Aluminum difluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to AlF2+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
2.25 ± 0.13TDEqSrivastava, Uy, et al., 1974EA: 26.5 kcal < EA(F), new EA(F) data used; B

Ionization energy determinations

IE (eV) Method Reference Comment
10.EIUy, Srivastava, et al., 1972LLK
9. ± 1.EIEhlert and Margrave, 1964RDSH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 Sym. stretch 755.3 Ar IR Hassanzadeh, Citra, et al., 1996
Davlyatshin and Osin, 1997
2 Bend 253.7 Ar IR Davlyatshin and Osin, 1997
b2 3 Asym. stretch 887.5 Ar IR Hassanzadeh, Citra, et al., 1996
Davlyatshin and Osin, 1997

Additional references: Jacox, 1998, page 192; Jacox, 2003, page 134


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Srivastava, Uy, et al., 1974
Srivastava, R.D.; Uy, O.M.; Farber, M., Experimental determination of heats of formation of negative ions and electron affinities of several boron and aluminum fluorides, J. Chem. Soc. Faraday Trans. 1, 1974, 70, 1033. [all data]

Uy, Srivastava, et al., 1972
Uy, O.M.; Srivastava, R.D.; Farber, M., Mass spectrometric determination of the heats of formation of the gaseous molecules AlOF2 and AlF2, High Temp. Sci., 1972, 4, 227. [all data]

Ehlert and Margrave, 1964
Ehlert, T.C.; Margrave, J.L., The heat of atomization of aluminum difluoride, J. Am. Chem. Soc., 1964, 86, 3901. [all data]

Hassanzadeh, Citra, et al., 1996
Hassanzadeh, P.; Citra, A.; Andrews, L.; Neurock, M., Laser-Evaporated Aluminum Atom Reactions with Halogen Molecules. Infrared Spectra of AlX, J. Phys. Chem., 1996, 100, 18, 7317, https://doi.org/10.1021/jp953065a . [all data]

Davlyatshin and Osin, 1997
Davlyatshin, D.I.; Osin, S.B., Vestn. Mosk. Univ., 1997, Ser. 2: Khim. 38, 306. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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