Aniline, N-methyl-
- Formula: C7H9N
- Molecular weight: 107.1531
- IUPAC Standard InChI: InChI=1S/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H3
- IUPAC Standard InChIKey: AFBPFSWMIHJQDM-UHFFFAOYSA-N
- CAS Registry Number: 100-61-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: (Methylamino)benzene; Benzenamine, N-methyl-; Anilinomethane; Methylphenylamine; N-Methylaniline; N-Methylbenzenamine; N-Methylphenylamine; N-Monomethylaniline; N-Phenylmethylamine; N-Methylaminobenzene; Monomethylaniline; Methylaniline; Benzeneamine, N-methyl-; UN 2294; NSC 3502
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Normal boiling point
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
| Tboil (K) | Reference | Comment |
|---|---|---|
| 469.4 | Weast and Grasselli, 1989 | BS |
| 467.15 | Costello and Bowden, 1959 | Uncertainty assigned by TRC = 0.4 K; TRC |
| 469.4 | Lecat, 1946 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 469.4 | Lecat, 1943 | Uncertainty assigned by TRC = 0.25 K; TRC |
| 469.4 | Timmermans and Hennaut-Roland, 1935 | Uncertainty assigned by TRC = 0.3 K; TRC |
| 467.9 | Mathews and Fehlandt, 1931 | Uncertainty assigned by TRC = 0.6 K; TRC |
| 469.25 | Lecat, 1930 | Uncertainty assigned by TRC = 0.3 K; not clear that this is a new measurement; TRC |
| 467.05 | Herz and Neukirch, 1923 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 469.25 | Timmermans, 1914 | Uncertainty assigned by TRC = 0.2 K; not clear that this is a new measurement; TRC |
| 464.9 | Falk, 1909 | Uncertainty assigned by TRC = 1. K; TRC |
| 468.9 | Richards and Mathews, 1908 | Uncertainty assigned by TRC = 1. K; TRC |
| 468.65 | Perkin, 1896 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 465.15 | Hoffmann, 1850 | Uncertainty assigned by TRC = 5. K; TRC |
References
Go To: Top, Normal boiling point, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Costello and Bowden, 1959
Costello, J.M.; Bowden, S.T.,
The Temperature Variation of Orthobaric Density Difference in Liquid-Vapour Systems. V. Amines,
Recl. Trav. Chim. Pays-Bas, 1959, 78, 391. [all data]
Lecat, 1946
Lecat, M.,
Azeotropes of Amines,
Ann. Soc. Sci. Bruxelles, Ser. 1, 1946, 60, 169. [all data]
Lecat, 1943
Lecat, M.,
Azeotropes of Ethyl Urethane and other Azeotropes,
C. R. Hebd. Seances Acad. Sci., 1943, 217, 273. [all data]
Timmermans and Hennaut-Roland, 1935
Timmermans, J.; Hennaut-Roland, M.,
Physical constants of 20 organic compounds. VII. Supplement,
J. Chim. Phys. Phys.-Chim. Biol., 1935, 32, 589. [all data]
Mathews and Fehlandt, 1931
Mathews, J.H.; Fehlandt, P.R.,
The Heats of Vaporization of Some Organic Compounds,
J. Am. Chem. Soc., 1931, 53, 3212. [all data]
Lecat, 1930
Lecat, M.,
Azeotropism in Binary Mixtures Containing an Alcohol Mixed with an amine, a nitro derivative, an ether or water.,
Z. Anorg. Allg. Chem., 1930, 186, 119. [all data]
Herz and Neukirch, 1923
Herz, W.; Neukirch, E.,
On Knowldge of the Critical State,
Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1923, 104, 433-50. [all data]
Timmermans, 1914
Timmermans, J.,
Freezing temperature of organic compounds. II.,
Bull. Soc. Chim. Belg., 1914, 27, 334. [all data]
Falk, 1909
Falk, K.G.,
The Change in Refractive Index with Temperature II.,
J. Am. Chem. Soc., 1909, 31, 806-20. [all data]
Richards and Mathews, 1908
Richards, T.W.; Mathews, J.H.,
The Relation Between Compressibility, Surface Tension, and Other Properties of Material,
J. Am. Chem. Soc., 1908, 30, 8-13. [all data]
Perkin, 1896
Perkin, W.H.,
LXIX. On Magnetic Rotatory Power, especially of Aromatic Compounds,
J. Chem. Soc., 1896, 69, 1025-1257. [all data]
Hoffmann, 1850
Hoffmann, A.W.,
Researches Regarding Molecular Constitution of the Volatile Org. Bases,
J. Chem. Soc., 1850, 3, 279. [all data]
Notes
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- Symbols used in this document:
Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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