Boron trifluoride etherate
- Formula: C4H10BF3O
- Molecular weight: 141.928
- IUPAC Standard InChIKey: MZTVMRUDEFSYGQ-UHFFFAOYSA-N
- CAS Registry Number: 109-63-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Boron trifluoride diethyl etherate; Boron trifluoride-ethyl ether complex; Boron trifluoride diethyl etherate complex; Boron trifluoride ethyl etherate; Boron trifluoride diethyl ether complex; Boron fluoride-ethyl ether complex; Boron, trifluoro[1,1'-oxybis[ethane]]-, (T-4)-; Ethyl ether, compd. with boron fluoride (BF3) (1:1); Borane, trifluoro-, compd. with 1,1'-oxybis(ethane) (1:1); Boron fluoride diethyl etherate; Boron fluoride etherate; Boron fluoride-ethyl etherate; Boron fluoride monoetherate; Boron trifluoride-ether complex; Boron trifluoride-ethyl ether; Trifluoroborane diethyl etherate; Trifluoroboron etherate; UN 2604; Boron fluoride diethyl ether complex; Boron trifluoride ethyl etherate (1:1); Diethyl ether trifluoroborane complex; Ethyl ether, cmpd with boron fluoride (BF3) (1:1); Trifluoroborane-1,1'-oxybis(ethane) (1:1); diethyl ether--boron trifluoride
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Phase change data
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Robert L. Brown and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 399. to 400. | K | N/A | PCR Inc., 1990 | |
Tboil | 397. | K | N/A | American Tokyo Kasei, 1988 |
Gas phase ion energetics data
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
BF3+ | 15.00 ± 0.10 | (C2H5)2O | EI | Murphy and Enrione, 1971 |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-2816 |
NIST MS number | 231623 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
American Tokyo Kasei, 1988
American Tokyo Kasei,
TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]
Murphy and Enrione, 1971
Murphy, C.B., Jr.; Enrione, R.E.,
Mass spectrometric determination of bond dissociation energies in BF3.OEt2,
Chem. Commun., 1971, 1622. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References
- Symbols used in this document:
AE Appearance energy Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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