Digallium monoxide

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference
8.0 ± 0.5EIShchukarev, Semenov, et al., 1969
7.4 ± 0.5EIUy, Muenow, et al., 1968
8.4 ± 0.6EIBurns, 1966
12.1 ± 0.5EIShchukarev, Semenov, et al., 1962

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
GaO+13.1 ± 0.5GaEIShchukarev, Semenov, et al., 1962 
Ga2+16. ± 0.5OEIShchukarev, Semenov, et al., 1969 

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 36939 ± 15 Ar C-X 265 271 Douglas, Hauge, et al., 1983
To = 36226 ± 15 Kr C-X 270 276 Douglas, Hauge, et al., 1983
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1 GaO s-stretch 527 Ar AB Douglas, Hauge, et al., 1983
2 Bend 182 Ar AB Douglas, Hauge, et al., 1983
2 Bend 218 Kr AB Douglas, Hauge, et al., 1983

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 28328 ± 15 Kr B-X 353 403 Douglas, Hauge, et al., 1983

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 20600 ± 15 Kr Douglas, Hauge, et al., 1983

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σu+ 3 Asym. stretch 822.3 Ar IR Makowiecki, Lynch, et al., 1971
Hinchcliffe and Ogden, 1973
Zehe, Lynch, et al., 1979
Burkholder, Yustein, et al., 1992
3 Asym. stretch 809.4 N2 IR Hinchcliffe and Ogden, 1969
Makowiecki, Lynch, et al., 1971
Hinchcliffe and Ogden, 1971
Zehe, Lynch, et al., 1979

Additional references: Jacox, 1994, page 64; Jacox, 2003, page 80

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shchukarev, Semenov, et al., 1969
Shchukarev, S.A.; Semenov, G.A.; Rat'kovskii, I.A., A thermal investigation of the evaporation of gallium and indium oxides, Zh. Neorgan. Khim. 14,, 1969, 1. [all data]

Uy, Muenow, et al., 1968
Uy, O.M.; Muenow, D.W.; Ficalora, P.J.; Margrave, J.L., Mass spectrometric studies at high temperatures. Part 30. Vaporization of Ga2S3, Ga2Se3 and Ga2Te3, and stabilities of the gaseous gallium chalcogenides, J. Chem. Soc. Faraday Trans., 1968, 64, 2998. [all data]

Burns, 1966
Burns, R.P., Systematics of the evaporation coefficient Al2O3, Ga2O3, In2O3, J. Chem. Phys., 1966, 44, 3307. [all data]

Shchukarev, Semenov, et al., 1962
Shchukarev, S.A.; Semenov, G.A.; Rat'kovskii, I.A., Study of the evaporation of gallium, indium, and thallium with the aid of the mass spectrometer, Zh. Prikl. Khim., 1962, 35, 1454, In original 1401. [all data]

Douglas, Hauge, et al., 1983
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., High Temp. Sci., 1983, 16, 35. [all data]

Makowiecki, Lynch, et al., 1971
Makowiecki, D.M.; Lynch, D.A.; Carlson, K.D., Infrared spectra of the aluminum family suboxides, J. Phys. Chem., 1971, 75, 1963. [all data]

Hinchcliffe and Ogden, 1973
Hinchcliffe, A.J.; Ogden, J.S., Matrix isolation studies on the gallium-indium-oxygen system. Infrared spectra and structures of molecular gallium(I) oxide, indium(I) oxide and indium gallium suboxide (InOGa), J. Phys. Chem., 1973, 77, 21, 2537, https://doi.org/10.1021/j100907a010 . [all data]

Zehe, Lynch, et al., 1979
Zehe, M.J.; Lynch, D.A., Jr.; Kelsall, B.J.; Carlson, K.D., Matrix reactions of molecular oxygen with indium and gallium atoms, J. Phys. Chem., 1979, 83, 6, 656, https://doi.org/10.1021/j100469a004 . [all data]

Burkholder, Yustein, et al., 1992
Burkholder, T.R.; Yustein, J.T.; Andrews, L., Reactions of pulsed laser evaporated gallium and indium atoms with molecular oxygen: matrix infrared spectra of new gallium dioxide and indium dioxide species, J. Phys. Chem., 1992, 96, 25, 10189, https://doi.org/10.1021/j100204a019 . [all data]

Hinchcliffe and Ogden, 1969
Hinchcliffe, A.J.; Ogden, J.S., Chem. Commun., 1969, 1053. [all data]

Hinchcliffe and Ogden, 1971
Hinchcliffe, A.J.; Ogden, J.S., Vibrational analysis for the molecules gallium oxide, indium oxide, and thallium oxide. Comment, J. Phys. Chem., 1971, 75, 25, 3908, https://doi.org/10.1021/j100694a030 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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