GA108 [D2], Me-TMS
- Formula: C23H32O5Si
- Molecular weight: 416.5827
- IUPAC Standard InChI: InChI=1S/C23H32O5Si/c1-12-13-10-14(28-29(4,5)6)23-16(12)21(23,11-13)15(18(24)26-3)17-20(2)8-7-9-22(17,23)27-19(20)25/h13-17H,1,7-11H2,2-6H3/t13?,14-,15+,16?,17+,20+,21+,22-,23-/m0/s1
- IUPAC Standard InChIKey: HMLNHQYKESBMFJ-NQQLTTLESA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: 11β-hydroxy-9,15-cyclo-GA9 (GA108), MeTMS; GA108, Me-TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2407. | Oyama, Yamauchi, et al., 1996 | 160. C @ 2. min, 16. K/min; Column length: 15. m; Column diameter: 0.258 mm; Tend: 280. C |
| Capillary | DB-1 | 2408. | Oyama, Yamauchi, et al., 1996 | 160. C @ 2. min, 16. K/min; Column length: 15. m; Column diameter: 0.258 mm; Tend: 280. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 2412. | Yamauchi, Oyama, et al., 1997 | Helium; Column length: 15. m; Column diameter: 0.258 mm; Program: 120 0C (2 min) 6 0C/min -> 216 0C (5 min) 8 0C/min -> 280 0C |
| Capillary | DB-1 | 2413. | Yamauchi, Oyama, et al., 1997 | Helium; Column length: 15. m; Column diameter: 0.258 mm; Program: 120 0C (2 min) 6 0C/min -> 216 0C (5 min) 8 0C/min -> 280 0C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Oyama, Yamauchi, et al., 1996
Oyama, N.; Yamauchi, T.; Yamane, H.; Murofushi, N.; Agatsuma, M.; Pour, M.; Mander, L.N.,
Identification of gibberellins and 9,15-cyclogibberellins in developing apple seeds,
Biosci. Biotechnol. Biochem., 1996, 60, 2, 305-308, https://doi.org/10.1271/bbb.60.305
. [all data]
Yamauchi, Oyama, et al., 1997
Yamauchi, T.; Oyama, N.; Yamane, H.; Mirofushi, N.; Schraudoff, H.; Pour, M.; Seto, H.; Mander, L.N.,
Biosynthesis of GA73 Methyl Ester in Lygodium Ferns,
Plant Physiol., 1997, 113, 773-778. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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