infrared Spectra of MF, J. Phys. Chem. A, 2010, 114, 6, 2293, https://doi.org/10.1021/jp910936d . [all data]


Notes

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