1,4-Androstadien-3,17-dione, di-trimethylsilyl
- Formula: C25H40O2Si2
- Molecular weight: 428.7549
- IUPAC Standard InChI: InChI=1S/C25H40O2Si2/c1-24-15-13-19(26-28(3,4)5)17-18(24)9-10-20-21-11-12-23(27-29(6,7)8)25(21,2)16-14-22(20)24/h9,12-13,15,17,20-22H,10-11,14,16H2,1-8H3
- IUPAC Standard InChIKey: FDLXAQMQAOPIDT-UHFFFAOYSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Boldione, di-trimethylsilyl; Androstadienedione, di-trimethylsilyl; Dehydroandtrostenedione, di-trimethylsilyl; Androsta-1,4-diene-3,17-dione, per-TMS; Androsta-1,4-dien-3,17-dione,bis-TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5MS | 2687. | Parr, Zapp, et al., 2007 | 16.5 m/0.25 mm/0.25 μm, He, 20. K/min, 320. C @ 2. min; Tstart: 140. C |
| Capillary | SE-54 | 2668. | Schänzer and Donike, 1992 | 15. m/0.2 mm/0.33 μm, He, 5. K/min; Tstart: 200. C; Tend: 300. C |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Parr, Zapp, et al., 2007
Parr, M.K.; Zapp, J.; Becker, M.; Opfermann, G.; Bartz, U.; Schanzer, W.,
Steroidal isomers with uniform mass spectra of their per-TMS derivatives: Synthesis of 17-hydroxyandrostan-3-ones, androst-1-, and -4-ene-3,17-diols,
Steroids, 2007, 72, 6-7, 545-551, https://doi.org/10.1016/j.steroids.2007.03.006
. [all data]
Schänzer and Donike, 1992
Schänzer, W.; Donike, M.,
Metabolism of boldenone in man: gas chromatographic/mass spectrometric identification of urinary excreted metabolites and determination of excretion rates,
Biol. Mass Spectrom., 1992, 21, 1, 3-16, https://doi.org/10.1002/bms.1200210104
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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